Chlorodiphenylphosphine supplier

Name
Chlorodiphenylphosphine
EINECS 214-093-2
CAS No. 1079-66-9
Article Data87
CAS DataBase
Density 1.229 g/mL at 25 °C(lit.)
Solubility reacts violently with water
Melting Point 14-16 °C
Formula C₁₂H₁₀ClP
Boiling Point 319.998 °C at 760 mmHg
Molecular Weight 220.638
Flash Point 147.33 °C
Transport Information UN 3265 8/PG 2
Appearance Colorless to light yellow liquid
Safety 26-36/37/39-45-8-30-25-27
Risk Codes 14-34-29-36
Molecular Structure
Hazard Symbols C
Synonyms Phosphinouschloride, diphenyl- (6CI,8CI,9CI);Chlorodiphenylphosphine;Diphenylchlorophosphine;Diphenylphosphine chloride;Diphenylphosphinouschloride;Diphenylphosphorus chloride;NSC 60407;Phosphine, chlorodiphenyl-;
PSA 13.59000
LogP 3.27310

Synthetic route

: 4559-70-0
Diphenylphosphine oxide

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With acetyl chloride In tetrahydrofuran at 100℃; for 12h; Temperature; Reagent/catalyst; Inert atmosphere; Sealed tube;	99%
With acetyl chloride In tetrahydrofuran at 25℃; Solvent; Temperature; Reagent/catalyst; Inert atmosphere;	93%
With phosphorus trichloride In toluene at 20℃; for 1h; Inert atmosphere;

: 603-35-0
triphenylphosphine

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With zinc trifluoromethanesulfonate; phosphorus trichloride In tetrachloromethane at 0 - 60℃; for 12h;	93%
With chlorine Destillation des entstandenen Triphenylphosphindichlorids;

: 644-97-3
Dichlorophenylphosphine

: 603-35-0
triphenylphosphine

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
at 350℃; for 5h;	85%

: 97108-40-2
2-chloro-2,2-diphenyl-3,5-bis(1,1,2,2-tetrafluoroethyl)-1,4,2-dioxaphospholane

A: 756-04-7
2,2,3,3-tetrafluoropropionaldehyde

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
under 0.06 Torr; Heating;	A 55.5% B 80%

: 97108-41-3
2-chloro-3,5-bis(1,1,2,2,3,3,4,4-octafluorobutyl)-2,2-diphenyl-1,4,2-dioxaphospholane

A: 2648-47-7
2,2,3,3,4,4,5,5-octafluorovaleraldehyde

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
under 0.06 Torr; Heating;	A 45.7% B 75%
under 0.06 Torr; Heating;	A 45.7% B 75%

: 1159415-91-4, 1306641-30-4, 1306641-41-7
[Pd(BIMIONAP)Cl2]

A: C30H24Cl2N2PPd

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With tetraethylammonium chloride In acetonitrile at 50℃; for 3h; Inert atmosphere;	A 62% B n/a

: 75-77-4
chloro-trimethyl-silane

: 20472-49-5
ethyl diphenylthiophosphinite

: 100-52-7
benzaldehyde

A: 107-46-0
Hexamethyldisiloxane

B: 1079-66-9
chloro-diphenylphosphine

C: <α-(ethylthio)benzyl>diphenylphosphine sulfide

Conditions

Conditions	Yield
at 200℃; for 2h;	A 57% B n/a C 30%

...Expand

: 1,1,3,3-Tetrafluoro-4,6-bis-trifluoromethyl-1,3-dihydro-isobenzofuran

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With aluminium trichloride; phosphorus trichloride at 140 - 150℃; for 5h;	52%

: 71-43-2
benzene

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With aluminium trichloride; phosphorus trichloride for 15h; Heating;	52%
Stage #1: benzene With aluminum (III) chloride; phosphorus trichloride at 140 - 150℃; for 8.8h; Stage #2: With α-picoline at 25 - 40℃;	47.5%
Stage #1: benzene With aluminum (III) chloride; trichlorophosphate at 60℃; for 2h; Inert atmosphere; Stage #2: at 116 - 120℃; under 1275.13 - 1350.14 Torr; for 5h; Temperature; Autoclave;

: 104892-86-6
α-ethylthio-β,β,β-trichloroethyl diphenylphosphonite

A: 18271-61-9
α,β,β,β-tetrachloroethyl ethyl sulfide

B: 95028-66-3
β,β-dichlorovinyl diphenyl phosphonate

C: 20472-49-5
ethyl diphenylthiophosphinite

D: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
Product distribution; Heating; thermal decomposition;	A 41.6% B 33.3% C 42.2% D 38.7%

...Expand

: 17564-64-6
N-(chloromethyl)phthalimide

: 1636-15-3
(diethylamino)diphenylphosphine

A: 1079-66-9
chloro-diphenylphosphine

B: diethylamidodiphenyl(N-phthalimidomethyl)phosphonium chloride

Conditions

Conditions	Yield
In Petroleum ether at 90 - 100℃; for 2.5h;	A n/a B 33.7%

...Expand

: tin(ll) chloride

: 1017-89-6
diphenyltrichlorophosphorane

A: 2(C6H5)2PCl2(1+)*SnCl6(2-) = ((C6H5)2PCl2)2SnCl6

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
In dichloromethane Ar atmosphere; addn. of SnCl2 to org. compd. in CH2Cl2 with stirring; filtration, washing(CH2Cl2), drying (vac.); elem. anal.;	A 31% B n/a

...Expand

: 20472-49-5
ethyl diphenylthiophosphinite

: 100-52-7
benzaldehyde

A: 1079-66-9
chloro-diphenylphosphine

B: <α-(ethylthio)benzyl>diphenylphosphine sulfide

Conditions

Conditions	Yield
With chloro-trimethyl-silane at 200℃; for 2h; Yields of byproduct given;	A n/a B 30%

...Expand

: 71-43-2
benzene

A: 644-97-3
Dichlorophenylphosphine

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With aluminium trichloride; phosphorus trichloride at 140 - 150℃; for 5h; Product distribution; Mechanism; var. temps; var. molar proportion of reactants; var. time;	A 14% B 20%

: 1015-38-9
diphenylphosphinodithioic acid

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With chlorine beim anschliessenden Erhitzen mit rotem Phosphor;

: 28557-00-8
phenylzinc chloride

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With phosphorus trichloride

: 644-97-3
Dichlorophenylphosphine

: 587-85-9
diphenylmercury(II)

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
at 220 - 230℃;

: 644-97-3
Dichlorophenylphosphine

: 587-85-9
diphenylmercury(II)

A: 1079-66-9
chloro-diphenylphosphine

B: 1499-21-4
Diphenylphosphinic chloride

Conditions

Conditions	Yield
at 230 - 240℃;
at 230 - 240℃;

...Expand

: 644-97-3
Dichlorophenylphosphine

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
at 300℃;
With phosphorus; chlorobenzene at 380℃; for 4h; Temperature; Autoclave; Large scale;	219.5 kg

: 1017-89-6
diphenyltrichlorophosphorane

: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
With alkali metal
With magnesium
With pyrographite
With phosphorus
With phosphorous acid trimethyl ester; triethyl phosphite

: 56372-47-5
N,N-diethyl P,P-diphenylphosphinamide

A: 1079-66-9
chloro-diphenylphosphine

B: 1101-41-3
Tetraphenyldiphosphin

C: 1499-21-4
Diphenylphosphinic chloride

Conditions

Conditions	Yield
With pyridine; trichlorosilane In benzene Title compound not separated from byproducts;

...Expand

: 542-18-7
cyclohexyl chloride

: chlorodiphenylphosphonium tetrachloroaluminate

A: (C6H5)2PH2(1+)*AlCl4(1-)={(C6H5)2PH2}AlCl4

B: C18H21P*AlCl4(1-)*H(1+)

C: C18H21ClP(1+)*AlCl4(1-)

D: 1079-66-9
chloro-diphenylphosphine

...Expand

: 63507-05-1
2,2-dimethyl-1-propyl diphenylphosphinite

A: 1079-66-9
chloro-diphenylphosphine

B: C17H21OP*ClH

Conditions

Conditions	Yield
With hydrogenchloride In diethyl ether; dichloromethane-d2 at 25℃; Product distribution; Mechanism; Variation of temperature.;

: 81456-78-2
(Dichloracetyl)diphenylphosphan

A: 29804-89-5
chloroketene

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
at 80℃;

: 81456-79-3
(2,2-Dichlorpropionyl)diphenylphosphan

A: 1079-66-9
chloro-diphenylphosphine

B: 13363-86-5
chloro-methyl-ketene

Conditions

Conditions	Yield
at 90℃;

: 81456-80-6
Diphenyl(trichloracetyl)phosphan

A: 1079-66-9
chloro-diphenylphosphine

B: 1017-89-6
diphenyltrichlorophosphorane

Conditions

Conditions	Yield
at 80℃; Product distribution; in dependence on temperature, time;

: 4559-70-0
Diphenylphosphine oxide

: 1499-21-4
Diphenylphosphinic chloride

A: 1707-03-5
diphenyl-phosphinic acid

B: 1079-66-9
chloro-diphenylphosphine

Conditions

Conditions	Yield
Heating;
Heating;	A 0.209 g B n/a

...Expand

: 1-[Diphenylphosphanyl-(triphenyl-λ5-phosphanylidene)-methanesulfonyl]-4-methyl-benzene; hydrochloride

A: 1079-66-9
chloro-diphenylphosphine

B: Triphenyl-(toluene-4-sulfonylmethyl)-phosphonium; chloride

Conditions

Conditions	Yield
at -80 - -20℃;

: 756-04-7
2,2,3,3-tetrafluoropropionaldehyde

: 1079-66-9
chloro-diphenylphosphine

: 97108-40-2
2-chloro-2,2-diphenyl-3,5-bis(1,1,2,2-tetrafluoroethyl)-1,4,2-dioxaphospholane

Conditions

Conditions	Yield
In diethyl ether at 0℃; for 1h;	100%

: 2648-47-7
2,2,3,3,4,4,5,5-octafluorovaleraldehyde

: 1079-66-9
chloro-diphenylphosphine

: 97108-41-3
2-chloro-3,5-bis(1,1,2,2,3,3,4,4-octafluorobutyl)-2,2-diphenyl-1,4,2-dioxaphospholane

Conditions

Conditions	Yield
for 1h;	100%

: 1079-66-9
chloro-diphenylphosphine

: 18156-74-6
1-(Trimethylsilyl)imidazole

A: 75-77-4
chloro-trimethyl-silane

B: 54877-59-7
1-(di-phenylphosphino)imidazole

Conditions

Conditions	Yield
In dichloromethane for 1h; Ambient temperature;	A n/a B 100%

...Expand

: 1079-66-9
chloro-diphenylphosphine

: 55249-23-5
diphenylselenophosphinic chloride

Conditions

Conditions	Yield
With selenium In tetrahydrofuran at 120℃; for 3h;	100%
With selenium In toluene at 120℃; for 3h;	100%
With selenium
With selenium at 120℃; for 6h;

: 1079-66-9
chloro-diphenylphosphine

: 1101-41-3
Tetraphenyldiphosphin

Conditions

Conditions	Yield
With bis(trimethylsilyl) telluride In acetonitrile Inert atmosphere;	100%
With lithium In tetrahydrofuran	90%
With 1,1',3,3'-tetraethyl-2,2'-biimidazolidinylidene In benzene at 0℃; for 2h;	88%

: 1079-66-9
chloro-diphenylphosphine

: 23356-96-9
(S)-1-Pyrrolidin-2-yl-methanol

: 83728-79-4
(S)-(N-diphenylphosphino)(2-diphenylphosphinoxymethyl)pyrrolidine

Conditions

Conditions	Yield
With triethylamine In toluene Ambient temperature;	100%
With triethylamine In toluene at 0℃; for 16h; Yield given;
With triethylamine In toluene

: 1079-66-9
chloro-diphenylphosphine

: 95-76-1
m,p-dichloroaniline

: C18H14Cl2NP

Conditions

Conditions	Yield
	100%

: 67175-80-8
1-methoxy-4-(2-hydroxyethyl)-cyclohexa-1,4-diene

: 1079-66-9
chloro-diphenylphosphine

: C21H23O2P

Conditions

Conditions	Yield
With triethylamine In dichloromethane at 25℃; for 13h; Condensation;	100%

: 1079-66-9
chloro-diphenylphosphine

: 347143-19-5
bis[(diphenylphosphino)(2-pyridyl)amino]dimethylsilane

: 125291-85-2
N-(diphenylphosphino)-P,P-diphenyl-N-2-pyridinylphosphinous amide

Conditions

Conditions	Yield
In dichloromethane at 20℃; for 1h;	100%

: 1079-66-9
chloro-diphenylphosphine

: tetraethyl-ammonium; pyridine-2-selenolate

: C17H14NPSe

Conditions

Conditions	Yield
In acetonitrile at 0℃; for 2h;	100%

: 1079-66-9
chloro-diphenylphosphine

: 366491-14-7
1-n-butyl-3-methyl-2,3-dihydro-imidazol-2-ylidene

: 1-butyl-2-diphenylphosphanyl-3-methyl-3H-imidazol-1-ium; chloride

Conditions

Conditions	Yield
In hexane; dichloromethane at -78℃; for 1h;	100%

: 1202-34-2
di(pyridin-2-yl)amine

: 1079-66-9
chloro-diphenylphosphine

: 472959-76-5
(bis(2-pyridyl)amino)diphenylphosphane

Conditions

Conditions	Yield
With n-butyllithium In diethyl ether; hexane at 20℃; for 48h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (Z)-(R)-1-Naphthalen-1-yl-hex-4-en-3-ol

: C28H27OP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (E)-(R)-1-Naphthalen-1-yl-hex-4-en-3-ol

: C28H27OP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (E)-(R)-4-Methyl-1-naphthalen-1-yl-hex-4-en-3-ol

: C29H29OP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (E)-(R)-1-Naphthalen-1-yl-non-4-en-3-ol

: C31H33OP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (E)-(R)-5-Naphthalen-1-yl-1-pyridin-2-yl-pent-1-en-3-ol

: C32H28NOP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 1079-66-9
chloro-diphenylphosphine

: (E)-(R)-5-Methyl-1-naphthalen-1-yl-non-4-en-3-ol

: C32H35OP

Conditions

Conditions	Yield
With dmap In diethyl ether at 20℃; for 0.5h;	100%

: 60-12-8
2-phenylethanol

: 1079-66-9
chloro-diphenylphosphine

: 849604-79-1
2-phenylethyl diphenylphosphinite

Conditions

Conditions	Yield
With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h;	100%
With n-butyllithium In tetrahydrofuran at 0℃; for 1h;
With triethylamine In dichloromethane at 20℃; for 2h; Inert atmosphere;
Stage #1: 2-phenylethanol With n-butyllithium In tetrahydrofuran at 0℃; for 1h; Inert atmosphere; Schlenk technique; Stage #2: chloro-diphenylphosphine In tetrahydrofuran at 20℃; for 1h; Inert atmosphere; Schlenk technique;

: 6928-85-4
N-amino-N'-methylpiperazine

: 1079-66-9
chloro-diphenylphosphine

: 849371-46-6
1-diphenylphosphinoamino-4-methylpiperazine

Conditions

Conditions	Yield
With triethylamine In diethyl ether at 20℃; for 1h;	100%
With triethylamine In tetrahydrofuran for 5h;	85%

: 2213-43-6
1-Aminopiperidine

: 1079-66-9
chloro-diphenylphosphine

: 849371-47-7
1-diphenylphosphinoaminopiperidine

Conditions

Conditions	Yield
With triethylamine In diethyl ether at -78 - 20℃; for 1.5h;	100%

: 103-05-9
4-phenyl-2-methyl-2-butanol

: 1079-66-9
chloro-diphenylphosphine

: 820961-79-3
1,1-dimethyl-3-phenylpropyl diphenylphosphinite

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	98%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	95%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	91%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;

: 698-87-3
3-phenyl-2-propanol

: 1079-66-9
chloro-diphenylphosphine

: 1-phenylpropan-2-yl diphenylphosphinite

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%

: 2344-70-9
1-phenyl-3-butanol

: 1079-66-9
chloro-diphenylphosphine

: 820961-78-2
4-phenylbutan-2-yl diphenylphosphinite

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%
With n-butyllithium In tetrahydrofuran at 0℃; for 1h;
With n-butyllithium In tetrahydrofuran; hexane at 0℃; for 1h;
With triethylamine In chloroform-d1 at 20℃; for 2h; Reagent/catalyst; Concentration; Inert atmosphere;	86 %Spectr.

: 27544-18-9
(S)-1-(2-Naphthyl)ethanol

: 1079-66-9
chloro-diphenylphosphine

: C24H21OP

Conditions

Conditions	Yield
With dmap In tetrahydrofuran at 0℃; for 1h;	100%

: 25501-32-0
(S)-indanol

: 1079-66-9
chloro-diphenylphosphine

: C21H19OP

Conditions

Conditions	Yield
With dmap In tetrahydrofuran at 0℃; for 1h;	100%

: 114079-44-6
1-O-(tert-butyl)diphenylsilyl-1,3-butanediol

: 1079-66-9
chloro-diphenylphosphine

: 4-(t-butyldiphenylsilyloxy)butan-2-yl diphenylphosphinite

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%

: C13H20N(1-)*C6H16N2*Li(1+)

: 1079-66-9
chloro-diphenylphosphine

: 864848-06-6
(para-diphenylphosphanyl-phenyl)-(1-isopropyl-2-methyl-propyl)-amine

Conditions

Conditions	Yield
In diethyl ether; hexane at -78 - 20℃; for 18h;	100%

: 1079-66-9
chloro-diphenylphosphine

: 1730-25-2
allylmagnesium bromide

: 127686-75-3
allyl(diphenyl)phosphine-borane

Conditions

Conditions	Yield
Stage #1: chloro-diphenylphosphine With dimethylsulfide borane complex In diethyl ether at 0℃; for 2h; Stage #2: allylmagnesium bromide In diethyl ether at 0 - 20℃; for 3h;	100%

: 1079-66-9
chloro-diphenylphosphine

: 75-86-5
2-hydroxy-2-methylpropanenitrile

: 2-[(diphenylphosphino)oxy]-2-methylpropionitrile

Conditions

Conditions	Yield
With dmap; triethylamine In tetrahydrofuran at 20℃; for 2h;	100%

Chlorodiphenylphosphine Specification

The Chlorodiphenylphosphine, with the CAS registry number 1079-66-9, is also known as Phosphine, chlorodiphenyl-. It belongs to the product categories of Pharmaceutical Intermediates; Chlorophosphines; Phosphines; Ligand; Organophosphine halide. Its EINECS number is 214-093-2. This chemical's molecular formula is C₁₂H₁₀ClP and molecular weight is 220.64. What's more, its systematic name is Diphenylphosphinous chloride. It is a colourless oily liquid with a pungent odor that is often described as being garlic-like and detectable even in the ppb range. It is useful reagent for introducing the Ph₂P group into molecules, which includes many ligands. This product is used in the synthesis of various phosphines. This chemical is stable at common pressure and temperature, and it should be sealed and stored in containers with dry inert gas which are placed in a cool and dry place. Moreover, it should be protected from oxides, water, alcohol and reactive metal.

Physical properties of Chlorodiphenylphosphine are: (1)ACD/LogP: 3.601; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 3.60; (4)ACD/LogD (pH 7.4): 3.60; (5)ACD/BCF (pH 5.5): 321.32; (6)ACD/BCF (pH 7.4): 321.32; (7)ACD/KOC (pH 5.5): 2168.05; (8)ACD/KOC (pH 7.4): 2168.05; (9)#H bond acceptors: 0; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 13.59 Å²; (13)Flash Point: 147.33 °C; (14)Enthalpy of Vaporization: 53.928 kJ/mol; (15)Boiling Point: 319.998 °C at 760 mmHg ; (16)Vapour Pressure: 0.001 mmHg at 25°C.

Preparation of Chlorodiphenylphosphine: this chemical can be prepared by diphenylphosphinous acid chloride at the temperature of 350 °C. This reaction time is 5 hours. The yield is about 85%.

Chlorodiphenylphosphine can be prepared by diphenylphosphinous acid chloride at the temperature of 350 °C

Uses of Chlorodiphenylphosphine: it can be used to produce diphenylphosphinous acid methyl ester. It will need reagent triethylamine and solvent diethyl ether with the reaction time of 3 hours. The yield is about 82%.

Chlorodiphenylphosphine can be used to produce diphenylphosphinous acid methyl ester

When you are using this chemical, please be cautious about it as the following:
This chemical can cause buins, and it will react violently with water. When contact with water, it will liberate toxic gas. You must keep the container dry and never add water to this product. This product is irritating to eyes. You should avoid contact with eyes. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. When using it, you need wear suitable protective clothing, gloves and eye/face protection. You should take off immediately all contaminated clothing. In case of accident or if you feel unwell, you need to seek medical advice immediately (show the label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: ClP(c1ccccc1)c2ccccc2
(2)Std. InChI: InChI=1S/C12H10ClP/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H
(3)Std. InChIKey: XGRJZXREYAXTGV-UHFFFAOYSA-N

Product Name

Chlorodiphenylphosphine

Synthetic route

Chlorodiphenylphosphine Specification

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