• Name

  BUTYL OLEATE

• EINECS 205-559-6
• CAS No. 142-77-8
• Article Data47
• CAS DataBase
• Density 0.87 g/cm³
• Solubility
• Melting Point -55 °C
• Formula C₂₂H₄₂O₂
• Boiling Point 414.9 °C at 760 mmHg
• Molecular Weight 338.574
• Flash Point 89.7 °C
• Transport Information
• Appearance
• Safety 26-36
• Risk Codes 36/37/38
• Molecular Structure
• Hazard Symbols Xi
• Synonyms Kesscoflex BO;Plasthall 914;Wilmar ButylOleate;Witcizer 100;Witcizer 101;n-Butyl oleate;9-Octadecenoicacid (Z)-, butyl ester;Oleic acid, butyl ester (6CI,7CI,8CI);Advaplast 42;Butyl (Z)-9-octadecenoate;Butyl cis-9-octadecenoate;Hallco C503;Kemester 4000;Kessco 554;SINOCHEM BOT;
• PSA 26.30000
• LogP 7.36720

Synthetic route

112-80-1

cis-Octadecenoic acid

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
Stage #1: cis-Octadecenoic acid; butan-1-ol With 1-octyl-3-methyl-imidazolium hydrogen sulfate at 28℃; for 0.166667h; Green chemistry; Stage #2: With 1-butyl-3-methylimidazolium Tetrafluoroborate at 100℃; for 8h; Reagent/catalyst; Temperature; Inert atmosphere; Green chemistry;	95.2%
With mesoporous silica modified Fe3O4 nanoparticle fabricated by 3-sulfopropyl-1-(3-propyltrimethoxysilane) imida-zolium hydrogen sulfate at 109.84℃; for 4h; Green chemistry;	91.5%
at 30℃; for 72h; Corynebacterium sp. S-401, phosphate buffer;	25%

112-62-9

Methyl oleate

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
ruthenium trichloride at 116.9℃; for 11h;
With sodium butanolate at 25℃; for 1.5h;
With CpLIP2 from Candida parapsilosis In aq. phosphate buffer at 30℃; for 0.25h; pH=6.5; Concentration; Reagent/catalyst; Enzymatic reaction;

542-69-8

1-iodo-butane

112-80-1

cis-Octadecenoic acid

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
With tetramethyl ammoniumhydroxide In methanol for 0.25h; Ambient temperature;

112-80-1

cis-Octadecenoic acid

71-36-3

butan-1-ol

A

142-77-8

oleic acid butyl ester

B

7732-18-5

water

Conditions

Conditions	Yield
Equilibrium constant; Enthalpie der Reaktion;

...Expand

109-65-9

1-bromo-butane

silver oleate

silver oleate

142-77-8

oleic acid butyl ester

112-80-1

cis-Octadecenoic acid

7664-93-9

sulfuric acid

71-36-3

butan-1-ol

A

142-77-8

oleic acid butyl ester

B

7732-18-5

water

Conditions

Conditions	Yield
Equilibrium constant; Enthalpie der Reaktion;

...Expand

122-32-7

trioleoylglycerol

71-36-3

butan-1-ol

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
With sulfuric acid at 30℃; Kinetics;
With C2F6NO4S2(1-)*C20H39N2(1+) at 60℃; Enzymatic reaction;

122-32-7

trioleoylglycerol

71-36-3

butan-1-ol

A

142-77-8

oleic acid butyl ester

B

2442-61-7, 3738-74-7, 22202-42-2, 24529-88-2, 26540-69-2, 33735-55-6, 38738-56-6, 98719-67-6

1,2-dioleoylglycerol

Conditions

Conditions	Yield
With immobilized cp283 Candida antarctica lipase B In tert-Amyl alcohol at 55℃; Enzymatic reaction;

...Expand

2566-91-8

epoxidized methyl oleate

107-66-4

dibutyl phosphate

A

112-62-9

Methyl oleate

B

142-77-8

oleic acid butyl ester

C

1842-70-2

methyl 9-oxooctadecanoate

D

10-Butoxy-9-hydroxy-octadecanoic acid methyl ester

E

C23H45O6P

Conditions

Conditions	Yield
With titanium(IV) oxide at 120℃; for 72h; Reagent/catalyst;

...Expand

111-62-6

oleic acid ethyl ester

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: CpLIP2 from Candida parapsilosis / aq. phosphate buffer / 0.25 h / 30 °C / pH 6.5 / Enzymatic reaction 2: CpLIP2 from Candida parapsilosis / aq. phosphate buffer / 0.25 h / 30 °C / pH 6.5 / Enzymatic reaction View Scheme

112-62-9

Methyl oleate

71-36-3

butan-1-ol

A

112-80-1

cis-Octadecenoic acid

B

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
With lipase/acyltransferase from Candida albicans; water In aq. phosphate buffer at 30℃; pH=6.5; Catalytic behavior; Reagent/catalyst; Enzymatic reaction;

...Expand

111-62-6

oleic acid ethyl ester

A

112-80-1

cis-Octadecenoic acid

B

142-77-8

oleic acid butyl ester

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: water; lipase/acyltransferase from Candida dubliniensis / aq. phosphate buffer / 30 °C / pH 6.5 / Enzymatic reaction 2: water; lipase/acyltransferase from Candida albicans / aq. phosphate buffer / 30 °C / pH 6.5 / Enzymatic reaction View Scheme

142-77-8

oleic acid butyl ester

70240-75-4

9,10-dihydroxyoctadecanoic acid butyl ester

Conditions

Conditions	Yield
With phosphotungstic acid; dihydrogen peroxide In isopropyl alcohol at 30 - 60℃; for 4h; Molecular sieve;	81%
Multi-step reaction with 2 steps 1: formic acid; dihydrogen peroxide / water / 6 h / 50 °C 2: phosphonic Acid / water / 3 h / 90 °C View Scheme
Stage #1: oleic acid butyl ester With formic acid; dihydrogen peroxide at 40℃; for 24h; Stage #2: With potassium carbonate In ethanol at 25℃; for 24h;	33.1 g

142-77-8

oleic acid butyl ester

A

112-92-5

1-octadecanol

B

143-28-2

oleoyl alcohol

Conditions

Conditions	Yield
With zinc chromite at 300℃; Hydrogenation;
With zinc molybdate at 300℃; Hydrogenation;

142-77-8

oleic acid butyl ester

143-28-2

oleoyl alcohol

Conditions

Conditions	Yield
With sodium; butan-1-ol

142-77-8

oleic acid butyl ester

17363-94-9, 27640-90-0, 32142-11-3, 125412-22-8, 125412-23-9, 3687-45-4

oleic acid oleylester

Conditions

Conditions	Yield
With zinc-chromium-oxide at 282℃; under 152000 Torr; Hydrogenation;

142-77-8

oleic acid butyl ester

copper-chromium-oxide

copper-chromium-oxide

112-92-5

1-octadecanol

Conditions

Conditions	Yield
at 250℃; under 147102 Torr; Hydrogenation;

142-77-8

oleic acid butyl ester

nitrogen

nitrogen

74-90-8

hydrogen cyanide

Conditions

Conditions	Yield
in fluessiger Phase mit durch elektrische Entladungen aktiviertem Stickstoff;

142-77-8

oleic acid butyl ester

71-36-3

butan-1-ol

sodium

sodium

143-28-2

oleoyl alcohol

...Expand

142-77-8

oleic acid butyl ester

zinc-chromium-oxide

zinc-chromium-oxide

A

112-92-5

1-octadecanol

B

143-28-2

oleoyl alcohol

C

oleyl oleate

oleyl oleate

Conditions

Conditions	Yield
at 280 - 300℃; under 147102 Torr; Hydrogenation;

...Expand

142-77-8

oleic acid butyl ester

56-81-5

glycerol

122-32-7

trioleoylglycerol

Conditions

Conditions	Yield
With immobilized Candida antarctica lipase B at 23℃; Enzymatic reaction;

142-77-8

oleic acid butyl ester

56-81-5

glycerol

A

111-03-5, 2716-53-2, 30836-40-9, 34487-30-4, 69483-90-5, 99297-71-9, 129784-87-8

1-monooleoyl glycerol

B

71-36-3

butan-1-ol

Conditions

Conditions	Yield
With immobilized cp283 Candida antarctica lipase B In tert-Amyl alcohol at 23℃; Kinetics; Enzymatic reaction;

...Expand

BUTYL OLEATE Chemical Properties

BUTYL OLEATE Uses

BUTYL OLEATE Toxicity Data With Reference

BUTYL OLEATE Consensus Reports

BUTYL OLEATE Safety Profile

A skin irritant. Combustible when exposed to heat or flame. To fight fire, use CO₂, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS; n-BUTYL ALCOHOL; and OLEIC ACID.
Hazard Codes:  Xi: Harmful
Risk Statements: 36/37/38: Irritating to eyes, respiratory system and skin 
Safety Statements: 26-36:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing
WGK Germany: 1