• Name

  Ferrous acetylacetonate

• EINECS 237-851-4
• CAS No. 14024-17-0
• Density
• Solubility
• Melting Point 175 °C (dec.)(lit.)
• Formula C₁₀H₁₄FeO₄
• Boiling Point 187.6oC at 760 mmHg
• Molecular Weight 254.06
• Flash Point 71.9oC
• Transport Information
• Appearance dark brown powder
• Safety 26-36
• Risk Codes 36/37/38
• Molecular Structure
• Hazard Symbols Xi
• Synonyms Iron,bis(2,4-pentanedionato)- (6CI,7CI,8CI);Iron, bis(2,4-pentanedionato-O,O')-;Bis(2,4-pentanedionato)iron;Bis(acetylacetonate)iron;Bis(acetylacetonato)iron;Ferrous acetylacetonate;Ironbis(acetylacetonate);Iron(II) acetylacetonate;NSC 141152;
• PSA 68.28000
• LogP 1.10650

Synthetic route

14024-17-0

iron(acetylacetonate)2

2Li(1+)*{(C5H3)Si2(CH3)4Si2(CH3)4(C5H3)}(2-) = Li2{(C5H3)Si2(CH3)4Si2(CH3)4(C5H3)}

51905-34-1

pentamethylcyclopentadienyllithium

135043-07-1

((C5H3)Si2(CH3)4Si2(CH3)4(C5H3))Fe

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: Li(acac), LiC5Me5; to a solution of Fe(acac)2 was added a suspension of C5Me5Li at -80°C; stirring for 30 min at -60°C; warmed at 0°C; the Si-compound was added at -70°C; warmed; stirring 1 h at room temperature; evaporated in vacuo; residue was treated with hexane; solution was evaporated; crystallization at -20°C; elem. anal.;	40%

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Ferrous acetylacetonate Specification