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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Cefuroxime Acid supplier in China

Cas:7783-63-3

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

Titanic fluoride

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $100.0 / 150.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 7783-63-3 with best quality

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Manufacturer of Titanium tetrafluoride by lowest price

Cas:7783-63-3

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hefei TNJ chemical industry co.,ltd

♦ We are one of the domestic largest manufacturers of API; ♦ We are always supplier of products with higher quality and at more competitive price; ♦ We are supplier of safe and ecofriendly products ; ♦ We pr

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Titanium fluoride(TiF4), (T-4)- (9CI) 7783-63-3

Cas:7783-63-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $14.0 / 16.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Titanium fluoride(TiF4), (T-4)- (9CI)

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply CEFUROXIME,FREE ACID

Cas:7783-63-3

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Cefuroxime Acid

Cas:7783-63-3

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and als

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

SHANGHAI SYSTEAM BIOCHEM CO., LTD

We are one of a few suppliers that can offer custom synthesis service of this product We are specialized in custom synthesis, chemical/pharmaceutical/ pesticides outsourcing and contract research. We are committed to prov

Manufacturer of Titanium tetrafluoride by lowest price

Cas:7783-63-3

Min.Order:100 Gram

FOB Price: $100.0 / 2000.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so

TIANFUCHEM--7783-63-3--Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Metric Ton

FOB Price: $500.0

Type:Lab/Research institutions

inquiry

Xiamen Jenny Chemical Technology Co., Ltd.

GMP standard, high purity, competitive price, in stock 1. Quick Response: within 6 hours after receiving your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA, and approved by a third-party lab in China, USA,

Titaniumtetrafluoride

Cas:7783-63-3

Min.Order:1 Milligram

Negotiable

Type:Trading Company

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality products. Cle

hot sale Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Titanium(IV) fluoride

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Titanic fluoride

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Other

inquiry

Wuxi TAA Chemical Industry Co.,LTD.

1.A strong technical force and advanced processing equipments. The quality of the products has been strictly inspected and all kinds of index have reached or exceeded domestic and international standards.2. Now we have established long-term stable re

Titanium tetrafluoride CAS 7783-63-3

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Other

inquiry

Lonwin Chemical Group Limited

Shanghai Lonwin Chemical company is a subsidiary of Lonwin Industry Group Limited, was established in 2011 and is headquartered in Shanghai, adjacent to China National Convention and Exhibition Center and Hongqiao transportation hub.Lonwinchem is

High Purity Cefuroxime Acid 7783-63-3

Cas:7783-63-3

Min.Order:100 Kilogram

FOB Price: $100.0 / 150.0

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Titanium tetrafluoride

Cas:7783-63-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

stannous fluoride

stannous fluoride

titanium
7440-32-6

titanium

A

tin
7440-31-5

tin

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In melt Kinetics; placing of mixt. of Ti with SnF2 (molar ratio SnF2:Ti=4.04) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.00 h at 230°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;A 13.8%
B n/a
titanium
7440-32-6

titanium

chlorine trifluoride
7790-91-2

chlorine trifluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride reaction of ClF3 with Ti in HF-suspension at -78°C;;
In hydrogen fluoride HF (liquid); reaction of ClF3 with Ti in HF-suspension at -78°C;;
titanium
7440-32-6

titanium

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With hydrogen fluoride In water byproducts: H2; at room temp.;
With fluorine gentle heating;
With hydrogen fluoride byproducts: H2; at red heat;
hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride
100-120°C;
HF free of water;;
titanium(III) fluoride
13470-08-1

titanium(III) fluoride

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

hydrogen
1333-74-0

hydrogen

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In water Kinetics;
titanium(IV) oxyfluoride

titanium(IV) oxyfluoride

hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
Kinetics; 220 to 400°C, 0.2 to 1 atm HF;
hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) oxide

titanium(IV) oxide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
Kinetics; byproducts: oxide, fluorides; => 200°C;
With sulfuric acid In water0%
antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: HCl; vigorous reaction;
byproducts: HCl; vigorous reaction;
titanium(IV) oxide

titanium(IV) oxide

A

fluoroboroxine
13703-95-2

fluoroboroxine

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With boron trifluoride at 500°C;
With BF3 at 500°C;
Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

titanium(IV) oxide

titanium(IV) oxide

A

TiCl2F2

TiCl2F2

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C

titanium tetrachloride
7550-45-0

titanium tetrachloride

Conditions
ConditionsYield
In neat (no solvent) reaction at 700-750°C;;
titanium
7440-32-6

titanium

hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: H2; red heat;
titanium
7440-32-6

titanium

fluorine
7782-41-4

fluorine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With Ar In neat (no solvent) at 150°C for 2 d;
In neat (no solvent)
(O2)2Ti7F30

(O2)2Ti7F30

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With F2; Ar In hydrogen fluoride HF (liquid); 300°C, 1 d, cooling (20°C/d to room temp., 3 weeks);
barium fluorotitanate
31252-79-6

barium fluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: BaF2; glowing;
chloryl fluoride
13637-83-7

chloryl fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

2ClO2(1+)*TiF6(2-)=(ClO2)2TiF6

2ClO2(1+)*TiF6(2-)=(ClO2)2TiF6

B

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

C

chlorine
7782-50-5

chlorine

D

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In neat (no solvent) at -100°C;;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2; UF6 in excess;
byproducts: Cl2; UF6 in excess;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

C

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2; TiCl4 in excess;
byproducts: Cl2; TiCl4 in excess;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2, UF4; TiCl4 in excess;
byproducts: Cl2, UF4; TiCl4 in excess;
β-uranium(V) fluoride
13775-07-0

β-uranium(V) fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

C

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

ammonium hexafluorotitanate

ammonium hexafluorotitanate

A

ammonium fluoride

ammonium fluoride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
heating in N2-stream, NH4F evolution above 100°C, TiF4-loss from 150°C;
heating in N2-stream, NH4F evolution above 100°C, TiF4-loss from 150°C;
titanium oxyfluoride
13537-16-1

titanium oxyfluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: TiO2; by heating;
titanium oxyfluoride
13537-16-1

titanium oxyfluoride

A

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

B

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
decompn. at 600°C;
titanium(IV) oxide

titanium(IV) oxide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With boron trifluoride 500°C;
With BF3
lithium hexafluorotitanate

lithium hexafluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: F2; above 900°C;
byproducts: F2; above 900°C;
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: C5H5N; heating in moist. air;
Ba(2+)*TiF6(2-)*0.5H2O=Ba{TiF6}*0.5H2O

Ba(2+)*TiF6(2-)*0.5H2O=Ba{TiF6}*0.5H2O

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
very strong heating;
very strong heating;
ammonium pentafluoroperoxotitanate

ammonium pentafluoroperoxotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With hydrogen fluoride In water byproducts: H2O2;
With HF In water
magnesium hexafluorotitanate

magnesium hexafluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: H2O; at 300°C;
byproducts: H2O; at 300°C;
titanium
7440-32-6

titanium

fluorine
7782-41-4

fluorine

A

titanium(III) fluoride
13470-08-1

titanium(III) fluoride

B

TiF

TiF

C

titanium(II) fluoride

titanium(II) fluoride

D

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In solid matrix Irradiation (UV/VIS); Ti atoms evapd., trapped in F2/Ar matrix at ca 10 K, photolyzed using Hg-Xe, annealed to 25 K; not isolated, detected by IR;
titanium(III) fluoride
13470-08-1

titanium(III) fluoride

fluorine
7782-41-4

fluorine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid);
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

trimethylsilylazide
4648-54-8

trimethylsilylazide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C10H8N14Ti

C10H8N14Ti

Conditions
ConditionsYield
In acetonitrile at -196 - 20℃; for 8h;100%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

trimethylsilylazide
4648-54-8

trimethylsilylazide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C12H8N14Ti

C12H8N14Ti

Conditions
ConditionsYield
In acetonitrile at -196 - 20℃; for 16h;100%
1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

(TiF4((CH3)2PCH2CH2P(CH3)2))
1258515-14-8

(TiF4((CH3)2PCH2CH2P(CH3)2))

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 2 h; solvent was removed in vacuo, residue was washed with hexane, filtered off and dried in vacuo; elem. anal.;91%
15-crown-5
33100-27-5

15-crown-5

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[(titanium)(fluorine)2([15]crown-5][(titanium)4(fluorine)18]*0.5MeCN

[(titanium)(fluorine)2([15]crown-5][(titanium)4(fluorine)18]*0.5MeCN

Conditions
ConditionsYield
In acetonitrile soln. of (15)crown-5 in MeCN added to soln. of TiF4 in MeCN; concd., stored at room temp. for several h; elem. anal.;90%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

1,3,4,5-tetramethylimidazol-2-ylidene
141556-40-3

1,3,4,5-tetramethylimidazol-2-ylidene

trans-TiF4(1,3,4,5-tetramethylimidazol-2-ylidene)2

trans-TiF4(1,3,4,5-tetramethylimidazol-2-ylidene)2

Conditions
ConditionsYield
In tetrahydrofuran (N2); addn. of THF soln. of titanium fluoride to THF soln. of imidazole deriv. at -79°C, stiring for 30 min at -79°C, warming to room temp., stirring for 6 h at room temp.; filtration, washing with THF, drying in vac., recrystn. (CH2Cl2), elem. anal.;90%
dichloromethane
75-09-2

dichloromethane

1,2-bis(dimethylphosphino)benzene
7237-07-2

1,2-bis(dimethylphosphino)benzene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[TiF4(o-C6H4(PMe3)2)]*CH2Cl2

[TiF4(o-C6H4(PMe3)2)]*CH2Cl2

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 1 h; solvent was removed in vacuo, residue was triturated with hexane and stirred for 2 h, ppt. was filtered off and dried in vacuo; elem. anal.;85%
2,2,6,6-tetramethylheptane-3,5-dione
1118-71-4

2,2,6,6-tetramethylheptane-3,5-dione

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(dipivaloylmethanide)2F2

Ti(dipivaloylmethanide)2F2

Conditions
ConditionsYield
In dichloromethane dry N2-atmosphere; refluxing for 6 h; elem. anal.;84%
1,1,1-trifluoro-4-(2-thienyl)butane-2,4-dione

1,1,1-trifluoro-4-(2-thienyl)butane-2,4-dione

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

difluorobis[1,1,1-trifluoro-4-(2'-thienyl)butane-2,4-dionato] titanium(IV)

difluorobis[1,1,1-trifluoro-4-(2'-thienyl)butane-2,4-dionato] titanium(IV)

Conditions
ConditionsYield
In dichloromethane TiF4 refluxed in CH2Cl2 with the organic compound for 12 h, soln. cooled; filtered, concentrated under a stream of N2, hexane added, recrystd. from CH2Cl2-hexane; elem. anal.;83%
bis(acetylacetonate)oxidovanadium(IV)

bis(acetylacetonate)oxidovanadium(IV)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(CH3COCHCOCH3)2F2
16986-93-9

Ti(CH3COCHCOCH3)2F2

B

oxo difluoro vanadium (IV)

oxo difluoro vanadium (IV)

Conditions
ConditionsYield
In n-heptane; 1,2-dichloro-ethane at 20℃; Schlenk technique; Inert atmosphere;A 81%
B n/a
15-crown-5
33100-27-5

15-crown-5

antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

trans-difluoro(15-crown-5)titanium(IV) hexafluoroantimonate(V)

trans-difluoro(15-crown-5)titanium(IV) hexafluoroantimonate(V)

Conditions
ConditionsYield
In acetonitrile under N2; solns. of TiF4 in MeCN, 15-crown-5 in MeCN and SbF5 (molar ratio 1:1:2.4) in MeCN mixed at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;80%
1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol
718-64-9

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Conditions
ConditionsYield
With BuLi In hexane; toluene byproducts: LiF; (N2); addn. of soln. of BuLi in hexane to soln. of propanol deriv. in toluenen at -78°C, stirring at -78°C for 1 h and at room temp. for 1 h, addn. to suspn. of titanium compd. in toluene at room temp.,stirring for 2 h, refluxing for 1 d; filtration, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;80%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(κ2-1,2-dimethoxyethane)tetrachlorotitanium(IV)
19289-14-6

(κ2-1,2-dimethoxyethane)tetrachlorotitanium(IV)

Conditions
ConditionsYield
In dichloromethane (Ar), TiF4 in CH2Cl2 treated with 1 equiv. of ligand, stirred at room temp. for 4 h; evapd.(vac.), elem. anal.;80%
titanium(IV) oxide bis(2,4-pentanedionate)

titanium(IV) oxide bis(2,4-pentanedionate)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(CH3COCHCOCH3)2F2
16986-93-9

Ti(CH3COCHCOCH3)2F2

B

OTi(2+)*2F(1-)

OTi(2+)*2F(1-)

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20℃; Schlenk technique; Inert atmosphere;A 78%
B 80%
tetrakis(dimethylamido)titanium(IV)

tetrakis(dimethylamido)titanium(IV)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(TiF2(N(CH3)2)2)4
53787-11-4

(TiF2(N(CH3)2)2)4

Conditions
ConditionsYield
In acetonitrile under N2 atm. soln. TiF4 in MeCN was added soln. Ti(NMe2)4 in MeCN at room temp. and stirred for 30 min; ppt. was filtered, washed with MeCN, and dried in vacuo overnight; elem.anal.;75%
antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

fac-trifluorotris(acetonitrile)titanium(IV) hexafluoroantimonate(V)*(acetonitrile)
867253-68-7

fac-trifluorotris(acetonitrile)titanium(IV) hexafluoroantimonate(V)*(acetonitrile)

Conditions
ConditionsYield
In acetonitrile under N2; SbF5 (1 equiv.) distd. under vac.; MeCN condensed onto SbF5 at-79°C; warmed; added to soln. of TiF4 (1 equiv.) in MeCN at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;70%
In acetonitrile under N2; SbF5 (2 or 3 equiv.) distd. under vac.; MeCN condensed onto SbF5 at -79°C; warmed; added to soln. of TiF4 (1 equiv.) in MeCN atroom temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2;
tetrahydrofuran
109-99-9

tetrahydrofuran

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

cis-[(THF)2TiF4]
30116-61-1

cis-[(THF)2TiF4]

Conditions
ConditionsYield
In tetrahydrofuran (N2) soln. TiF4 in THF was stirred for 30 min; soln. was filtered, concd. in vacuo and refrigerated for 24 h, ppt. was filtered off and dried in vacuo; elem. anal.;69%
Schlenk technique; Glovebox; Inert atmosphere;
dichloromethane
75-09-2

dichloromethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[TiF4(Et2P(CH2)2PEt2)]*CH2Cl2

[TiF4(Et2P(CH2)2PEt2)]*CH2Cl2

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 2 h; solvent was removed in vacuo, residue was stirred overnight with hexane and CH2Cl2, ppt. was filtered off and dried in vacuo; elem. anal.;68%
5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene
189832-67-5

5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[(TiF)2(μ-F)(p-tert-butylcalix[6]arene(-5H))]2*6.5(acetonitrile)

[(TiF)2(μ-F)(p-tert-butylcalix[6]arene(-5H))]2*6.5(acetonitrile)

Conditions
ConditionsYield
Stage #1: 5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene; titanium(IV) fluoride In toluene for 12h; Reflux; Inert atmosphere;
Stage #2: acetonitrile at 0℃; for 48h; Inert atmosphere;
68%
Ti(O2CNEt2)4
62532-34-7

Ti(O2CNEt2)4

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

TiF2(O2CNEt2)2

TiF2(O2CNEt2)2

Conditions
ConditionsYield
In dichloromethane at 24.84℃; for 30h; Schlenk technique; Reflux; Inert atmosphere;66%
N-tris(pentafluorobenzyl)-B-trichloroborazine
14560-21-5

N-tris(pentafluorobenzyl)-B-trichloroborazine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

N-tris(pentafluorobenzyl)-B-trifluoroborazine
15057-92-8

N-tris(pentafluorobenzyl)-B-trifluoroborazine

Conditions
ConditionsYield
64%
64%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

lithium hexamethyldisilazane
4039-32-1

lithium hexamethyldisilazane

fluoro-tris(bis-trimethylsilyl-amido)titanum
157369-02-3

fluoro-tris(bis-trimethylsilyl-amido)titanum

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiF; Ar; stoichiometric amounts; room temperature; stirring for 1 d;; evapn. to dryness; addn. of hexane; filtration on celite; solvent concentration; crystn. upon cooling to -30 ° C; ekem. anal.;;60%
18-crown-6 ether
17455-13-9

18-crown-6 ether

antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

trans-difluoro(18-crown-6)titanium(IV) hexafluoroantimonate(V)

trans-difluoro(18-crown-6)titanium(IV) hexafluoroantimonate(V)

Conditions
ConditionsYield
In acetonitrile under N2; solns. of TiF4 in MeCN, 18-crown-6 in MeCN and SbF5 (molar ratio 1:1:3) in MeCN mixed at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;60%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

2,8-dimethylnonane-4,6-dione
7307-08-6

2,8-dimethylnonane-4,6-dione

Ti(diisobutyrylmethanide)2F2

Ti(diisobutyrylmethanide)2F2

Conditions
ConditionsYield
In dichloromethane dry N2-atmosphere; refluxing for 5.5 h; elem. anal.;60%
p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene
1313016-01-1

p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[Ti4F14(p-methyl-dimethyldiazacalix[6]arene)H2(H)2]·2.5MeCN

[Ti4F14(p-methyl-dimethyldiazacalix[6]arene)H2(H)2]·2.5MeCN

Conditions
ConditionsYield
Stage #1: p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene; titanium(IV) fluoride In toluene for 12h; Inert atmosphere; Schlenk technique; Reflux;
Stage #2: acetonitrile Inert atmosphere; Schlenk technique;
56%
diphenylboronchloride
3677-81-4

diphenylboronchloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(diphenyl)fluoroborane
36140-35-9

(diphenyl)fluoroborane

Conditions
ConditionsYield
stirring for 1 h; distn.;54%
stirring for 1 h; distn.;54%
B-trichloro-N-triphenylborazine
981-87-3

B-trichloro-N-triphenylborazine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

2,4,6-trifluoro-1,3,5-triphenyl-borazine
1960-46-9

2,4,6-trifluoro-1,3,5-triphenyl-borazine

Conditions
ConditionsYield
52%
52%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
In further solvent(s) byproducts: FCH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
18-crown-6 ether
17455-13-9

18-crown-6 ether

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

[(cis-TiF4)2(18-crown-6)]
847836-02-6

[(cis-TiF4)2(18-crown-6)]

Conditions
ConditionsYield
In acetonitrile Schlenk techique, under N2; CH3CN condenced into mixt. of TiF4 (6.5 mmol) + 18-crown-6 (3.0 mmol) (-79°C); warmed to 50°C; filtered; concd.; kept (room temp., 5 d); crystals filtered; washed withCH2Cl2 (from -20 to -40°C); elem. anal.;50%
1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol
718-64-9

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

A

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

(THF)2Li(μ-F)2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Li(THF)2

(THF)2Li(μ-F)2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Li(THF)2

Conditions
ConditionsYield
With MeLi In tetrahydrofuran; diethyl ether byproducts: LiF; (N2); addn. of soln. of 2 equiv. of MeLi in ether to soln. of 2 equiv. of propanol deriv. in THF at -78°C, stirring at -78°C for 1h and at room temp., addn. to soln. of titanium compd. in THF at room t emp., stirring for 2 h; evapn., keeping at room temp. for 2 d; first product: filtration, washing with CH2Cl2, drying in vac., elem. anal.; second product: evapn. of filtrate, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;A n/a
B 50%
With MeLi In tetrahydrofuran; diethyl ether byproducts: LiF; (N2); addn. of soln. of 3 equiv. of MeLi in ether to soln. of 3 equiv. of propanol deriv. in THF at -78°C, stirring at -78°C for 1h and at room temp., addn. to soln. of titanium compd. in THF at room t emp., stirring for 2 h; evapn., keeping at room temp. for 2 d; first product: filtration, washing with CH2Cl2, drying in vac., elem. anal.; second product: evapn. of filtrate, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;A 40%
B 30%
dibromo(phenyl)borane
4151-77-3

dibromo(phenyl)borane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

difluoro-phenyl-borane
368-98-9

difluoro-phenyl-borane

Conditions
ConditionsYield
C6H5BBr2 + TiF4 mixed to a pulp, after 15 min stirring it liquefies, boiled using backflow for 2 h; distn.;49%
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