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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Quality Oled CAS 613-32-1 Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 5,10-DIHYDRO-PHENAZINE Synonyms: AURORA KA-4601;5,10-DIHYDRO-PHENAZINE;Phenazine,5,10-dihydro- CAS: 613-32-1 MF: C12H10N2 MW: 182.22 Mol File: 613-32-1.mol Appearance:white powder Storage:room tempu

613-32-1 5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 613-32-1 with competitive price

Cas:613-32-1

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

5,10-DIHYDRO-PHENAZINE CAS:613-32-1 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

5,10-DIHYDRO-PHENAZINE CAS:613-32-1

Cas:613-32-1

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

5,10-Dihydrophenazine

Cas:613-32-1

Min.Order:1 Gram

FOB Price: $1348.0

Type:Trading Company

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Shaanxi Cuicheng Biomedical Technology Co., Ltd.

Why Choose Us: 1. Factory direct sales, so we can provide the competitive price and high quality product base on 8 years of production and R&D experience. 2. It is available in stock for quick shipment.Products could be packaged according to cu

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:1 Gram

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

We Huarong Pharm can provide Customized Synthesis & Process R&D & APIs and intermediates Production & Quality Research & Registration Application, especially our GMP validation service which complies with SFDA, FDA, WHO and EU EMPA. O

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

5,10-Dihydrophenazine cas no. 613-32-1 98%

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec 5,10-Dihydrophenazine 250mg

Cas:613-32-1

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other Value-added customer services, for diversified range products of chemicals

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Phenazine,5,10-dihydro-

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU TIANYE CHEMICALS CO., LTD.

"HANGZHOU TIANYE CHEMICALS Co.LTD , Located in Eastern Science and Innovation Park Hangzhou .We are a high-tech enterprise specialized in technical research and development, production, development and trade of chemical products. We supply Multiple s

5,10-dihydrophenazine

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

DB BIOTECH CO., LTD

best seller Application:API

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Phenazine,5,10-dihydro- cas 613-32-1Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Phenazine,5,10-dihydro- cas 613-32-1

Cas:613-32-1

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. located in Lingang industrial areas, our plant covers an area of 6000 square meters.ZeErRui dedicated to the development, production and marketing of chemicals. We have earned ourselves a good reputation at home an

5,10-dihydrophenazine manufacture

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

laboratory Application:Synthetic building block

Phenazine, 5,10-dihydro-

Cas:613-32-1

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

5,10-Dihydrophenazine 613-32-1

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemlyte Solutions

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

5,10-dihydrophenazine

Cas:613-32-1

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

613-32-1

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Muhuang Technology Co., Ltd

best seller Application:API

5,10-DIHYDRO-PHENAZINE

Cas:613-32-1

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

Phenazin
92-82-0

Phenazin

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With sodium dithionite; water In ethanol for 2.5h; Ambient temperature;98%
With sodium dithionite In ethanol; water at 20℃; for 4h; Inert atmosphere;98%
With sodium dithionite In ethanol; water at 85℃; for 0.5h; Inert atmosphere;97.5%
2-iodophenylamine
615-43-0

2-iodophenylamine

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With 18-crown-6 ether; copper; caesium carbonate In 1,2-dichloro-benzene for 24h; Reflux;72.1%
With copper(l) iodide; 2,2'-biimidazole; caesium carbonate In N,N-dimethyl-formamide at 120℃; for 24h; Ullmann reaction; Inert atmosphere;63%
2-bromoaniline
615-36-1

2-bromoaniline

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); acetophenone p-toluenesulfonylhydrazone; lithium tert-butoxide In 1,4-dioxane at 100℃; for 6h; Inert atmosphere;70%
Phenazin
92-82-0

Phenazin

A

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

B

1,2,3,4,6,7,8,9-octahydrophenazine
4006-50-2

1,2,3,4,6,7,8,9-octahydrophenazine

Conditions
ConditionsYield
With Cp*Rh(2-(2-pyridyl)phenyl)H; hydrogen In tetrahydrofuran at 80℃; under 3040.2 Torr; for 48h; Catalytic behavior; Glovebox;A 19%
B 54%
4‑methoxy‑N’‑(1‑phenylethylidene)benzenesulfonohydrazide

4‑methoxy‑N’‑(1‑phenylethylidene)benzenesulfonohydrazide

2-bromoaniline
615-36-1

2-bromoaniline

A

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

B

2-(1-phenylvinyl)aniline
64097-92-3

2-(1-phenylvinyl)aniline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butoxide; XPhos In 1,4-dioxane at 110℃; Inert atmosphere;A 30%
B 35%
4‑ntro‑N’‑(1‑phenylethylidene)benzenesulfonohydrazide

4‑ntro‑N’‑(1‑phenylethylidene)benzenesulfonohydrazide

2-bromoaniline
615-36-1

2-bromoaniline

A

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

B

2-(1-phenylvinyl)aniline
64097-92-3

2-(1-phenylvinyl)aniline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butoxide; XPhos In 1,4-dioxane at 110℃; Inert atmosphere;A 35%
B 15%
N'‑(1‑phenylethylidene)benzenesulfonohydrazide
56975-77-0

N'‑(1‑phenylethylidene)benzenesulfonohydrazide

2-bromoaniline
615-36-1

2-bromoaniline

A

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

B

2-(1-phenylvinyl)aniline
64097-92-3

2-(1-phenylvinyl)aniline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butoxide; XPhos In 1,4-dioxane at 110℃; Inert atmosphere;A 11%
B 30%
acetophenone p-toluenesulfonylhydrazone
4545-21-5

acetophenone p-toluenesulfonylhydrazone

2-bromoaniline
615-36-1

2-bromoaniline

A

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

B

2-(1-phenylvinyl)aniline
64097-92-3

2-(1-phenylvinyl)aniline

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); lithium tert-butoxide; XPhos In 1,4-dioxane at 110℃; Inert atmosphere;A 22%
B 28%
bis(2-nitrophenyl)amine
18264-71-6

bis(2-nitrophenyl)amine

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With methanol; sodium
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

A

Phenazin
92-82-0

Phenazin

B

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
at 200 - 210℃; im Rohr;
benzene-1,2-diol
120-80-9

benzene-1,2-diol

1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Phenazin
92-82-0

Phenazin

hydrogen sulfide
7783-06-4

hydrogen sulfide

ammonia
7664-41-7

ammonia

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Phenazin
92-82-0

Phenazin

Na2S2O4

Na2S2O4

aqueous-alcoholic NaOH-solution

aqueous-alcoholic NaOH-solution

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

pyridine
110-86-1

pyridine

Phenazin
92-82-0

Phenazin

platinum

platinum

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
Hydrogenation;
Phenazin-mono-N-Oxyd
304-81-4

Phenazin-mono-N-Oxyd

ethanol
64-17-5

ethanol

sodium amalgam

sodium amalgam

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: K2CO3
2: sodium; methanol
View Scheme
2-nitro-aniline
88-74-4

2-nitro-aniline

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: K2CO3
2: sodium; methanol
View Scheme
1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

N1-(2-bromophenyl)benzene-1,2-diamine

N1-(2-bromophenyl)benzene-1,2-diamine

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; caesium carbonate In toluene at 110℃; Inert atmosphere;
N1-(2-chlorophenyl)benzene-1,2-diamine
74864-94-1

N1-(2-chlorophenyl)benzene-1,2-diamine

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate; caesium carbonate In toluene at 110℃; Inert atmosphere;
1,2-dichloro-benzene
95-50-1

1,2-dichloro-benzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: caesium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate / toluene / 110 °C / Inert atmosphere
2: caesium carbonate; dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; palladium diacetate / toluene / 110 °C / Inert atmosphere
View Scheme
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

1-Bromo-2-iodobenzene
583-55-1

1-Bromo-2-iodobenzene

4-bromo-1,1'-biphenyl
92-66-0

4-bromo-1,1'-biphenyl

5-biphenyl-4-yl-10-(2-bromophenyl)-5,10-dihydro-phenazine

5-biphenyl-4-yl-10-(2-bromophenyl)-5,10-dihydro-phenazine

Conditions
ConditionsYield
Stage #1: 5,10-dihydrophenazine; 4-bromo-1,1'-biphenyl With tris-(dibenzylideneacetone)dipalladium(0); palladium diacetate In toluene for 8h; Reflux;
Stage #2: 1-Bromo-2-iodobenzene In toluene for 8h; Reflux;
97%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

Phenazin
92-82-0

Phenazin

Conditions
ConditionsYield
With oxygen; silver carbonate at 100℃; under 517.162 Torr; for 0.0833333h; Reagent/catalyst; Time;96%
durch Sublimieren;
With ethanol
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

methyl iodide
74-88-4

methyl iodide

fully reduced 5-methylphenazinium
20057-16-3

fully reduced 5-methylphenazinium

Conditions
ConditionsYield
Stage #1: 5,10-dihydrophenazine With potassium tert-butylate In tetrahydrofuran at 20℃; for 1h;
Stage #2: methyl iodide With phosphorus In tetrahydrofuran at 66℃; for 4h;
92%
With n-butyllithium In 1,2-dimethoxyethane; hexane for 0.5h; Ambient temperature; Yield given;
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

2-bromonaphthalene
580-13-2

2-bromonaphthalene

N,N-5,10-di(2-naphthalene)-5,10-dihydrophenazine

N,N-5,10-di(2-naphthalene)-5,10-dihydrophenazine

Conditions
ConditionsYield
With chloro-(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 10h; Sealed tube; Inert atmosphere;90%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

2-bromo-5,10-dihydrophenazine
496269-44-4

2-bromo-5,10-dihydrophenazine

Conditions
ConditionsYield
With N-Bromosuccinimide In N,N-dimethyl-formamide at 0 - 20℃; Inert atmosphere;89.5%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

terephthaloyl chloride
100-20-9

terephthaloyl chloride

Terephthaloyl-5',5''-bis(5,10-dihydrophenazin)
158670-59-8

Terephthaloyl-5',5''-bis(5,10-dihydrophenazin)

Conditions
ConditionsYield
With dmap In tetrahydrofuran; pyridine at 80℃; for 5h;85%
bromobenzene
108-86-1

bromobenzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

5,10-dihydro-5,10-diphenylphenazine
3665-72-3

5,10-dihydro-5,10-diphenylphenazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene at 80℃;85%
With chloro(2-dicyclohexylphosphino-2′,6′-di-i-propoxy-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)-palladium(II); sodium t-butanolate; ruphos In 1,4-dioxane at 100℃; for 10h; Buchwald-Hartwig Coupling; Inert atmosphere;0.75 g
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

1-benzyl-4-bromo-benzene
2116-36-1

1-benzyl-4-bromo-benzene

5,10-bis(4-benzylphenyl)-5,10-dihydrophenazine

5,10-bis(4-benzylphenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene Reflux;85%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

4-methoxycarbonylphenyl bromide
619-42-1

4-methoxycarbonylphenyl bromide

dimethyl 4,4'-(phenazine-5,10-diyl)dibenzoate

dimethyl 4,4'-(phenazine-5,10-diyl)dibenzoate

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; XPhos In o-xylene at 130℃; for 12h;85%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

4-N,N-diphenylamino-1-bromobenzene
36809-26-4

4-N,N-diphenylamino-1-bromobenzene

5,10-di-(p-diphenylaminophenyl)-5,10-dihydrophenazine

5,10-di-(p-diphenylaminophenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In o-xylene at 20℃; for 3h;83%
With chloro-(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 12h; Inert atmosphere;20%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

bis(trichloromethyl) carbonate
32315-10-9

bis(trichloromethyl) carbonate

5,10-dihydrophenazine-5-carbamoyl chloride

5,10-dihydrophenazine-5-carbamoyl chloride

Conditions
ConditionsYield
With triethylamine In dichloromethane at 20℃; Reagent/catalyst; Inert atmosphere;83%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

2-chloro-5-bromonitrobenzene
41513-04-6

2-chloro-5-bromonitrobenzene

5,10-bis(4-chloro-2-nitrophenyl)-5,10-dihydrophenazine

5,10-bis(4-chloro-2-nitrophenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With copper; potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 180℃; for 5h; Inert atmosphere;82%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

para-iodoanisole
696-62-8

para-iodoanisole

5,10-bis(4-methoxyphenyl)-5,10-dihydrophenazine

5,10-bis(4-methoxyphenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique;82%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

6‐chloro‐5‐nitroquinoline
86984-32-9

6‐chloro‐5‐nitroquinoline

C30H18N6O4

C30H18N6O4

Conditions
ConditionsYield
With copper; potassium carbonate In 5,5-dimethyl-1,3-cyclohexadiene at 180℃; for 5h; Inert atmosphere;81%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

chloroformic acid ethyl ester
541-41-3

chloroformic acid ethyl ester

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diethylester

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diethylester

Conditions
ConditionsYield
at 80℃; for 5h;79%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

2-chloroethyl methyl ether
627-42-9

2-chloroethyl methyl ether

5,10-bis(2-methoxyethyl)-5,10-dihydrophenazine

5,10-bis(2-methoxyethyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
Stage #1: 5,10-dihydrophenazine With n-butyllithium In tetrahydrofuran; hexane at 20℃; for 0.5h; Inert atmosphere;
Stage #2: 2-chloroethyl methyl ether In tetrahydrofuran; hexane at 20℃; Inert atmosphere;
78.2%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

1-bromo-4-phenylethynylbenzene
13667-12-4

1-bromo-4-phenylethynylbenzene

5,10-bis(4-(phenylethynyl)phenyl)-5,10-dihydrophenazine

5,10-bis(4-(phenylethynyl)phenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene Reflux;78%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

7-bromo-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene

7-bromo-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene

5,10-di(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracen-7-yl)-5,10-dihydrophenazine

5,10-di(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracen-7-yl)-5,10-dihydrophenazine

Conditions
ConditionsYield
Stage #1: 5,10-dihydrophenazine; 7-bromo-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene With potassium carbonate In toluene for 0.166667h; Buchwald-Hartwig Coupling; Inert atmosphere;
Stage #2: With tri-tert-butyl phosphine; palladium diacetate In toluene Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;
78%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

methyl chloroformate
79-22-1

methyl chloroformate

5,10-Dihydrophenazin-5,10-dicarbonsaeure-dimethylester
85926-31-4

5,10-Dihydrophenazin-5,10-dicarbonsaeure-dimethylester

Conditions
ConditionsYield
at 80℃; for 5h;77%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

benzene-1,3-dicarbonyl dichloride
99-63-8

benzene-1,3-dicarbonyl dichloride

Isophthaloyl-5',5''-bis(5,10-dihydrophenazin)
158670-60-1

Isophthaloyl-5',5''-bis(5,10-dihydrophenazin)

Conditions
ConditionsYield
With dmap In tetrahydrofuran; pyridine at 80℃; for 5h;77%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

7-bromo-2,12-di-tert-butyl-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene

7-bromo-2,12-di-tert-butyl-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene

5,10-bis(2,12-di-tert-butyl-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracen-7-yl)-5,10-dihydrophenazine

5,10-bis(2,12-di-tert-butyl-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracen-7-yl)-5,10-dihydrophenazine

Conditions
ConditionsYield
Stage #1: 5,10-dihydrophenazine; 7-bromo-2,12-di-tert-butyl-5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene With potassium carbonate In toluene for 0.166667h; Buchwald-Hartwig Coupling; Inert atmosphere;
Stage #2: With tri-tert-butyl phosphine; palladium diacetate In toluene for 20h; Buchwald-Hartwig Coupling; Reflux; Inert atmosphere;
75%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

phenyl chloroformate
1885-14-9

phenyl chloroformate

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester
158670-54-3

5,10-Dihydrophenazin-5,10-dicarbonsaeure-diphenylester

Conditions
ConditionsYield
With dmap In pyridine for 3h; Heating;74%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

p-trifluoromethylphenyl bromide
402-43-7

p-trifluoromethylphenyl bromide

5,10-bis(4-(trifluoromethyl)phenyl)-5,10-dihydrophenazine

5,10-bis(4-(trifluoromethyl)phenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique;73%
With chloro(2-dicyclohexylphosphino-2′,6′-di-i-propoxy-1,1′-biphenyl)(2′-amino-1,1′-biphenyl-2-yl)-palladium(II); sodium t-butanolate; ruphos In 1,4-dioxane at 100℃; for 10h; Buchwald-Hartwig Coupling; Inert atmosphere;0.96 g
With chloro-(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 10h; Inert atmosphere; Sealed tube;
1-bromo-4-methoxy-benzene
104-92-7

1-bromo-4-methoxy-benzene

5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

5,10-bis(4-methoxyphenyl)-5,10-dihydrophenazine

5,10-bis(4-methoxyphenyl)-5,10-dihydrophenazine

Conditions
ConditionsYield
With chloro-(2-dicyclohexylphosphino-2’,6’-diisopropoxy-1,1‘-biphenyl)[2-(2-aminoethyl)phenyl] palladium(ll) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 16h; Buchwald-Hartwig Coupling; Schlenk technique; Inert atmosphere;73%
With chloro-(2-dicyclohexylphosphino-2’,6’-diisopropoxy-1,1‘-biphenyl)[2-(2-aminoethyl)phenyl] palladium(ll) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 10h; Inert atmosphere; Sealed tube;46%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

2-bromo-4,6-diphenyl-1,3,5-triazabenzene
80984-79-8

2-bromo-4,6-diphenyl-1,3,5-triazabenzene

5-(3,5-diphenyltriazine 2-yl)-10H-dihydrophenazine

5-(3,5-diphenyltriazine 2-yl)-10H-dihydrophenazine

Conditions
ConditionsYield
With copper; sodium t-butanolate In toluene for 24h; Inert atmosphere; Reflux;71%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

iodobenzene
591-50-4

iodobenzene

5-phenyl-5,10-dihydro-phenazine
49662-17-1

5-phenyl-5,10-dihydro-phenazine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 115℃; for 12h; Inert atmosphere;70.9%
5,10-dihydrophenazine
613-32-1

5,10-dihydrophenazine

iodobenzene
591-50-4

iodobenzene

5,10-dihydro-5,10-diphenylphenazine
3665-72-3

5,10-dihydro-5,10-diphenylphenazine

Conditions
ConditionsYield
With chloro-(2-dicyclohexylphosphino-2′,6′-diisopropoxy-1,1′-biphenyl)[2-(2-aminoethyl)phenyl]palladium(II) methyl-tert-butyl ether adduct; sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 10h; Inert atmosphere; Sealed tube;69%
With sodium t-butanolate; ruphos In 1,4-dioxane at 110℃; for 12h; Buchwald-Hartwig Coupling; Schlenk technique;25%

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