Dibutyltin diacetate supplier

Name
Dibutyltin diacetate
EINECS 213-928-8
CAS No. 1067-33-0
Article Data28
CAS DataBase
Density 1.31 g/cm³
Solubility Insoluble in water
Melting Point 7-10 °C(lit.)
Formula C₁₂H₂₄O₄Sn
Boiling Point 280.688 °C at 760 mmHg
Molecular Weight 351.03
Flash Point 123.556 °C
Transport Information UN 2922 8/PG 2
Appearance clear yellow liquid.
Safety 26-36/37/39-45-37/39-28A
Risk Codes 25-34-36/38
Molecular Structure
Hazard Symbols T
Synonyms Metacure T-1;diacetoxydibutylstannane;Dibutylstannanediyl diacetate;Ba 2726;Syl-off-23A;di-n-butyltin diacetate;dibutylin diacetate;Dibutyltin Diacetate;Fomrez sul-3;dibutyl tin diacetate;
PSA 52.60000
LogP 3.15500

Synthetic route

: (C4H9)2ISnCH(CH3)CH(CH3)O2CCH3

A: 590-18-1
(Z)-2-Butene

B: iodoacetoxydibutylstannane

C: 2865-19-2
dibutyl tin diiodide

D: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) heating at 50°C for a few hours; same result in CCl4 at 50°C;	A 100% B n/a C n/a D n/a

...Expand

: (C4H9)2ISnCH(CH3)CH(CH3)O2CCH3

A: iodoacetoxydibutylstannane

B: 624-64-6
trans-2-Butene

C: 2865-19-2
dibutyl tin diiodide

D: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) heating at 50°C for a few hours; same result in CCl4 at 50°C;	A n/a B 100% C n/a D n/a

...Expand

: 10581-60-9, 69475-44-1
tin tetraacetate

: 1461-25-2
tetra-n-butyltin(IV)

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
210°C, 10 h;	73.4%

: 683-18-1
dibutyltin chloride

: 127-08-2
potassium acetate

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
With ethanol

: 1002-53-5
dibutylstannane

: 64-19-7
acetic acid

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In not given reaction at room temperature;;

: 1002-53-5
dibutylstannane

: 64-19-7
acetic acid

A: 54460-73-0
1,2-bis(acetyloxy)tetrabutyldistannane

B: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In not given reaction at room temperature;;
In not given reaction at room temperature;;

...Expand

: lead(IV) tetraacetate

: 6452-61-5
di-n-butyldiphenyltin

A: 6928-68-3
diphenyllead(IV) diacetate

B: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
boiling for 6h;;

...Expand

: 818-08-6
di(n-butyl)tin oxide

: 64-19-7
acetic acid

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
dissoln. of Sn-compd. in excess acid;

: 14764-54-6
Triacetoxybutylstannane

: 56-36-0
tributyltin acetate

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
at 180°C, 10 h;
at 250℃; for 0.5h; Product distribution / selectivity; Inert atmosphere;
at 180°C, 10 h;

: 125610-50-6
(C4H9)2Sn(CH2CH(C6H5)OCOCH3)2

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) byproducts: PhCH=CH2; thermal decompn.;

: 125610-43-7
bis(2-acetoxyethyl)dibutyltin

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: C2H4; decompn. (140°C, 3 h);

: 125610-51-7
bis(2-acetoxy-2-methylethyl)dibutyltin

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: CH3CH=CH2; thermal decompn. (80°C, 0.3 h);

: 125610-52-8
(C4H9)2Sn(CH2CH(CF3)OCOCH3)2

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; byproducts: CF3CH=CH2; thermal decompn.;

: 660402-31-3
tri-n-butyl(3-methylbutyloxy)tin

: 660402-29-9
1,1,3,3-tetrabutyl-1,3-bis(3-methylbutyloxy)distannoxane

: 108-24-7
acetic anhydride

: 64-19-7
acetic acid

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
at 155℃; for 5h; Product distribution / selectivity; Inert atmosphere;

...Expand

: 660402-29-9
1,1,3,3-tetrabutyl-1,3-bis(3-methylbutyloxy)distannoxane

: 108-24-7
acetic anhydride

A: 14764-54-6
Triacetoxybutylstannane

B: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
at 200℃; Product distribution / selectivity; Inert atmosphere;
With acetic acid Industry scale;

...Expand

: 660402-31-3
tri-n-butyl(3-methylbutyloxy)tin

: 660402-29-9
1,1,3,3-tetrabutyl-1,3-bis(3-methylbutyloxy)distannoxane

: 108-24-7
acetic anhydride

A: 1067-33-0
dibutyltin diacetate

B: 56-36-0
tributyltin acetate

Conditions

Conditions	Yield
at 25℃; for 1h; Product distribution / selectivity; Inert atmosphere;

...Expand

: 108-24-7
acetic anhydride

: 34833-46-0
1,1,3,3-tetra-n-butyl-1,3-di(n-butyloxy)-distanoxane

A: 14764-54-6
Triacetoxybutylstannane

B: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
at 200℃; for 5.3h; Product distribution / selectivity;

...Expand

: 819792-09-1
dibutyl-bis(2-ethylbutyloxy)tin

: 14764-54-6
Triacetoxybutylstannane

: 56-36-0
tributyltin acetate

: 1067-33-0
dibutyltin diacetate

Conditions

Conditions	Yield
at 250℃; for 0.5h; Product distribution / selectivity; Inert atmosphere;

...Expand

: 54460-70-7
1,1,2,2-tetrabutyl-1,2-dichloro distannane

: 1067-33-0
dibutyltin diacetate

: 683-18-1
dibutyltin chloride

: 1067-33-0
dibutyltin diacetate

: 1067-33-0
dibutyltin diacetate

: 5761-97-7
methyl(phenyl)phosphinic chloride

: 166772-38-9
[Sn(C4H9)2(O2P(CH3)(C6H5))2]

Conditions

Conditions	Yield
In toluene byproducts: CH3COCl, n-Bu2SnCl2; dry conditions; 2 d, room temp., excess of R2Sn(OAc)2; pptn., filtn., washing (PhMe, Et2O), driyng (vac.); elem. anal.;	97%
In toluene byproducts: CH3COCl, n-Bu2SnCl2; dry conditions; molar ratio R2Sn(OAc)2:chloride 1:2;
In neat (no solvent) byproducts: CH3COCl, n-Bu2SnCl2; dry conditions; molar ratio R2Sn(OAc)2:chloride 1:2;
In diethyl ether byproducts: CH3COCl, n-Bu2SnCl2; dry conditions; molar ratio R2Sn(OAc)2:chloride 1:2;

: 1067-33-0
dibutyltin diacetate

: 5761-97-7
methyl(phenyl)phosphinic chloride

: 10586-75-1
Dibutylzinn-bis-diphenylphosphonat

Conditions

Conditions	Yield
In toluene byproducts: CH3COCl; dry conditions; 2 d, room temp., excess of tin compound; pptn., filtn., washing (PhMe, Et2O), driyng (vac.); elem. anal.;	97%

: 1067-33-0
dibutyltin diacetate

: 26138-28-3
phenylytterbium iodide

: 6452-61-5
di-n-butyldiphenyltin

Conditions

Conditions	Yield
With hydrogenchloride In tetrahydrofuran byproducts: [O(YbI)2]; soln. of Yb-compd. addn. (dropwise, under Ar, Schlenk flask) with Sn-compd., stirring (2-3 h), aq. HCl addn., extraction (ether), extracts drying (MgSO4);	96%

: 1067-33-0
dibutyltin diacetate

: 1461-25-2
tetra-n-butyltin(IV)

Conditions

Conditions	Yield
With n-butyllithium In diethyl ether 0°C;	80%

: 1067-33-0
dibutyltin diacetate

: 62-55-5
thioacetamide

: 200567-57-3
(C4H9)2Sn(CH3COO)2 * (thioacetamide)2

Conditions

Conditions	Yield
In acetone mixing solns. with stirring, heating (10 min); standing (2 h, 25°C), filtration, washing (2 x acetone, Et2O), drying (owen, 110°C, 6 h, then vac. desiccator); elem. anal.;	72%

: 1067-33-0
dibutyltin diacetate

: 536-74-3
phenylacetylene

: 20662-90-2
2-methyl-4-phenyloxazole

Conditions

Conditions	Yield
With trimethylsilylazide In toluene for 4h; Time; Reflux;	66%

: 366-18-7
[2,2]bipyridinyl

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: 142-73-4
iminodiacetic acid

: 1198025-98-7
(di-n-butyltin(iminodiacetate)(H2O))2*2,2'-bipyridine

Conditions

Conditions	Yield
In ethanol; water Sn-compd. in EtOH added dropwise to a magnetically stirred iminodiaceticacid and 2,2'-bipyridine in H2O at room temp., stirred overnight, reflu xed for 6 h, cooled; elem. anal.;	64%

...Expand

: 66-71-7
1,10-Phenanthroline

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: 142-73-4
iminodiacetic acid

: 1198026-01-5
(di-n-butyltin(iminodiacetate)(H2O))2*1,10-phenanthroline

Conditions

Conditions	Yield
In ethanol; water Sn-compd. in EtOH added dropwise to a magnetically stirred iminodiaceticacid and 1,10-phenanthroline in H2O at room temp., stirred overnight, r efluxed for 6 h, cooled; elem. anal.;	64%

...Expand

: 110-99-6
2,2'-oxybis-acetic acid

: 66-71-7
1,10-Phenanthroline

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: [Sn(oxydiacetate)(1,10-phenanthroline)(H2O)2]

Conditions

Conditions	Yield
In ethanol for 4h; Reflux;	64%

...Expand

: 108-89-4
picoline

: 110-99-6
2,2'-oxybis-acetic acid

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: [(n-Bu)2Sn(oda)(4-pic)]2·2H2O

Conditions

Conditions	Yield
In ethanol at 20℃; for 5h; pH=9 - 10; Reflux;	62%

...Expand

: 98-05-5
phenylarsonic acid

: 1067-33-0
dibutyltin diacetate

: 88652-66-8
(C4H9)2Sn[C6H5AsOHO2]2

Conditions

Conditions	Yield
In methanol Sn-complex and ligand were stirred in MeOH at room temp. for ca. 12 h; filtered, washed with EtOH, dried under vac. at 20°C for 10 h; elem. anal.;	60%

: 499-83-2
Pyridine-2,6-dicarboxylic acid

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: [(n-Bu)2Sn(pda)(H2O)]2

Conditions

Conditions	Yield
With triethylamine In ethanol at 20℃; for 5h; pH=9 - 10; Reflux;	59%

...Expand

: 1067-33-0
dibutyltin diacetate

: 56-36-0
tributyltin acetate

Conditions

Conditions	Yield
270°C, 4 h;	56.2%
270°C, 4 h;	56.2%

: 110-99-6
2,2'-oxybis-acetic acid

: 366-18-7
[2,2]bipyridinyl

: 7732-18-5
water

: 1067-33-0
dibutyltin diacetate

: [Sn(oxydiacetate)(2,2'-bipyridine)(H2O)2]

Conditions

Conditions	Yield
In ethanol for 4h; Reflux;	56%

...Expand

: 3283-12-3
dimethylphosphinic acid

: 1067-33-0
dibutyltin diacetate

: 43190-16-5
di-n-butyltin dimethylphosphinate

Conditions

Conditions	Yield
In benzene room temp., 2 d; pptn., filtn., washing (C6H6, Et2O), drying (vac.); elem. anal.;	54%

: 1067-33-0
dibutyltin diacetate

: 132464-91-6
4'-isobutyl phenylacetylene

: 4-(4-isobutylphenyl)-2-methyloxazole

Conditions

Conditions	Yield
With trimethylsilylazide In toluene for 2h; Reflux;	35%

: cyano(4-isobutylphenyl)methyl diethylphosphate

: 1067-33-0
dibutyltin diacetate

: 4-(4-isobutylphenyl)-2-methyloxazole

Conditions

Conditions	Yield
With trimethylsilylazide In toluene for 2h; Reflux;	27%

: 111-20-6
1,10-decanedioic acid

: 1067-33-0
dibutyltin diacetate

: 1225070-99-4
C20H38O6Sn

Conditions

Conditions	Yield
With acetic acid In chlorobenzene at -15 - 120℃;

: 80937-33-3
oxygen

: 1067-33-0
dibutyltin diacetate

: tin(IV) oxide

Conditions

Conditions	Yield
In neat (no solvent) Ar as carrier gas; (110) Si wafers as substrate; prepn. by thermal chemical vapor deposition at 425-500°C;
In gaseous matrix dibutyltin diacetate reacted with O2, flow rate: 100 sccm using Ar carrier gas with 100 sccm, temp. 90 °C;

: 1002-53-5
dibutylstannane

: 1067-33-0
dibutyltin diacetate

: 54460-73-0
1,2-bis(acetyloxy)tetrabutyldistannane

Conditions

Conditions	Yield
In not given
bis-triphenylphosphine-palladium(II) chloride In neat (no solvent) in a Schlenk tube under N2 mixing of Sn-compds., after 5 min addn. of catalyst and stirring at room temp. for 2 h; using resulting oil without further purifn., purity (>94%) monitored by (119)Sn-NMR;

Dibutyltin diacetate Chemical Properties

MF: C₁₂H₂₄O₄Sn
MW: 351.03
EINECS: 213-928-8
mp： 7-10 °C(lit.)
bp： 142-145 °C10 mm Hg(lit.)
density： 1.32 g/mL at 25 °C(lit.)
vapor density： 12 (vs air)
vapor pressure： 1.3 mm Hg ( 25 °C)
refractive index： n20/D 1.471(lit.)
Fp： >230 °F
Water Solubility： insoluble
Synonyms:Ba 2726;ba2726;bis(acetyloxy)dibutyl-stannan;Bis(acetyloxy)dibutylstannane;bis(acetyloxy)dibutyl-Stannane;Diacetoxybutyltin;Diacetoxydibutlyltin;diacetoxydibutyl-stannan
The structure of DIACETOXYDIBUTYL STANNANE is:

Dibutyltin diacetate Toxicity Data With Reference

1、RTECS#: CAS# 1067-33-0: WH6880000
2、LD50/LC50: RTECS: CAS# 1067-33-0: Draize test, rabbit, skin: 500 mg/30M Severe;Oral, mouse: LD50 = 46 mg/kg;Oral, rat: LD50 = 32 mg/kg;Skin, rabbit: LD50 = 2318 mg/kg;
3、Carcinogenicity: Dibutyltin diacetate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
4、Other: See actual entry in RTECS for complete information. The toxicological properties have not been fully investigated.

Dibutyltin diacetate Consensus Reports

NCI Carcinogenesis Bioassay (feed); Inadequate Studies: mouse, rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-183 ,1979. Reported in EPA TSCA Inventory.

Dibutyltin diacetate Safety Profile

Hazard Codes： T
Risk Statements： 25-34-36/38
Safety Statements： 26-36/37/39-45-37/39-28A
RIDADR： UN 2922 8/PG 2
WGK Germany： 3
RTECS： WH6880000
TSCA： Yes
HazardClass： 6.1
PackingGroup： II
HS Code： 29310095
Poison by ingestion and intravenous routes. Experimental reproductive effects. Combustible when exposed to heat or flame; can react with oxidizing materials. To fight fire, use water, foam, CO₂, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

Dibutyltin diacetate Standards and Recommendations

OSHA PEL: TWA 0.1 mg(Sn)/m³ (skin)
ACGIH TLV: TWA 0.1 mg(Sn)/m³; STEL 0.2 mg(Sn)/m³ (skin).
NIOSH REL: (Organotin Compounds) TWA 0.1 mg(Sn)/m³

Dibutyltin diacetate Analytical Methods

For occupational chemical analysis use NIOSH: Organotin Compounds 5504.

Dibutyltin diacetate Specification

1、Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
2、Handling and Storage
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Take precautionary measures against static discharges. Use only in a chemical fume hood.
Storage: Store in a cool, dry place. Do not store in direct sunlight. Store in a tightly closed container.

Product Name

Dibutyltin diacetate

Synthetic route

Dibutyltin diacetate Chemical Properties

Dibutyltin diacetate Toxicity Data With Reference

Dibutyltin diacetate Consensus Reports

Dibutyltin diacetate Safety Profile

Dibutyltin diacetate Standards and Recommendations

Dibutyltin diacetate Analytical Methods

Dibutyltin diacetate Specification

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