Product Name

  • Name

    Ammonium dihydrogen orthophosphate

  • EINECS 231-764-5
  • CAS No. 7722-76-1
  • Density 1.02 g/mL at 20 °C
  • Solubility H2O: 0.1 M at 20 °C
  • Melting Point 190 °C (dec.)(lit.)
  • Formula NH6PO4
  • Boiling Point 158 °C at 760 mmHg
  • Molecular Weight 115.026
  • Flash Point
  • Transport Information UN 3264
  • Appearance white crystalline powder
  • Safety 24/25-36-26
  • Risk Codes 36/37/38
  • Molecular Structure Molecular Structure of 7722-76-1 (Ammonium dihydrogen orthophosphate)
  • Hazard Symbols IrritantXi
  • Synonyms azanium,dihydrogen phosphate;Ammonium dihydrogen phosphate;
  • PSA 90.40000
  • LogP -0.11420

Synthetic route

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

urea
57-13-6

urea

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

carbon dioxide
124-38-9

carbon dioxide

Conditions
ConditionsYield
With water Kinetics;
tricalcium diphosphate

tricalcium diphosphate

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

Conditions
ConditionsYield
With ammonium sulfate; sulfuric acid In not given byproducts: CaSO4; in presence of 16.2-22.2% (NH4)2SO4;
With H2SO4; (NH4)2SO4 In not given byproducts: CaSO4; in presence of 16.2-22.2% (NH4)2SO4;
tricalcium diphosphate

tricalcium diphosphate

ammonium sulfate

ammonium sulfate

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
In not given with H3PO4 soln., at higher temp.;
In not given with H3PO4 soln., at higher temp.;
phosphorus

phosphorus

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With ammonia; water at high temp., in sealed quarz tube in N2 flow;
With NH3; H2O at high temp., in sealed quarz tube in N2 flow;
phosphoramidic acid
14700-20-0, 2817-45-0

phosphoramidic acid

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With phosphoramidic acid In water boiling;
With phosphoramidic acid In water boiling;
With water In water-d2 Kinetics; hydrolysis in D2O; catalyst: acids;;
P4N6

P4N6

A

diammonium hydrogenphosphate

diammonium hydrogenphosphate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

C

ammonium dihydrogenphosphite
13446-12-3

ammonium dihydrogenphosphite

Conditions
ConditionsYield
With water In neat (no solvent) heating in sealed tube at 215°C, 12 h;
With H2O In neat (no solvent) heating in sealed tube at 215°C, 12 h;
P4N6

P4N6

phosphorus(V) nitride

phosphorus(V) nitride

A

diammonium hydrogenphosphate

diammonium hydrogenphosphate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

C

ammonium dihydrogenphosphite
13446-12-3

ammonium dihydrogenphosphite

Conditions
ConditionsYield
With water hydrolysis;
With H2O hydrolysis;
phosphorus(V) nitride

phosphorus(V) nitride

A

diammonium hydrogenphosphate

diammonium hydrogenphosphate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With water In neat (no solvent) heating in sealed tube at 215°C, 12 h;
With H2O In neat (no solvent) heating in sealed tube at 215°C, 12 h;
anhydrous calcium hydrogen phosphate

anhydrous calcium hydrogen phosphate

ammonium bicarbonate
1066-33-7

ammonium bicarbonate

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
In not given at higher temp.;
In not given at higher temp.;
ammonium dihydrogenphosphite
13446-12-3

ammonium dihydrogenphosphite

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With water byproducts: H2; heated under pressure;
With H2O byproducts: H2; heated under pressure;
diammonium hydrogenphosphate

diammonium hydrogenphosphate

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
warming at 100°C in dry air flow, 2h;
In neat (no solvent) heated in platinum boat to 155°C;
warming at 100°C in dry air flow, 2h;
In neat (no solvent) heated in platinum boat to 155°C;
diammonium hydrogenphosphate

diammonium hydrogenphosphate

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

ammonia
7664-41-7

ammonia

diammonium hydrogenphosphate

diammonium hydrogenphosphate

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
In not given added equiv. amt. H3PO4 to (NH4)2HPO4 soln.;
In not given added equiv. amt. H3PO4 to (NH4)2HPO4 soln.;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

ammonia
7664-41-7

ammonia

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

Mg(2+)*2NH4(1+)*4H(1+)*2P2O7(4-)*2H2O = Mg(NH4)2H4(P2O7)2*2H2O

Mg(2+)*2NH4(1+)*4H(1+)*2P2O7(4-)*2H2O = Mg(NH4)2H4(P2O7)2*2H2O

C

diammonium-dihydrogenodiphosphate

diammonium-dihydrogenodiphosphate

D

(Fe,Al)(NH4)P2O7

(Fe,Al)(NH4)P2O7

Conditions
ConditionsYield
In not given neutralization of H3PO4 (made by wet process from natural Karatau phosphorite) with NH3, evapn., dehydration (230 - 250.degree, 3.0 - 3.5 h); mixt. not sepd.; X-ray diffraction;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

ammonia
7664-41-7

ammonia

A

diammonium hydrogenphosphate

diammonium hydrogenphosphate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
In water Kinetics; injection of a micro-drop of H3PO4 (concn. 50-88.5%) into a flowing mixt. of He and NH3 or leading a dose of NH3 in a He flow over H3PO4 (concn. 50-88.5%), 203-353K;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

ammonia
7664-41-7

ammonia

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
75% H3PO4 soln.;
In ammonia added NH3 soln. to H3PO4 (to acidic reaction of litmus and no more ppt. with BaCl2);
In not given neutralised of H3PO4 soln. with NH3 by methyl orange indicator; purifn. by repeated recrystn., dried over P2O5 in vac.;
calcium hydrogen phosphate
7789-77-7

calcium hydrogen phosphate

ammonium bisulfate
7803-63-6

ammonium bisulfate

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
CaHPO4 was treated with equivalent amount of NH4HSO4;;
CaHPO4 was treated with equivalent amount of NH4HSO4;;
hydrogen
1333-74-0

hydrogen

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

hydroxylamine phosphate

hydroxylamine phosphate

C

nitrous oxide
227934-46-5

nitrous oxide

D

nitrogen
7727-37-9

nitrogen

Conditions
ConditionsYield
With palladium on activated charcoal In further solvent(s) Kinetics; 40 °C, P(H2) = 50 kPa, P(NO) = 10 kPa;
calcium dihydrogen phosphate

calcium dihydrogen phosphate

ammonium sulfate

ammonium sulfate

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
Ca(H2PO4)2 was treated with equivalent amount of (NH4)2SO4;;
Ca(H2PO4)2 was treated with equivalent amount of (NH4)2SO4;;
2NH4(1+)*H(1+)*P2O6NH2(3-)=(NH4)2HP2O6NH2

2NH4(1+)*H(1+)*P2O6NH2(3-)=(NH4)2HP2O6NH2

A

diammonium hydrogenphosphate

diammonium hydrogenphosphate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With H2O In water decompn. by heating (at ambient temp. very slow);
ammonium cyclotriphosphate

ammonium cyclotriphosphate

water
7732-18-5

water

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
In neat (no solvent) heating (glass ampoule, H2O pressure 24 GPa, 200 and 252+/-0.2°C); thin layer chromy., X-ray diffraction;
ammonium cyclotriphosphate

ammonium cyclotriphosphate

ammonia
7664-41-7

ammonia

water
7732-18-5

water

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

diammonium-dihydrogenodiphosphate

diammonium-dihydrogenodiphosphate

Conditions
ConditionsYield
In neat (no solvent) heating (glass ampoule, H2O pressure 24 GPa, NH3 pressure 906 GPa, 220 or 286°C); thin layer chromy., X-ray diffraction;
urea phosphate
4861-19-2

urea phosphate

A

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

B

ammonium metaphosphate

ammonium metaphosphate

C

carbon dioxide
124-38-9

carbon dioxide

D

ammonia
7664-41-7

ammonia

E

urea
57-13-6

urea

Conditions
ConditionsYield
at 140°C;
hexaaminocyclotriphosphazene
13597-92-7

hexaaminocyclotriphosphazene

A

ammonium sulfate

ammonium sulfate

B

ammonium dihydrogen phosphate
7722-76-1

ammonium dihydrogen phosphate

Conditions
ConditionsYield
With H2SO4 In not given react. with H2SO4; formation of a mixture of NH4H2PO4 and (NH4)2SO4 and white vapors of volatile N compounds;;

Ammonium dihydrogen phosphate Specification

Ammonium dihydrogen phosphate is also known as Monoammonium phosphate. It is a white tetragonal crystals with chemical formula NH4H2PO4. Its EINECS registry number is 231-764-5 and its CAS number is 7722-76-1. What's more, the substance is soluble in water which will melt at 190 °C. Ammonium dihydrogen phosphate can be mixed with all water-soluble fertilisers, except for calcium fertilisers and concentrated magnesium solutions. It should be kept in a tightly closed container, stored in a cool, dry, ventilated area and protected against physical damage. Ammonium dihydrogen phosphate is stable under ordinary conditions of use and storage.

Physical properties about Ammonium dihydrogen phosphate are: (1)ACD/LogP: -2.148; (2)ACD/LogD (pH 5.5): -5.41; (3)ACD/LogD (pH 7.4): -6.38; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)#H bond acceptors: 4; (7)#H bond donors: 3; (8)Boiling Point: 158 °C at 760 mmHg; (9)Vapour Pressure: 1.41 mmHg at 25°C

Preparation of Ammonium dihydrogen phosphate: Ammonium dihydrogen phosphate can be prepared by venturi cyclic reaction method. Firstly, you should dilute 85% thermal phosphoric acid to 1.3~1.4 times and then add into reactor where it mixed and reacted with ammonia.

H3PO4 + NH3 → NH4H2PO4

There also are neutralization method and multiple decomposite method in industrial production, but neutralization method is more commonly used. It will need phosphoric acid and aqueous ammonia.

H3PO4 + NH4OH → NH4H2PO4 + H2O

Uses of Ammonium dihydrogen phosphate: Ammonium dihydrogen phosphate is often used in the blending of dry agricultural fertilizers. It is a widely used crystal in the field of optics due to its birefringence properties. The compound is also a component of the ABC powder in some dry chemical fire extinguishers. This substance is also supplied in an emerald green or aquamarine crystal growing box kit for kids.

When using Ammonium dihydrogen phosphate, you should very cautious about it. This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [NH4+].OP(=O)(O)[O-]
(2)InChI: InChI=1S/H3N.H3O4P/c;1-5(2,3)4/h1H3;(H3,1,2,3,4)
(3)InChIKey: LFVGISIMTYGQHF-UHFFFAOYSA-N

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