Product Name

  • Name

    HAFNIUM OXIDE

  • EINECS 235-013-2
  • CAS No. 12055-23-1
  • Article Data1
  • CAS DataBase
  • Density 9.68 g/mL at 25 °C(lit.)
  • Solubility Insoluble in water.
  • Melting Point 2810 °C
  • Formula HfO2
  • Boiling Point
  • Molecular Weight 210.489
  • Flash Point
  • Transport Information
  • Appearance powder
  • Safety 22-24/25
  • Risk Codes
  • Molecular Structure Molecular Structure of 12055-23-1 (HAFNIUM OXIDE)
  • Hazard Symbols
  • Synonyms Hafnia;Hafnia (HfO2);Hafnium dioxide;Hafnium dioxide (HfO2);Hafnotrast;Hf 05;Hf 05 (oxide);NSC 158931;
  • PSA 34.14000
  • LogP -0.23760

Synthetic route

hafnium

hafnium

urea hydrogen peroxide adduct
124-43-6

urea hydrogen peroxide adduct

A

hafnium dioxide
12055-23-1

hafnium dioxide

B

C

HHfO

HHfO

D

hafnium dihydroxide
91223-89-1

hafnium dihydroxide

Conditions
ConditionsYield
In gaseous matrix laser-ablated Hf atoms were reacted with H2O2 molecules in excess argon during condensation onto a 10 K cesium iodide window; Andrews, L. Chem. Soc. Rev., 2004, 33, 123; detected by IR spectra;
hafnium

hafnium

hydrogen
1333-74-0

hydrogen

oxygen
80937-33-3

oxygen

A

hafnium dioxide
12055-23-1

hafnium dioxide

B

hafnium hydroxide
12027-05-3

hafnium hydroxide

C

HHfO

HHfO

D

hafnium dihydroxide
91223-89-1

hafnium dihydroxide

E

HfH2
12770-26-2

HfH2

Conditions
ConditionsYield
In gaseous matrix byproducts: HfH4; other Radiation; laser-ablated Hf atoms were reacted with H2 and O2 molecules in excess argon full-arc irradiation and annealin to 24-30 K; Andrews, L. Chem. Soc. Rev., 2004, 33, 123; detected by IR spectra;
hafnium dioxide
12055-23-1

hafnium dioxide

phenyl chloroformate
1885-14-9

phenyl chloroformate

bis(phenyl) carbonate
102-09-0

bis(phenyl) carbonate

hafnium dioxide
12055-23-1

hafnium dioxide

phenol
108-95-2

phenol

bis(phenyl) carbonate
102-09-0

bis(phenyl) carbonate

Hafnium oxide (HfO2) Specification

The Hafnium oxide (HfO2), with its CAS registry number 12055-23-1, has the systematic name of dioxohafnium. It has the molecular foumula of HfO2 and the formula weight of 210.49. And it belongs to the product categories which include Inorganics; Hafnium; Metal and Ceramic Science; Oxides. When you are using this chemical, you should avoid contacting with skin and eyes and then do not breathe dust. This chemical is stable when in normal temperature and normal pressure. When keep this chemical, store it in the cool and well-ventilated place, away from the acid. When comes to its usage, it is often used in the spectral analysis, catalyst system and resistance material.

The characteristics of Hafnium oxide (HfO2) are as follows: (1)#H bond acceptors: 2; (2)#H bond donors: 0; (3)#Freely Rotating Bonds: 0; (4)Polar Surface Area: 34.14. As to its producing method, the hafnium could react with oxygen to produce hafnium oxide.

What's more, the following datas could be converted into the molecular structure:
(1)SMILES:O=[Hf]=O
(2)InChI:InChI=1/Hf.2O/rHfO2/c2-1-3
(3)InChIKey:CJNBYAVZURUTKZ-MSHMTBKAAI
(4)Std. InChI:InChI=1S/Hf.2O
(5)Std. InChIKey:CJNBYAVZURUTKZ-UHFFFAOYSA-N

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