BIS(TRIPHENYLSILYL)CHROMATE 96

Reported in EPA TSCA Inventory. Chromium and its compounds are on the Community Right-To-Know List.

OSHA PEL: CL 0.1 mg(CrO₃)/m³
ACGIH TLV: TWA 0.05 mg(CrO₃)/m³
NIOSH REL: (Chromium(VI)): TWA 0.025 mg(Cr(VI))/m³; CL 0.05/15M

For occupational chemical analysis use NIOSH: Chromium Hexavalent 7024.

The Bis(triphenylsilyl) chromate, with the CAS registry number 1624-02-8, is also known as Chromic acid (H₂CrO₄), bis(triphenylsilyl) ester. It belongs to the product categories of Organometallics; Others; Oxidation; Synthetic Reagents. Its EINECS number is 216-612-8. This chemical's molecular formula is C₃₆H₃₀CrO₄Si₂ and molecular weight is 634.79. What's more, its systematic name is Dioxo[bis(triphenylsilanolato)]chromium. This chemical is stable at common pressure and temperature, and it should be sealed and stored in a ventilated and dry place. Moreover, it should be protected from light. It is commonly used as organic synthesis reagents.

Physical properties of Bis(triphenylsilyl) chromate are: (1)#H bond acceptors: 4; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 10; (4)Polar Surface Area: 52.6 Å².

When you are using this chemical, please be cautious about it as the following:
This chemical may cause sensitisation by skin contact and may cause cancer by inhalation. It is very toxic to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. In case of accident or if you feel unwell, you must seek medical advice immediately (show the label where possible). It should be avoided exposure, and you must obtain special instructions before use. This material and its container must be disposed of as hazardous waste. You should avoid releasing it to the environment, and you need to refer to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: O=[Cr](=O)(O[Si](c1ccccc1)(c2ccccc2)c3ccccc3)O[Si](c4ccccc4)(c5ccccc5)c6ccccc6
(2)Std. InChI: InChI=1S/2C18H15OSi.Cr.2O/c2*19-20(16-10-4-1-5-11-16,17-12-6-2-7-13-17)18-14-8-3-9-15-18;;;/h2*1-15H;;;/q2*-1;+2;;
(3)Std. InChIKey: AQLZCGLPNYEIDH-UHFFFAOYSA-N

The toxicity data is as follows: