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inquiryTRIS(PENTAFLUOROPHENYL)BORANE Basic information Product Name: TRIS(PENTAFLUOROPHENYL)BORANE Synonyms: PERFLUOROTRIPHENYLBORANE;TRIS(PENTAFLUOROPHENYL)BORANE;TRIS(PE
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inquiryAppearance:white powder Storage: Inert atmosphere,Store in freezer, under -20°C Package:25kg/Barrel Application:APIs Transportation:Express/Sea/Air Port:Any port in China
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inquiryProduct Name: TRIS(PENTAFLUOROPHENYL)BORANE CAS: 1109-15-5 MF: C18BF15 MW: 511.98 EINECS: 000-000-0 Mol File: 1109-15-5.mol TRIS(PENTAFLUOROPHENYL)BORANE Structure TRIS(PENTAFLUOROPHENYL)BORANE Chemical Properties Melting point
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inquiryTRIS(PENTAFLUOROPHENYL)BORANE CAS: 1109-15-5 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality org
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inquiryHello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryA substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc
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inquiryProduct name: Tris(Pentafluorophenyl)Boron CAS No.:1109-15-5 Molecule Formula:C18BF15 Molecule Weight:511.98 Purity: 98% Package: 25kg/drum Description:White powder Manufacture Standards:Enterprise Standard TESTING ITEMS
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inquiryZhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed
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inquiryfactory Storage:Shading, sealed and preserved. Package:Grams, Kilograms Application:An organic synthetic intermediate used Transportation:According to customer request Port:Qingdao
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inquiryLower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe
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inquirybromopentafluorobenzene
boron trifluoride diethyl etherate
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether at 20℃; Stage #2: boron trifluoride diethyl etherate In toluene at 0℃; for 1h; Schlenk technique; Inert atmosphere; Stage #3: In diethyl ether; toluene at 100℃; for 1h; Schlenk technique; Inert atmosphere; | 95% |
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether for 1h; Reflux; Stage #2: boron trifluoride diethyl etherate In toluene at 100℃; for 1h; | 88% |
Stage #1: bromopentafluorobenzene With magnesium In diethyl ether at 20℃; for 1h; Inert atmosphere; Stage #2: boron trifluoride diethyl etherate In toluene at 100℃; for 1h; Inert atmosphere; | 88% |
Conditions | Yield |
---|---|
Stage #1: bromopentafluorobenzene With n-butyllithium In hexane at -80℃; for 0.666667h; Stage #2: With boron trichloride In hexane at -80 - 20℃; | 85% |
Multi-step reaction with 2 steps 1: n-BuLi / light petroleum; hexane / 1 h / -78 °C 2: 48 percent / boron tribromide / light petroleum; hexane / 15 h / Ambient temperature View Scheme | |
Multi-step reaction with 2 steps 1: magnesium; 1-bromo-butane / dibutyl ether / 2.5 h / 30 °C / Inert atmosphere 2: methyl cyclohexane; dibutyl ether / 2.5 h / 20 - 30 °C / Inert atmosphere View Scheme |
bromopentafluorobenzene
boron trichloride
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
Stage #1: bromopentafluorobenzene With n-butyllithium In hexane at -80℃; for 1h; Inert atmosphere; Schlenk technique; Glovebox; Stage #2: boron trichloride In hexane at -80 - 20℃; for 17h; Inert atmosphere; Schlenk technique; Glovebox; | 84% |
Stage #1: bromopentafluorobenzene With n-butyllithium In hexane; pentane at -78℃; for 1h; Stage #2: boron trichloride In hexane; pentane at 20℃; | 68% |
Stage #1: bromopentafluorobenzene With n-butyllithium In hexane at -80℃; for 1.5h; Inert atmosphere; Stage #2: boron trichloride In hexane at -80 - 25℃; Inert atmosphere; | 67% |
Conditions | Yield |
---|---|
In dichloromethane-d2 byproducts: atactic oligopropylene; Zr complex reacted with 15-fold excess of vinyl chloride at 25° for 5 min to produce a dark-red soln.; within 24 h at 25° the soln. turned to yellow; NMR monitoring; intermediates and products detd. by NMR spectra; | A 81% B n/a |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
With boron tribromide In dichloromethane | 80% |
boron trifluoride diethyl etherate
2,3,4,5,6-pentafluorophenylmagnesium bromide
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
80% |
boron tribromide
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In dichloromethane under N2; soln. of BBr3 (0.33 equiv) in CH2Cl2 added dropwise to soln. of (Cu(C6F5))4(η2-toluene)2 in CH2Cl2 at -78 °C; mixt. stirredat -78 °C for 1 h, allowed to slowly warm to room temp., and sti rred for addnl. 12 h; react. mixt. filtered through fritted glass disk and washed twice with CH2Cl2; all volatiles removed under vac.; crude product purified by high-vac. sublimation at 80 °C; | 80% |
boron tribromide
A
tris(pentafluorophenyl)borate
B
(pentafluoro phenyl) dibromo borane
Conditions | Yield |
---|---|
In toluene under N2; soln. of BBr3 (1.00 equiv) in toluene added to soln. of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stirred at -78°C for 1 h and then allowed to gradually warm to room temp.; products not sepd.; product distribution in supernatant estimated by (19)F-NMR spectroscopy; | A 10% B 74% C 16% |
In toluene under N2; soln. of BBr3 (0.50 equiv) in toluene added to soln. of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stirred at -78°C for 1 h and then allowed to gradually warm to room temp.; products not sepd.; product distribution in supernatant estimated by (19)F-NMR spectroscopy; | A 43% B 34% C 23% |
Conditions | Yield |
---|---|
In neat (no solvent) byproducts: propylene; under Ar; mixt. of Ti complex and n-propyl iodide stirred at 20°Cfor several minutes, stored for 24 h; soln. concd., stored at 20°C under Ar for 3 d, crystals sepd. by decantation, dried at 20°C for 2 h under vac., soln. evapd. undervac. to dryness, residue extd. with n-hexane; elem. anal.; | A 70% B 0% C n/a |
2,3,4,5,6-pentafluorophenylmagnesium bromide
boron trichloride
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
at -15 - 20℃; Temperature; | 63.8% |
Conditions | Yield |
---|---|
With boron tribromide In dichloromethane | A 3 % Spectr. B 62% C 10 % Spectr. |
(pentafluorophenyl)copper
boron tribromide
A
tris(pentafluorophenyl)borate
B
(pentafluoro phenyl) dibromo borane
Conditions | Yield |
---|---|
In dichloromethane under N2; soln. of C6F5Cu in CH2Cl2 added dropwise over 20 min to soln. of BBr3 (3 equiv) in CH2Cl2 at -78 °C; mixt. stirred at -78 °C for 1 h and then slowly warmed to room temp. and stirred for 3 h; mixt. filtered; volatiles slowly removed at -20 °C under high vac.; crude product distd. under dynamic vac. (DV) at ca. 50°C into cold trap (liq. N2), transferred under static vac. into storage flask and kept under DV at 0°C for 6 h; | A n/a B 62% C n/a |
Conditions | Yield |
---|---|
With tert.-butyl lithium; boron trichloride In octane; hexane; di-isopropyl ether; pentane | 61.3% |
With n-butyllithium; boron trichloride In diethyl ether; hexane; toluene | 55.8% |
A
tris(pentafluorophenyl)borate
B
bis(pentafluorophenyl)boron chloride
C
dichloro(pentafluorophenyl)borane
Conditions | Yield |
---|---|
With boron trichloride In dichloromethane | A 8 % Spectr. B 27 % Spectr. C 57% |
(pentafluorophenyl)copper
boron trichloride
A
tris(pentafluorophenyl)borate
B
bis(pentafluorophenyl)boron chloride
C
dichloro(pentafluorophenyl)borane
Conditions | Yield |
---|---|
In dichloromethane under N2; soln. of C6F5Cu in CH2Cl2 added dropwise over 20 min to soln. of BCl3 (3 equiv) in CH2Cl2 at -78 °C; mixt. stirred at -78 °C for 1 h and then allowed to slowly warm to room temp. and stirred for 3 h; after filtration all volatiles slowly removed under high vac. first at -25 °C and subsequently over 3 h at 0 °C; crude product distd. under dynamic vac. at ca. 40 °C into cold trap (liq. N2); vac. transfer into storage flask; | A n/a B n/a C 57% |
boron trichloride
A
tris(pentafluorophenyl)borate
B
bis(pentafluorophenyl)boron chloride
C
dichloro(pentafluorophenyl)borane
Conditions | Yield |
---|---|
In hexane; toluene under N2; soln. of BCl3 (1.00 equiv) in hexanes added to soln. of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stirred at -78°C for 1 h and then allowed to gradually warm to room temp.; products not sepd.; product distribution in supernatant estimated by (19)F-NMR spectroscopy; | A 14% B 30% C 56% |
In hexane; toluene under N2; soln. of BCl3 (0.50 equiv) in hexanes added to soln. of (Cu(C6F5))4(η2-toluene)2 in toluene at -78 °C; mixt. stirred at -78°C for 1 h and then allowed to gradually warm to room temp.; products not sepd.; product distribution in supernatant estimated by (19)F-NMR spectroscopy; | A 37% B 35% C 28% |
dibutyl ether
Pentafluorobenzene
butylsodium
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In decane; hexane | 52% |
A
trans-2,6-dimethyl-2,6-diphenylpiperidine
B
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In (2)H8-toluene byproducts: H2; (Ar); borate was stirred in toluene-d8 at 110°C for 36 h; detected by NMR; | A 50% B 50% |
Conditions | Yield |
---|---|
With boron tribromide In hexane; Petroleum ether for 15h; Ambient temperature; | 48% |
bromopentafluorobenzene
boron tribromide
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
With n-BuLi In hexane (N2); addn. of n-BuLi in hexane to C6BrF5 in light petroleum at -78°C, stirring (1 h), addn. of BBr3 in light petroleum at -78°C, further stirring (room temp., 15 h); filtration (Celite), concn., decantation, drying (vac.), further purifn.by vac. sublimation (140°C, E-1 Torr); | 48% |
Conditions | Yield |
---|---|
With tert.-butyl lithium In octane; diethyl ether; pentane | 45% |
tris(perfluorophenyl)borane-acetonitrile adduct
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
byproducts: CH3CN; vac. (1E-5 Torr); | 0% |
at 84.84℃; under 0.09 Torr; for 72h; Thermodynamic data; Time; Inert atmosphere; Sealed tube; |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In chloroform-d1 Product distribution; Photolysis; |
Conditions | Yield |
---|---|
With boron trifluoride diethyl etherate In diethyl ether at 28 - 37℃; for 3.33333 - 4h; | |
With boron trifluoride diethyl etherate In diethyl ether; toluene at 28 - 40℃; for 2h; Reactivity; |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
With [Ph3C][BBun(C6F5)4-n] In benzene-d6 Ar-atmosphere, NMR tube; detd. by NMR spectroscopy; |
bromopentafluorobenzene
trifluoroborane diethyl ether
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
With magnesium In diethyl ether; toluene refluxing (1 h), ether removal, heating (100°C, 18 h); evapn., sublimation, cecrystn. (hexane); |
n-butyllithium
bromopentafluorobenzene
boron trichloride
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In pentane BCl3 is added to a stirred suspension of n-butyllithium and pentafluorophenyl bromide in pentane at -78°C; warming up slowly to room temp.; |
boron trichloride
pentafluorophenyl lithium
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In pentane suspension in pentane, reaction at 25°C;; | 30-50 |
In hexane at -80 - 20℃; for 2h; Inert atmosphere; |
2,3,4,5,6-pentafluorophenylmagnesium bromide
boron trichloride
A
tris(pentafluorophenyl)borate
B
bis(pentafluorophenyl)boron chloride
Conditions | Yield |
---|---|
In toluene for 5h; Heating; | 100% |
In toluene at 20℃; | 91.9% |
In toluene to soln. B(C6F5)3 and imidazole in toluene triethylamine in toluene wasadded, react. mixt. was stirred overnight at room temp.; soln. was concd., hexane was added, ppt. was filtered, washed with hexane and dried under reduced pressure; elem. anal.; | 91.9% |
tris(pentafluorophenyl)borate
acetonitrile
tris(perfluorophenyl)borane-acetonitrile adduct
Conditions | Yield |
---|---|
Inert atmosphere; Sealed tube; | 100% |
In pentane Ar-atmosphere; pptn. Lewis base dropwise addn., stirring (room temp., 2 h); filtering, washing (pentane), drying (vac.); elem. anal.; | 94% |
In acetonitrile; pentane stirring at room temp. for 1 h; evapn., drying (vac., 1E-5 Torr, room temp.); elem. anal.; | 89% |
In pentane Schlenk techniques; MeCN added to suspn. of B(C6F5)3 (molar ratio 3.4:1) in pentane; stirred for 1 h; filtered; ppt. dried in vac.; | 78% |
With 2,6-dimethylpyridine In toluene N2 glove box; mixt. 2,6-lutidine, B(C6F5)3 and MeCN (1:1:1 mol) in toluene stirred for 20 min; evapd. (vac.); NMR; |
pyrrole
tris(pentafluorophenyl)borate
N-[tris(pentafluorophenyl)borane]-5H-pyrrole
Conditions | Yield |
---|---|
In dichloromethane at 20℃; | 100% |
[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)zirconium
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
at 25℃; Schlenk technique; Glovebox; Inert atmosphere; | 100% |
In toluene all manipulations under Ar atm.; soln. of complex treated with B compd. at room temp., stirred for 30 min; cooled to -35°C, filtered, dried in vac., elem. anal.; | 83% |
In benzene-d6 in sealed NMR tube; | |
In toluene detd. by NMR; |
(t)BuC(N(i)Pr)2GaMe2
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In further solvent(s) under N2; in C6D5Cl, 23°C, 15 min; not isolated; NMR; | 100% |
tris(pentafluorophenyl)borate
[(CH3C(NCH(CH3)2)2)2Al2(CH3)3](1+)*[CH3B(C6F5)3](1-)=[(CH3C(NCH(CH3)2)2)2Al2(CH3)3][CH3B(C6F5)3]
Conditions | Yield |
---|---|
In further solvent(s) under N2; in C6D5Cl, 23°C, 10 min; not isolated; NMR; | 100% |
In dichloromethane under N2; 23°C, 30 min; evapn. under vac., trituration with pentane; elem. anal.; | 83% |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In dichloromethane at room temp., 30 min; NMR; | 100% |
Conditions | Yield |
---|---|
In hexane | 100% |
In hexane; toluene B(C6F5)3 and AlMe3 in 1:3 toluene/hexanes mixt.; | 99% |
In hexane; toluene (inert atm.); reaction of borane deriv. with trimethylaluminium in hexane/toluene (3:1); | 99% |
tris(pentafluorophenyl)borate
[(CH3C(NCH(CH3)2)2)2Ga2(CH3)3](1+)*[CH3B(C6F5)3](1-)=[(CH3C(NCH(CH3)2)2)2Ga2(CH3)3][CH3B(C6F5)3]
Conditions | Yield |
---|---|
In further solvent(s) under N2; in C6D5Cl, 23°C, 15 min; not isolated; NMR; | 100% |
In hexane; dichloromethane under N2; 23°C, 3 h; solid filtered off, washed with hexane and dried under vac.; elem. anal.; | 71% |
Cp2ZrMe(pentafluorophenyl)
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In dichloromethane-d2 NMR tube, -78°C; detd. by NMR spectroscopy; | 100% |
Zr(η3-C4H7)(η4-1,3-butadiene)(η5-1,3-C5H3(Si(CH3)3)2)
tris(pentafluorophenyl)borate
[Zr(C6F5)(CH2CHCHCHB(C6F5)2)(C5H3(Si(CH3)3)2)]
Conditions | Yield |
---|---|
In (2)H8-toluene (N2); addn. of B(C6F5)3 in toluene-d8 at -60°C to the Zr complexin toluene-d8, warming to room temp.; NMR monitoring; | 100% |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In dichloromethane | 100% |
In dichloromethane under N2; a soln. of B(C6F5)3 in CH2Cl2 was added to a soln. of Ir complex in CH2Cl2, the soln. was stirred for 5 min; the mixt. was evapd. in vac.; elem. anal.; | 88% |
tris(pentafluorophenyl)borate
(C6H5CH2)Zr(C12H24O4N2)(1+)*(C6H5CH2)B(C6F5)3(1-)=[(C6H5CH2)Zr(C12H24O4N2)][(C6H5CH2)B(C6F5)3]
Conditions | Yield |
---|---|
In benzene | 100% |
tris(pentafluorophenyl)borate
[Hf(C3H5)(CH2C(CH3)CHCH2B(C6F5)3)(C5H3(Si(CH3)3)2)]
Conditions | Yield |
---|---|
In (2)H8-toluene (N2); addn. of B(C6F5)3 in toluene-d8 at -40°C to the Hf complex in toluene-d8; NMR monitoring; | 100% |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In dichloromethane-d2 Ar-atmosphere, room temp.; detd. by NMR spectroscopy; | 100% |
nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)
tris(pentafluorophenyl)borate
((CH3)3CC8H3NN)4ReNB(C6F5)3
Conditions | Yield |
---|---|
In dichloromethane Re compd. dissolved in CH2Cl2 and cooled to -5°C, electrophile added dropwise to this soln., stirred for 6 h at -5°C; solvent removed at -5°C, elem. anal.; | 100% |
Conditions | Yield |
---|---|
for 0.333333h; Inert atmosphere; | 100% |
In tetrahydrofuran; toluene (Ar); Schlenk technique; THF was added to soln. of B compd. in toluene; vilatiles removed; dried (vac.); | |
In toluene (inert atm.); addn. of THF to toluene soln. of borane deriv. at room temp.; drying in vac.; |
tris(pentafluorophenyl)borate
W(CH3)(NC6H5)(NC5H4C(CH3)(CH2NSi(CH3)3)2)(1+)*(CH3)B(C6F5)3(1-)=W(CH3)(NC6H5)(NC5H4C(CH3)(CH2NSi(CH3)3)2)(CH3)B(C6F5)3
Conditions | Yield |
---|---|
In not given treatment of W-complex with equivalent of B-compound; | 100% |
[(η5-1,3-(SiMe2-η-N-t-Bu)2-cyclopentadienyl)(methyl)zirconium]
tris(pentafluorophenyl)borate
(zirconium)(C5H3(SiMe2(η1-NtBu))2)B(C6F5)3(Me)
Conditions | Yield |
---|---|
at 25℃; Schlenk technique; Glovebox; Inert atmosphere; | 100% |
In benzene-d6 in sealed NMR tube; elem. anal.; |
di-tert-butyl(trimethylsilyl)phosphane
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In benzene at 20℃; | 100% |
In benzene byproducts: (CH3)3SiF; mixing phosphorus compd., boron compd. in C6H6 at room temp.; evapn.; |
N,N'-(1,4-phenylenebis(methylene))bis(2-methylpropan-2-amine)
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
With hydrogen In toluene at -196 - 25℃; under 3040.2 Torr; Inert atmosphere; three freeze-pump-thaw cycles; | 100% |
tris(pentafluorophenyl)borate
dicyclohexylmethylphosphine
Cy2MeP-B(C6F5)3
Conditions | Yield |
---|---|
Stage #1: dicyclohexylmethylphosphine With B,B'-dibromo-B,B'-dimesityldiborane(4) In dichloromethane-d2 Stage #2: tris(pentafluorophenyl)borate In dichloromethane-d2 | 100% |
tris(pentafluorophenyl)borate
Conditions | Yield |
---|---|
In bromobenzene-d5 Inert atmosphere; | 100% |
(2,6-(C6H3But)2pyridine)Au(CF3CO2)
tris(pentafluorophenyl)borate
cyclopentene
[(2,6-bis(4-tBuC6H3)2pyridine dianion)Au(eta2-cyclopentene)][CF3COOB(C6F5)4]
Conditions | Yield |
---|---|
In dichloromethane-d2 at -78 - -40℃; | 100% |
ethene
(2,6-(C6H3But)2pyridine)Au(CF3CO2)
tris(pentafluorophenyl)borate
[(2,6-bis(4-tBuC6H3)2pyridine dianion)Au(eta2-C2H4)][CF3COOB(C6F5)4]
Conditions | Yield |
---|---|
In dichloromethane-d2 at -78 - -30℃; | 100% |
Conditions | Yield |
---|---|
In toluene at 20℃; for 13h; Glovebox; Inert atmosphere; | 100% |
2-(pent-4-en-1-yl)pyridine
tris(pentafluorophenyl)borate
C28H13BF15N
Conditions | Yield |
---|---|
In toluene for 13h; Glovebox; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In toluene at 20℃; for 13h; Inert atmosphere; Glovebox; | 100% |
tri-tert-butyl phosphine
tris(pentafluorophenyl)borate
N-sulfinyl-4-methylaniline
Conditions | Yield |
---|---|
In toluene at 20℃; for 1h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In dichloromethane for 1h; Darkness; | 100% |
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