6-Chloro-2,4-dinitroaniline supplier

Name
2-Chloro-4,6-dinitroaniline
EINECS 222-564-9
CAS No. 3531-19-9
Density 1.708 g/cm³
Solubility
Melting Point 157-159 °C(lit.)
Formula C₆H₄ClN₃O₄
Boiling Point 376.3 °C at 760 mmHg
Molecular Weight 217.568
Flash Point 181.4 °C
Transport Information UN 2811 6.1/PG 3
Appearance yellow crystalline powder and/or chunks
Safety 26-28-36/37/39-45
Risk Codes 20/21/22-36/37/38
Molecular Structure
Hazard Symbols Xn
Synonyms Aniline,2-chloro-4,6-dinitro- (6CI,7CI,8CI);2,4-Dinitro-6-chloroaniline;2-Chloro-4,6-dinitroaniline;
PSA 117.66000
LogP 3.36620

Synthetic route

: 97-02-9
2,4-Dinitroanilin

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Stage #1: 2,4-Dinitroanilin With hydrogenchloride In water at 50 - 70℃; Stage #2: With sodium perchlorate In water at 70℃; for 2h;	98%
Stage #1: 2,4-Dinitroanilin With hydrogenchloride In water at 35℃; for 2h; Stage #2: With chlorine In water at 45℃; Stage #3: With dihydrogen peroxide In water at 60 - 65℃; for 6h; Temperature;	98.4%
With hydrogenchloride; dmap; dihydrogen peroxide In water at 20 - 30℃; for 3h; Reagent/catalyst;	97.2%

: 95-51-2
2-Chloroaniline

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With sulfuric acid; nitric acid at 0 - 40℃; for 1h;	56%
Multi-step reaction with 3 steps 1: diethyl ether 2: nitric acid / -15 °C / folgendes bei Raumtemperatur 3: water View Scheme

: 23789-10-8
5-chloro-4-methoxy-1,3-dinitrobenzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With methanol; ammonia

: 2213-80-1
1,2-dichloro-3,5-dinitrobenzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With ethanol; ammonia
Multi-step reaction with 2 steps 1: aq. NaN3 2: NH3, NaOAc / ethanol View Scheme

: 242477-68-5
1-chloro-2,3,5-trinitro-benzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With ethanol; ammonia

: 861366-66-7
N-ethyl-N'-(2-chloro-4,6-dinitro-phenyl)-N-nitro-urea

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With water

: 121-87-9
2-Chloro-4-nitroaniline

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With sulfuric acid; sulfur trioxide; nitric acid

: 89598-75-4
2-chloro-4,6-dinitrophenyl azide

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
With ammonia; sodium acetate In ethanol

: 7647-01-0
hydrogenchloride

: 7782-50-5
chlorine

: 64-19-7
acetic acid

: 97-02-9
2,4-Dinitroanilin

: 3531-19-9
2-chloro-4,6-dinitroaniline

...Expand

: 7647-01-0
hydrogenchloride

: 97-02-9
2,4-Dinitroanilin

potassium chlorate: potassium chlorate

: 3531-19-9
2-chloro-4,6-dinitroaniline

...Expand

: 7647-01-0
hydrogenchloride

: 97-02-9
2,4-Dinitroanilin

sodium hypochlorite: sodium hypochlorite

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
at 15 - 20℃;

...Expand

: 2213-80-1
1,2-dichloro-3,5-dinitrobenzene

: 7664-41-7
ammonia

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
at 105℃; im Rohr;

: 23789-10-8
5-chloro-4-methoxy-1,3-dinitrobenzene

methanol. NH3: methanol. NH3

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
at 100℃;

: 242477-68-5
1-chloro-2,3,5-trinitro-benzene

: 7664-41-7
ammonia

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 64-17-5
ethanol

: 861366-66-7
N-ethyl-N'-(2-chloro-4,6-dinitro-phenyl)-N-nitro-urea

: 7664-41-7
ammonia

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
at 100℃;

...Expand

: 861366-66-7
N-ethyl-N'-(2-chloro-4,6-dinitro-phenyl)-N-nitro-urea

: 7732-18-5
water

A: 19091-98-6
ethylnitramine

B: 3531-19-9
2-chloro-4,6-dinitroaniline

C: 15719-64-9, 15719-76-3, 97762-63-5
methylammonium carbonate

...Expand

: 62635-53-4
N-ethyl-N'-(2-chloro-phenyl)-urea

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: nitric acid / -15 °C / folgendes bei Raumtemperatur 2: water View Scheme

: 602-02-8
2,3-dinitrochlorobenzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: oleum; fuming nitric acid / 160 - 170 °C 2: alcohol; ammonia View Scheme

: 946-31-6
2-chloro-4,6-dinitro-phenol

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 2: alcohol; ammonia View Scheme
Multi-step reaction with 2 steps 1: diethylaniline 2: alcohol; ammonia View Scheme

: 602-03-9
2,3-dinitroaniline

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: nitrosylsulfuric acid / Diazotization.man traegt die Diazoniumsalz-Loesung in Kupfer(I)-chlorid-Loesung ein 2: oleum; fuming nitric acid / 160 - 170 °C 3: alcohol; ammonia View Scheme

: 610-53-7
2,4-dinitroacetanilide

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: concentrated sulfuric acid / 110 °C 2: hydrochloric acid; potassium chlorate View Scheme

: 95-50-1
1,2-dichloro-benzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: HNO3+H2SO4 2: alcohol; ammonia View Scheme

: 103-84-4
Acetanilid

: 3531-19-9
2-chloro-4,6-dinitroaniline

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: nitric acid / 0 °C 2: concentrated sulfuric acid / 110 °C 3: hydrochloric acid; potassium chlorate View Scheme

: 29745-44-6
pyridine-2-carbonyl chloride

: 3531-19-9
2-chloro-4,6-dinitroaniline

: C12H7ClN4O5

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sodium hydroxide In water for 0.5h; Stage #2: pyridine-2-carbonyl chloride In water at 5 - 20℃; for 3h;	95%

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 98-88-4
benzoyl chloride

: 91692-86-3
N-(6-chloro-2,4-dinitrophenyl)benzamide

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sodium hydroxide In water for 0.5h; Stage #2: benzoyl chloride In water at 5 - 20℃; for 3h;	91%
With pyridine

: 41717-28-6
2-benzofuroyl chloride

: 3531-19-9
2-chloro-4,6-dinitroaniline

: N-(6-chloro-2,4-dinitrophenyl)benzofuran-2-carboxamide

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sodium hydroxide In water for 0.5h; Stage #2: 2-benzofuroyl chloride In water at 5 - 20℃; for 3h;	90%

: 25084-14-4
5-nitrofuran-2-carboxylic chloride

: 3531-19-9
2-chloro-4,6-dinitroaniline

: N-(6-chloro-2,4-dinitrophenyl)-5-nitrofuran-2-carboxamide

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sodium hydroxide In water for 0.5h; Stage #2: 5-nitrofuran-2-carboxylic chloride In water at 5 - 20℃; for 3h;	90%

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 62348-13-4
isooxazole-5-carbonyl chloride

: N-(6-chloro-2,4-dinitrophenyl)isoxazole-5-carboxamide

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sodium hydroxide In water for 0.5h; Stage #2: isooxazole-5-carbonyl chloride In water at 5 - 20℃; for 3h;	87%

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 616-38-6
carbonic acid dimethyl ester

: 4-chloro-1,3-dimethyl-6-nitro-1H-benzo[d]imidazol-2(3H)-one

Conditions

Conditions	Yield
With copper(II) acetate monohydrate In neat (no solvent) at 100℃; under 7600.51 Torr; for 20h; Autoclave; Inert atmosphere; Green chemistry;	75%

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 122-04-3
4-nitro-benzoyl chloride

: 141245-77-4
2',4',4-trinitro-6'-chlorobenzanilide

Conditions

Conditions	Yield
In nitrobenzene at 190 - 200℃; for 4h;	74%

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 64-19-7
acetic acid

: 4-chloro-2-methyl-1H-benzimidazol-6-amine

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline; acetic acid With tin(II) chloride dihdyrate for 4h; Reflux; Stage #2: With hydrogenchloride In water for 1h; Reflux;	69%

: 938190-38-6
6-(9-carbazolyl)-3-oxahexane-1,5-diol

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 6-[3-(2-chloro-4,6-dinitrophenylazo)carbazol-9-yl]-3-oxahexane-1,5-diol

Conditions

Conditions	Yield
Stage #1: 2-chloro-4,6-dinitroaniline With sulfuric acid; sodium nitrite In water; acetic acid at 15℃; for 1h; Stage #2: 6-(9-carbazolyl)-3-oxahexane-1,5-diol In 2-methyl-propan-1-ol; water for 1h;	36%

: 64-18-6
formic acid

: 3531-19-9
2-chloro-4,6-dinitroaniline

A: 118134-23-9
5-amino-4,7-dichlorobenzimidazole

B: 118134-22-8
7(4)-chloro-5(6)-formylaminobenzimidazole

Conditions

Conditions	Yield
With hydrogenchloride; tin for 6h; Heating;	A 23.5% B 20%

...Expand

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 100191-51-3
1-chloro-2-iodo-3,5-dinitrobenzene

Conditions

Conditions	Yield
With sulfuric acid; acetic acid Diazotization.Eintragen des Reaktionsgemisches in gesaettigte wss. KI-Loesung;
Stage #1: 2-chloro-4,6-dinitroaniline With sulfuric acid; acetic acid; sodium nitrite at 70℃; Stage #2: With potassium iodide In water at 50℃; for 0.25h;

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 108-24-7
acetic anhydride

: 89894-26-8
acetic acid-(2-chloro-4,6-dinitro-anilide)

Conditions

Conditions	Yield
With sulfuric acid; acetic acid
With sulfuric acid

: 75-15-0
carbon disulfide

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 3926-62-3
sodium monochloroacetic acid

: 56205-33-5
3-(2-chloro-4,6-dinitro-phenyl)-2-thioxo-thiazolidin-4-one

Conditions

Conditions	Yield
(i) aq. NH3, (ii) /BRN= 3597157/; Multistep reaction;

...Expand

: 393-75-9
4-chloro-3,5-dinitrobenzotrifluoride

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 53393-21-8
6'-chloro-4-trifluoromethyl-2,2',4',6-tetranitrodiphenylamine

Conditions

Conditions	Yield
In N-methyl-acetamide
With sodium hydride

: 119-79-9
5-aminonaphthalene-2-sulfonic acid

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 4-Amino-1-hydroxy-N-[4-(2,4-di-tert-pentylphenoxy)butyl]-2-naphthamide

: 54179-88-3
C47H49ClN6O10S

Conditions

Conditions	Yield
Multistep reaction;

...Expand

: 392-95-0
1-chloro-2,4-dinitro-6-trifluoromethylbenzene

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 57729-69-8
(2-Chloro-4,6-dinitro-phenyl)-(2,4-dinitro-6-trifluoromethyl-phenyl)-amine

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 4-Acetylamino-5-hydroxy-naphthalene-2-sulfonic acid

: 4-Amino-1-hydroxy-N-[4-(2,4-di-tert-pentylphenoxy)butyl]-2-naphthamide

: 54180-03-9
C49H52ClN7O11S

Conditions

Conditions	Yield
Multistep reaction;

...Expand

: 3531-19-9
2-chloro-4,6-dinitroaniline

: 17625-81-9
6-chloro-2,4-diaminobenzimidazole

Conditions

Conditions	Yield
With hydrogen; palladium on activated charcoal In methanol; formic acid at 20℃; under 2280 Torr; for 23h;

6-Chloro-2,4-dinitroaniline Chemical Properties

Chemical Name: 2-Chloro-4,6-dinitroaniline
IUPAC NAME: 2-chloro-4,6-dinitroaniline
CAS No.: 3531-19-9
EINECS: 222-564-9
RTECS: BX9250000
RTECS Class: Mutagen
Molecular Formula: C₆H₄ClN₃O₄
Molecular Weight: 217.57 g/mol
Density: 1.708 g/cm³
Melting Point: 157-159 °C(lit.)
Flash Point: 181.4 °C
Boiling Point: 376.3 °C at 760 mmHg
The yellow powder insoltble in water,it is stable at room temperature in closed containers under normal storage and handling conditions.Following is the structure of 2-CHLORO-4,6-DINITROANILINE(3531-19-9):

The chemical synonymous of 2-CHLORO-4,6-DINITROANILINE(3531-19-9) are 2-chloro-4,6-dinitro-benzenamin;2-chloro-4,6-dinitro-Benzenamine;6-chloro-2,4-dinitro-anilin;LABOTEST-BB LT00159757;2-CHLORO-4,6-DINITROANILINE;2,6-DINITRO-4-CHLOROANILINE;TIMTEC-BB SBB003373;TIMTEC-BB SBB003374

6-Chloro-2,4-dinitroaniline Uses

2-CHLORO-4,6-DINITROANILINE(3531-19-9)is mainly used as a intermediates for disperse dye.

6-Chloro-2,4-dinitroaniline Production

Product Categories about 2-CHLORO-4,6-DINITROANILINE(3531-19-9) are Intermediates of Dyes and Pigments;Amines;C2 to C6;Nitrogen Compounds.

6-Chloro-2,4-dinitroaniline Toxicity Data With Reference

mmo-sat 500 µg/plate

SAIGBL Sangyo Igaku. Japanese Journal of Industrial Health. 29 (1987),34.

6-Chloro-2,4-dinitroaniline Consensus Reports

Reported in EPA TSCA Inventory.

6-Chloro-2,4-dinitroaniline Safety Profile

Mutation data reported. An explosive sensitive to heat or an initiating charge. Solution in nitrosylsulfuric acid explodes between 50-160°C depending on the concentration. When heated to decomposition it emits toxic fumes of Cl⁻ and NO_x. See also EXPLOSIVES, HIGH; EXPLOSIVES, LOW; EXPLOSIVES, PERMITTED and ANILINE DYES.
Hazard Codes:
Xn: Harmful

Risk Statements about 2-CHLORO-4,6-DINITROANILINE(3531-19-9):
    R20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
    R36/37/38 Irritating to eyes, respiratory system and skin.
Safety Statements about 2-CHLORO-4,6-DINITROANILINE(3531-19-9):
    S22 Do not breathe dust.
    S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
    S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

6-Chloro-2,4-dinitroaniline Specification

1. Storage: Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
2. Handling: Avoid ingestion and inhalation.Avoid contact with eyes, skin, and clothing. Wash thoroughly after handling. Use with adequate ventilation. Minimize dust generation and accumulation. Keep container tightly closed.
3. Personal Protection: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Product Name

2-Chloro-4,6-dinitroaniline

Synthetic route

6-Chloro-2,4-dinitroaniline Chemical Properties

6-Chloro-2,4-dinitroaniline Uses

6-Chloro-2,4-dinitroaniline Production

6-Chloro-2,4-dinitroaniline Toxicity Data With Reference

6-Chloro-2,4-dinitroaniline Consensus Reports

6-Chloro-2,4-dinitroaniline Safety Profile

6-Chloro-2,4-dinitroaniline Specification

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