N,N-diethyl-1,1,1-trimethylsilanamine
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
With sulfur tetrafluoride | |
With sulfur tetrafluoride In trichlorofluoromethane at -78 - -60℃; | |
With sulfur tetrafluoride In diethyl ether |
C9H13F10NOS
A
diethylamidosulfurous fluoride
B
1,1,2,2,3,3,4,4,5-nonafluoropentane
C
diethylamino-sulfur trifluoride
D
2,2,3,3,4,4,5,5-octafluoropentyl diethylamidosulfite
E
bis(2,2,3,3,4,4,5,5-octafluoropentyloxy)diethylaminofluorosulfurane
Conditions | Yield |
---|---|
under 0.05 - 0.08 Torr; Product distribution; the bath temperature gradually raised to 90 deg C; | A 1.12 g B 2.88 g C 1.6 g D 1.5 g E 3.05 g |
C9H13F10NOS
A
1,1,2,2,3,3,4,4,5-nonafluoropentane
B
diethylamino-sulfur trifluoride
C
2,2,3,3,4,4,5,5-octafluoropentyl diethylamidosulfite
D
bis(2,2,3,3,4,4,5,5-octafluoropentyloxy)diethylaminofluorosulfurane
Conditions | Yield |
---|---|
under 0.05 - 0.08 Torr; the bath temperature gradually raised to 90 deg C; Further byproducts given; | A 2.88 g B 1.6 g C 1.5 g D 3.05 g |
C11H13F14NOS
A
diethylamidosulfurous fluoride
B
diethylamino-sulfur trifluoride
C
1,1,2,2,3,3,4,4,5,5,6,6,7-tridecafluoroheptane
D
2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl diethylamidosulfite
E
bis(2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyloxy)diethylaminofluorosulfurane
Conditions | Yield |
---|---|
under 0.05 - 0.08 Torr; Product distribution; the bath temperature gradually raised to 90 deg C; | A 0.5 g B 3 g C 4.45 g D 4.2 g E 4.8 g |
C11H13F14NOS
A
diethylamidosulfurous fluoride
B
diethylamino-sulfur trifluoride
C
2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl diethylamidosulfite
D
bis(2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyloxy)diethylaminofluorosulfurane
Conditions | Yield |
---|---|
under 0.05 - 0.08 Torr; the bath temperature gradually raised to 90 deg C; Further byproducts given; | A 0.5 g B 3 g C 4.2 g D 4.8 g |
C11H13F14NOS
A
diethylamino-sulfur trifluoride
B
1,1,2,2,3,3,4,4,5,5,6,6,7-tridecafluoroheptane
C
2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyl diethylamidosulfite
D
bis(2,2,3,3,4,4,5,5,6,6,7,7-dodecafluoroheptyloxy)diethylaminofluorosulfurane
Conditions | Yield |
---|---|
under 0.05 - 0.08 Torr; the bath temperature gradually raised to 90 deg C; Further byproducts given; | A 3 g B 4.45 g C 4.2 g D 4.8 g |
triethylamine tris(hydrogen fluoride)
A
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
In [D3]acetonitrile at 20℃; for 0.166667h; Inert atmosphere; Molecular sieve; |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
In dichloromethane | 100% |
diethylamino-sulfur trifluoride
trimethyl-(1H,1H,7H-dodecafluoroheptyloxy)silane
C11H13F14NOS
Conditions | Yield |
---|---|
In diethyl ether 1.) 0 deg C - 5 deg C, 10 min; 2.) 20 deg C, 30 min.; | 99% |
diethylamino-sulfur trifluoride
trimethyl-(1H,1H,5H-octafluoropentyloxy)silane
C9H13F10NOS
Conditions | Yield |
---|---|
In diethyl ether 1.) 0 deg C - 5 deg C, 10 min; 2.) 20 deg C, 30 min.; | 99% |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
With antimony(III) chloride In dichloromethane at 20℃; for 3h; Cooling with ice; | 99% |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
In 4-(dicyanomethylene)-2-methyl-6-(p-dimethylaminostyryl)-4H-pyran at -78℃; for 0.5h; | 99% |
diethylamino-sulfur trifluoride
ethyl 2-bromophenyl-fluoroacetate
Conditions | Yield |
---|---|
In dichloromethane at -78 - 20℃; Inert atmosphere; | 98% |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
With tetrafluoroboric acid; diethyl ether at 20 - 30℃; Inert atmosphere; | 96% |
With tetrafluoroboric acid diethyl ether In diethyl ether at 20 - 30℃; for 0.833333h; Product distribution / selectivity; Inert atmosphere; | 96% |
With boron trifluoride diethyl etherate In diethyl ether at 5 - 20℃; Inert atmosphere; | 92% |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
In dichloromethane | 96% |
diethylamino-sulfur trifluoride
(trifluoromethyl)trimethylsilane
toluene-4-sulfonamide
Conditions | Yield |
---|---|
Stage #1: diethylamino-sulfur trifluoride; (trifluoromethyl)trimethylsilane With N-ethyl-N,N-diisopropylamine In dichloromethane at -20℃; for 1h; Inert atmosphere; Stage #2: toluene-4-sulfonamide In dichloromethane at 0 - 20℃; Inert atmosphere; | 95% |
Trifluoromethanesulfonamide
diethylamino-sulfur trifluoride
(trifluoromethyl)trimethylsilane
Conditions | Yield |
---|---|
Stage #1: diethylamino-sulfur trifluoride; (trifluoromethyl)trimethylsilane With N-ethyl-N,N-diisopropylamine In dichloromethane at -20℃; for 1h; Inert atmosphere; Stage #2: Trifluoromethanesulfonamide In dichloromethane at 0 - 20℃; Inert atmosphere; | 94% |
diethylamino-sulfur trifluoride
Conditions | Yield |
---|---|
In dichloromethane pptn. (hexanes); elem. anal.; | 93% |
diethylamino-sulfur trifluoride
1-(4-methyl-3-nitro-phenyl)-ethanone
Conditions | Yield |
---|---|
In dichloromethane at -40 - 60℃; for 24h; Inert atmosphere; | 93% |
diethylamino-sulfur trifluoride
boron trifluoride diethyl etherate
Conditions | Yield |
---|---|
In diethyl ether at 20 - 30℃; Inert atmosphere; Heating; Reflux; | 89% |
diethylamino-sulfur trifluoride
4-Chlorophenylboronic acid
N-(4-chlorophenylsulfinyl)-N,N-diethylamine
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 0.0833333h; Schlenk technique; | 88% |
3-Oxo-2,3,4,5,6,7-tetrahydrobenzofuran
diethylamino-sulfur trifluoride
2-(N,N-Diethyl-aminosulfanyl)-2-fluoro-4,5,6,7-tetrahydro-benzofuran-3-one
Conditions | Yield |
---|---|
87% |
The molecular structure of Diethylaminosulfur trifluoride (CAS NO.38078-09-0) is
IUPAC Name: N-ethyl-N-(trifluoro-λ4-sulfanyl)ethanamine
Molecular Formula: C4H10F3NS
Molecular Weight: 161.18g/mol
EINECS: 253-771-2
Liansport Information: UN 2920 8/PG 1
Appearance: colourless oil
Density: 1.14 g/cm3
Boiling Point: 163.7 °C at 760 mmHg
Flash Point: 23.9 °C
Solubility: reacts violently with water
Storage Temperature: 2-8°C
Freely Rotating Bonds: 3
Polar Surface Area: 3.24 Å2
Index of Refraction: 1.376
Molar Refractivity: 32.22 cm3
Molar Volume: 140.1 cm3
Surface Tension: 20.4 dyne/cm
Enthalpy of Vaporization: 40.02 kJ/mol
Vapour Pressure: 2.04 mmHg at 25°C
Product Categories: Inorganic Fluorides ; Biochemistry ; Fluorinating Reagents ; Fluorinating Reagents & Building Blocks for Fluorinated Biochemical Compounds ; Fluorination ; Halogenation ; Nucleophilic Fluorinating Reagents ; Reagents for Oligosaccharide Synthesis ; Synthetic Organic Chemistry
Diethylaminosulfur trifluoride, its CAS NO. is 38078-09-0. The chemical synonyms of Diethylaminosulfur trifluoride (CAS NO.38078-09-0) are (Beta-4)-sulfu ; (Diethylamino)trifluorosulfur ; (Diethylethan-aminato)trifluorosulfur ; (N,N-Diethylamino)sulfurtrifluoride ; (N-ethylethanaminato)-trifluorosulfur ; Diethylamino-schwefeltrifluorid ; Diethylaminotrifluorosulfur ; Ethanamine,N-ethyl-,sulfurcomplex .
Diethylaminosulfur trifluoride (CAS NO.38078-09-0) can be used in organic synthesis.
Decomposes violently above 90°C. Decomposes explosively on contact with water. When heated to decomposition it emits toxic fumes of F−, SOx, and NOx. See also FLUORIDES.
Hazard Codes: C,T,F
C: Corrosive
T: Toxic
F: Highly Flammable
Risk Statements: 10-14-20/21/22-34-5-35
5: Heating may cause an explosion
10: Flammable
14: Reacts violently with water
34: Causes burns
35: Causes severe burns
20/21/22: Harmful by inhalation, in contact with skin and if swallowed
Safety Statements: 16-26-36/37/39-45
16: Keep away from sources of ignition - No smoking
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
F 3-10-21
HazardClass: 8
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