CAS No.7790-91-2,CHLORINE TRIFLUORIDE Suppliers,MSDS download

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Amadis Chemical offer CAS#7790-91-2;CAT#A839288

Cas:7790-91-2

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

chlorine trifluoride: chlorine trifluoride

: 7782-41-4
fluorine

A: 27948-18-1
18F-fluoride

B: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In gas at 119 - 232°C in Al-tubes about 30 - 45 min;;	A 95% B n/a
In gas at 170°C in Ni-tubes about 40 min;;	A 12% B n/a
nickel(II) fluoride In gas Kinetics; at 467, 497 and 530°K in Ni-tubes;;

...Expand

: 7790-89-8
chlorine monofluoride

: 7782-41-4
fluorine

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) equilibrium react.;;
In neat (no solvent) Kinetics; equilibrium at 500 - 800°K;;
In neat (no solvent) Kinetics; equilibrium at 100 - 380°C;;

: 15321-10-5
rubidium tetrafluorochlorate(III)

A: rubidium fluoride

B: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) heated (nickel labyrinth crucible, dry N2 atm., heating rate 4-6 K/min.);

: 19195-69-8
potassium tetrafluoridochlorate(III)

A: potassium fluoride

B: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) heated (nickel labyrinth crucible, dry N2 atm., heating rate 4-6 K/min.);

: 10025-67-9
disulfur dichloride

: 7732-18-5
water

: sodium fluoride

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) heating S2Cl2 and NaF under refluxat 136°C; hydrolysis at -120°C;;	20-45

...Expand

: 184851-42-1, 478167-78-1, 13637-63-3, 676353-68-7, 478167-76-9
chlorine pentafluoride

A: 7790-91-2
chlorine trifluoride

B: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) equilibrium;;
In neat (no solvent) equilibrium between 211 - 271°K;;
In neat (no solvent) equilibrium between 211 - 271°K;;
In neat (no solvent) equilibrium;;

: 38785-48-7
ClF2 bismuth hexafluoride

A: 7787-62-4
bismuth pentafluoride

B: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) dry air atmosphere; heating (90-150°C, 4-6 K/min); TGA;

: potassium hydrogen bifluoride

: sodium fluoride

: lithium fluoride

A: 7790-91-2
chlorine trifluoride

B: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
With sodium fluoride In melt placing the fluorides in a Monel cylinder with a Ni-dip tube and outlet for gaseous phase (3 cooper traps, temp. from dry ice to room temp.); protecting from atmosphere; heating with electric furnace to 725°C; streaming Cl2 through melt for 5h; detecting ClF along with ClF3 by IR spectroscopy;

...Expand

: 13773-81-4
krypton difluoride

: silver(I) chloride

A: 7790-91-2
chlorine trifluoride

: 184851-42-1, 478167-78-1, 13637-63-3, 676353-68-7, 478167-76-9
chlorine pentafluoride

Conditions

Conditions	Yield
With polyethylene observed by IR and raman spectroscopy of KrF2;;

...Expand

: 13693-06-6
plutonium hexafluoride

: 7727-37-9
nitrogen

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
other Radiation; α-radiation;
other Radiation; α-radiation;

: 7783-44-0
dioxygen difluoride

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
With chlorine In neat (no solvent) Kinetics; addn. of Cl2 to - 130°C cooled O2F2;;

: 7783-44-0
dioxygen difluoride

: 7790-89-8
chlorine monofluoride

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) above 140°C;;
In neat (no solvent) above 140°C;;

: 7783-44-0
dioxygen difluoride

: 7790-89-8
chlorine monofluoride

A: 7790-91-2
chlorine trifluoride

B: 80937-33-3
oxygen

Conditions

Conditions	Yield
In neat (no solvent) at 140°K;;
In neat (no solvent) at 140°K;;

...Expand

: 7783-44-0
dioxygen difluoride

: 7790-89-8
chlorine monofluoride

A: 7790-91-2
chlorine trifluoride

B: 80937-33-3
oxygen

C: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) above 140°K;;

...Expand

: 14884-42-5
chromium pentafluoride

: 7782-50-5
chlorine

A: 7788-97-8
chromium(III) fluoride

B: 7790-91-2
chlorine trifluoride

C: 10049-11-3
chromium tetrafluoride

D: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
heating at 185°C for 20 h;

...Expand

: 75-69-4
trichlorofluoromethane

: 7782-41-4
fluorine

A: 7790-91-2
chlorine trifluoride

B: 75-72-9
chlorotrifluoromethane

C: 75-71-8
Dichlorodifluoromethane

Conditions

Conditions	Yield
In neat (no solvent) Kinetics; reaction in a pyrex vessel and He; mechanism discussed;;

...Expand

: 7782-50-5
chlorine

: 7782-41-4
fluorine

: 7790-91-2
chlorine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) at 270 - 280°C;;
In gas in nickel autoclave for 3 h at 280°C; strictly stoich. quantities; low-temp. distillation in vac.; DTA; chromy.;
In neat (no solvent) apparatus described;;

: 7782-50-5
chlorine

: 7782-41-4
fluorine

A: 7790-91-2
chlorine trifluoride

B: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
In neat (no solvent) reaction of Cl2 and F2 (1:3) at 300°C; apparatus described;; distillation;;
In neat (no solvent) reaction of Cl2 and F2 (1:3) at 300°C; apparatus described;; distillation;;
In neat (no solvent) reaction of Cl2 and F2 in Cu pig at 200°C;; fractionated distillation: at -70°C ClF3, at -150°C ClF; purification of ClF3 in vacuum at 20 Torr;;

...Expand

: 7790-89-8
chlorine monofluoride

A: 7790-91-2
chlorine trifluoride

B: 7782-50-5
chlorine

Conditions

Conditions	Yield
Kinetics; Irradiation (UV/VIS); cylindrical silica cell; λ = 260-370 nm, 293 K; spectrophotometry;

: 14104-20-2
silver tetrafluoroborate

A: 7790-91-2
chlorine trifluoride

B: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
With chlorine In neat (no solvent) byproducts: AgF, AgCl, BF3; packing AgBF4 in a copper tube connected to traps and on-line IR cell; evacuating; passing Cl2 through AgBF4; heating to 150°C (or 200 or 250°C) for 3h; detecting ClF and ClF3 by IR spectroscopy;

: 7783-44-0
dioxygen difluoride

: 7790-89-8
chlorine monofluoride

A: 7790-91-2
chlorine trifluoride

: 12133-60-7, 38680-84-1
chlorine dioxide trifluoride

C: 80937-33-3
oxygen

D: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) distillation of O2F2 into boron silicate glass in vacuum; cooling at 90°K; addn. of equimolar amount ClF at 119 - 140°K; cooling at 90°K; evacuation of F2 and Cl2;;

...Expand

: 7784-18-1
aluminum(III) fluoride

: chlorine trifluoride

A: 7790-91-2
chlorine trifluoride

B: Al(18)F3

Conditions

Conditions	Yield
In gas
In neat (no solvent, gas phase)

...Expand

: calcium fluoride

: chlorine trifluoride

A: 7790-91-2
chlorine trifluoride

B: Ca(18)F2

Conditions

Conditions	Yield
In gas
In neat (no solvent, gas phase)

...Expand

: copper (II)-fluoride

: chlorine trifluoride

A: 7790-91-2
chlorine trifluoride

B: copper difluoride

Conditions

Conditions	Yield
In neat (no solvent)
In neat (no solvent)

...Expand

: 7787-71-5
bromine trifluoride

: chlorine trifluoride

A: 7790-91-2
chlorine trifluoride

B: Br(18)F3

Conditions

Conditions	Yield
In neat (no solvent) in 10 min;;	A n/a B >90
In neat (no solvent) in 10 min;;	A n/a B >90

...Expand

: nickel(II) fluoride

: chlorine trifluoride

A: 7790-91-2
chlorine trifluoride

B: nickel difluoride

Conditions

Conditions	Yield
In neat (no solvent)
In neat (no solvent)

...Expand

: 12133-60-7, 38680-84-1
chlorine dioxide trifluoride

A: 7790-91-2
chlorine trifluoride

B: 80937-33-3
oxygen

Conditions

Conditions	Yield
In neat (no solvent) dissociation above 140°K;;

: 421-17-0
Trifluoromethylsulfenyl chloride

: 7790-91-2
chlorine trifluoride

: 374-10-7
trifluoro(trifluoromethyl)sulfur(IV)

Conditions

Conditions	Yield
In dichloromethane -78°C;	95%
In dichloromethane -78°C;	95%
In further solvent(s) in CF2Cl2 at -196 to -78°C;
In further solvent(s) in CF2Cl2 at -196 to -78°C;

: 7790-91-2
chlorine trifluoride

: 372-64-5
Bis(trifluoromethyl)disulfid

: 374-10-7
trifluoro(trifluoromethyl)sulfur(IV)

Conditions

Conditions	Yield
In dichloromethane -78°C;	95%
In dichloromethane -78°C;	95%
In Dichlorodifluoromethane excess ClF3, -196 to -78°C;
In Dichlorodifluoromethane excess ClF3, -196 to -78°C;

: 7790-91-2
chlorine trifluoride

: 7789-20-0
water-d2

A: 80937-33-3
oxygen

B: 7782-50-5
chlorine

C: 14333-26-7
hydrogen fluoride

Conditions

Conditions	Yield
In neat (no solvent) ClF3 was delivered to D2O through a nickel capillary (reactor shouldl becooled), DF was condensed to container at 77 K;	A n/a B n/a C 90%

...Expand

: uranium

: 7790-91-2
chlorine trifluoride

: 7783-81-5
uranium hexafluoride

Conditions

Conditions	Yield
In neat (no solvent) byproducts: ClF; condensation of ClF3 at -196°C to U in a reactor; warming to room temp. (cooling reactor with compressed air); pumping off volatile material after 1 h at -78°C; warming the bomb to -50°C; pumping off traces of ClF3;; sublimation;	85%
In hydrogen fluoride Kinetics; at 30°C; influence of HF, formed UF6, ClF3 and HF concn. and rise in temp. at 60°C in presence of BrF3;;
In neat (no solvent) Kinetics; above 60 - 80°C;;

: 20816-12-0
osmium(VIII) oxide

: 7790-91-2
chlorine trifluoride

A: 19184-41-9
osmium pentafluoride oxide

B: 24762-17-2, 58800-18-3
osmium trioxide difluoride

Conditions

Conditions	Yield
In neat (no solvent) OsO4 was condensed into a reaction tube at -196°C; ClF3 was condensed at the same temp. onto the osmium oxide; the mixt. was then allowed to warm up to ambient temp. and stored for 1 d;; OsOF5 was vaporized at -10°C and condensed into a trap at -196°C; OsO3F2 was sublimed in a static vac. in passivated sapphire tube at 130°C;;	A 15.6% B 82.7%

...Expand

: gadolinium(III) oxide

: 7790-91-2
chlorine trifluoride

: 13765-26-9
gadolinium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent)	80%
In neat (no solvent) at room temp. in presence of moisture;;	80%

: 7790-91-2
chlorine trifluoride

: 7790-89-8
chlorine monofluoride

Conditions

Conditions	Yield
With chlorine at 300℃; for 48h; Autoclave; Inert atmosphere;	72%
With chlorinated hydrocarbons In neat (no solvent)
With chlorine In neat (no solvent) heating 1:1 mixture at 180 - 350°C;;

: 7790-91-2
chlorine trifluoride

: 14797-71-8
18O-labeled water

: Cl(18)O2

Conditions

Conditions	Yield
In water-d2 byproducts: O2, HF, Cl2; ClF3 addn. to D2O (77 K), heating to room temp., pumping off of O2 and HF (77 K); fractional condensation (170 K); 70-95% (18)O;	50%

: yttrium(III) oxide

: 7790-91-2
chlorine trifluoride

: 13709-49-4
yttrium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at room temp. in presence of moisture;;	45%

: erbium(III) oxide

: 7790-91-2
chlorine trifluoride

: 13760-83-3
erbium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at room temp. in presence of moisture;;	12%

: 7790-91-2
chlorine trifluoride

: 124-38-9
carbon dioxide

: 353-49-1
fluoroformyl chloride

Conditions

Conditions	Yield
With catalyst: charcoal CO dild. with a double amt. of N2, -18°C;	10%

: 7790-91-2
chlorine trifluoride

: 10049-17-9
rhenium hexafluoride

: 4648-54-8
trimethylsilylazide

A: 84159-30-8
ReF5(NCl)

B: 84159-29-5
rhenium tetrafluoride nitride

Conditions

Conditions	Yield
In 1,1,2-Trichloro-1,2,2-trifluoroethane ReF6 was reacted with ligand at -50°C in CF3ClCFCl2, allowed to warm to 0°C, solvent was removed, residue was warmed to 70°C in vac., sublimed, involatile residue was reacted with ClF3 at 0°C; sublimed at 70°C in vac.;	A n/a B 10%

...Expand

: boron trioxide

: 7790-91-2
chlorine trifluoride

: 7637-07-2
boron trifluoride

: neodymium(III) oxide

: 7790-91-2
chlorine trifluoride

: 13709-42-7
neodymium(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at ambient temp.;;
room temp.;
In neat (no solvent) at room temp. in presence of moisture, (in absence of moisture not quantitative react.);;	>99

: lanthanum(III) oxide

: 7790-91-2
chlorine trifluoride

: 13709-38-1
lanthanum(III) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at room temp. in presence of moisture, (in absence of moisture not quantitative react.);;	>99

: 7790-91-2
chlorine trifluoride

: 7553-56-2
iodine

: 676353-70-1, 51096-45-8, 7783-66-6
iodine pentafluoride

B: 13873-84-2
iodine monofluoride

Conditions

Conditions	Yield
In neat (no solvent)

...Expand

: 7790-91-2
chlorine trifluoride

: 7726-95-6
bromine

: 7787-71-5
bromine trifluoride

Conditions

Conditions	Yield
In neat (no solvent) passing ClF3 into Br2 at 20 - 30°C;;	60-80
In neat (no solvent) bubbling ClF3 through liq. Br2; aerated with N2, distd.;	>99
In neat (no solvent) byproducts: Cl2; distd. (segregating 125-127°C fraction; cooled cyclically three times to 0°C in nickel container; chromy.; DTA;

: 7790-91-2
chlorine trifluoride

: 7726-95-6
bromine

: 177570-08-0, 7789-30-2, 676353-69-8
bromine pentafluoride

Conditions

Conditions	Yield
In neat (no solvent) passing excess of ClF3 into Br2 at 20 - 30°C;;

: ammonium fluoride

: 7790-91-2
chlorine trifluoride

A: 13637-87-1
chlorodifluoroamine

B: 7727-37-9
nitrogen

C: 7782-50-5
chlorine

Conditions

Conditions	Yield
In neat (no solvent) at -50 - -5°C;;
In neat (no solvent) at -50 - -5°C;;

...Expand

: rubidium fluoride

: 7790-91-2
chlorine trifluoride

: 15321-10-5
Rb(1+)*ClF4(1-)=RbClF4

Conditions

Conditions	Yield
In neat (no solvent) solvolysis at 100°C;;
In neat (no solvent) solvolysis at 100°C;;

: potassium fluoride

: 7790-91-2
chlorine trifluoride

: 19195-69-8
K(1+)*ClF4(1-)=KClF4

Conditions

Conditions	Yield
In neat (no solvent) solvolysis at 100°C;;
In neat (no solvent) solvolysis at 100°C;;

: 7440-56-4
germanium

: 7790-91-2
chlorine trifluoride

: sodium fluoride

: 128686-48-6
Na(1+)*GeF5(1-)=NaGeF5

Conditions

Conditions	Yield
In hydrogen fluoride byproducts: NaHF2; anhydrous HF;
In hydrogen fluoride byproducts: NaHF2; HF (liquid); anhydrous HF;

...Expand

: 7790-91-2
chlorine trifluoride

: silver(I) chloride

: silver(II) fluoride

Conditions

Conditions	Yield
In neat (no solvent) heating at 250°C;;
In neat (no solvent) at 250°C;;
In neat (no solvent) heating at 250°C;;
In neat (no solvent) at 250°C;;

: 7790-91-2
chlorine trifluoride

: 7647-14-5
sodium chloride

: sodium fluoride

Conditions

Conditions	Yield
byproducts: Cl2;

: 7790-91-2
chlorine trifluoride

: 13400-13-0
cesium fluoride

: 15321-10-5
Rb(1+)*ClF4(1-)=RbClF4

Conditions

Conditions	Yield
In neat (no solvent) solvolysis at 100°C;;
In neat (no solvent) solvolysis at 100°C;;

: 1313-99-1
nickel(II) oxide

: 7790-91-2
chlorine trifluoride

: nickel(II) fluoride

Conditions

Conditions	Yield
In neat (no solvent) at 25 - 180°C and 0.3 - 1 atm;;
In neat (no solvent) at 25 - 180°C and 0.3 - 1 atm;;

: 7790-91-2
chlorine trifluoride

: 7782-41-4
fluorine

Conditions

Conditions	Yield
In neat (no solvent) decompn. of ClF3 on heating (Ni wire);;

: 7790-91-2
chlorine trifluoride

A: 7790-89-8
chlorine monofluoride

B: 7782-41-4
fluorine

Conditions

Conditions	Yield
With metal In neat (no solvent)
In neat (no solvent) byproducts: Cl2; other Radiation; α-particles; at ambient temp.;;
In neat (no solvent) other Radiation; α-radiation;; detection by mass spectroscopy;;

: chromium(VI) oxide

: 7790-91-2
chlorine trifluoride

: CrOF3*0.3ClF3

Conditions

Conditions	Yield
In neat (no solvent) at 12°C;;
In neat (no solvent) at 120°C;;

Related products

7790-93-4

Chloric acid

7790-94-5

Chlorosulfuric acid

7790-98-9

Perchloricacid,ammoniumsalt

7790-99-0

Iodine chloride (ICl)

7791-03-9

Perchloric acid,lithium salt (1:1)

7791-07-3

Perchloric acid, sodiumsalt, monohydrate (8CI,9CI)

7791-08-4

Stibine, chlorooxo-

7791-11-9

Rubidiumchloride (RbCl)

7791-12-0

Thallium chloride(TlCl)

7791-13-1

Cobalt chloride(CoCl2), hexahydrate (8CI,9CI)

Hot Products

CAS No.:7790-91-2
Name:CHLORINE TRIFLUORIDE
Molecular Structure:
Formula:ClF3
Molecular Weight:92.4482
Synonyms:Chlorinefluoride (Cl2F6); Chlorine trifluoride; Chlorine trifluoride (ClF3);Chlorotrifluoride; Trifluorochlorine
EINECS:232-230-4
Density:3.18 （Relative vapour density (air = 1)）
Melting Point:-76ºC
Boiling Point:12ºC
Flash Point:
Solubility:reaction in water
Appearance:NEARLY COLOURLESS COMPRESSED LIQUEFIED GAS , WITH CHARACTERISTIC ODOUR.
Hazard Symbols:Explodes in contact with organic materials or with water. Dangerous fire risk. A poison, very toxic, corrosive to skin. TLV: ceiling 0.1 ppm.
Risk Codes8-35
Safety: Human poison by inhalation. An eye irritant. See also FLUORIDES, CHLORINE, and FLUORINE. Spontaneously flammable. A powerful oxidant which may react violently with oxidizable materials. A rocket propellant.
Explosive reaction with water, bis(trifluoro methyl)sulfide or -disulfide, polychlorotrifluoroethylene, trifluoromethanesulfenyl chloride, and other hydrogen- containing materials (e.g., ammonia, coal gas, hydrogen, hydrogen sulfide, methane, acetic acid, benzene, ether, cotton, paper, wood). Forms shock-sensitive explosive mixtures with highly chlorinated compounds (e.g., carbon tetrachloride), nitroaryl compounds (e.g., trinitrotoluene, hexanitrobiphenyl, hexanitrodiphenyl amine, hexanitro diphenyl sulfide, hexanitrodiphenyl ether). Reaction with ammonium fluoride or ammonium hydrogen fluoride forms explosive gaseous products.
Ignition on contact with boron-containing materials, iodine, finely divided refractory materials (e.g., asbestos, glass wool, sand, tungsten carbide), fluorinated polymers (with flowing trifluoride).
Violent reaction with acids (e.g., nitric or sulfuric), chromium trioxide, ruthenium, selenium tetrafluoride (above 106°C), metals, metal oxides, metal salts, nonmetals, nonmetal salts, organic matter, glass wool, acetic acid, Al, Sb, As, Cu, Ir, Fe, Pb, Mg, Mo, Os, P, K, Rh, Se, Si, Ag, Na, S, Te, Sn, W, Zn, oxides, CO, graphite, HgI₂, HNO₃, K₂CO₃, KI, rubber, AgN₃, AgNO₃, NaOH, V₂P₅, WO₃. Incompatible with fuels, nitro compounds. When heated to decomposition or in reaction with water or steam it emits toxic fumes of F⁻ and Cl⁻.
Transport Information:
PSA:0.00000
LogP:1.95010

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