5-VINYL-2-NORBORNENE supplier

Name
Vinylnorbornene
EINECS
CAS No. 3048-64-4
Article Data37
CAS DataBase
Density 1.006g/cm³
Solubility
Melting Point −80 °C(lit.)
Formula C9H12
Boiling Point 141°Cat760mmHg
Molecular Weight 120.194
Flash Point 26.2°C
Transport Information
Appearance clear liquid
Safety Mildly toxic by ingestion, inhalation, and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes.
Risk Codes R10;R20;R36/38;
Molecular Structure
Hazard Symbols Xn
Synonyms 2-Norbornene,5-vinyl- (6CI,7CI,8CI); 2-Vinyl-5-norbornene; 2-Vinylbicyclo[2.2.1]hept-5-ene;2-Vinylnorbornene; 5-Ethenylbicyclo[2.2.1]hept-2-ene; 5-Vinyl-2-norbornene;5-Vinylbicyclo[2.2.1]hept-2-ene; 5-Vinylnorbornene; NSC 61529; V 0062; VBH;Vinylnorbornene
PSA 0.00000
LogP 2.38460

Synthetic route

: 77891-01-1
5-Ethynylbicyclo<2.2.1>-2-heptene

: 3048-64-4
5-vinyl-2-norbornene

Conditions

Conditions	Yield
With zinc/copper couple In diethyl ether; water at 45 - 50℃; for 40h;	95%

: 542-92-7
cyclopenta-1,3-diene

: 106-99-0
buta-1,3-diene

: 3048-64-4
5-vinyl-2-norbornene

Conditions

Conditions	Yield
at 140 - 145℃;

: 77-73-6, 933-60-8, 1755-01-7
bi(cyclopentadiene)

: 106-99-0
buta-1,3-diene

A: 3048-65-5
bicyclo[4.3.0]nona-3,7-diene

B: 3048-64-4
5-vinyl-2-norbornene

Conditions

Conditions	Yield
at -20 - 205℃; for 1h; Temperature; Diels-Alder Cycloaddition; Autoclave; Inert atmosphere;	A 20 %Chromat. B 25 %Chromat.

...Expand

: 542-92-7
cyclopenta-1,3-diene

: 106-99-0
buta-1,3-diene

A: 3048-65-5
bicyclo[4.3.0]nona-3,7-diene

B: 3048-64-4
5-vinyl-2-norbornene

Conditions

Conditions	Yield
In hexane at -20 - 205℃; for 1h; Solvent; Diels-Alder Cycloaddition; Autoclave; Inert atmosphere;	A 25 %Chromat. B 22 %Chromat.
at -20 - 205℃; for 1h; Temperature; Diels-Alder Cycloaddition; Autoclave; Inert atmosphere;	A 17 %Chromat. B 25 %Chromat.
Stage #1: cyclopenta-1,3-diene; buta-1,3-diene With N-ethyl-N-hydroxy-ethanamine In toluene under 26252.6 Torr; Flow reactor; Heating; Stage #2: at 115.4℃; under 195.02 - 240.024 Torr; Flow reactor;
In cyclohexane at 200℃; under 20686.5 Torr; for 0.166667h; Solvent; Inert atmosphere;

...Expand

: 5-(1-methoxyethyl)bicyclo[2.2.1]hept-2-ene

: 3048-64-4
5-vinyl-2-norbornene

Conditions

Conditions	Yield
With magnesium oxide In m-xylene at 200℃; under 760.051 Torr; for 3h;

: 542-92-7
cyclopenta-1,3-diene

: 106-99-0
buta-1,3-diene

A: 3048-65-5
bicyclo[4.3.0]nona-3,7-diene

B: 3048-64-4
5-vinyl-2-norbornene

C: 77-73-6, 933-60-8, 1755-01-7
bi(cyclopentadiene)

Conditions

Conditions	Yield
With evonik TS-1 zeolite catalyst In toluene at 200℃; under 20252 Torr; for 0.166667h; Reagent/catalyst; Diels-Alder Cycloaddition; Inert atmosphere;

...Expand

: 3048-64-4
5-vinyl-2-norbornene

: 76-02-8
Trichloroacetyl chloride

: 5-(2',2'-dichlorocyclobutan-3'-onyl)bicyclo<2.2.1>hept-2-ene

Conditions

Conditions	Yield
With zinc In diethyl ether at 20 - 30℃; sonication;	95%

: 108-86-1
bromobenzene

: 3048-64-4
5-vinyl-2-norbornene

: (E)-5-styrylbicyclo[2.2.1]hept-2-ene

Conditions

Conditions	Yield
Stage #1: bromobenzene With palladium diacetate; heptakis(6-amino-6-deoxy)-β-cyclodextrin In water; N,N-dimethyl-formamide for 0.5h; Stage #2: 5-vinyl-2-norbornene With potassium carbonate In water; N,N-dimethyl-formamide at 80℃; for 10h;	92%

: 2487-90-3
trimethoxysilane

: 3048-64-4
5-vinyl-2-norbornene

: 68323-30-8
(2-bicyclo[2.2.1]hept-5-en-2-yl-ethyl)-trimethoxy-silane

Conditions

Conditions	Yield
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex; ammonium bicarbonate In toluene at 55 - 65℃; for 5h; Reagent/catalyst; Concentration;	91%

: 3048-64-4
5-vinyl-2-norbornene

: exo-2-chloro-6-ethenylbicyclo<2.2.1>heptane

: exo-2-chloro-5-ethenylbicyclo<2.2.1>heptane

Conditions

Conditions	Yield
With thionyl chloride; silica gel In dichloromethane for 0.25h; Title compound not separated from byproducts;	A 88% B n/a
With thionyl chloride; silica gel In dichloromethane for 0.25h; Title compound not separated from byproducts;	A n/a B 88%

: 3048-64-4
5-vinyl-2-norbornene

: 2886-88-6
6-epoxyethyl-3-oxatricyclo<3.2.1.02,4>octane

Conditions

Conditions	Yield
With potassium hydroxide; oxone In dichloromethane; acetone	85%
Stage #1: 5-vinyl-2-norbornene With water; hydrogen bromide; dihydrogen peroxide at 40℃; Stage #2: With potassium hydroxide In diethyl ether at 8 - 20℃; for 2.5h; Reagent/catalyst;	3.5 g

: 3048-64-4
5-vinyl-2-norbornene

: 89913-95-1
C36H48Cl8S4

Conditions

Conditions	Yield
With sulfur dichloride In dichloromethane at -7 - 0℃; for 1h;	78%

: 3048-64-4
5-vinyl-2-norbornene

: 15403-89-1
5-ethylbicyclo[2.2.1]hept-2-ene

Conditions

Conditions	Yield
With hydrogen; (η5-C5Me5)2YCH3(THF) In benzene under 760 Torr; for 2h; Ambient temperature;	72%

: 3144-09-0
methanesulfonamide

: 3048-64-4
5-vinyl-2-norbornene

: 1-(methylsulfonyl)octahydro-3a,6-methanoindole

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid at 85℃; for 14h; Inert atmosphere; Darkness; neat (no solvent);	70%

: 3048-64-4
5-vinyl-2-norbornene

: 70-55-3
toluene-4-sulfonamide

: 1-tosyloctahydro-3a,6-methanoindole

Conditions

Conditions	Yield
With (triphenyl phosphite)gold(I) chloride; silver trifluoromethanesulfonate at 90℃; for 0.5h; Inert atmosphere; Darkness; Microwave irradiation; air stream cooling; neat (no solvent);	70%

: 3048-64-4
5-vinyl-2-norbornene

: 57957-24-1
N-(1-phenylvinyl)acetamide

: C17H18O

Conditions

Conditions	Yield
With copper diacetate; palladium diacetate; triethylamine In dimethyl sulfoxide at 100℃;	70%

: 3048-64-4
5-vinyl-2-norbornene

A: 89913-96-2
5,5'-di(3-chloro-5-vinylbicyclo<2.2.1>heptyl) sulfide

B: 89913-95-1
C36H48Cl8S4

Conditions

Conditions	Yield
With sulfur dichloride In hexane at 5℃; for 36h;	A 51% B n/a

: 3048-64-4
5-vinyl-2-norbornene

: 3048-65-5, 38451-18-2, 66563-20-0, 98102-87-5, 98102-88-6, 117179-82-5
cis bicyclo<4.3.0>nona-3,7-diene

Conditions

Conditions	Yield
at 250℃; for 0.533333h; Pressure (range begins): 200 ;	47%
Product distribution; different temperatures (180 to 250 deg C), different heating times; Pressure (range begins): 200 ;

: 3048-64-4
5-vinyl-2-norbornene

: 2886-88-6
6-epoxyethyl-3-oxatricyclo<3.2.1.02,4>octane

B: 2886-87-5
2,3-epoxy-5-vinylnorbornane

Conditions

Conditions	Yield
With sodium hydroxide; dihydrogen peroxide; N-tosylimidazole In methanol for 3h;	A 11.5% B 29%

: 3048-64-4
5-vinyl-2-norbornene

: 25557-71-5
tetracyclo[4.2.1.0(2,5).0(3,7)]nonane

Conditions

Conditions	Yield
In acetone; benzene Irradiation;

: 3048-64-4
5-vinyl-2-norbornene

: 2146-41-0
2-ethylnorbornane

Conditions

Conditions	Yield
With hydrogen; platinum
With hydrogen In methanol at 20℃; under 760.051 Torr; for 0.833333h; Reagent/catalyst;	> 99 %Chromat.

: 3048-64-4
5-vinyl-2-norbornene

: 28304-67-8
5-ethylidene-2-norbornene

Conditions

Conditions	Yield
With aluminum oxide; sodium In n-heptane at 0℃;
With aluminium(III) triflate; tricarbonylbis(triphenylphosphine)ruthenium(0) In toluene at 60℃; for 5h; Reagent/catalyst;	88.1 %Chromat.

: 3048-64-4
5-vinyl-2-norbornene

: 4994-07-4
1-Vinyltricyclo<2.2.1.O2,6>heptane

Conditions

Conditions	Yield
With aluminum oxide; sodium In n-heptane

: 3048-64-4
5-vinyl-2-norbornene

: 28304-66-7
5-ethylidenebicyclo[2.2.1]hept-2-ene

Conditions

Conditions	Yield
With aluminum oxide; sodium In n-heptane at 90℃;

: 3048-64-4
5-vinyl-2-norbornene

: 106-99-0
buta-1,3-diene

: 66807-89-4, 66807-90-7, 37746-28-4
2-Vinyl-1,4-endo-methylen-1,2,3,4,5,5a,8,8a-octahydro-naphthalin

Conditions

Conditions	Yield
at 145 - 155℃;

: 64-18-6
formic acid

: 3048-64-4
5-vinyl-2-norbornene

A: 79657-39-9
exo-6-vinylbicyclo<2.2.1>heptan-exo-2-ol

B: 79703-61-0
endo-5-vinylbicyclo<2.2.1>heptan-exo-2-ol

Conditions

Conditions	Yield
With sodium hydroxide 1) 70 deg C, 4 h, 2) H2O-CH3OH, reflux, 2 h; Yield given. Multistep reaction. Title compound not separated from byproducts;

...Expand

: 64-18-6
formic acid

: 3048-64-4
5-vinyl-2-norbornene

A: 5-vinyl-2-norbornanone

B: 6-vinyl-2-norbornanone

Conditions

Conditions	Yield
With chromium(VI) oxide; sulfuric acid 1) 70 deg C, 4 h, 2) H2O, 20 - 30 deg C, overnight; Multistep reaction. Title compound not separated from byproducts;
Multistep reaction. Title compound not separated from byproducts;

...Expand

: 67-66-3
chloroform

: 3048-64-4
5-vinyl-2-norbornene

A: 93794-74-2
6-cyclopropylbicyclo<3.2.1>oct-2-ene

B: 93794-73-1
7-cyclopropylbicyclo<3.2.1>oct-2-ene

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; lithium 1) H2O, 25 deg C, 4 h; 2) Et2O, tBuOH, reflux, 2 h; Multistep reaction;

...Expand

: 67-66-3
chloroform

: 3048-64-4
5-vinyl-2-norbornene

: 93794-75-3
endo-6-cyclopropylbicyclo<3.2.1>octane

: 93794-75-3
exo-6-cyclopropylbicyclo<3.2.1>octane

Conditions

Conditions	Yield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride; hydrogen; lithium; nickel 1) H2O, 25 deg C, 4 h; 2) Et2O, tBuOH, reflux, 2 h; 3) MeOH, 3 h; Multistep reaction;

...Expand

: 3048-64-4
5-vinyl-2-norbornene

: 127-09-3
sodium acetate

: exo-2-acetoxy-endo-5-chlorobrendane

: exo-2-acetoxy-exo-5-chlorobrendane

Conditions

Conditions	Yield
triphenylphosphine; copper(l) chloride; palladium dichloride In acetic acid at 80℃; for 24h; Yield given. Yields of byproduct given;

...Expand

: 3048-64-4
5-vinyl-2-norbornene

A: 28304-67-8
5-ethylidene-2-norbornene

B: 28304-66-7
5-ethylidenebicyclo[2.2.1]hept-2-ene

Conditions

Conditions	Yield
γ-Al2O3-NaOH-Na at 25℃; for 3h; Product distribution;
γ-Al2O3-NaOH-Na at 25℃; for 3h; Yield given. Yields of byproduct given;
aluminum oxide; potassium amide at -0.1℃; for 0.166667h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

: 3048-64-4
5-vinyl-2-norbornene

: 2886-87-5, 88424-89-9, 88424-90-2
exo-2,3-epoxy-5-vinylbicylo<2.2.1>heptane

Conditions

Conditions	Yield
With oxygen; Pd(MeCN)2Cl(NO2) In benzene at 60℃; for 144h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
With phosphotungstic acid; cetylpyridinium chloride; dihydrogen peroxide In chloroform at 60℃; for 3h; Yield given;
With 4-tert-butylpyridine; potassium peroxomonosulfate; benzyldimethyltetradecylammonium chloride; (5,10,15,20-tetramesitylporphyrinato)manganese(III) chloride In phosphate buffer at 20℃; pH=7; Product distribution; Further Variations:; Catalysts; Reagents;	99 % Chromat.

: 3048-64-4
5-vinyl-2-norbornene

: 64-19-7
acetic acid

: exo-2-acetoxy-endo-5-chlorobrendane

: exo-2-acetoxy-exo-5-chlorobrendane

Conditions

Conditions	Yield
With oxygen; lithium chloride; copper dichloride; palladium dichloride at 80℃; for 36h; Yield given. Yields of byproduct given;
With lithium chloride; copper dichloride; palladium dichloride at 80℃; for 36h; Yield given. Yields of byproduct given;

...Expand

5-VINYL-2-NORBORNENE Chemical Properties

Product Name: 5-Vinyl-2-norbornene (CAS NO.3048-64-4)

Molecular Formula: C₉H₁₂
Molecular Weight: 120.19g/mol
Mol File: 3048-64-4.mol
Einecs: 221-259-8
Appearance: Clear liquid
Melting Point: −80 °C(lit.)
Boiling point: 141 °C at 760 mmHg
Storage Temperature: 0-6°C
Flash Point: 26.2 °C
Density: 0.841 g/mL at 25 °C(lit.)
Refractive index: n20/D 1.481(lit.)
Surface Tension: 37.3 dyne/cm
Enthalpy of Vaporization: 36.26 kJ/mol
Vapour Pressure: 7.47 mmHg at 25°C
XLogP3-AA: 2.7
H-Bond Donor: 0
H-Bond Acceptor: 0
Product Categories: Acyclic; Alkenes; Organic Building Blocks

5-VINYL-2-NORBORNENE Toxicity Data With Reference

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LC50	inhalation	17700mg/m3/2H (17700mg/m3)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 18(10), Pg. 52, 1974.
mouse	LD50	oral	5667mg/kg (5667mg/kg)		Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 18(10), Pg. 52, 1974.
rabbit	LD50	skin	15900uL/kg (15.9mL/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.
rat	LC50	inhalation	2231ppm/4H (2231ppm)	PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE BEHAVIORAL: TREMOR BEHAVIORAL: ATAXIA	National Technical Information Service. Vol. OTS0536315,
rat	LD50	oral	5190uL/kg (5.19mL/kg)		American Industrial Hygiene Association Journal. Vol. 30, Pg. 470, 1969.

5-VINYL-2-NORBORNENE Consensus Reports

Reported in EPA TSCA Inventory.

5-VINYL-2-NORBORNENE Safety Profile

Mildly toxic by ingestion, inhalation, and skin contact. When heated to decomposition it emits acrid smoke and irritating fumes.
Safety Information of 5-Vinyl-2-norbornene (CAS NO.3048-64-4):
Hazard Codes: Xi
Risk Statements: 10-36/38
10: Flammable
36: Irritating to the eyes
38: Irritating to the skin
Safety Statements: 16-26-36/37
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
37: Wear suitable gloves

5-VINYL-2-NORBORNENE Specification

5-Vinyl-2-norbornene ,its CAS NO. is 3048-64-4,the synonyms is 2-Norbornene, 5-vinyl- ; 2-Norbornene,5-vinyl-[qr] ; 2-Vinyl-5-norbornene ; 2-Vinylbicyclo[2.2.1]hept-5-ene ; 2-Vinylnorbornene ; 2-Vinylnorbornene[qr] ; 5-Ethenyl-bicyclo(2.2.1)hept-2-en ; 5-Ethenyl-bicyclo(2.2.1)hept-2-ene .

Product Name

Vinylnorbornene

Synthetic route

5-VINYL-2-NORBORNENE Chemical Properties

5-VINYL-2-NORBORNENE Toxicity Data With Reference

5-VINYL-2-NORBORNENE Consensus Reports

5-VINYL-2-NORBORNENE Safety Profile

5-VINYL-2-NORBORNENE Specification

Related Products

Hot Products