Ferbam supplier | CasNO.14484-64-1

Name
FERBAM
EINECS 238-484-2
CAS No. 14484-64-1
Article Data9
CAS DataBase
Density 0.21[at 20℃]
Solubility 130 mg l-1 (room temperature)
Melting Point 180 °C (dec.)
Formula C₉H₁₈FeN₃S₆
Boiling Point 129.4 °C at 760 mmHg
Molecular Weight 416.505
Flash Point 32 °C
Transport Information UN 3077 9/PG 3
Appearance odourless black solid
Safety 26-36/37/39-61-60
Risk Codes 36/37/38-50/53
Molecular Structure
Hazard Symbols Xi; N
Synonyms Carbamodithioic acid, dimethyl-, ironcomplex;Aafertis;Dimethyldithiocarbamic acid iron(3+)salt;Ferric N,N-dimethyldithiocarbamate;Irondimethyldithiocarbamate;Iron tris(dimethyldithiocarbamate);Liromate;Stauffer ferbam;Trimanzone;Tris(N,N-dimethyldithiocarbamato)iron;Tris(dimethyldithiocarbamato)iron;
PSA 181.89000
LogP 3.08870

Synthetic route

: Fe(diethyldithiocarbamate)2SCN

: 128-04-1
sodium dimethyldithiocarbamate

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In chloroform; acetone mixing of Fe-complex (in CHCl3) with excess of Na2S2CNEt2 (in acetone); concn. (vac.), crystn. on EtOH addn., filtration, washing (EtOH);

: iron(III)

: 128-04-1
sodium dimethyldithiocarbamate

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In water iron(III) salt;;

: tris(diethyldithiocarbamato)iron(III)

: 128-04-1
sodium dimethyldithiocarbamate

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In acetone addn. of excess NaS2CNMe2 to Fe-complex, stirring (room temp., 30 min); concn. (vac.), addn. of EtOH, concn. (vac., crystn.), filtration, washing (EtOH, acetone); elem. anal.;

: 7439-89-6
iron(II)

: 128-04-1
sodium dimethyldithiocarbamate

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In water iron(II) salt;;

: chlorobis(N,N-diethyldithiocarbamato)iron(III)

: 128-04-1
sodium dimethyldithiocarbamate

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In chloroform; acetone addn. of Fe-complex (in CHCl3) to excess of Na2S2CNMe2 (in acetone); pptn. on concn. (vac.), filtration;

: 115-09-3
methylmercury(II) chloride

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: chlorobis(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In dichloromethane room temp., 10 min (pptn.); collection, washing (CH2Cl2), drying (vac., 100°C, several days);	99%
In benzene room temp., 10 min (pptn.); collection, washing (C6H6), drying (vac., 100°C, several days); elem. anal.;	99%

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: 107-27-7
ethylmercury(II) chloride

: chlorobis(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In benzene room temp., 10 min (pptn.); collection, washing (C6H6), drying (vac., 100°C, several days);	99%
In dichloromethane room temp., 10 min (pptn.); collection, washing (CH2Cl2), drying (vac., 100°C, several days);	99%

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: tris(dimethyldithiocarbamato)iron(I2I)

Conditions

Conditions	Yield
With oxalic acid In methanol; benzene Kinetics; kinetic runs at 30°C in MeOH-C6H6, at least 10-fold excess of oxalic acid over the complex; not isolated; measuring absorbance at 348 nm;

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: 20624-25-3
sodium diethyldithiocarbamate trihydrate

: tris(diethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
In acetone addn. of excess NaS2CNEt2 to Fe-complex; concn. (vac.), addn. of EtOH (pptn.), filtration, washing (EtOH), drying (70°C);

: Cu(4+)*3(S2CN(CH3)2)(1-)*BF4(1-)={Cu(S2CN(CH3)2)3}BF4

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

A: Fe(4+)*3(S2CN(CH3)2)(1-)*BF4(1-)={Fe(S2CN(CH3)2)3}BF4

B: bis(dimethyldithiocarbamato)copper(II)

Conditions

Conditions	Yield
addn. of diethyl ether;; elem. anal.;;

...Expand

: 29972-72-3
iodine

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: Fe(3+)*2(CH3)2NCS2(1-)*(129)I2(1-)=Fe((CH3)2NCS2)2(129)I2

Conditions

Conditions	Yield
In dichloromethane addn. of hexane, mixt. was left for 3 h, crystals were collected, washed with hexane, recrystd. from CH2Cl2-hexane mixt.;

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: 79933-21-4
bis(N,N-dimethyldithiocarbamato)iron(III) diiodide

Conditions

Conditions	Yield
With iodine In dichloromethane addn. of hexane, mixt. was left for 3 h, crystals were collected, washed with hexane, recrystd. from CH2Cl2-hexane mixt.;

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: iodobis(N,N-dimethyldithiocarbamato)iron(III)

Conditions

Conditions	Yield
With iodomethane In further solvent(s) standing of Fe-complex in iodomethane (room temp., crystn.); recrystn. (CH2Cl2 or CH2Cl2/C6H6 or hexane), drying (vac., 80°C, several days);

: 14484-64-1
tris(N,N-dimethyldithiocarbamato)iron(III)

: Fe(N,N-dimethyldithiocarbamate)2I2

Conditions

Conditions	Yield
With I2 In benzene addn. of excess I2 to soln. of Fe-complex; crystn. on standing, collection, washing (C6H6), recrystn. (CH2Cl2/C6H6), drying (vac., 80°C); elem. anal.;

Ferbam Consensus Reports

IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 (1987),p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 12 (1976),p. 121.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Ferbam Standards and Recommendations

OSHA PEL: TWA Total Dust: 10 mg/m³; Respirable Fraction: 5 mg/m³
ACGIH TLV: TWA 10 mg/m³; Not Classifiable as a Human Carcinogen
DFG MAK: 15 mg/m³

Ferbam Specification

The Ferbam with CAS registry number of 14484-64-1 is also called Tris(dimethyldithiocarbamato)iron. The IUPAC name is N,N-dimethylcarbamodithioate; iron(3+). Its EINECS registry number is 238-484-2. In addition, the molecular formula is C₉H₁₈FeN₃S₆ and the molecular weight is 416.49. It is a kind of odourless black solid and belongs to the classes of Organometallics; Classes of Metal Compounds; Fe (Iron) Compounds; Transition Metal Compounds.

Physical properties about Ferbam are: (1)ACD/LogP: 0.75; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -1.06; (4)ACD/LogD (pH 7.4): -2.68; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 1; (10)Polar Surface Area: 74.13 Å²; (11)Flash Point: 32 °C; (12)Enthalpy of Vaporization: 36.7 kJ/mol; (13)Boiling Point: 129.4 °C at 760 mmHg; (14)Vapour Pressure: 10.2 mmHg at 25°C.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, respiratory system and skin. And it is very toxic to aquatic organisms. It may cause long-term adverse effects in the aquatic environment. During using it, wear suitable protective clothing, gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. This material and its container must be disposed of as hazardous waste. What's more, you should avoid release to the environment. And you can refer to special instructions/safety data sheets.

You can still convert the following datas into molecular structure:
(1)SMILES: [Fe+3].S=C([S-])N(C)C.[S-]C(=S)N(C)C.[S-]C(=S)N(C)C
(2)InChI: InChI=1/3C3H7NS2.Fe/c3*1-4(2)3(5)6;/h3*1-2H3,(H,5,6);/q;;;+3/p-3
(3)InChIKey: WHDGWKAJBYRJJL-DFZHHIFOAH

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LDLo	intraperitoneal	2300mg/kg (2300mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
guinea pig	LDLo	oral	2gm/kg (2000mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
mouse	LD50	intraperitoneal	3gm/kg (3000mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
mouse	LD50	oral	3400mg/kg (3400mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA	Journal of Toxicology and Environmental Health. Vol. 4, Pg. 93, 1978.
rabbit	LDLo	intraperitoneal	1500mg/kg (1500mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
rabbit	LDLo	oral	3gm/kg (3000mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
rat	LD50	intraperitoneal	2700mg/kg (2700mg/kg)		Journal of the American Pharmaceutical Association, Scientific Edition. Vol. 41, Pg. 662, 1952.
rat	LD50	oral	1130mg/kg (1130mg/kg)		Farmakologiya i Toksikologiya Vol. 32, Pg. 356, 1969.

Product Name

FERBAM

Synthetic route

Ferbam Consensus Reports

Ferbam Standards and Recommendations

Ferbam Specification

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