Product Name

  • Name

    Anthracene

  • EINECS 204-371-1
  • CAS No. 120-12-7
  • Article Data897
  • CAS DataBase
  • Density 1.13 g/cm3
  • Solubility water: 0.045 mg/L (25 °C)
  • Melting Point 215-218 °C
  • Formula C14H10
  • Boiling Point 337.355 °C at 760 mmHg
  • Molecular Weight 178.233
  • Flash Point 146.606 °C
  • Transport Information UN 3077 9/PG 3
  • Appearance colourless crystalline solid
  • Safety 26-60-61-24/25-16-9-45-36/37-62-36
  • Risk Codes 36/37/38-50/53-67-36-11-39/23/24/25-23/24/25-65-38
  • Molecular Structure Molecular Structure of 120-12-7 (Anthracene)
  • Hazard Symbols IrritantXi,DangerousN,FlammableF
  • Synonyms Green Oil;Anthracene, pure;Tetra Olive N2G;Coal tar pitch volatiles: anthracene;Anthracin;Anthracene oil (coal tar fraction);Anthracene (C14H10);Bis-alkylamino anthracene;Paranaphthalene;
  • PSA 0.00000
  • LogP 3.99300

Synthetic route

1,2,3,4-tetrahydroxy-1β,2α,3α,4β,4aβ,9α,9aβ,10α-hexahydro-9,10<1',2'>benzenoanthracene
125459-20-3

1,2,3,4-tetrahydroxy-1β,2α,3α,4β,4aβ,9α,9aβ,10α-hexahydro-9,10<1',2'>benzenoanthracene

A

anthracene
120-12-7

anthracene

B

conduritol A
526-87-4, 351885-26-2

conduritol A

Conditions
ConditionsYield
at 460℃; under 0.1 Torr; for 0.5h;A 100%
B 100%
2,3-dihydroxy-1,4-dimethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene
125459-21-4, 127761-11-9

2,3-dihydroxy-1,4-dimethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene

A

anthracene
120-12-7

anthracene

B

<1α,2α,3β,6β>-3,6-dimethoxycyclohex-4-ene-1,2-diol
125459-24-7

<1α,2α,3β,6β>-3,6-dimethoxycyclohex-4-ene-1,2-diol

Conditions
ConditionsYield
at 440℃; under 0.05 Torr; for 2h;A 100%
B 99%
C15H12S
59102-56-6

C15H12S

A

thioformaldehyde
865-36-1

thioformaldehyde

B

anthracene
120-12-7

anthracene

C

CS2, H2S

CS2, H2S

Conditions
ConditionsYield
at 651.9℃; under 1E-06 Torr; sublimation through a short path flash vacuum pyrolysis (fvp) oven;A n/a
B 100%
C n/a
C15H12OS
59102-57-7

C15H12OS

A

sulfinylmethane
40100-16-1

sulfinylmethane

B

anthracene
120-12-7

anthracene

C

SO2

SO2

Conditions
ConditionsYield
at 651.9℃; under 1E-06 Torr; sublimation through a short path flash vacuum pyrolysis (fvp) oven;A n/a
B 100%
C n/a
C20H18O2

C20H18O2

A

3,7-dioxabicyclo[3.3.0]oct-1,5-ene
53720-71-1

3,7-dioxabicyclo[3.3.0]oct-1,5-ene

B

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
at 600℃; under 0.06 Torr;A n/a
B 100%
2-benzylbenzaldehyde
32832-95-4

2-benzylbenzaldehyde

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With boron trifluoride diethyl etherate; toluene-4-sulfonamide In toluene at 20℃; for 0.166667h;100%
With boron trifluoride diethyl etherate; toluene-4-sulfonamide In toluene at 20℃; for 0.166667h;99%
With indium(III) triflate In 1,2-dichloro-ethane at 115℃; for 6h; Inert atmosphere;94%
C14H10Yb
129823-92-3

C14H10Yb

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With oxygen In 1,2-dimethoxyethane addn. of dry oxygen to a suspension of Yb complex;100%
C14H10Sm

C14H10Sm

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With oxygen In 1,2-dimethoxyethane addn. of dry oxygen to a suspension of Sm complex;100%
9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With sulfuric acid; dinitrogen monoxide; Ru(5,10,15,20-tetramesitylporphyrin)(O)2 In benzene at 120℃; under 7600 Torr; for 4h;99%
With oxygen; 2,3-dicyano-5,6-dichloro-p-benzoquinone; sodium nitrite In toluene at 120℃; under 9750.98 Torr; for 8h;99%
With C64H50F8N6Ru In dichloromethane-d2 at 20℃; Reagent/catalyst; Schlenk technique; Inert atmosphere;99%
9-chloroanthracene
716-53-0

9-chloroanthracene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With SmI2(hmpa)4 In tetrahydrofuran at 20℃; for 0.0166667h;99%
With potassium tert-butylate; N,N-dimethyl-formamide at 35℃; for 24h; Schlenk technique; Inert atmosphere; Irradiation;70%
With triethylamine In acetonitrile Product distribution; Quantum yield; Mechanism; Ambient temperature; Irradiation; quenching rate constants by azulene, ferrocene, and amines, decay rate constants of the radical anion;
With tetraethylammonium perchlorate In acetonitrile at 24.99℃; Electrochemical reaction;
9-Bromoanthracene
1564-64-3

9-Bromoanthracene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With 2-H-1,3-di-tert-butyl-1,3,2-diazaphosphorinane; 2,2'-azobis(isobutyronitrile) In toluene at 90℃; for 5h;99%
With 1,3-bis(2,6-diisopropylphenyl)-2,4-diphenylimidazole In N,N-dimethyl-formamide at 20℃; for 36h; Glovebox;98%
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide at 20℃; Inert atmosphere;96%
<2α,3aβ,4β,4aβ,5β,10β,10aβ,11β,11aβ>-4,11-dimethoxy-2-phenyl-3a,4,4a,5,10,10a,11,11a-octahydro-5,10<1',2'>benzenoanthra<2,3-d>-1,3-dioxole

<2α,3aβ,4β,4aβ,5β,10β,10aβ,11β,11aβ>-4,11-dimethoxy-2-phenyl-3a,4,4a,5,10,10a,11,11a-octahydro-5,10<1',2'>benzenoanthra<2,3-d>-1,3-dioxole

A

anthracene
120-12-7

anthracene

B

<2α,3aα,4α,7α,7aα>-2-phenyl-3a,4,7,7a-tetrahydro-1,3-benzodioxole

<2α,3aα,4α,7α,7aα>-2-phenyl-3a,4,7,7a-tetrahydro-1,3-benzodioxole

Conditions
ConditionsYield
at 440℃;A 99%
B 95%
anthracene-9-boronic acid
100622-34-2

anthracene-9-boronic acid

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With [bis(trifluoromethanesulfonyl)imidate](triphenylphosphine)gold(I); water In toluene at 90℃; for 2h; Microwave irradiation; Green chemistry;99%
With acetic acid at 130℃; for 3h; Green chemistry;92%
With sodium hypochlorite; tetrabutylammomium bromide; water at 100℃;91%
With copper(l) chloride In methanol at 25℃; for 3h;
1,2,3,4-tetramethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene
125459-22-5

1,2,3,4-tetramethoxy-1β,2α, 3α,4β,4aβ,9α,9aβ,10α-octahydro-9,10<1',2'>benzenoanthracene

A

anthracene
120-12-7

anthracene

B

3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol
86632-82-8

3α,4β,5β,6α-tetramethoxycyclohex-4-ene-1α,2α-diol

Conditions
ConditionsYield
at 410℃; under 0.03 Torr; for 1.5h;A 57 mg
B 98%
9-anthracene aldehyde
642-31-9

9-anthracene aldehyde

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With palladium diacetate; potassium carbonate In ethyl acetate at 150℃; under 12929 Torr; for 0.833333h; Microwave irradiation; Molecular sieve;98%
With palladium nanoparticles supported on fibrous silica In cyclohexane at 130℃; for 20h; Molecular sieve;98%
With palladium diacetate In cyclohexane at 140℃; for 24h; Molecular sieve; air;97%
9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

[(C12H8N2)2Mn(μ-O)2Mn(C12H8N2)2](ClO4)4

[(C12H8N2)2Mn(μ-O)2Mn(C12H8N2)2](ClO4)4

A

[(1,10-phenanthroline)2Mn(η1-OClO3)2]
100685-12-9, 463965-74-4

[(1,10-phenanthroline)2Mn(η1-OClO3)2]

B

anthracene
120-12-7

anthracene

C

anthracen-9(10H)-one
90-44-8

anthracen-9(10H)-one

D

9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
In acetonitrile Kinetics; the soln. in acetonitrile was allowed to stand overnight at room temp.; the organic products were detected by GC/MS; the soln. was layered with ether;A n/a
B 97%
C 0.8%
D 2%
2-(2-benzylphenyl)-1,3-dioxolane

2-(2-benzylphenyl)-1,3-dioxolane

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With trifluorormethanesulfonic acid at 0 - 20℃; for 1h;97%
9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

A

anthracene
120-12-7

anthracene

B

9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With tert.-butylhydroperoxide; H5PV2Mo10O40(1,11) In toluene for 24h; Ambient temperature;A 96%
B 4%
With dinitrogen monoxide; Ru(5,10,15,20-tetramesitylporphyrin)(O)2 In benzene at 200℃; under 7600 Torr; for 20h; Product distribution; Further Variations:; Solvents; Reagents; Temperatures;A 9%
B 90%
With dinitrogen monoxide; dioxo(tetramesitylporphyrinato)ruthenium(VI) In benzene at 200℃; under 7600 Torr; for 20h; Product distribution; Further Variations:; Reagents; Solvents; Temperatures;A 9%
B 90%
anthracen-9(10H)-one
90-44-8

anthracen-9(10H)-one

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
aluminum oxide In isopropyl alcohol at 400℃; benzene as solvent;95%
With iodine; magnesium In methanol at 20℃; for 3.5h;94%
With sulfur In isopropyl alcohol at 400℃; for 5h;90%
phenyl anthracene-9-carboxylate
1503-84-0

phenyl anthracene-9-carboxylate

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With nickel(II) acetate tetrahydrate; 1,2-bis-(dicyclohexylphosphino)ethane In toluene at 170℃; for 24h; Inert atmosphere; Glovebox; Sealed tube;95%
9-cyanoanthracene
1210-12-4

9-cyanoanthracene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triisopropyl phosphite; chlorotriisopropylsilane In toluene at 160℃; for 15h; Inert atmosphere;94%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; triisopropyl phosphite; chlorotriisopropylsilane In toluene at 160℃; for 15h; Inert atmosphere;94%
Multi-step reaction with 2 steps
1: 12 percent / NH4Cl, NaN3 / dimethylformamide / 360 h / 90 °C
2: 9 percent / 600 °C / 0 - 0.1 Torr
View Scheme
With [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride; ethanol; potassium hexamethylsilazane In toluene at 150℃; for 8h; Inert atmosphere;62 %Spectr.
9-chloroanthracene
716-53-0

9-chloroanthracene

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With dicyclohexyl-(2',6'-dimethoxybiphenyl-2-yl)-phosphane; tris-(dibenzylideneacetone)dipalladium(0); lithium chloride In toluene at 100℃; for 15h;94%
9,10-dihydro-9,10-(2-phenyl-1-thiaethano)anthracene
84040-16-4

9,10-dihydro-9,10-(2-phenyl-1-thiaethano)anthracene

2,3-dimethyl-buta-1,3-diene
513-81-5

2,3-dimethyl-buta-1,3-diene

A

anthracene
120-12-7

anthracene

B

3,4-dimethyl-6-phenyl-5,6-dihydro-2H-thiopyran
84040-18-6

3,4-dimethyl-6-phenyl-5,6-dihydro-2H-thiopyran

Conditions
ConditionsYield
In toluene at 98 - 99℃; for 1h;A 92%
B 92%
Heating;A 92%
B 92%
o-benzylbenzylidene chloride
87619-43-0

o-benzylbenzylidene chloride

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
at 475℃; under 0.1 Torr; flash vacuum pyrolysis;91%
9,10-dihydroanthracen-9-ol
611-63-2

9,10-dihydroanthracen-9-ol

A

anthracene
120-12-7

anthracene

B

anthracen-9(10H)-one
90-44-8

anthracen-9(10H)-one

C

9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With aluminum oxide; Ru(OH)x; oxygen In para-xylene at 129.85℃; under 760 Torr; for 0.166667h;A 91%
B 7%
C 2%
benzyl alcohol
100-51-6

benzyl alcohol

benzene
71-43-2

benzene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With aluminum (III) chloride at 60℃; for 3.5h;90.3%
With aluminium trichloride at 60℃;
With aluminium trichloride
1-(chloromethyl)-2-(phenylmethyl)benzene
7510-28-3

1-(chloromethyl)-2-(phenylmethyl)benzene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
at 575℃; under 0.1 Torr; flash vacuum pyrolysis;90%
C18H14O
93103-39-0

C18H14O

A

anthracene
120-12-7

anthracene

B

C18H14O
93103-38-9

C18H14O

Conditions
ConditionsYield
With boron trifluoride In diethyl etherA n/a
B 90%
(9,10-dihydro-9,10-anthracenylene)-3a,6a-(4,5-dihydro-1H,3H-thieno<3,4-c>thiophene)
79482-99-8

(9,10-dihydro-9,10-anthracenylene)-3a,6a-(4,5-dihydro-1H,3H-thieno<3,4-c>thiophene)

A

anthracene
120-12-7

anthracene

B

4,5-dihydro-1H,3H-thieno<3,4-c>thiophene

4,5-dihydro-1H,3H-thieno<3,4-c>thiophene

Conditions
ConditionsYield
at 700℃; under 0.001 Torr;A 90%
B 83%
1,4-dihydro-1,4-epoxyanthracene
22187-13-9

1,4-dihydro-1,4-epoxyanthracene

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With triphenyl phosphite; ammonium perrhenate In toluene at 80℃; for 18h; Inert atmosphere;90%
With isopropylmagnesium bromide In tetrahydrofuran for 2h; Heating;42%
Multi-step reaction with 2 steps
1: 95 percent / Mg / 10percent Pd/C / methanol / 25 °C
2: HCl gas / ethanol / 2 h / Heating
View Scheme
anthracene
120-12-7

anthracene

9,10-dihydroanthracene
613-31-0

9,10-dihydroanthracene

Conditions
ConditionsYield
With tetrabutylammonium tetrafluoroborate; water; lithium cation In N,N-dimethyl-formamide cathodic reduction;100%
With tetraethylammonium bromide In ethanol at 60℃; electrolysis, lead cathode;100%
With tetrabutylammonium tetrafluoroborate; water; lithium cation In N,N-dimethyl-formamide Product distribution; cathodic reduction; other hydroxy compounds, other solvent;100%
anthracene
120-12-7

anthracene

9-chloroanthracene
716-53-0

9-chloroanthracene

Conditions
ConditionsYield
With chloro-trimethyl-silane; bis-[(trifluoroacetoxy)iodo]benzene In dichloromethane at 20℃; for 18h; Reagent/catalyst; Inert atmosphere;100%
With Iodine monochloride In chloroform; acetonitrile for 3h;98.1%
With N-chloro-succinimide; dimethyl sulfoxide In chloroform at 25℃; for 12h; Schlenk technique;75%
anthracene
120-12-7

anthracene

9-Bromoanthracene
1564-64-3

9-Bromoanthracene

Conditions
ConditionsYield
With bis(trifluoroacetoxy)iodobencene; trimethylsilyl bromide In dichloromethane at 20℃; Inert atmosphere;100%
With N,N,N’,N’-tetrabromobenzene-1,3-disulfonamide In dichloromethane at 25℃; for 0.583333h;98%
With copper(ll) bromide In chloroform Reflux;94%
anthracene
120-12-7

anthracene

9,10-Dibromoanthracene
523-27-3

9,10-Dibromoanthracene

Conditions
ConditionsYield
With N-Bromosuccinimide; lithium perchlorate; silica gel In dichloromethane at 20℃; for 0.0833333h;100%
With oxygen; 1,2-dibromomethane at 20℃; for 2h;99%
With N-Bromosuccinimide; lithium perchlorate; silica gel In dichloromethane for 0.5h;99%
anthracene
120-12-7

anthracene

9,10-phenanthrenequinone
84-65-1

9,10-phenanthrenequinone

Conditions
ConditionsYield
With nicotinium dichromate In acetic acid for 0.75h; Heating;100%
With potassium bromate In acetic acid Heating;100%
With ruthenium trichloride; dihydrogen peroxide; acetic acid100%
4-Phenyl-1,2,4-triazolidine-3,5-dione
4233-33-4

4-Phenyl-1,2,4-triazolidine-3,5-dione

anthracene
120-12-7

anthracene

9,10-(4’-phenyl)urazolo-9,10-dihydroanthracene
10316-56-0

9,10-(4’-phenyl)urazolo-9,10-dihydroanthracene

Conditions
ConditionsYield
In toluene at 20℃; for 2h;100%
In chloroform-d1 at 25℃; Equilibrium constant; Temperature; Diels-Alder reaction; Darkness;84 %Spectr.
In chloroform at 24.84℃; Kinetics; Solvent; Diels-Alder Cycloaddition;
1,4-anthraquinone
635-12-1

1,4-anthraquinone

anthracene
120-12-7

anthracene

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane for 1h; Ambient temperature;100%
With aluminium trichloride In dichloromethane Diels-Alder reaction;87%
With zinc(II) chloride for 4.5h; Diels-Alder Cycloaddition; Sealed tube;87%
anthracene
120-12-7

anthracene

(E)-But-2-enedioic acid methyl ester (1S,2R,3S,4R)-4,7,7-trimethyl-3-phenylcarbamoyloxy-bicyclo[2.2.1]hept-2-yl ester
76529-71-0

(E)-But-2-enedioic acid methyl ester (1S,2R,3S,4R)-4,7,7-trimethyl-3-phenylcarbamoyloxy-bicyclo[2.2.1]hept-2-yl ester

C36H37NO6
76529-77-6

C36H37NO6

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at -30℃; for 24h;100%
anthracene
120-12-7

anthracene

trans-9,10-bis(trichlorogermyl)-9,10-dihydroanthracene

trans-9,10-bis(trichlorogermyl)-9,10-dihydroanthracene

Conditions
ConditionsYield
With oxygen; germanium hydride trichloride In benzene at 5℃; Product distribution; Mechanism;100%
anthracene
120-12-7

anthracene

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

dianthracene
1627-06-1

dianthracene

Conditions
ConditionsYield
In benzene Irradiation;100%
anthracene
120-12-7

anthracene

1,6-bis(3,5-dioxo-1,2,4-triazoline4-yl)hexane
38727-98-9

1,6-bis(3,5-dioxo-1,2,4-triazoline4-yl)hexane

C38H32N6O4

C38H32N6O4

Conditions
ConditionsYield
In dichloromethane for 0.5h; Ambient temperature;100%
fumaryl dichloride
627-63-4

fumaryl dichloride

anthracene
120-12-7

anthracene

9,10-ethenoanthracene-trans-11,12-dicarboxylic acid dichloride

9,10-ethenoanthracene-trans-11,12-dicarboxylic acid dichloride

Conditions
ConditionsYield
In toluene for 4h; Diels-Alder Cycloaddition; Reflux;100%
In toluene for 24h; Heating;36%
anthracene
120-12-7

anthracene

4-n-propyl-1,2,4-triazoline-3,5-dione
90046-99-4

4-n-propyl-1,2,4-triazoline-3,5-dione

C19H17N3O2

C19H17N3O2

Conditions
ConditionsYield
In dichloromethane for 4h; Ambient temperature;100%
anthracene
120-12-7

anthracene

Phenyl[2-(trimethylsilyl)phenyl]iodonium trifluoromethanesulfonate

Phenyl[2-(trimethylsilyl)phenyl]iodonium trifluoromethanesulfonate

triptycene
477-75-8

triptycene

Conditions
ConditionsYield
With tetrabutyl ammonium fluoride In tetrahydrofuran; dichloromethane at 20℃; for 0.5h; cycloaddition; elimination;100%
anthracene
120-12-7

anthracene

hexafluorothioacetone
1490-33-1

hexafluorothioacetone

C14H10SC(CF3)2
1539-85-1

C14H10SC(CF3)2

Conditions
ConditionsYield
100%
100%
samarium
7440-19-9

samarium

anthracene
120-12-7

anthracene

C14H10Sm

C14H10Sm

Conditions
ConditionsYield
With C2H4I2 In 1,2-dimethoxyethane activation of Sm with C2H4I2 soln. (2h,room temp.) , flask cooled to -20°C and charged with anthracene , after 2h reaction time the flask was warmed to room temp. and the mixt. stirred overnight ; suspension; not isolated , GC anal.;100%
anthracene
120-12-7

anthracene

ytterbium

ytterbium

C14H10Yb
129823-92-3

C14H10Yb

Conditions
ConditionsYield
With C2H4I2 In 1,2-dimethoxyethane activation of Yb with C2H4I2 soln. (2h,room temp.) , flask cooled to -20°C and charged with anthracene , after 2h reaction time the flask was warmed to room temp. and the mixt. stirred overnight ; suspension; not isolated , GC anal.;100%
anthracene
120-12-7

anthracene

[(1,10-fc(NSitBuMe2)2)Y(THF)]2(μ-η3:η3-(E)-stilbene)

[(1,10-fc(NSitBuMe2)2)Y(THF)]2(μ-η3:η3-(E)-stilbene)

[(1,10-fc(NSitBuMe2)2)Y(THF)]2(μ-anthracene)

[(1,10-fc(NSitBuMe2)2)Y(THF)]2(μ-anthracene)

Conditions
ConditionsYield
In benzene-d6 at 70℃; for 1.16667h; Inert atmosphere; Schlenk technique;100%
anthracene
120-12-7

anthracene

ethenetetracarbonitrile
670-54-2

ethenetetracarbonitrile

2,2,3,3-Tetracyan-1,4-(o-phenylen)-tetralin

2,2,3,3-Tetracyan-1,4-(o-phenylen)-tetralin

Conditions
ConditionsYield
at 20℃; for 0.0333333h; Diels-Alder Cycloaddition;100%
(2,4-bis(2,6-diisopropylphenylimino)pentan-3-ide-.kappa2N,N')aluminum(I)
325465-25-6

(2,4-bis(2,6-diisopropylphenylimino)pentan-3-ide-.kappa2N,N')aluminum(I)

anthracene
120-12-7

anthracene

C43H51AlN2

C43H51AlN2

Conditions
ConditionsYield
In benzene-d6 at 25 - 100℃; for 88h; Glovebox; Inert atmosphere;100%
anthracene
120-12-7

anthracene

cyclohexa-1,3-diene
1165952-91-9

cyclohexa-1,3-diene

C20H18
63840-04-0

C20H18

Conditions
ConditionsYield
With C44H36B4F4N4O8S2 In dichloromethane at 20℃; for 12h; Reagent/catalyst; Inert atmosphere; Irradiation;100%

Anthracene Chemical Properties

The Molecular Structure of Anthracene (CAS NO.120-12-7):

Empirical Formula: C14H10
Molecular Weight: 178.2292
Nominal Mass: 178 Da
Average Mass: 178.2292 Da
Monoisotopic Mass: 178.07825 Da 
Index of Refraction: 1.714
Molar Refractivity: 61.93 cm3
Molar Volume: 157.6 cm3
Surface Tension: 47.9 dyne/cm
Density: 1.13 g/cm3
Flash Point: 146.6 °C
Enthalpy of Vaporization: 55.76 kJ/mol
Boiling Point: 337.4 °C at 760 mmHg
Vapour Pressure: 0.000206 mmHg at 25°C 
Appearance:  Colourless Crystalline Solid
IUPAC Name:  anthracene 
Product Categories: Pharmaceutical Intermediates;Aromatic Compounds;Aromatics Compounds;Anthracenes;Highly Purified Reagents;Other Categories;Zone Refined Products;Aromatics;AM to AQAnalytical Standards;AromaticsChemical Class;Chemical Class;Hydrocarbons;NeatsAnalytical Standards;PAHs;ArenesEssential Chemicals;Reagent Plus;Routine Reagents;Arenes;Building Blocks;Organic Building Blocks;A;A-BAlphabetic;Alpha Sort;AM to AQ;Volatiles/ Semivolatiles;ArenesOrganic Electronics and Photonics;Light Emitters and Dopants;OLED and PLED Materials;DetectionSpectroscopy;Biochemicals and Reagents;Fluorescence/Luminescence;Fluorescent Probes, Labels, Particles and Stains;Luminescent Compounds/Detection;Scintillation reagents;Scintillation ReagentsBiochemicals and Reagents 
Synonyms: Anthracene ; AI3-00155 ; ANTHRACENE ; Anthracen ; Anthracen [German] ; Bis-alkylamino anthracene ; CCRIS 767 ; EINECS 204-371-1 ; Green Oil ; HSDB 702 ; Paranaphthalene ; Tetra Olive N2G ; Anthracene ; Anthracene, pure ; Anthracene ; Anthracene oil (coal tar fraction) ; Coal tar pitch volatiles: anthracene     

Anthracene Uses

1. Anthracene (CAS NO.120-12-7) is used in the artificial production of the red dye alizarin. It is also used in wood preservatives, insecticides, and coating materials.
2. Anthracene (CAS NO.120-12-7) is an organic semiconductor. It is used as a scintillator for detectors of high energy photons, electrons and alpha particles. Plastics such as polyvinyltoluene can be doped with anthracene to produce a plastic scintillator that is approximately water equivalent for use in radiation therapy dosimetry.

Anthracene Toxicity Data With Reference

1.    

skn-mus 118 µg MLD

    CALEDQ    Cancer Letters (Shannon, Ireland). 4 (1978),333.
2.    

mma-sat 100 µg/plate ABCHA6 43,1433,79

3.    

dns-hmn:fbr 10 mg/L

    CNREA8    Cancer Research. 38 (1978),2091.
4.    

hma-mus/sat 125 mg/kg

    JNCIAM    Journal of the National Cancer Institute. 62 (1979),911.
5.    

dnd-mam:lym 100 µmol

    BIPMAA    Biopolymers. 9 (1970),689.
6.    

orl-mus LD:>17 g/kg

    GTPZAB    Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 13 (5)(1969),59.
7.    

ipr-mus LD50:430 mg/kg

    PMRSDJ    Progress in Mutation Research. 1 (1981),682.

Anthracene Consensus Reports

IARC Cancer Review: Group 3 IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56; Animal Inadequate Evidence IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 105 ; Human No Adequate Data IMEMDT    IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 32 (1983),p. 105 . Reported in EPA TSCA Inventory. Community Right-To-Know List.

Anthracene Safety Profile

Hazard Codes: IrritantXiHarmfulXnFlammableFToxicTDangerousN
Risk Statements: 36/37/38-50/53-67-36-11-39/23/24/25-23/24/25-65-38 
R36/37/38: Irritating to eyes, respiratory system and skin
R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
R67: Vapours may cause drowsiness and dizziness
R36: Irritating to eyes
R11: Highly flammable
R23/24/25: Toxic by inhalation, in contact with skin and if swallowed
R65: Harmful: may cause lung damage if swallowed
R38: Irritating to skin
Safety Statements: 26-60-61-24/25-16-9-45-36/37-62-36 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S60: This material and its container must be disposed of as hazardous waste
S61: Avoid release to the environment. Refer to special instructions / safety data sheets
S24/25: Avoid contact with skin and eyes
S16: Keep away from sources of ignition
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S36/37: Wear suitable protective clothing and gloves
S62: If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label
S36: Wear suitable protective clothing
RIDADR: UN 3077 9/PG 3
WGK Germany: 2
HS Code: 29029010
Moderately toxic by intraperitoneal route. A skin irritant and allergen. Questionable carcinogen with experimental neoplastigenic and tumorigenic data. Combustible when exposed to heat, flame, or oxidizing materials. Moderately explosive when exposed to flame, Ca(OCl)2, chromic acid. To fight fire, use water, foam, CO2, water spray or mist, dry chemical. Explodes on contact with fluorine.

Anthracene Standards and Recommendations

OSHA PEL: TWA 0.2 mg/m3

Anthracene Analytical Methods

For occupational chemical analysis use OSHA: #ID-58 or NIOSH: Polynuclear Aromatic Hydrocarbons (HPLC), 5506; (GC), 5515.

Anthracene Specification

1. Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion. 
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam. 
2. Handling and Storage
Handling: Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes. Avoid ingestion and inhalation. 
Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

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