CAS No.7782-41-4,Fluorine Suppliers,MSDS download

: 7783-81-5
uranium hexafluoride

: 13775-07-0
uranium pentafluoride

B: 7782-41-4
fluorine

Conditions

Conditions	Yield
In gas Irradiation (UV/VIS); photolysis by UV light at room temp.;	A 98.8% B n/a
In neat (no solvent, gas phase) Irradiation (UV/VIS); photolysis by UV light at room temp.;	A 98.8% B n/a
In gas Irradiation (UV/VIS); photolysis at 1-10 Torr; nearly complete decompn. within some h;
In neat (no solvent, gas phase) Irradiation (UV/VIS); photolysis at 1-10 Torr; nearly complete decompn. within some h;

: KH2F3

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) Electrolysis; melt of KH2F3; passing through column with granuled NaF;	95%

: calcium fluoride

: 7732-18-5
water

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) passing over 1.0 g/min water-steam in 120 ml air at 1300°C for 30 minutes;;	92.1%
In neat (no solvent) passing over 1.0 g/min water-steam in 120 ml air at 1300°C for 30 minutes;;	92.1%
With silica gel In neat (no solvent) passing 1.0 g/min water-steam in 120 ml air over a mixture of 2.38 g CaF2 and 2.62 g SiO2 at 1300°C for 30 minutes;;	90.5%

: 7787-62-4
bismuth pentafluoride

: 17218-47-2
K2NiF6

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In solid 1 equiv of K2NiF6 and ca. 3 equiv of BiF5 were premixed at ambient temp., F2 evolution started when the mixt. heated to about 60-70°C, peak pressure 990 Torr;	75%

: calcium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
With silica gel In neat (no solvent) passing dry air over a mixture of 2.38 g CaF2 and 2.62 g SiO2 at 1300°C for 30 minutes;;	52.9%
With SiO2 In neat (no solvent) passing dry air over a mixture of 2.38 g CaF2 and 2.62 g SiO2 at 1300°C for 30 minutes;;	52.9%
With silica gel In neat (no solvent) passing dry air over a mixture of 2.38 g CaF2 and 2.62 g SiO2 at 1200°C for 30 minutes;;	12.2%

: 7787-62-4
bismuth pentafluoride

: 43070-30-0
Cs2CuF6

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In solid 1 equiv of Cs2CuF6 and ca. 2 equiv of BiF5 were premixed at ambient temp., F2 evolution started when the mixt. heated to about 60-70°C, peak pressure 836 Torr;	46%

: 7787-62-4
bismuth pentafluoride

: 17218-47-2
K2NiF6

: 7783-63-3
titanium(IV) fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In solid equimolar amts. of reactants were premixed at ambient temp., F2 evolution started when the mixt. heated to about 60-70°C, peak pressure 820 Torr;	45%

...Expand

: 7787-62-4
bismuth pentafluoride

: 16962-46-2
Cs2MnF6

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In solid 1 equiv of Cs2MnF6 and 3 equiv of BiF5 were premixed at ambient temp., F2 evolution started when the mixt. heated to about 60-70°C, peak pressure 929 Torr;	41%

: 17218-47-2
K2NiF6

: 7783-63-3
titanium(IV) fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In solid equimolar amts. of reactants were premixed at ambient temp., F2 evolution started when the mixt. heated to about 60-70°C, peak pressure 810 Torr;	14%

: cesium hydrogen fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis;
In melt Electrolysis;

: KF*1.6HF

: lithium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of KF1.6HF with 0.1-2,5% LiF at 100-110°C; current density: 0.097A/cmcm; C-anode with 35-47% Cu, steel cathode;;

: KF*3HF

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; KF*3HF (m.p.: 0-150°C); electrode: Fe, Ni, Cu or alloys of these metals; copper diaphragma;;
In melt Electrolysis; electrolysis of KF*3HF; open or closed system; crucible of Cu; various cathode and anode; with or without diaphragma; various temp.;;
In melt Electrolysis;

: KF*1.8HF

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; closed crucible (cathode) and diaphragma of copper;;
In melt Electrolysis; closed crucible (cathode) and diaphragma of copper;;
In melt Electrolysis; electrolysis of KF*1.8HF in a closed crucible (cathode) of Cu at 160-250°C, 20 A and 8.5-9 V ; diaphragma of copper; graphite anode; current efficiency: 92-94%;;

: KF*2HF

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of KF*2HF in a crucible (cathode) of monel metal at 73-75°C and 12 A; diaphragma of copper; Ni anode; current efficiency: 72%; sealed with Portland cement;;
In melt Electrolysis; electrolysis of KF*2HF in a crucible (cathode) of monel metal at 73-75°C and 12 A; diaphragma of copper; Ni anode; current efficiency: 72%; sealed with Portland cement;;

: KF*2HF

: sodium fluoride

: lithium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of KF*2HF with 1% LiF and 2% NaF at 100°C, 300 A and 11 V; coal anode, steel cathode;;

...Expand

: 1279123-63-5
potassium hydrogenfluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In hydrogen fluoride Electrochem. Process; laboratory fluorine cell (40 -42 % HF, 100 A, 80 - 100°C); passing through column with granulated NaF;
In melt Electrolysis; graphite anode; description and drawing of apparatus given;;
In melt Electrolysis; graphite anode; description and drawing of apparatus given;;

: 1279123-63-5
potassium hydrogenfluoride

: 7664-39-3
hydrogen fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; KHF2 presaturated with HF (40 - 42 wt. %); adsorption on column packed with NaF pellets;

KF*(2.9-6.7)HF: KF*(2.9-6.7)HF

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of KF*(2.9-6.7)HF at 15-50°C; various material for vessel, cathode and anode;;
In melt Electrolysis;
In melt Electrolysis;

KF*(1.8-2.2)HF: KF*(1.8-2.2)HF

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; at 80-110°C;;

: rubidium hydrogenfluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis;

: potassium hydrogen bifluoride

: sodium hydrogenfluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;

: 7664-39-3
hydrogen fluoride

: 7732-18-5
water

A: 7782-41-4
fluorine

B: 10028-15-6
ozone

Conditions

Conditions	Yield
In water Electrolysis; reaction by use of aq. HF solns., mechanism discussed;;
In water Electrolysis; reaction by use of aq. HF solns., mechanism discussed;;

...Expand

: (x)FH*(x)FK

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt byproducts: H2; Electrolysis; anode: 40% anthracite and 60% coke pressed at 1250-1300°C and 300-400 at; 70-85°C; 2000 A; pilot plant;;
In melt Electrolysis;
In melt Electrolysis;

: rubidium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of RbF; hollow C-anode (permeable to gas); current density: 0.0775 A/cm*cm; Cu-cathode;;

: potassium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In melt Electrolysis; electrolysis of KF; hollow C-anode (permeable to gas); current density: 0.0775 A/cm*cm; Cu-cathode;;

: potassium fluoride

: 7664-39-3
hydrogen fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In hydrogen fluoride Electrolysis; electrolysis of non-aq. HF and KF at -30 to -40°C;;
In hydrogen fluoride HF (liquid); Electrolysis; electrolysis of non-aq. HF and KF at -30 to -40°C;;

: sodium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
With oxygen In neat (no solvent) byproducts: Na4P2O7; heating of a mixt. of NaF and Na2P2O6 at 650-750°C in air;;
With Na2P2O6; O2 In neat (no solvent) byproducts: Na4P2O7; heating of a mixt. of NaF and Na2P2O6 at 650-750°C in air;;

: 124-43-6
sodium pyrophosphate

: sodium fluoride

A: 7782-41-4
fluorine

B: sodium phosphate

Conditions

Conditions	Yield
With oxygen

...Expand

: 7664-39-3
hydrogen fluoride

: sodium fluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In hydrogen fluoride byproducts: H2; HF (liquid); Electrolysis; photoelectrolysis of anhydrous HF/NaF at a TiO(2-x)F(x) or n-TiO(2-x) electrode under 365 nm illumination or in the dark;; F2 identified by volatility at -196 °C, IR inactivity, MS and chemical behaviour;;

: sodium metaphposphate

: sodium fluoride

A: 124-43-6
sodium pyrophosphate

B: 7782-41-4
fluorine

Conditions

Conditions	Yield
With oxygen

...Expand

: 7782-41-4
fluorine

: tin(IV) oxide

: 7783-62-2
tin(IV) fluoride

Conditions

Conditions	Yield
In neat (no solvent) formation at fluorination of SnO2 with F2 at 500-550°C;;	100%
In neat (no solvent) formation at fluorination of SnO2 with F2 at 400°C;;	80%
In neat (no solvent) reaction with fluorine at 500-550°C under formation of SnF4;;
In neat (no solvent) reaction with fluorine at 500-550°C under formation of SnF4;;

: tantalum

: niobium

: 7782-41-4
fluorine

: [Nb2Ta2F20]

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; all manipulations in metal vac. line; mixt. of calcd. amts. of metal powders reacted with 10% excess of F2 gas at 393 K for 3 h in steel autoclave, cooled to room temp.; excess F2 removed in dynamic vac., crystalline product scraped from upper surfaces of autoclave; elem. anal.;	100%

...Expand

: tantalum

: niobium

: 7782-41-4
fluorine

: 900794-96-9
[NbTa3F20]

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; all manipulations in metal vac. line; mixt. of calcd. amts. of metal powders reacted with 10% excess of F2 gas at 393 K for 3 h in steel autoclave, cooled to room temp.; excess F2 removed in dynamic vac., crystalline product scraped from upper surfaces of autoclave; elem. anal.;	100%

...Expand

: tantalum

: niobium

: 7782-41-4
fluorine

: 900794-98-1
[Nb3TaF20]

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; all manipulations in metal vac. line; mixt. of calcd. amts. of metal powders reacted with 10% excess of F2 gas at 393 K for 3 h in steel autoclave, cooled to room temp.; excess F2 removed in dynamic vac., crystalline product scraped from upper surfaces of autoclave; elem. anal.;	100%

...Expand

: 7788-97-8
chromium(III) fluoride

: 7782-41-4
fluorine

: 14884-42-5
chromium pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) anhydrous CrF3 and F2 shaked for 29 h at 270-303 ° C; remaining F2 removed at -196 ° C;	100%
addn. of F2 to CrF3 at -196°C, then 260°C for 65 h;	92.5%
In neat (no solvent) High Pressure; CrF3 was loaded into a Monel autoclave in a dry-box; after evacuation F2 was admitted (30 atm); heating at 350°C for 2 h;; cooling to room temp.; autoclave was evacuated to 1E-1 torr for severalhours and subsequently opened in a dry-box; elem. anal.;;

: tantalum

: 7782-41-4
fluorine

: tantalum pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) High Pressure; all manipulations in metal vac. line; metal powder reacted with 10% excess of F2 gas at 393 K for 3 h in steel autoclave, cooled to room temp.; excess F2 removed in dynamic vac., crystalline product scraped from upper surfaces of autoclave; elem. anal.;	100%

: ammonium hexachloridoplatinate(IV)

: 7782-41-4
fluorine

: 7647-14-5
sodium chloride

: sodium hexafluoridoplatinate(IV)

Conditions

Conditions	Yield
at 450℃; for 144h; Inert atmosphere; Milling;	100%

...Expand

: 7787-62-4
bismuth pentafluoride

: 7664-39-3
hydrogen fluoride

: silver fluoride

: 7782-41-4
fluorine

: Ag(2+)*2BiF6(1-)=Ag(BiF6)2

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); dry Ar-atmosphere; metal reactor lined with fluorinated plastic, prepassivated with F2; 2 atm F2,(pptn. of AgF2 in one part), mechanical transfer of excess BiF5 onto AgF2, stirring (15 h); evapn., repeated treatment with BF3 (dissoln. of AgF2) and decantation,drying (dynamic vac.);	99.7%

...Expand

: xenon

: 7782-41-4
fluorine

: 13709-36-9
xenon difluoride

Conditions

Conditions	Yield
In neat (no solvent) Xe and F2 condensed into nickel can (-196°C), warmed (room temp., pressure 34 atm.), preheated electric furnace (400°C) placed around the nickel can (7 h, pressure 78 atm.), quenched to room temp. in water, cooled (-78°C); excess Xe condensed into a storage cylinder (-196°C), evapn. (through a cold trap, -78°C);	99.3%
In gas react. temp. of 400°C, Xe:F2 about 2.0, Monel vessel with volume between 95 and 1200 ml; cooling down with H2O;;	>95
Electric Arc; react. of F2 with an excess of Xe in an electrical discharge; sublimation in vac., discarding the leading fraction;

: 7782-50-5
chlorine

: 7782-41-4
fluorine

: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
In gas byproducts: ClO2, ClF3; Irradiation (UV/VIS); pulsed irradiation of gaseous stoichiometric mixt. of F2 and Cl2 in a closed space at room temp. (light pulses lasting 5E-6 to E-3 s with λ=200-450 nm); impurities detected by spectroscopic methods; presence of ;	99%
In neat (no solvent) equilibrium react. at 250°C;;
In neat (no solvent) Cl2 and an excess of F2;;

: 34035-97-7
ammonium pertechnetate

: 7782-41-4
fluorine

: technetium hexafluoride

Conditions

Conditions	Yield
In hydrogen fluoride byproducts: O2, N2; HF (liquid); High Pressure; at 600°C for 1 h in an autoclave; evapd. at -196°C, condensed, sealed, recrystd. by cooling from 0 to -78°C;	99%

: 7553-56-2
iodine

: 7782-41-4
fluorine

: 22520-96-3
IF3

Conditions

Conditions	Yield
In trichlorofluoromethane Ar/F2 mixture bubbled into I2 in CFCl3 (at -45°C) until the I2 disappeared completely; solv. evapd., warmed (to -30°C), cooled (to -78°C);	99%

: di(rhodium)tetracarbonyl dichloride

: 201230-82-2
carbon monoxide

: 7783-70-2
antimony pentafluoride

: 7782-41-4
fluorine

: chloropentacarbonylrhodium(III) undecafluorodiantimonate(V)

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); HF added to Rh complex under vac., kept at -196°C, F2 added, stirred for ca. 2 h, further addn. of F2, stirred at room temp. for 1 h, excess F2 removed at -196°C, HF and SbF5 added, warmed to room temp., stirred at 70°C, CO added,; stirred at -20°C for 20 h; removal of all volatiles under vac.;	99%

...Expand

: 353-50-4
Carbonyl fluoride

: 7782-41-4
fluorine

: 373-91-1
hypofluorous acid trifluoromethyl ester

Conditions

Conditions	Yield
rubidium fluoride equimolar amt. of educts, steel vessel, -78°C, yield: 97 mol-%;	97%
potassium fluoride equimolar amt. of educts, steel vessel, -78°C, yield: 97 mol-%;	97%
cesium fluoride equimolar amt. of educts, steel vessel, -78°C, yield: 97 mol-%;	97%

: xenon

: 7782-41-4
fluorine

: 13709-61-0
xenon tetrafluoride

Conditions

Conditions	Yield
In gas Holloway's apparatus; continous working possible;; yields of 11gXeF4/h of very pure XeF4 are obtained;;	97%
on heating of a Xe-F2 mixture (1:5) in a closed, 1600ml Ni vessel at 400°C with following chilling of react. vessel in water;; on pumping off of excess fluorine at -78°C and removing of resting Xe with U tube (with temp. of -195°C); in 1 hour 10g XeF4 with a yield >99% are obtained;;	>99
Electrochem. Process; on electrical discharge at -78°C; detailed information about react. conditions and apparatus given;;

: chromium(VI) oxide

: 7790-89-8
chlorine monofluoride

: 7782-41-4
fluorine

A: 13637-83-7
chloryl fluoride

B: CrF3O

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl2, O2; ClF added to CrO3, mixt. heated at 110°C for 4 h with periodic shaking, vessel evacuated at -196, -78°C, at room temp., vessel charged with F2, heated to 120°C for 12 h, removed F2 and ClO2F, repeated react. with F2 for 2 and 3 h; at -196°C removed excess F2, at room temp. removed ClO2F, elem. anal.;	A n/a B 97%

...Expand

: chromium oxyfluoride

: 7790-89-8
chlorine monofluoride

: 7782-41-4
fluorine

A: 13637-83-7
chloryl fluoride

B: CrF3O

Conditions

Conditions	Yield
In neat (no solvent) byproducts: Cl2, O2; ClF added to CrO2F2, mixt. heated to 100°C for 12 h, vessel evacuated at -196, -78°C, at room temp., vessel charged with F2, heated to 120°C for 4 h; at -196°C removed excess F2, at room temp. removed ClO2F, elem. anal.;	A n/a B 97%

...Expand

: 117678-68-9
dodecacarbonyltetrairidium

: 7782-41-4
fluorine

: 146168-99-2, 146237-54-9
fac-iridiumtricarbonyltrifluoride

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); (Schlenk, N2) to a soln. of Ir-complex in HF 2 atm of F2 at -78°Cwas added, the soln. was allowed to warm to room temp., stirred for 16 h; the soln. was removed in vac.;	96%

: 353-50-4
Carbonyl fluoride

: 7782-41-4
fluorine

A: 373-91-1
hypofluorous acid trifluoromethyl ester

B: 927-84-4
bis(trifluoromethyl)peroxide

Conditions

Conditions	Yield
yttrium(III) fluoride Kinetics; 150°C, 10 h;	A n/a B 95%
bismuth(III) fluoride Kinetics; 150°C, 12 h;	A n/a B 95%
terbium(III) fluoride Kinetics; 100°C, 30 h;	A n/a B 95%

...Expand

: chlorine trifluoride

: 7782-41-4
fluorine

A: 27948-18-1
18F-fluoride

B: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In gas at 119 - 232°C in Al-tubes about 30 - 45 min;;	A 95% B n/a
In gas at 170°C in Ni-tubes about 40 min;;	A 12% B n/a
nickel(II) fluoride In gas Kinetics; at 467, 497 and 530°K in Ni-tubes;;

...Expand

: 7782-41-4
fluorine

: Perfluor-(polyacrylnitril)

Conditions

Conditions	Yield
With polyacrylonitrile volume ratio of polyacrylnitrile:F2 = 1:60, at 20°C for 6 h then with F2 for 30 h; F2 dild. with He;	95%
With polyacrylonitrile volume ratio of polyacrylnitrile:F2 = 1:60, at 20°C for 6 h then with F2 for 30 h; F2 dild. with He;	95%

: 40934-88-1
boron tris{pentafluoro-oxotellurate(VI)}

: 7782-41-4
fluorine

: 83314-21-0
TeF5OF

Conditions

Conditions	Yield
In neat (no solvent) byproducts: BF3, TeF5OH, TeF6; under dry N2, B(OTeF5)3 in a Monel vessel evacd., cooled to -196°C, addn. of F2, closed vessel warmed to ambient temp., placed in an oven at 100°C, 67 h; cooled to -196°C, excess F2 pumped off, volatiles sepd. by fractional condensation during warming to room temp., TeF5OF retained in a trap cooled at -126°C;	95%
In neat (no solvent) byproducts: BF3, TeF5OH, TeF6; under dry N2; B(OTeF5)3 in a Monel vessel evacd., cooled to -196°C, addn. of F2, closed vessel warmed to ambient temp., placed in an oven at 115°C, 24 h;; cooled to -196°C, excess F2 pumped off, volatiles sepd. by fractional condensation during warming to room temp., TeF5OF retained in a trap cooled at -126°C;;	94%
In neat (no solvent) byproducts: BF3, TeF5OH, TeF6; under dry N2, B(OTeF5)3 in a stainless steel vessel evacd., cooled to -196°C, addn. of F2, closed vessel warmed to ambient temp., placed in an oven at 115°C, 51 h; cooled to -196°C, excess F2 pumped off, volatiles sepd. by fractional condensation during warming to room temp., TeF5OF retained in a trap cooled at -126°C;	81%

: 7783-70-2
antimony pentafluoride

: 7440-57-5, 457905-15-6
gold

: 7782-41-4
fluorine

: Au(SbF6)2Au(AuF4)2

Conditions

Conditions	Yield
In hydrogen fluoride HF (liquid); Argon atmosphere, fluorocarbon polymer tube, addn. of fluorine (5 h, 800Torr), vigorous agitation (20°C, 21 h); decantation, washing (HF);	95%

...Expand

: 168098-42-8
deca-B-methyl-1,12-dicarba-closo-dodecaborane(12)

: 7782-41-4
fluorine

: sodium fluoride

: 356060-61-2
perfluro-deca-B-methyl-para-carborane

Conditions

Conditions	Yield
In further solvent(s) a soln. (perfluorononane) of B compd. pumped into reactor with N2/F2 bubbling, gradually heated to 110°C (24 h), held for 4 d; F2 turned off, allowed to purge for 4 h, filtered, solvent removed (vac.), sublimated (65°C/0.01 mm);	94%

...Expand

: sodium sulfamate

: 7782-41-4
fluorine

: 911368-67-7
sodium difluorosulfamate

Conditions

Conditions	Yield
In water byproducts: HF; soln. NaSO3NH2 (H2O) placed into teflon-FEP ampule; cooling to 0°C, F2 (10% v/v in N2) introduced; 45 min of fluorination; mixt. pumped to dryness at 0°C;	94%

: 517-25-9
trinitromethane

: 7782-41-4
fluorine

: 1840-42-2
fluorotrinitromethane

Conditions

Conditions	Yield
With sodium hydroxide In water at 0-5°C 1.5 h;	92.3%
With NaOH In water at 0-5°C 1.5 h;	92.3%
In water 40% F2 in N2; velocity of flow 9l/h; at 0-5°C;	90%

: 1279123-63-5
potassium hydrogenfluoride

: 60-29-7
diethyl ether

: 12-ammoniocarba-closo-dodecaborane

: 7664-39-3
hydrogen fluoride

: 7782-41-4
fluorine

: 1-H-12-H3N-closo-1-CB11F10·0.1Et2O

Conditions

Conditions	Yield
Stage #1: potassium hydrogenfluoride; 12-ammoniocarba-closo-dodecaborane; hydrogen fluoride; fluorine at -78 - 20℃; Stage #2: diethyl ether In hexane	92%

...Expand

Conditions	Yield
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;
In melt Electrolysis; electrolysis of a mixt. of KFHF (65%) and NaFHF (35%); vessel and diaphragma of Mg or Monel metal;;

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