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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

Trioctylphosphine oxide Manufacturer/High quality/Best price/In stock

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance White solid Conforms Assay(GC) 98%min

High purity Trioctylphosphinoxide with high quality and best price cas:791-28-6

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $150.0 / 800.0

Type:Manufacturers

inquiry

Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Trioctylphosphine Oxide supplier in China

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Trioctylphosphine Oxide

Cas:78-50-2

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Product Name: Trioctylphosphine oxide Synonyms: CYANEX 921;TOPO;TRI-N-OCTYLPHOSPHINE OXIDE;TRI-N-OCTYLPHOSPHINOXIDE;TRIOCTYLPHOSPHINE OXIDE;hostarexpx324;trioctyl-phosphineoxid;TRIOCTYLPHOSPHINE OXIDE, TECH

TIANFU-CHEM Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

78-50-2 Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Industrial GradeCAS 78-50-2 with high quality products

Cas:78-50-2

Min.Order:10 Gram

FOB Price: $146.0 / 176.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

Trioctylphosphine oxide CAS NO.78-50-2

Cas:78-50-2

Min.Order:20 Kilogram

FOB Price: $10.0 / 100.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Phosphine oxide,trioctyl- 78-50-2

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

Trioctylphosphine oxide Organic phosphine compounds

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

Trioctylphosphine oxide CAS:78-50-2 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic inte

Trioctylphosphine oxide CAS:78-50-2

Cas:78-50-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Phosphine oxide,trioctyl-

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Lonwin Chemical Group Limited

Trioctylphosphine oxide CAS: 78-50-2 Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard Shelf life 2 years Storage should be stored in a well-

Factory supply Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Phosphine oxide,trioctyl-

Cas:78-50-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Trioctylphosphine Oxide

Cas:78-50-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $40.0 / 50.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Trioctylphosphine Oxide

Cas:78-50-2

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:10g/bag,or as your request Application:Used as Pharmaceutical Intermediates Tr

Phosphine oxide,trioctyl-

Cas:78-50-2

Min.Order:1 Gram

Negotiable

Type:Trading Company

inquiry

Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

Quality Manufacturer Trioctylphosphine oxide

Cas:78-50-2

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Trioctylphosphine oxide Basic information Product Name: Trioctylphosphine oxide Synonyms: Trioctylphosphineoxide,99%TOPO;Trioctylphosphineoxide,min.90%TOPO;Phosphine oxide, trioctyl-;HISHICOLIN PO-8;CYANEX 921;TOPO;TRI-N-OCTYLPHOSPHINE OXIDE;T

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Tri-n-octylphosphine oxide

Cas:78-50-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trioctylphosphine oxide

Cas:78-50-2

Min.Order:0

Negotiable

Type:Other

inquiry

JINHUA HUAYI CHEMICAL CO., LTD.

Jinhua huayi chemical co., ltd. is dedicated to the development, production and marketing of chemicals. On the basis of equality and mutual benefit, and under the principle of customer first, credit first, quality first, we are ready to join hands

Tri-N-Octylphosphine Oxide

Cas:78-50-2

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With fluorosulfonylchloride In dichloromethane for 1h; Ambient temperature;98%
Stage #1: TOP With water; dihydrogen peroxide In toluene at 0 - 20℃; for 12h; Inert atmosphere;
Stage #2: In toluene at 20℃; for 4h; Molecular sieve;
90%
In 1,2,4-trimethylbenzene at 25℃; for 1h; Inert atmosphere;
With selenium; octadec-1-ene
octanol
111-87-5

octanol

dioctylphosphinyl chloride
7539-86-8

dioctylphosphinyl chloride

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
In chloroform at 50℃; for 2h;95.1%
C24H51BrClP

C24H51BrClP

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With water In toluene at 20℃; for 1h;92.6%
4-chlorophenylphosphonoyl dichloride
22585-81-5

4-chlorophenylphosphonoyl dichloride

A

cyanex-921
78-50-2

cyanex-921

B

4-chlorophenyldichlorophosphine
1005-33-0

4-chlorophenyldichlorophosphine

Conditions
ConditionsYield
In dichloromethaneA n/a
B 84%
oct-1-ene
111-66-0

oct-1-ene

oxyde de dioctyl phosphine
3011-82-3

oxyde de dioctyl phosphine

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With acetic acid at 120 - 135℃; for 8h;81.4%
1-Chlorooctane
111-85-3

1-Chlorooctane

oxyde de dioctyl phosphine
3011-82-3

oxyde de dioctyl phosphine

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With sodium amide; tert-butyl alcohol In tetrahydrofuran at 40℃; for 0.833333h;72%
3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan
106446-20-2

3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan

A

cyanex-921
78-50-2

cyanex-921

B

azoxy(4-chlorophenylfurazan)
106446-23-5

azoxy(4-chlorophenylfurazan)

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In 1,2-dichloro-ethane for 2h; Heating;A n/a
B 60%
1-Chlorooctane
111-85-3

1-Chlorooctane

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
In toluene; Petroleum ether39%
With hydrogenchloride; trichlorophosphate In 5,5-dimethyl-1,3-cyclohexadiene; diethyl ether; water
1-bromo-octane
111-83-1

1-bromo-octane

A

oxyde de dioctyl phosphine
3011-82-3

oxyde de dioctyl phosphine

B

cyanex-921
78-50-2

cyanex-921

C

octylphosphinic acid
6196-68-5

octylphosphinic acid

Conditions
ConditionsYield
With potassium hydroxide semihydrate; phosphorus; N-benzyl-N,N,N-triethylammonium chloride In toluene at 60 - 62℃; for 5h; Reagent/catalyst; Inert atmosphere;A n/a
B n/a
C 19%
octylmagnesium bromide
17049-49-9

octylmagnesium bromide

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With diethyl ether; trichlorophosphate
With trichlorophosphate
1-Chlorooctane
111-85-3

1-Chlorooctane

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

A

cyanex-921
78-50-2

cyanex-921

B

dioctyl(phenyl)phosphine oxide
2845-09-2

dioctyl(phenyl)phosphine oxide

Conditions
ConditionsYield
With sodium hydroxide 1.) 200 deg C, 24 h, 2.) reflux, 3 h; Yield given. Multistep reaction. Yields of byproduct given;
1-Chlorooctane
111-85-3

1-Chlorooctane

octylphenylphosphinous acid
107694-27-9

octylphenylphosphinous acid

A

cyanex-921
78-50-2

cyanex-921

B

dioctyl(phenyl)phosphine oxide
2845-09-2

dioctyl(phenyl)phosphine oxide

Conditions
ConditionsYield
With sodium hydroxide 1.) 200 deg C, 24 h, 2.) reflux, 3 h; Yield given. Multistep reaction. Yields of byproduct given;
1-Iodooctane
629-27-6

1-Iodooctane

A

dioctylphosphinic acid
683-19-2

dioctylphosphinic acid

B

cyanex-921
78-50-2

cyanex-921

C

1-methylheptyl-n-octylphosphinic acid

1-methylheptyl-n-octylphosphinic acid

Conditions
ConditionsYield
With phosphorus; iodine 1) 125 - 130 deg C, 36 h, 2) H2O; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
1-Iodooctane
629-27-6

1-Iodooctane

A

dioctylphosphinic acid
683-19-2

dioctylphosphinic acid

B

cyanex-921
78-50-2

cyanex-921

C

1-methylheptyl-n-octylphosphinic acid

1-methylheptyl-n-octylphosphinic acid

D

1-methylheptyl-di-n-octylphosphine oxide
128144-48-9

1-methylheptyl-di-n-octylphosphine oxide

Conditions
ConditionsYield
With phosphorus; iodine 1) 150 - 160 deg C, 16 h, 2) H2O; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
1-bromo-octane
111-83-1

1-bromo-octane

phenylphosphinic acid
1779-48-2

phenylphosphinic acid

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With potassium hydroxide 1.) 200 deg C, 7.5 h, 2.) reflux, 4 h; Yield given. Multistep reaction;
1-bromo-octane
111-83-1

1-bromo-octane

octylphenylphosphinous acid
107694-27-9

octylphenylphosphinous acid

A

cyanex-921
78-50-2

cyanex-921

B

dioctyl(phenyl)phosphine oxide
2845-09-2

dioctyl(phenyl)phosphine oxide

Conditions
ConditionsYield
With sodium hydroxide 1.) 200 deg C, 5 h, 2.) reflux, 3 h; Yield given. Multistep reaction. Yields of byproduct given;
1-bromo-octane
111-83-1

1-bromo-octane

A

oxyde de dioctyl phosphine
3011-82-3

oxyde de dioctyl phosphine

B

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With phosphorus; potassium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In tetrahydrofuran at 60 - 65℃; for 6h; Yield given;
3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan
106446-20-2

3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan

A

cyanex-921
78-50-2

cyanex-921

B

3-(4-chlorophenyl)-4-nitrofurazan
106446-22-4

3-(4-chlorophenyl)-4-nitrofurazan

C

azoxy(4-chlorophenylfurazan)
106446-23-5

azoxy(4-chlorophenylfurazan)

Conditions
ConditionsYield
With 3,3-dimethyldioxirane In acetone for 16h; Ambient temperature;
octylmagnesium halide

octylmagnesium halide

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With trichlorophosphate Alkylation;
phosphoric acid tributyl ester
126-73-8

phosphoric acid tributyl ester

Th(NO3)4(tri-noctylphosphine oxide)2

Th(NO3)4(tri-noctylphosphine oxide)2

A

cyanex-921
78-50-2

cyanex-921

B

Th(NO3)4(tributylphosphate)2

Th(NO3)4(tributylphosphate)2

Conditions
ConditionsYield
In chloroform at 20℃; Inert atmosphere; Schlenk technique;
phosphoric acid tributyl ester
126-73-8

phosphoric acid tributyl ester

LaCl3(tri-noctylphosphine oxide)3

LaCl3(tri-noctylphosphine oxide)3

A

cyanex-921
78-50-2

cyanex-921

B

LaCl3(tributylphosphate)3

LaCl3(tributylphosphate)3

Conditions
ConditionsYield
In chloroform at 20℃; Inert atmosphere; Schlenk technique;
sodium dioctylphosphinate
67206-59-1

sodium dioctylphosphinate

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: chloroform / 16 h / 80 °C
2: chloroform / 2 h / 50 °C
View Scheme
Multi-step reaction with 3 steps
1: chloroform / 16 h / 80 °C
2: water / chloroform
3: acetic acid / 8 h / 120 - 135 °C
View Scheme
Multi-step reaction with 3 steps
1: chloroform / 16 h / 80 °C
2: toluene / 24 h / 100 °C
3: water / toluene / 1 h / 20 °C
View Scheme
oct-1-ene
111-66-0

oct-1-ene

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: sodium hypophosphite; acetic acid / 4 h / 120 - 135 °C
2: chloroform / 16 h / 80 °C
3: chloroform / 2 h / 50 °C
View Scheme
Multi-step reaction with 4 steps
1: sodium hypophosphite; acetic acid / 4 h / 120 - 135 °C
2: chloroform / 16 h / 80 °C
3: water / chloroform
4: acetic acid / 8 h / 120 - 135 °C
View Scheme
Multi-step reaction with 4 steps
1: sodium hypophosphite; acetic acid / 4 h / 120 - 135 °C
2: chloroform / 16 h / 80 °C
3: toluene / 24 h / 100 °C
4: water / toluene / 1 h / 20 °C
View Scheme
dioctylphosphinyl chloride
7539-86-8

dioctylphosphinyl chloride

cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: toluene / 24 h / 100 °C
2: water / toluene / 1 h / 20 °C
View Scheme
cyanex-921
78-50-2

cyanex-921

dioxomolybdenum(VI) dibromide bis(trioctyl phosphine oxide)

dioxomolybdenum(VI) dibromide bis(trioctyl phosphine oxide)

Conditions
ConditionsYield
In diethyl ether mixed; evapd.(vac. room temp.), elem. anal.;99%
cyanex-921
78-50-2

cyanex-921

3-amino-4-(p-chlorophenyl)-1,2,5-oxadiazole
21741-98-0

3-amino-4-(p-chlorophenyl)-1,2,5-oxadiazole

3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan
106446-20-2

3-(4-chlorophenyl)-4-trioctylphosphiniminofurazan

Conditions
ConditionsYield
With trifluoromethanesulfonic acid anhydride In dichloromethane 1.) -5 deg C, 0.5 h; 2.) -5 deg C, 3 h, then room temperature, overnight;93%
cyanex-921
78-50-2

cyanex-921

dihydrogen peroxide
7722-84-1

dihydrogen peroxide

molybdenum(VI) oxide

molybdenum(VI) oxide

[MoO(O2)2(OP(C8H17)3)]

[MoO(O2)2(OP(C8H17)3)]

Conditions
ConditionsYield
In water suspending MoO3 in aq. H2O2 at 40°C for 4 h, addn. of the ligand,kept for 2 h; concn. (vac.), extn. (CH2Cl2), evapn., washing (H2O), drying (vac.); elem. anal.;93%
uranyl(VI) nitrate

uranyl(VI) nitrate

1-Phenyl-3-methyl-4-acetyl-5-pyrazolon
4173-74-4

1-Phenyl-3-methyl-4-acetyl-5-pyrazolon

cyanex-921
78-50-2

cyanex-921

UO2(C6H5NNCCH3CCOCH3CO)2(C8H17)3PO

UO2(C6H5NNCCH3CCOCH3CO)2(C8H17)3PO

Conditions
ConditionsYield
In water; benzene UO2(NO3)2 soln. at pH 2 extd. with benzene soln. of PMAP and TOPO; benzene layer dried with Na2SO4, evapd. dryness in rotary evaporator and product recrystd. twice from n-hexane; elem. anal.;89%
cyanex-921
78-50-2

cyanex-921

lanthanide(III)chloride heptahydrate

lanthanide(III)chloride heptahydrate

LaCl3(tri-noctylphosphine oxide)3

LaCl3(tri-noctylphosphine oxide)3

Conditions
ConditionsYield
In chloroform at 20℃; Inert atmosphere; Schlenk technique;81.7%
cyanex-921
78-50-2

cyanex-921

[(κ2-P,O-2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)PdCl(μ-Na)]2

[(κ2-P,O-2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)PdCl(μ-Na)]2

[(κ2-P,O-2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)PdMe(OPOct3)]
1366181-66-9

[(κ2-P,O-2-(bis(2-methoxyphenyl)phosphino)benzenesulfonato)PdMe(OPOct3)]

Conditions
ConditionsYield
With AgBF4 In dichloromethane byproducts: AgCl, NaBF4; using Schlenk techniques; stirring of suspn. of ((κ2-P,O-2-(2-MeOC6H4)2PC6H4SO3)PdCl(μ-Na))2 (0.5 equiv.), AgBF4 (1 equiv.) and OPOct3 (1 equiv.) in CH2Cl2 for 30 min in the dark; pptn., filtration, evapn., washing with pentane, drying under vac.; elem. anal.;81%
thorium(IV) nitrate pentahydrate

thorium(IV) nitrate pentahydrate

cyanex-921
78-50-2

cyanex-921

Th(NO3)4(tri-noctylphosphine oxide)2

Th(NO3)4(tri-noctylphosphine oxide)2

Conditions
ConditionsYield
In chloroform at 20℃; Inert atmosphere; Schlenk technique;80.8%
europium(III) nitrate hexahydrate

europium(III) nitrate hexahydrate

cyanex-921
78-50-2

cyanex-921

bis(trifluoromethane)sulfonimide lithium
90076-65-6

bis(trifluoromethane)sulfonimide lithium

[Eu(tri-n-octylphosphine oxide)4(NO3)2]bis(trifluoromethylsulfonyl)imide

[Eu(tri-n-octylphosphine oxide)4(NO3)2]bis(trifluoromethylsulfonyl)imide

Conditions
ConditionsYield
Stage #1: cyanex-921; bis(trifluoromethane)sulfonimide lithium In ethanol at 60℃;
Stage #2: europium(III) nitrate hexahydrate In ethanol; water at 60℃; for 4h;
76%
europium(III) nitrate pentahydrate

europium(III) nitrate pentahydrate

cyanex-921
78-50-2

cyanex-921

C22H13F3O2

C22H13F3O2

[Eu(TphTA)3]*TOPO*H2O

[Eu(TphTA)3]*TOPO*H2O

Conditions
ConditionsYield
In ethanol at 20 - 50℃; for 21h;75%
peroxotungstic acid

peroxotungstic acid

cyanex-921
78-50-2

cyanex-921

trioctylphosphine oxide-peroxotungstic acid
185897-00-1

trioctylphosphine oxide-peroxotungstic acid

Conditions
ConditionsYield
In 1,4-dioxane W compd. addn. to P-compd. soln. with stirring; oily phase sepn., washing (water, MeOH), solvent elimination (heating, 50°C, vac.), solidification (refrigerator); elem. anal.;73%
europium(III) nitrate pentahydrate

europium(III) nitrate pentahydrate

cyanex-921
78-50-2

cyanex-921

C22H13F3O2

C22H13F3O2

[Eu(TphTA)3]*2TOPO

[Eu(TphTA)3]*2TOPO

Conditions
ConditionsYield
In ethanol at 20 - 50℃; for 21h;71%
europium(III) nitrate pentahydrate

europium(III) nitrate pentahydrate

cyanex-921
78-50-2

cyanex-921

C22H13F3O2

C22H13F3O2

[Eu(TphTA)2]*NO3*2TOPO

[Eu(TphTA)2]*NO3*2TOPO

Conditions
ConditionsYield
In ethanol at 20 - 50℃; for 21h;68%
europium(III) nitrate pentahydrate

europium(III) nitrate pentahydrate

cyanex-921
78-50-2

cyanex-921

4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione
893-33-4

4,4,4-trifluoro-1-(2-naphthyl)-1,3-butanedione

(nitrato)bis{trioctylphosphine oxide}bis{4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionato}-europium(III)

(nitrato)bis{trioctylphosphine oxide}bis{4,4,4-trifluoro-1-(2-naphthyl)butane-1,3-dionato}-europium(III)

Conditions
ConditionsYield
In ethanol; water addition of 0.05 g Eu salt (as nitrate hydrate) in H2O (10 ml) to 0.08 g of the dione and 0.078 g of the phosphine oxide in 10 ml ethanol and solvation of the precipitate by addition of ethanol with stirring;; crystallization on standing in a beaker overnight; elem. anal., detn. by (1)H NMR-, IR spectroscopy, X-ray diffraction;;60%
diammonium cerium(IV) nitrate

diammonium cerium(IV) nitrate

cyanex-921
78-50-2

cyanex-921

Ce(NO3)4(Oct3PO)2

Ce(NO3)4(Oct3PO)2

Conditions
ConditionsYield
In chloroform-d1 Solvent;60%
cyanex-921
78-50-2

cyanex-921

Conditions
ConditionsYield
With pinacolboronic acid In acetonitrile at 100℃; for 120h; Inert atmosphere; Glovebox; Sealed tube; Schlenk technique;57%
With 1,1,3,3-Tetramethyldisiloxane; titanium(IV) isopropylate In various solvent(s) at 100℃; for 10h;
With indium(III) bromide; 1,1,3,3-Tetramethyldisiloxane In toluene at 100℃; for 18h; Inert atmosphere; Sealed tube;
(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne)
148509-02-8

(meso-5,10,15,20-tetra-p-tolylporphyrinato)Ti(η2-3-hexyne)

cyanex-921
78-50-2

cyanex-921

(meso-5,10,15,20-tetra-p-tolylporphyrinato)bis(trioctylphosphine oxide)Ti
326474-31-1

(meso-5,10,15,20-tetra-p-tolylporphyrinato)bis(trioctylphosphine oxide)Ti

Conditions
ConditionsYield
In toluene byproducts: 3-hexyne; under N2; Ti complex and 2 equiv. of ligand in toluene stirred for 2.5 h; concd.; redissolved in hexanes; reduced in vac.; cooled to -25°C for 1 d; elem. anal.;52%
cyanex-921
78-50-2

cyanex-921

tris(pentafluorophenyl)borate
1109-15-5

tris(pentafluorophenyl)borate

B(C6F5)3(C8H17)3PO
356074-07-2

B(C6F5)3(C8H17)3PO

Conditions
ConditionsYield
In pentane (N2); addn. of 1 equiv. of boron compd. to a soln. of phosphine in pentane; elem. anal.;51%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
In further solvent(s) byproducts: ClCH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium(IV) bromide
7789-68-6

titanium(IV) bromide

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
In further solvent(s) byproducts: BrCH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
In further solvent(s) byproducts: FCH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium(IV) iodide
7720-83-4

titanium(IV) iodide

rutile

rutile

Conditions
ConditionsYield
In further solvent(s) byproducts: ICH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
cyanex-921
78-50-2

cyanex-921

europium(III) chloride hexahydrate

europium(III) chloride hexahydrate

1-phenyl-3-[4-(4-propylcyclohexyl)phenyl]propane-1,3-dione

1-phenyl-3-[4-(4-propylcyclohexyl)phenyl]propane-1,3-dione

C120H183EuO8P2

C120H183EuO8P2

Conditions
ConditionsYield
With potassium hydroxide In ethanol43%
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