A poison by ingestion and inhalation. Corrosive to the skin, eye, and mucous membranes. Very unstable. A powerful oxidizer which can react violently with oxidizable materials. A very dangerous explosion hazard; it explodes on slightest provocation. The liquid explodes on freezing at −167°C. The gas explodes when exposed to sparks, flame, or on contact with grease, dust, rubber, or aqueous potassium iodide. Ignites in contact with hydrogen gas. When heated to decomposition it emits highly toxic fumes of F
− and Cl
−. See also
FLUORINE and
PERCHLORATES.