Conditions | Yield |
---|---|
With diiron nonacarbonyl In benzene at 40 - 50℃; for 2.5h; | 90% |
With triiron dodecarbonyl at 25 - 30℃; for 1h; Irradiation; | 85% |
With potassium tert-butylate In dimethyl sulfoxide at 70℃; for 0.833333h; Inert atmosphere; | 70% |
(PMe3)2Rh(D2O)2*BF4 In water-d2 at 25℃; for 0.5h; | 95 % Spectr. |
Conditions | Yield |
---|---|
2-ethyl-N-(2-ethylhexyl)-1-hexanamine; toluene-4-sulfonic acid | 77.5% |
With quinoline; phosphorus pentoxide distillation at a bath temp. 150 deg C; | 75% |
With quinoline; phosphorus pentoxide vermutlich entsteht als Gemisch von cis- und trans-Form; | |
With sodium hydrogen sulfate vermutlich entsteht als Gemisch von cis- und trans-Form; | |
With silver-asbestos at 280℃; vermutlich entsteht als Gemisch von cis- und trans-Form; |
3-ethoxy-2-methyl-acrylic acid
A
ethyl 1-propenyl ether
B
methylammonium carbonate
ethyl 1-propenyl ether
Conditions | Yield |
---|---|
bei vorsichtigem Kochen; |
Conditions | Yield |
---|---|
With tricyclohexylphosphine[1,3-bis(2,4,6-trimethylphenyl)-4,5-dihydroimidazol-2-ylidine][benzylidene]ruthenium(II) dichloride In benzene-d6 at 60℃; for 1h; |
3-ethoxyprop-1-ene
Triethoxysilane
A
ethylpropylether
B
ethyl 1-propenyl ether
C
triethoxy(3-ethoxypropyl)silane
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; diethylene glycol dimethyl ether at 70℃; for 12h; Inert atmosphere; |
3-ethoxyprop-1-ene
tris(2-methoxyethoxy)silane
A
ethylpropylether
B
ethyl 1-propenyl ether
Conditions | Yield |
---|---|
With platinum(0)-1,3-divinyl-1,1,3,3-tetramethyldisiloxane complex In 5,5-dimethyl-1,3-cyclohexadiene; toluene at 70℃; for 12h; Inert atmosphere; |
Conditions | Yield |
---|---|
In benzene at 80℃; for 24h; | 100% |
5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide
ethyl 1-propenyl ether
Conditions | Yield |
---|---|
Stage #1: 5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide; ethyl 1-propenyl ether With triethylamine; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) In DMF (N,N-dimethyl-formamide) at 100℃; Stage #2: With hydrogenchloride; water In DMF (N,N-dimethyl-formamide) for 1.5h; | 99% |
Stage #1: 5-iodo-6-methyl-N-[4-(methylsulfonyl)benzyl]-2-oxo-1-[3-(trifluoromethyl)phenyl]-1,2-dihydropyridine-3-carboxamide; ethyl 1-propenyl ether With triethylamine; bis[1,2-bis(diphenylphosphino)ethane]palladium(0) In DMF (N,N-dimethyl-formamide) at 100℃; Stage #2: With hydrogenchloride; water In DMF (N,N-dimethyl-formamide) for 1.5h; | 99% |
ethyl 1-propenyl ether
diphenyl ketene
3-ethoxy-4-methyl-2,2-diphenylcyclobutanone
Conditions | Yield |
---|---|
In diethyl ether at 20℃; | 99% |
Conditions | Yield |
---|---|
at 0 - 20℃; for 18.33h; Inert atmosphere; | 97% |
ethyl 1-propenyl ether
1,3-Dimethyl-6-bromopteridine-2,4(1H,3H)-dione
1,3-Dimethyl-6-propionylpteridine-2,4(1H,3H)-dione
Conditions | Yield |
---|---|
Multistep reaction.; | 96% |
Conditions | Yield |
---|---|
With tris(pentafluorophenyl)borate at 110℃; for 8h; Sealed tube; | 96% |
ethyl 1-propenyl ether
(1R)-trans-5-methyl-cyclohex-2-enol
(3R,5S)-3-(2-Bromo-1-ethoxy-propoxy)-5-methyl-cyclohexene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In diethyl ether | 95% |
Conditions | Yield |
---|---|
Stage #1: ethyl 1-propenyl ether; trifluoroacetyl chloride With pyridine at -10 - 20℃; for 20h; Inert atmosphere; Stage #2: ethanol With sodium ethanolate for 0.5h; | 95% |
Stage #1: ethyl 1-propenyl ether; trifluoroacetyl chloride With pyridine at -10 - 23℃; for 20h; Inert atmosphere; Stage #2: ethanol With sodium ethanolate for 0.5h; |
ethyl 1-propenyl ether
sodium ethanolate
Trichloroacetyl chloride
ethyl (ethoxymethylene)methylacetate
Conditions | Yield |
---|---|
Stage #1: ethyl 1-propenyl ether; trifluoroacetyl chloride With pyridine at -10 - 23℃; for 20h; Inert atmosphere; Stage #2: sodium ethanolate In ethanol for 0.5h; | 95% |
Stage #1: ethyl 1-propenyl ether; trifluoroacetyl chloride With pyridine at -10 - 23℃; for 20h; Inert atmosphere; Stage #2: sodium ethanolate In ethanol for 0.5h; | |
Stage #1: ethyl 1-propenyl ether; trifluoroacetyl chloride With pyridine In dichloromethane at -10 - 23℃; for 20h; Inert atmosphere; Stage #2: sodium ethanolate for 0.5h; |
Conditions | Yield |
---|---|
In dichloromethane for 10h; Sealed tube; Inert atmosphere; Irradiation; | 95% |
ethyl 1-propenyl ether
(1R,5R)-5-methyl-2-cyclohexenol
(3R,5R)-3-(2-Bromo-1-ethoxy-propoxy)-5-methyl-cyclohexene
Conditions | Yield |
---|---|
With N-Bromosuccinimide In diethyl ether | 94% |
ethyl 1-propenyl ether
isobutyryl chloride
cis-3-ethyloxy-2,2,4-trimethylcyclobutanone
Conditions | Yield |
---|---|
With triethylamine In tetrahydrofuran at 80℃; for 3.5h; Cooling with ice; | 94% |
ethyl 1-propenyl ether
Methyl (4α,5α)-4-ethoxy-5-methylcyclopent-1-ene-1-carboxylate
Conditions | Yield |
---|---|
diethylaluminium chloride In dichloromethane at -78℃; | 93% |
ethyl 1-propenyl ether
Conditions | Yield |
---|---|
With dirhodium tetraacetate In toluene at 80℃; for 7h; Diels-Alder Cycloaddition; Inert atmosphere; chemoselective reaction; | 93% |
pentaamminetrifluoromethanesulfonato osmium(III) trifluoromethanesulfonate
ethyl 1-propenyl ether
Conditions | Yield |
---|---|
With Zn/Hg In methanol stirring (15 min), filtration; pptn. of filtrate (CH2Cl2,Et2O); elem. anal.; | 92% |
ethyl 1-propenyl ether
2,4,7,9-tetramethyl-4,7-dihydroperoxy-5,6-dioxadecane
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In isododecane at 15 - 20℃; for 0.5h; | 91% |
2-chloro-8-methyl-quinoline-3-carbaldehyde
ethyl 1-propenyl ether
3-methyl-1-(4-methylphenyl)-2-pyrazolin-5-one
Conditions | Yield |
---|---|
With triethylammonium acetate for 0.166667h; Microwave irradiation; Green chemistry; | 91% |
Conditions | Yield |
---|---|
With C29H39FO2P2Rh(1+)*C32H12BF24(1-) In acetone at 55℃; for 3h; Inert atmosphere; Glovebox; | 91% |
dimethylketene
ethyl 1-propenyl ether
cis-3-ethyloxy-2,2,4-trimethylcyclobutanone
Conditions | Yield |
---|---|
With triethylamine In various solvent(s) | 90% |
In diethyl ether at 20℃; | 88% |
Conditions | Yield |
---|---|
With copper diacetate; manganese triacetate In dichloromethane at 40℃; | 90% |
With copper diacetate; manganese triacetate In dichloromethane at 40℃; for 18h; | 90% |
ethyl 1-propenyl ether
para-methylphenylmagnesium bromide
1-methyl-4-(prop-1-enyl)benzene
Conditions | Yield |
---|---|
With C68H72Cl2N6NiP2 In tetrahydrofuran at 50℃; for 12h; Inert atmosphere; | 90% |
2-chloro-8-methyl-quinoline-3-carbaldehyde
ethyl 1-propenyl ether
edaravone
Conditions | Yield |
---|---|
With triethylammonium acetate for 0.183333h; Microwave irradiation; Green chemistry; | 90% |
ethyl 1-propenyl ether
3-chloro-1H-indole-2-carboxaldehyde
3-methyl-1-(4-methylphenyl)-2-pyrazolin-5-one
Conditions | Yield |
---|---|
With triethylammonium acetate for 0.15h; Microwave irradiation; Green chemistry; | 90% |
Conditions | Yield |
---|---|
With aluminum (III) chloride at -10 - -5℃; for 0.166667h; Reagent/catalyst; Temperature; Inert atmosphere; | 88% |
With aluminum (III) chloride at -10 - 5℃; for 0.166667h; Reagent/catalyst; Temperature; Inert atmosphere; | 88% |
With iron(III) chloride | |
With diethyl ether; boron trifluoride at 45 - 50℃; | |
With boron trifluoride diethyl etherate at 65℃; |
ethyl 1-propenyl ether
orthoformic acid triethyl ester
1,1,3,3-tetraethoxy-2-methyl-propane
Conditions | Yield |
---|---|
Stage #1: ethyl 1-propenyl ether; orthoformic acid triethyl ester With boron trifluoride diethyl etherate at 45℃; for 1h; Stage #2: With sodium carbonate at 45℃; for 3h; | 88% |
Stage #1: ethyl 1-propenyl ether; orthoformic acid triethyl ester; boron trifluoride diethyl etherate at 25℃; for 1h; Stage #2: With sodium carbonate for 1h; | 80% |
unter Zusatz des Borfluorid-Aether-Addukts; |
ethyl 1-propenyl ether
S-diethoxycarbonylmethyl O-ethyl dithiocarbonate
diethyl 2-(1-ethoxypropan-2-yl)malonate
Conditions | Yield |
---|---|
With triethyl borane; 4-tert-Butylcatechol In hexane; dichloromethane at 20℃; Giese Free Radical Synthesis; Inert atmosphere; | 88% |
2-chloro-8-methyl-quinoline-3-carbaldehyde
ethyl 1-propenyl ether
1,3-diphenyl-5-oxo-4,5-dihydro-1H-pyrazole
Conditions | Yield |
---|---|
With triethylammonium acetate for 0.15h; Microwave irradiation; Green chemistry; | 87% |
Conditions | Yield |
---|---|
With triethylammonium acetate for 0.166667h; Microwave irradiation; Green chemistry; | 87% |
ethyl 1-propenyl ether
2-diazo-1H-phenalene-1,3(2H)-dione
Conditions | Yield |
---|---|
dirhodium tetraacetate Cyclization; | 86% |
Molecular structure of Ether, ethyl propenyl (CAS NO.928-55-2) is:
Product Name: Ether, ethyl propenyl
CAS Registry Number: 928-55-2
IUPAC Name: (Z)-1-ethoxyprop-1-ene
Molecular Weight: 86.1323 [g/mol]
Molecular Formula: C5H10O
XLogP3-AA: 1.4
H-Bond Donor: 0
H-Bond Acceptor: 1
EINECS: 213-176-0
Refractive index: n20/D 1.398(lit.)
Storage temp.: Flammables area
Water Solubility: soluble
Surface Tension: 21 dyne/cm
Density: 0.775 g/cm3
Flash Point: -2 °F
Enthalpy of Vaporization: 29.71 kJ/mol
Boiling Point: 68.2 °C at 760 mmHg
Vapour Pressure: 153 mmHg at 25°C
Classification Code: Skin / Eye Irritant
Ether, ethyl propenyl (CAS NO.928-55-2) is used in organic synthesis.It is also used in coating, adhesive, additives, plasticizer, etc.
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
rabbit | LD50 | skin | 3970uL/kg (3.97mL/kg) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. | |
rat | LCLo | inhalation | 8000ppm/4H (8000ppm) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. | |
rat | LD50 | oral | 4660uL/kg (4.66mL/kg) | Toxicology and Applied Pharmacology. Vol. 28, Pg. 313, 1974. |
Hazard Codes: F, Xi
Risk Statements: 11-36/37/38
R11:Highly flammable.
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 16-26-36/37/39-37/39
S16:Keep away from sources of ignition.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S37/39:Wear suitable gloves and eye/face protection.
RIDADR: UN 3271 3/PG 2
WGK Germany: 3
RTECS: KO0525000
HazardClass: 3
PackingGroup: II
Ether, ethyl propenyl , its cas register number is 928-55-2. It also can be called 1-Ethoxy-1-propene ; 1-Ethoxypropene ; Ethyl 1-propenyl ether ; Ethyl propenyl ether ; Propenyl ethyl ether ; 1-Propene, 1-ethoxy- .It is a clear colorless to light yellow liquid.
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