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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

2-(Methylthio)benzaldehyde

Cas:7022-45-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

2-(Methylmercapto)-benzaldehyde

Cas:7022-45-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7022-45-9 with best quality

Cas:7022-45-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Benzaldehyde,2-(methylthio)- 7022-45-9

Cas:7022-45-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Qingdao Beluga Import and Export Co., LTD

2-(METHYLTHIO) BENZALDEHYDE CAS:7022-45-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organi

2-(METHYLTHIO) BENZALDEHYDE CAS:7022-45-9

Cas:7022-45-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Benzaldehyde,2-(methylthio)-

Cas:7022-45-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzaldehyde,2-(methylthio)-

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

7022-45-9 2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

2-(methylthio) Benzaldehyde

Cas:7022-45-9

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

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Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzaldehyde,2-(methylthio)-

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

2-(methylthio)Benzaldehyde

Cas:7022-45-9

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

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SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

7022-45-9 2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: 2-(METHYLTHIO) BENZALDEHYDE Synonyms: 2-(METHYLTHIO) BENZALDEHYDE;2-(Methylmercapto)-benzaldehyde;o-(Methylthio)benzaldehyde;2-(METHYLTHIO)BENZALDEHYDE / 2-THIOANISALDEHYDE;2-Methylsulfanylbenzaldehyde;2-(methylthio) Benz

7022-45-9 2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:1 Kilogram

FOB Price: $8900.0

Type:Lab/Research institutions

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

2-(methylthio) Benzaldehyde

Cas:7022-45-9

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

2-(methylthio) Benzaldehyde

Cas:7022-45-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

2-(methylthio) Benzaldehyde

Cas:7022-45-9

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

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Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

2-(Methylthio)benzaldehyde

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Manufacturers

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

2-(methylthio) Benzaldehyde

Cas:7022-45-9

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Win-Win chemical Co.Ltd

Stock products, own laboratory Package:Grams, Kilograms Application:For R&D Transportation:According to customer request Port:Shanghai

2-(Methylthio) Benzaldehyde cas no. 7022-45-9 98%

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

2-Methylthiobenzaldehyde

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

2-(Methylthio)benzaldehyde

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Aecochem Corp.

Our clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS

2-(Methylthio)Benzaldehyde

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Fandachem Co.,Ltd

FandaChem , a China-based chemical company, specialize in exporting 2-(Methylthio)benzaldehyde cas 7022-45-9 (Fandachem), Please contact us by email freely. Appearance:white crystalline powder Storage:Store in dry, dark and

2-(Methylthio)benzaldehyde cas 7022-45-9 (Fandachem)

Cas:7022-45-9

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzaldehyde,2-(methylthio)-

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

7022-45-9 2-(METHYLTHIO) BENZALDEHYDE Application:7022-45-9 2-(METHYLTHIO) BENZALDEHYDE

7022-45-9 2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Other

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Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

2-(METHYLTHIO) BENZALDEHYDE CAS No.7022-45-9

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Trading Company

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DB BIOTECH CO., LTD

best seller Application:API

2-(METHYLTHIO) BENZALDEHYDE

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Sartort Biopharma Co., Ltd

Best quality with low price Storage:ln stock Package:25kg/Barrel Application:Chemicals Transportation:Express/Sea/Air Port:Shanghai

2-(Methylthio)benzaldehyde

Cas:7022-45-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

2-(methylthio)benzyl alcohol
33384-77-9

2-(methylthio)benzyl alcohol

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With dimethylsulfide; N-succinimide; triethylamine In toluene94%
With pyridinium chlorochromate In dichloromethane at 20℃; for 1h;69%
With pyridinium chlorochromate In dichloromethane at 0 - 20℃; for 12h;65%
dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

ortho-bromobenzaldehyde
6630-33-7

ortho-bromobenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; copper(l) iodide at 130℃; for 12h; Sealed tube; Inert atmosphere;93%
2-chloro-benzaldehyde
89-98-5

2-chloro-benzaldehyde

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
In N,N,N,N,N,N-hexamethylphosphoric triamide for 5h; Heating;86%
In N,N-dimethyl-formamide at 20℃; for 44h;44%
2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

sodium thiomethoxide
5188-07-8

sodium thiomethoxide

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In dichloromethane; N,N-dimethyl-formamide at 55℃; for 24h; Inert atmosphere;85%
In N,N-dimethyl-formamide at 0.15℃; Inert atmosphere;85%
In acetonitrile Heating;
methylthiol
74-93-1

methylthiol

2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 55℃; for 24h;85%
Stage #1: methylthiol With sodium hydride In N,N-dimethyl-formamide; mineral oil at 0℃; for 1.5h; Inert atmosphere;
Stage #2: 2-Fluorobenzaldehyde In N,N-dimethyl-formamide; mineral oil at -40℃; for 2h; Inert atmosphere;
methyl sodium sulfide

methyl sodium sulfide

2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In dichloromethane; N,N-dimethyl-formamide85%
methylthiol
74-93-1

methylthiol

2-halobenzaldehyde

2-halobenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With potassium carbonate In N,N-dimethyl-formamide at 55 - 80℃; for 24h; Inert atmosphere;85%
dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

2-Fluorobenzaldehyde
446-52-6

2-Fluorobenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In water at 189℃; for 24h;64%
dimethyl sulfoxide
67-68-5

dimethyl sulfoxide

2-nitro-benzaldehyde
552-89-6

2-nitro-benzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine In water at 189℃; for 15h;56%
2-(Methylthio)thiobenzoesaeure-S-mesitylester
77418-23-6

2-(Methylthio)thiobenzoesaeure-S-mesitylester

A

2.2'-Bis(methylthio)benzil
53271-52-6

2.2'-Bis(methylthio)benzil

B

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

C

bis(2,4,6-trimethylphenyl)disulfide
1483-92-7

bis(2,4,6-trimethylphenyl)disulfide

Conditions
ConditionsYield
In benzene at 20℃; for 70h; Irradiation;A 22%
B 11%
C 41%
<2-methylthio-α-oxo-phenylmethan>-diphenylphosphin
75087-02-4

<2-methylthio-α-oxo-phenylmethan>-diphenylphosphin

A

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

B

<2-Methylthio-α-hydroxyphenylmethan>-diphenyl-phosphinoxid
75087-03-5

<2-Methylthio-α-hydroxyphenylmethan>-diphenyl-phosphinoxid

Conditions
ConditionsYield
In benzene at 22℃; for 120h; Irradiation;A 16%
B 14%
2-Methylthiobenzoesaeuremesitylester
77408-42-5

2-Methylthiobenzoesaeuremesitylester

A

2.2'-Bis(methylthio)benzil
53271-52-6

2.2'-Bis(methylthio)benzil

B

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

C

2-Methylthio-2'.4'.6'-trimethyl-biphenyl

2-Methylthio-2'.4'.6'-trimethyl-biphenyl

Conditions
ConditionsYield
In benzene at 20℃; for 77h; Irradiation;A 9%
B 7%
C 5%
N'-p-Toluolsulfonyl-N-<2-methylmercapto-benzoyl>-hydrazin
92580-60-4

N'-p-Toluolsulfonyl-N-<2-methylmercapto-benzoyl>-hydrazin

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With sodium carbonate In ethylene glycol at 160℃;
With sodium carbonate In diethylene glycol
1-chloromethyl-2-methylsulfanylbenzene
26190-68-1

1-chloromethyl-2-methylsulfanylbenzene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With hexamethylenetetramine; acetic acid
2-Methylmercaptobenzoesaeure-methylanilid
7022-44-8

2-Methylmercaptobenzoesaeure-methylanilid

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
With lithium aluminium tetrahydride In tetrahydrofuran
(i) LiAlH4, THF, (ii) aq. HCl; Multistep reaction;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

1,3-dimethyl-2-phenylimidazolidine
23229-37-0

1,3-dimethyl-2-phenylimidazolidine

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Yield given. Multistep reaction;
Dimethyldisulphide
624-92-0

Dimethyldisulphide

1,3-dimethyl-2-phenylimidazolidine
23229-37-0

1,3-dimethyl-2-phenylimidazolidine

A

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

B

1-(Bis-methylsulfanyl-methyl)-2-methylsulfanyl-benzene

1-(Bis-methylsulfanyl-methyl)-2-methylsulfanyl-benzene

Conditions
ConditionsYield
Yield given. Multistep reaction. Yields of byproduct given;
C8H10OS*C5H5N*Br3H

C8H10OS*C5H5N*Br3H

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
In acetic acid at 19.9℃; Rate constant; Kinetics; Thermodynamic data; ΔH(excit.), ΔS(excit.), ΔG(excit.), var. temp.;
2-(Methylsulfinyl)thiobenzoesaeure-S-mesitylester
77408-41-4

2-(Methylsulfinyl)thiobenzoesaeure-S-mesitylester

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 2 percent / benzene / 70 h / 20 °C / Irradiation
2: 11 percent / benzene / 70 h / 20 °C / Irradiation
View Scheme
2-methylsulfanyl-benzoyl chloride
1442-03-1

2-methylsulfanyl-benzoyl chloride

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 56 percent / toluene / 2 h / Heating
2: 7 percent / benzene / 77 h / 20 °C / Irradiation
View Scheme
Multi-step reaction with 2 steps
1: 42 percent / toluene / 2 h / Heating
2: 11 percent / benzene / 70 h / 20 °C / Irradiation
View Scheme
Multi-step reaction with 2 steps
1: 40 percent / diethyl ether
2: 16 percent / benzene / 120 h / 22 °C / Irradiation
View Scheme
Multi-step reaction with 2 steps
1: aq. NaOH / dioxane
2: LiAlH4 / tetrahydrofuran
View Scheme
ethyl 2-(methylthio)benzoate
1442-00-8

ethyl 2-(methylthio)benzoate

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: LiAlH4 / tetrahydrofuran
2: SOCl2 / benzene
3: hexamethylenetetramine, aq. AcOH
View Scheme
anthranilic acid
118-92-3

anthranilic acid

deuterium oxide

deuterium oxide

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: (i) (diazotization), (ii) aq. Na2S2, (iii) aq. Na2S2O4,(iv) (methylation)
2: (i) SOCl2, (ii) /BRN= 1718733/
3: LiAlH4 / tetrahydrofuran
4: SOCl2 / benzene
5: hexamethylenetetramine, aq. AcOH
View Scheme
2-(methylthio)benzoic acid
3724-10-5

2-(methylthio)benzoic acid

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: (i) SOCl2, (ii) /BRN= 1718733/
2: LiAlH4 / tetrahydrofuran
3: SOCl2 / benzene
4: hexamethylenetetramine, aq. AcOH
View Scheme
Multi-step reaction with 2 steps
1: (i) SOCl2, benzene, (ii) /BRN= 741982/
2: (i) LiAlH4, THF, (ii) aq. HCl
View Scheme
Multi-step reaction with 3 steps
1: SOCl2
2: aq. NaOH / dioxane
3: LiAlH4 / tetrahydrofuran
View Scheme
2-methylthiobenzohydrazide
885949-42-8

2-methylthiobenzohydrazide

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: Py
2: Na2CO3 / ethane-1,2-diol / 160 °C
View Scheme
[Rh(mer-κ3-DPEphos)(H)(C(O)C6H4SMe)][CB11H12]

[Rh(mer-κ3-DPEphos)(H)(C(O)C6H4SMe)][CB11H12]

2-(methylthio)cyclohex-1-ene-1-carbaldehyde
49571-45-1

2-(methylthio)cyclohex-1-ene-1-carbaldehyde

A

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

[Rh(mer-κ3-DPEphos)(H)(C(O)C6H8SMe)][CB11H12]

[Rh(mer-κ3-DPEphos)(H)(C(O)C6H8SMe)][CB11H12]

Conditions
ConditionsYield
at 24.84℃; for 0.0833333h; Inert atmosphere; Schlenk technique; Glovebox;
sodium thiomethoxide
5188-07-8

sodium thiomethoxide

2-halidebenzaldehyde

2-halidebenzaldehyde

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
In N,N-dimethyl-formamide
methyl 2-(methylthio)benzoate
3704-28-7

methyl 2-(methylthio)benzoate

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: lithium aluminium tetrahydride / tetrahydrofuran / 2 h / 0 °C
2: pyridinium chlorochromate / dichloromethane / 12 h / 0 - 20 °C
View Scheme
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

2-(methylsulfinyl)benzaldehyde
62351-49-9

2-(methylsulfinyl)benzaldehyde

Conditions
ConditionsYield
With C42H70O35*Br3Fe; ferric nitrate In acetonitrile at 20℃; for 3h; chemoselective reaction;100%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃;89%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane at 0 - 20℃;89%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(1R,2R)-1,2-diaminocyclohexane
20439-47-8

(1R,2R)-1,2-diaminocyclohexane

(1R,2R)-N,N'-bis[(2-(methylthio)benzylidene)]-1,2-cyclohexanediamine
1383610-91-0

(1R,2R)-N,N'-bis[(2-(methylthio)benzylidene)]-1,2-cyclohexanediamine

Conditions
ConditionsYield
In ethanol at 80℃;100%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

3,4-dichloro-benzeneacetonitrile
3218-49-3

3,4-dichloro-benzeneacetonitrile

3-amino-2-(3,4-dichlorophenyl)-1-(2-(methylthio)phenyl)propan-1-ol

3-amino-2-(3,4-dichlorophenyl)-1-(2-(methylthio)phenyl)propan-1-ol

Conditions
ConditionsYield
Stage #1: 3,4-dichloro-benzeneacetonitrile With n-butyllithium In tetrahydrofuran at -75℃; for 0.333333h;
Stage #2: 2-(methylsulfanyl)benzaldehyde In tetrahydrofuran at -75℃; for 0.5h;
Stage #3: With borane-THF In tetrahydrofuran at -75℃; Temperature; Reflux;
100%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

4-methoxy-aniline
104-94-9

4-methoxy-aniline

(E)-N-(4-methoxyphenyl)-1-(2-(methylthio)phenyl)methanimine

(E)-N-(4-methoxyphenyl)-1-(2-(methylthio)phenyl)methanimine

Conditions
ConditionsYield
In dichloromethane at 20℃; for 18h; Inert atmosphere; Molecular sieve;100%
1,1-pentamethylene-1,2-nonadiene
1173936-61-2

1,1-pentamethylene-1,2-nonadiene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

2-(cyclohexylidenemethyl)-1-(2-(methylthio)phenyl)octan-1-one
1173936-88-3

2-(cyclohexylidenemethyl)-1-(2-(methylthio)phenyl)octan-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;99%
C13H18O
1173936-62-3

C13H18O

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-2-(2-(furan-2-yl)vinyl)-1-(2-(methylthio)phenyl)octan-1-one
1173936-89-4

(E)-2-(2-(furan-2-yl)vinyl)-1-(2-(methylthio)phenyl)octan-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;99%
C13H18S
1173936-63-4

C13H18S

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-1-(2-(methylthio)phenyl)-2-(2-(thiophen-2-yl)vinyl)octan-1-one
1173936-90-7

(E)-1-(2-(methylthio)phenyl)-2-(2-(thiophen-2-yl)vinyl)octan-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(4-methylpenta-1,2-dien-1-yl)benzene
141821-03-6

(4-methylpenta-1,2-dien-1-yl)benzene

(E)-2-isopropyl-1-(2-(methylthio)phenyl)-4-phenylbut-3-en-1-one
1173936-86-1

(E)-2-isopropyl-1-(2-(methylthio)phenyl)-4-phenylbut-3-en-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

buta-1,2-diene-1,4-diyldibenzene
141821-06-9

buta-1,2-diene-1,4-diyldibenzene

(E)-2-benzyl-1-(2-(methylthio)phenyl)-4-phenylbut-3-en-1-one
1173936-85-0

(E)-2-benzyl-1-(2-(methylthio)phenyl)-4-phenylbut-3-en-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

[Rh(bis(di-tert-butylphosphino)methane)(cyclooctene)(NCCH2BF3)]
1362860-09-0

[Rh(bis(di-tert-butylphosphino)methane)(cyclooctene)(NCCH2BF3)]

acetone
67-64-1

acetone

[Rh(bis(di-tert-butylphosphino)methane)(hydrido)(κ2-(S,C)-2-SMe-C6H4CO)(NCCH2BF3)]

[Rh(bis(di-tert-butylphosphino)methane)(hydrido)(κ2-(S,C)-2-SMe-C6H4CO)(NCCH2BF3)]

Conditions
ConditionsYield
In acetone99%
(4-bromo-2-ethynylphenyl)carbamic acid 1,1-dimethylethyl ester
1038779-13-3

(4-bromo-2-ethynylphenyl)carbamic acid 1,1-dimethylethyl ester

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

tert-butyl (E)-(4-bromo-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

tert-butyl (E)-(4-bromo-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 20℃; for 0.333333h; Inert atmosphere;99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane
25015-63-8

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

C14H21BO3S

C14H21BO3S

Conditions
ConditionsYield
With C28H26FeN2S4 In benzene-d6 at 20℃; for 0.5h;99%
With [CoCl2(4'-(4-pyridyl)-2,2':6',2''-terpyridine)]·2H2O; potassium tert-butylate In tetrahydrofuran at 25℃; for 16h; Inert atmosphere; Glovebox;95 %Chromat.
With two-dimensional iron(II) coordination polymer based on a divergent 4'-(4-diphenylamino)phenyl-4,2';6',4''-terpyridine ligand; potassium tert-butylate In neat (no solvent) at 20℃; for 0.5h; Green chemistry; chemoselective reaction;88 %Chromat.
With potassium tert-butylate; Mn(2+)*C20H14N4*2Cl(1-) In tetrahydrofuran at 25℃; for 2h; Inert atmosphere; Glovebox;
With 0.55C27H43N3Si3V*0.45C27H44N3Si3V In diethyl ether at 20℃; for 2h; Inert atmosphere; Glovebox; Schlenk technique; chemoselective reaction;
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

2-ethynyl-6-methoxynaphthalene
129113-00-4

2-ethynyl-6-methoxynaphthalene

C21H18O2S

C21H18O2S

Conditions
ConditionsYield
Stage #1: 2-ethynyl-6-methoxynaphthalene With n-butyllithium In tetrahydrofuran
Stage #2: 2-(methylsulfanyl)benzaldehyde In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere;
99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

4-trifluoromethylphenylacetylene
705-31-7

4-trifluoromethylphenylacetylene

C17H13F3OS

C17H13F3OS

Conditions
ConditionsYield
Stage #1: 4-trifluoromethylphenylacetylene With n-butyllithium In tetrahydrofuran
Stage #2: 2-(methylsulfanyl)benzaldehyde In tetrahydrofuran at -78℃; for 0.5h; Inert atmosphere;
99%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

acetylenemagnesium bromide
4301-14-8

acetylenemagnesium bromide

C10H10OS

C10H10OS

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;99%
2-tert-butyl-5-methoxy-phenylamine
478701-44-9

2-tert-butyl-5-methoxy-phenylamine

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(2-tert-butyl-5-methoxy-phenyl)-(2-thiomethyl-benzylidene)-amine

(2-tert-butyl-5-methoxy-phenyl)-(2-thiomethyl-benzylidene)-amine

Conditions
ConditionsYield
In toluene Heating;98%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

2-(1,1-dimethylethyl)-benzenamine
6310-21-0

2-(1,1-dimethylethyl)-benzenamine

(2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine
958877-81-1

(2-tert-butylphenyl)-(2-thiomethyl-benzylidene)-amine

Conditions
ConditionsYield
In toluene Heating;98%
oct-1-ene
111-66-0

oct-1-ene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

1-(2-(methylthio)phenyl)nonan-1-one
1085561-73-4

1-(2-(methylthio)phenyl)nonan-1-one

Conditions
ConditionsYield
With C21H44N2P2Rh*C32H12BF24 In acetone at 55℃; for 3h; Inert atmosphere;98%
With chloro(1,5-cyclooctadiene)rhodium(I) dimer; silver perchlorate; bis[2-(diphenylphosphino)phenyl] ether In acetone at 55℃; for 24h; Inert atmosphere;73%
With potassium phosphate; chloro(1,5-cyclooctadiene)rhodium(I) dimer; (11aR)-(+)-10,11,12,13-tetrahydrodiindeno[7,1-de:1', 7'-fg][1,3,2]dioxaphosphocin-5-bis[(R)-1-phenylethyl]amine In 1,2-dichloro-ethane at 70℃; for 72h; Inert atmosphere;48%
With [Rh(η6-C6H5F)(bis(dicyclohexylphosphino)methane)][B(C6H3-3,5-(CF3)2)4] In 1,2-dichloro-ethane at 80℃; for 2h; Inert atmosphere;
With C29H39FO2P2Rh(1+)*C32H12BF24(1-) In acetone at 24.84℃; for 0.0833333h; Reagent/catalyst;
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-2-(3-methylbut-1-enyl)-1-(2-(methylthio)phenyl)heptan-1-one
1173936-82-7

(E)-2-(3-methylbut-1-enyl)-1-(2-(methylthio)phenyl)heptan-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;98%
N-methylmaleimide
930-88-1

N-methylmaleimide

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

1-methyl-3-(2-(methylthio)benzoyl)pyrrolidine-2,5-dione
1362860-36-3

1-methyl-3-(2-(methylthio)benzoyl)pyrrolidine-2,5-dione

Conditions
ConditionsYield
With C29H39FO2P2Rh(1+)*C32H12BF24(1-) In acetone at 55℃; for 3h; Inert atmosphere; Glovebox;98%
With C29H52N2P2Rh*C32H12BF24 In acetone at 55℃; for 3h; Inert atmosphere;81%
(2-propenyl)propanedioic acid diethyl ester
2049-80-1

(2-propenyl)propanedioic acid diethyl ester

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

1,3-diethyl 2-(4-(2-(methylthio)phenyl)-4-oxobutyl)malonate
1362860-33-0

1,3-diethyl 2-(4-(2-(methylthio)phenyl)-4-oxobutyl)malonate

Conditions
ConditionsYield
With C21H44N2P2Rh*C32H12BF24 In acetone at 55℃; for 3h; Inert atmosphere;98%
With [Rh(η6-C6H5F)(bis(dicyclohexylphosphino)methane)][B(C6H3-3,5-(CF3)2)4] In 1,2-dichloro-ethane at 80℃; for 2h; Inert atmosphere;
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

tert-butyl (5-chloro-2-ethynylphenyl)carbamate

tert-butyl (5-chloro-2-ethynylphenyl)carbamate

tert-butyl (E)-(5-chloro-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

tert-butyl (E)-(5-chloro-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 20℃; for 2h; Inert atmosphere;98%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

tert-butyl (4-acetyl-2-ethynylphenyl)carbamate

tert-butyl (4-acetyl-2-ethynylphenyl)carbamate

tert-butyl (E)-(4-acetyl-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

tert-butyl (E)-(4-acetyl-2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)phenyl)carbamate

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 20℃; for 0.5h; Inert atmosphere;98%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

tert-butyl (2-ethynyl-4-nitrophenyl)carbamate

tert-butyl (2-ethynyl-4-nitrophenyl)carbamate

tert-butyl (E)-(2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)-4-nitrophenyl)carbamate

tert-butyl (E)-(2-(3-(2-(methylthio)phenyl)-3-oxoprop-1-en-1-yl)-4-nitrophenyl)carbamate

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 20℃; for 0.333333h; Inert atmosphere;98%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

ethylenediamine
107-15-3

ethylenediamine

N,N-bis[(2-methylthio)phenylmethylene]-1,2-ethanediamine
90148-99-5

N,N-bis[(2-methylthio)phenylmethylene]-1,2-ethanediamine

Conditions
ConditionsYield
In acetonitrile97%
In ethanol at 80℃; Inert atmosphere;
2-ethynyl-1-nitrobenzene
16433-96-8

2-ethynyl-1-nitrobenzene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-3-(4-methoxy-2-nitrophenyl)-1-(2-(methylthio)phenyl)prop-2-en-1-one

(E)-3-(4-methoxy-2-nitrophenyl)-1-(2-(methylthio)phenyl)prop-2-en-1-one

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 55℃; for 0.25h; Inert atmosphere;97%
1-ethynyl-4-methoxy-2-nitrobenzene
889134-73-0

1-ethynyl-4-methoxy-2-nitrobenzene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-3-(4-methoxy-2-nitrophenyl)-1-(2-(methylthio)phenyl)prop-2-en-1-one

(E)-3-(4-methoxy-2-nitrophenyl)-1-(2-(methylthio)phenyl)prop-2-en-1-one

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; bis(dicyclohexylphosphino)methane In acetone at 55℃; for 0.333333h; Inert atmosphere;97%
2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

ethyl (triphenylphosphoranylidene)acetate
1099-45-2

ethyl (triphenylphosphoranylidene)acetate

o-Methylthio-zimtsaeure-aethylester
26833-02-3

o-Methylthio-zimtsaeure-aethylester

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; for 12h;97%
3-Aethyl-1.1-diphenylallen
33863-95-5

3-Aethyl-1.1-diphenylallen

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

2-ethyl-1-(2-(methylthio)phenyl)-4,4-diphenylbut-3-en-1-one
1173936-87-2

2-ethyl-1-(2-(methylthio)phenyl)-4,4-diphenylbut-3-en-1-one

Conditions
ConditionsYield
With [Rh(dppe)]ClO4 In acetone at 55℃; Inert atmosphere; regioselective reaction;96%
3-ethynylthiophene
67237-53-0

3-ethynylthiophene

2-(methylsulfanyl)benzaldehyde
7022-45-9

2-(methylsulfanyl)benzaldehyde

(E)-1-(2-(methylthio)phenyl)-3-(thiophen-3-yl)prop-2-en-1-one
1311381-67-5

(E)-1-(2-(methylthio)phenyl)-3-(thiophen-3-yl)prop-2-en-1-one

Conditions
ConditionsYield
With bis(norbornadiene)rhodium(l)tetrafluoroborate; 1,2-bis-(dicyclohexylphosphino)ethane In acetone at 20℃; for 2h; Inert atmosphere; regioselective reaction;96%

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