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Synthetic route

sodium molybdate

sodium molybdate

ammonium dihydrogen phosphate

ammonium dihydrogen phosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
Stage #1: sodium molybdate; ammonium dihydrogen phosphate With caesium carbonate In neat (no solvent, solid phase) at 850℃; for 24h;
Stage #2: In neat (no solvent, solid phase) at 680℃; for 85h;
Stage #3: In neat (no solvent, solid phase) at 20℃; for 66h;
ammonium dihydrogen phosphate

ammonium dihydrogen phosphate

sodium carbonate
497-19-8

sodium carbonate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
Stage #1: ammonium dihydrogen phosphate; sodium carbonate In neat (no solvent, solid phase) at 350℃; for 24h;
Stage #2: In neat (no solvent, solid phase) at 600℃; for 120h; Calcination;
sodium phosphate

sodium phosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With silver cyanide In neat (no solvent) byproducts: NaCN, NaCNO, Ag; heating with AgCN in presence of (CN)2 to 270°C;;75%
With sulfur In neat (no solvent) grinding phosphate with sulfur; heating to 1000°C in quartz crucible in a stream of air (10 K/min);; detn. by 31P-NMR;
With mercury(II) cyanide In neat (no solvent) molar ratio Na3PO4:Hg(CN)2=1:1 or 2:1, heating for 1.5h;;74-77
With oxygen; Nitrogen dioxide In neat (no solvent) Kinetics; byproducts: NaNO3; mixing with NO2 and O2 directly in the quartz reaction vessel contg. Na3PO4, heating on a platinum support at different temp. for different times; not isolated; Raman, NMR;
tetrasodium pyrophosphate decahydrate

tetrasodium pyrophosphate decahydrate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; heating to 300°C for several days;;
byproducts: H2O; heating at 100-105°C to const. mass;
In solid byproducts: H2O; dehydrating the decahydrate at 130°C to constant weight;
sodium phosphate dibasic dodecahydrate

sodium phosphate dibasic dodecahydrate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O; dehydration at elevated temp., decompn. at red heat (Pt-vessel);;
In melt; neat (no solvent) byproducts: H2O; dehydration of melt in presence of 2-25% condensed phosphates; heating resulting dihydrate to 300-400°C;;
In melt; neat (no solvent) byproducts: H2O; dehydration of melt, heating resulting dihydrate to 300-400°C;;
sodium metaphposphate

sodium metaphposphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

sodium phosphate

sodium phosphate

Conditions
ConditionsYield
With H2O In water formation of orthophosphate and pyrophosphate by hydratation of metaphosphate in alkaline solns.;;
disodium hydrogenphosphate

disodium hydrogenphosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
sodium nitrate In neat (no solvent) increase of react. rate by NaNO3 (decompn. of impurities);;
With sodium nitrate In neat (no solvent) oxidation of organic material in educt mixt. by NaNO3, light product;;
With thionyl chloride In neat (no solvent) byproducts: SO2, HCl; heating on a water bath;;
sodium fluorophosphate

sodium fluorophosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In melt thermal decompn.;;
With water In water byproducts: HF; hydrolyzed at 883 K;
In neat (no solvent) on heating;;
In neat (no solvent) on heating;;
phosphorus

phosphorus

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With air In neat (no solvent) spraying Na posphates (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;;
With air In sodium hydroxide P flame, react. vessel coated with a layer of alk. orthophosphate-soln. (Na2O:P2O5=2:1), dehydration of resulting soln., calcination to Na4P2O7;;
With air In neat (no solvent) spraying sodium-phosphates-hydrate melts (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;;
Sodium trimetaphosphate

Sodium trimetaphosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With oxygen In neat (no solvent) Kinetics; on heating;;
With sodium nitrite In neat (no solvent) 240-570°C, different molar ratios of Na2O and P2O5;;
With NaNO2 In neat (no solvent) 240-570°C, different molar ratios of Na2O and P2O5;;
With O2; Na-acetate or NaNO3 or Na2CO3 In neat (no solvent) Kinetics; on heating;;
tetrasodium pyrophosphate decahydrate

tetrasodium pyrophosphate decahydrate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

water
7732-18-5

water

Conditions
ConditionsYield
In water at 80°C;;
In neat (no solvent) complete dehydration in a stream of dry NH3 within 8d;;
In neat (no solvent) isothermic dehydration at 23°C;;
In ammonia NH3 (liquid); dehydration with liquid NH3 at -78.5°C;;
phosphorus

phosphorus

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH; apparatus described;;
With oxygen In neat (no solvent) byproducts: metaphosphate; combustion of P in a vessel coated with NaCl, react. of P2O5 with molten NaCl;;
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH;;
Graham's salt

Graham's salt

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With zinc diacetate In water heating an aq. soln. with zinc acetate at 40 °C;;
With zinc acetate In water heating an aq. soln. with zinc acetate at 40 °C;;
sodium dihydrogenphosphate dihydrate

sodium dihydrogenphosphate dihydrate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent, solid phase) at 900℃; Heating;
disodium dihydrogen diphosphate 6-hydrate

disodium dihydrogen diphosphate 6-hydrate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With ammonia In neat (no solvent) byproducts: (NH4)2H2P2O7, H2O; with NH3-gas at 100°C;; product-mixture;;
With NH3 In neat (no solvent) byproducts: (NH4)2H2P2O7, H2O; with NH3-gas at 100°C;; product-mixture;;
sodium imido diphosphate 10-hydrate

sodium imido diphosphate 10-hydrate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With water In solid byproducts: NH3; moist air, at 200°C, for 0.5 and for 3 h; not isolated, detected by (31)P-NMR;
sodium monothiophosphate

sodium monothiophosphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
With air In neat (no solvent, solid phase) 315°C;
sodium phosphite

sodium phosphite

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

Sodium trimetaphosphate

Sodium trimetaphosphate

C

sodium peroxodiphosphate

sodium peroxodiphosphate

D

sodium phosphate

sodium phosphate

Conditions
ConditionsYield
With sodium hydroxide In water Electrolysis; 16 mM sodium phosphite was electrolyzed on B-doped diamond electrode at pH 12 (1 N NaOH) and 20°C for 500 min; ion chromy.;
With sulfuric acid In water Electrolysis; 9.7-29 mM sodium phosphite was electrolyzed on B-doped diamond electrodeat pH 2 or 7 (1 N H2SO4) and 10-40°C for 500 min; ion chromy.;
sodium cyanide
773837-37-9

sodium cyanide

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With sodium hypophosphate; oxygen In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;;
With NaPO3; O2 In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;;
sodium subphosphate

sodium subphosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With nitric acid In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;;
With HNO3 In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;;
NaHPO3

NaHPO3

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With nitric acid In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;;
With HNO3 In not given evapn. of Na2PO3 soln. in platinum crucible; oxidation (HNO3) and calcination;;
disodium pyrophoshate

disodium pyrophoshate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With sodium hydroxide In not given pptn. of Na4P2O7 from a soln. satd. with NaOH;;
With NaOH In not given pptn. of Na4P2O7 from a soln. satd. with NaOH;;
Sodium tripolyphosphate

Sodium tripolyphosphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

Phosphate
14265-44-2

Phosphate

Conditions
ConditionsYield
With water In water Kinetics; 100°C; NMR monitoring;
With water; urea In water Kinetics; 100°C; NMR monitoring;
tetrasodium hypophosphate*10H2O

tetrasodium hypophosphate*10H2O

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With nitric acid In neat (no solvent) oxidation with HNO3 and then calcinated;;>99
With HNO3 In neat (no solvent) oxidation with HNO3 and then calcinated;;>99
{Co(NH3)6}(3+)*Na(1+)*P2O7(4-)*11.5H2O={Co(NH3)6}NaP2O7*11.5H2O

{Co(NH3)6}(3+)*Na(1+)*P2O7(4-)*11.5H2O={Co(NH3)6}NaP2O7*11.5H2O

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

4{Co(NH3)6}(3+)*3P2O7(4-)*20H2O={Co(NH3)6}4(P2O7)3*20H2O

4{Co(NH3)6}(3+)*3P2O7(4-)*20H2O={Co(NH3)6}4(P2O7)3*20H2O

Conditions
ConditionsYield
With water In water hot H2O;;
With H2O In water hot H2O;;
sodium phosphate

sodium phosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With silver cyanide In neat (no solvent) byproducts: NaCN, NaCNO, Ag; heating with AgCN in presence of (CN)2 to 270°C;;75%
With sulfur In neat (no solvent) grinding phosphate with sulfur; heating to 1000°C in quartz crucible in a stream of air (10 K/min);; detn. by 31P-NMR;
With mercury(II) cyanide In neat (no solvent) molar ratio Na3PO4:Hg(CN)2=1:1 or 2:1, heating for 1.5h;;74-77
With oxygen; Nitrogen dioxide In neat (no solvent) Kinetics; byproducts: NaNO3; mixing with NO2 and O2 directly in the quartz reaction vessel contg. Na3PO4, heating on a platinum support at different temp. for different times; not isolated; Raman, NMR;
aluminum oxide
1333-84-2, 1344-28-1

aluminum oxide

Sodium tripolyphosphate

Sodium tripolyphosphate

phosphorus oxynitride
23369-45-1

phosphorus oxynitride

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

Na3AlP3O9N

Na3AlP3O9N

Conditions
ConditionsYield
In neat (no solvent) heating in a sintered corund crucible at 800°C for 90 min, at 480°C for 120 min.;; extn. of byproducts (aq. HCl); elem. anal.;;A n/a
B 64.9%
silver(I) cyanide
506-64-9

silver(I) cyanide

sodium phosphate

sodium phosphate

A

sodium cyanide
773837-37-9

sodium cyanide

B

sodium pyrophosphate
124-43-6

sodium pyrophosphate

C

sodium isocyanate
917-61-3

sodium isocyanate

Conditions
ConditionsYield
In neat (no solvent) byproducts: Ag; heating dry Na3PO4 with AgCN at 270°C;;
In neat (no solvent) byproducts: Ag; at 270°C;;
In neat (no solvent) byproducts: Ag; heating dry Na3PO4 with AgCN at 270°C;;
disodium hydrogenphosphate

disodium hydrogenphosphate

sodium phosphite

sodium phosphite

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2; 400-900°C, small excess of Na2HPO4 needed to avoid formation of PH3;;
zinc pyrophosphate

zinc pyrophosphate

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: ZnCl2; calcination;;
In neat (no solvent) byproducts: ZnCl2; calcination;;
zinc pyrophosphate

zinc pyrophosphate

sodium chloride
7647-14-5

sodium chloride

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

zinc(II) chloride
7646-85-7

zinc(II) chloride

Conditions
ConditionsYield
In neat (no solvent) calcination of NaCl with Zn2P4O7;; evaporation of ZnCl2;;
iron(III) oxide

iron(III) oxide

Sodium tripolyphosphate

Sodium tripolyphosphate

Sodium trimetaphosphate

Sodium trimetaphosphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

6Na(1+)*2Fe(3+)*3P2O7(4-)=Na6Fe2(P2O7)3

6Na(1+)*2Fe(3+)*3P2O7(4-)=Na6Fe2(P2O7)3

Conditions
ConditionsYield
In further solvent(s) dissolution mechanism for 30 mole% NaCl + 70 mole% NaPO3 at 700°C;
sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In water spraying method using NaH2PO4 soln. (from neutralization of H3PO4 with Na2CO3);;
In neat (no solvent) prepn. by calcination at 800°C;
sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With ammonia In neat (no solvent) byproducts: NH4Cl; heating in presence of NH3, sublimation of NH4Cl;;
sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

sodium hydrogen monothiophosphate

sodium hydrogen monothiophosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: Na4P2O6S; at 224°C;;
In neat (no solvent) byproducts: Na4P2O6S; at 224°C;;
disodium hydrogenphosphate

disodium hydrogenphosphate

sodium dihydrogenphosphate
10049-21-5

sodium dihydrogenphosphate

A

disodium pyrophoshate

disodium pyrophoshate

B

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) on heating a stoichiometric mixture;; product mixture;;
sulfur dioxide
7446-09-5

sulfur dioxide

sodium phosphate

sodium phosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With oxygen Kinetics; byproducts: Na2SO3, Na2SO4; at heating from 200°C up to 1000°C; raman spectroscopy; NMR;
sulfur dioxide
7446-09-5

sulfur dioxide

sodium phosphate

sodium phosphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

sodium sulfate
7757-82-6

sodium sulfate

Conditions
ConditionsYield
In neat (no solvent) byproducts: sulfur; heating of Na3PO4 in a SO2 atmosphere at 400-1000°C; not separated, detected by Raman-, (31)P-NMR-spectroscopy and X-ray diffraction;;
mercury(II) cyanide
592-04-1

mercury(II) cyanide

sodium phosphate

sodium phosphate

A

sodium cyanide
773837-37-9

sodium cyanide

B

sodium pyrophosphate
124-43-6

sodium pyrophosphate

C

sodium isocyanate
917-61-3

sodium isocyanate

Conditions
ConditionsYield
In neat (no solvent) heating at 300°C;;
In neat (no solvent) heating at 300°C;;
sodium metaphposphate

sodium metaphposphate

sodium fluoride

sodium fluoride

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

fluorine
7782-41-4

fluorine

Conditions
ConditionsYield
With oxygen
phosphorus

phosphorus

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH; apparatus described;;
With oxygen In neat (no solvent) byproducts: metaphosphate; combustion of P in a vessel coated with NaCl, react. of P2O5 with molten NaCl;;
With air In sodium hydroxide spraying NaCl into a P flame (introduction of excess air and H2O vapor), sepn. of volatile impurities, react. of generated metaphosphates with aq. NaOH;;
lead(II) pyrophosphate

lead(II) pyrophosphate

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) byproducts: PbCl2; calcination;;
In neat (no solvent) byproducts: PbCl2; calcination;;
lead(II) pyrophosphate

lead(II) pyrophosphate

sodium chloride
7647-14-5

sodium chloride

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

lead(II) chloride

lead(II) chloride

Conditions
ConditionsYield
In neat (no solvent) calcination of NaCl with Pb2P4O7;; evaporating of PbCl2;;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In water byproducts: HCl; heating H3PO4 and NaCl until formation of HCl is finished, concg. of melt with H2O (150-250°C, 7-14 atm); addn. of Ca(OH)2 to the filtarte until a ratio of Na2P:P2O5=2;1 is reached, evapn. of filtrate, heating to ca. 550° for 45-60 min;;
In neat (no solvent) byproducts: HCl, H2O; calcination;;
In neat (no solvent) byproducts: HCl; heating to red heat in presence of SiO2;;
In neat (no solvent) byproducts: HCl, H2O; calcination;;
phosphorus pentoxide

phosphorus pentoxide

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With oxygen In neat (no solvent) byproducts: Cl2; at about 1000°C, exclusion of H2O;;
sodium metaphposphate

sodium metaphposphate

sodium chloride
7647-14-5

sodium chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With O2
tellurium(IV) oxide
7446-07-3

tellurium(IV) oxide

sodium metaphposphate

sodium metaphposphate

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

sodium tetraphosphate

sodium tetraphosphate

C

sodium phosphate

sodium phosphate

Conditions
ConditionsYield
In neat (no solvent) 1123 K, 0.5 h; quenching, paper chromy.;
phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

sodium cation
17341-25-2

sodium cation

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In water evapn. of a mixt. of H3PO4 with Na salts of volatile acids, molar ratio Na2O:P2O5=2:1;;
In water purifn. of H3PO4 by addn. of Ca(OH)2 or CaO, pptn. of impurities, addn. of Na(1+) to the filtrate until a ratio Na2O:P2O5=2:1 is reached;;
phosphorus

phosphorus

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With air In neat (no solvent) spraying Na posphates (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;;
With air In sodium hydroxide P flame, react. vessel coated with a layer of alk. orthophosphate-soln. (Na2O:P2O5=2:1), dehydration of resulting soln., calcination to Na4P2O7;;
With air In neat (no solvent) spraying sodium-phosphates-hydrate melts (Na2O:P2O5 >2:1) into a P flame, temp. up to 1000°C;;
phosphorus

phosphorus

sodium hydroxide
1310-73-2

sodium hydroxide

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With air In neat (no solvent) spraying solid NaOH into a P flame, temp. up to 1000°C;;
Sodium trimetaphosphate

Sodium trimetaphosphate

silicon
7440-21-3

silicon

A

sodium pyrophosphate
124-43-6

sodium pyrophosphate

B

phosphorus

phosphorus

Conditions
ConditionsYield
In neat (no solvent) Kinetics; evacuated quartz vessel, 700-1000°C, condensation in cold zone; yield depending on educt ratio, reaction time and temperature; product mixt. not sepd., detd. by powder X-ray diffraction and (31)P-NMRspectroscopy;
disodium dihydrogen pyrophosphate

disodium dihydrogen pyrophosphate

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In neat (no solvent) heating recrystd. educt to about 110°C, then for 1h to red heat;; recrystn., heating; very pure product;;
In neat (no solvent) heating recrystd. educt to about 110°C, then for 1h to red heat;; recrystn., heating; very pure product;;
disodium hydrogenphosphate

disodium hydrogenphosphate

thionyl chloride
7719-09-7

thionyl chloride

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
In not given byproducts: SO2, HCl; heating Na2HPO4 with SOCl2 on a water bath;;
In not given byproducts: SO2, HCl; heating Na2HPO4 with SOCl2 on a water bath;;
sodium cyanide
773837-37-9

sodium cyanide

sodium pyrophosphate
124-43-6

sodium pyrophosphate

Conditions
ConditionsYield
With sodium hypophosphate; oxygen In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;;
With NaPO3; O2 In neat (no solvent) byproducts: (CN)2; heating at 500°C, 1h;;
sodium pyrophosphate
124-43-6

sodium pyrophosphate

tin(II) chloride dihdyrate
10025-69-1

tin(II) chloride dihdyrate

tin(II) pyrophosphate

tin(II) pyrophosphate

Conditions
ConditionsYield
In water at 60℃; for 0.5h;95%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

sodium pyrophosphate
124-43-6

sodium pyrophosphate

palladium diacetate
3375-31-3

palladium diacetate

[(Pd(2,2'-bipyridine))2(μ-P2O7)]*5.5H2O

[(Pd(2,2'-bipyridine))2(μ-P2O7)]*5.5H2O

Conditions
ConditionsYield
In water Pd salt, bipyridine and Na salt were dissolved with stirring in H2O at 60°C; left for 2 h; slowly evapd. at room temp. for few d; dried in vac. overnight; elem. anal.;85%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

sodium pyrophosphate
124-43-6

sodium pyrophosphate

water
7732-18-5

water

copper hydroxide
20427-59-2

copper hydroxide

([(2,2'-bipyridine)Cu(H2O)(μ-P2O7)Na2(H2O)6]*4H2O)

([(2,2'-bipyridine)Cu(H2O)(μ-P2O7)Na2(H2O)6]*4H2O)

Conditions
ConditionsYield
In water aq. suspn. Cu(OH)2 was treated with 2,2'-bipyridine at room temp. and stirred for 15 min, Na4P2O7 was added and stirred for 4 h; soln. was allowed to stand over several days; elem. anal.;80%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

sodium pyrophosphate
124-43-6

sodium pyrophosphate

VO(4+)*2SO4(2-)*2H2O=VO(SO4)2*2H2O

VO(4+)*2SO4(2-)*2H2O=VO(SO4)2*2H2O

([(2,2'-bipyridine)(VO)2]2(μ-P2O7)]*3.5H2O)

([(2,2'-bipyridine)(VO)2]2(μ-P2O7)]*3.5H2O)

Conditions
ConditionsYield
In water 2,2'-bipyridine was added to aq. soln. VO(SO4)2*2H2O, aq. soln. Na4P2O7 was added; ppt. was filtered, washed with water and air dried; elem. anal.;80%
sodium pyrophosphate
124-43-6

sodium pyrophosphate

perchloric acid
7601-90-3

perchloric acid

[Ga2(2,6-bis((N,N′-bis(2-picolyl)amino)methyl)-4-tertbutylphenolate)(OH)2(H2O)2](ClO4)3·4H2O

[Ga2(2,6-bis((N,N′-bis(2-picolyl)amino)methyl)-4-tertbutylphenolate)(OH)2(H2O)2](ClO4)3·4H2O

water
7732-18-5

water

[Ga2(2,6-bis((N,N′-bis(2-picolyl)amino)methyl)-4-tertbutylphenolate)(HP2O7)](ClO4)2·3H2O

[Ga2(2,6-bis((N,N′-bis(2-picolyl)amino)methyl)-4-tertbutylphenolate)(HP2O7)](ClO4)2·3H2O

Conditions
ConditionsYield
In methanol; acetone at 20℃;77%
sodium pyrophosphate
124-43-6

sodium pyrophosphate

sodium tetrachloropalladate(II)

sodium tetrachloropalladate(II)

N-(pyridin-2-yl)formamidine

N-(pyridin-2-yl)formamidine

water
7732-18-5

water

C12H14N6O7P2Pd2*4H2O

C12H14N6O7P2Pd2*4H2O

Conditions
ConditionsYield
With nitric acid; potassium hydroxide In ethanol; water at 60℃; for 15h; pH=8;74.6%

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