Product Name

  • Name

    HAFNIUMCHLORIDE

  • EINECS
  • CAS No. 37230-84-5
  • Density g/cm3
  • Solubility
  • Melting Point
  • Formula Cl4Hf
  • Boiling Point °Cat760mmHg
  • Molecular Weight 320.3
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety Poison by intraperitoneal route. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of Cl. See also HAFNIUM and CHLORIDES.
  • Risk Codes
  • Molecular Structure Molecular Structure of 37230-84-5 (HAFNIUMCHLORIDE)
  • Hazard Symbols
  • Synonyms
  • PSA 0.00000
  • LogP 0.00000

Hafnium chloride Chemical Properties

 Hafnium chloride with cas register number of 37230-84-5 is also named as Hafnium tetrachloride ; Hafnium(IV) chloride ; HfCl4 ; 590592_ALDRICH ; 51302_FLUKA ; MolPort-003-928-717 ; CID37715 ; EINECS 236-826-5 ,and so on. Hafnium chloride (CAS No.37230-84-5) is colourless solid which is the precursor to most hafnium organometallic compounds.
IUPAC Name: Tetrachlorohafnium
CAS: 37230-84-5
Molecular Formula:  Cl4Hf
Molecular Weight: 320.302
Molecular structure:
H bond acceptors:  0 
H bond donors:  0 
Freely Rotating Bonds:  0 
Enthalpy of Vaporization:  16.15 kJ/mol 
Vapour Pressure:  33900 mmHg at 25°C 
Topological Polar Surface Area: 0
Heavy Atom Count: 5
Formal Charge: 0
Complexity: 19.1
Isotope Atom Count 0
Defined Atom StereoCenter Count: 0
Undefined Atom StereoCenter Count: 0
Defined Bond StereoCenter Count: 0
Undefined Bond StereoCenter Count: 0
Covalently-Bonded Unit Count: 1

Hafnium chloride Uses

 Hafnium chloride (CAS No.37230-84-5) is commonly used as a Lewis acid and catalyst for certain alkylation and isomerism reactions. It also can be used in organic synthesis and materials science applications.

Hafnium chloride Production

 Hafnium chloride (CAS No.37230-84-5) can be prepared by following steps:
(1) the reaction of carbon tetrachloride and hafnium oxide at above 450 °C;
(2) chlorination of a mixture of HfO2 and carbon above 600 °C;
(3) chlorination of hafnium carbide above 250 °C.

Hafnium chloride Toxicity Data With Reference

1.    

skn-rbt 500 mg MLD

    34ZIAG    Toxicology of Drugs and Chemicals ,Deichmann, W.B.,New York, NY,Academic Press, Inc..: 1969,296.
2.    

orl-rat LD50:2362 mg/kg

    85GMAT    Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,71.
3.    

ipr-mus LD50:135 mg/kg

    EQSSDX    Environmental Quality and Safety, Supplement. 1 (1975),1.

Hafnium chloride Safety Profile

Poison by intraperitoneal route. Moderately toxic by ingestion. A skin irritant. When heated to decomposition it emits toxic fumes of Cl. See also HAFNIUM and CHLORIDES.

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