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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Boron trichloride

Cas:10294-34-5

Min.Order:1

Negotiable

Type:Other

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Boron trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Boron trichloride

Cas:10294-34-5

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable

Boron Trichloride

Cas:10294-34-5

Min.Order:1 Metric Ton

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

BCl3 Boron trichloride 10294-34-5

Cas:10294-34-5

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Product name Boron trichloride Synonyms chloruredebore(french);boronchloride(bcl3);Chlorure de bore;chloruredebore;boron trichloride - 2-chloroethanol reagent;boron trichloride solution;BORONTRICHLOR

Boron trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Lonwin Chemical Group Limited

Boron trichloride price CAS: 10294-34-5 Specification melting point −107 °c(lit.) boiling point 12.5 °c(lit.) density 1.326 g/ml at 25 °c vapor density 4.05 (vs air) vapor p

Factory supply Boron trichloride price

Cas:10294-34-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Three boron chloride

Cas:10294-34-5

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:colourless gas Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:For preparing methyl esters of fatty acids and for tran

Boron trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

We are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)

Boron trichloride CAS NO.: 10294-34-5

Cas:10294-34-5

Min.Order:1 Kilogram

FOB Price: $5.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Borontrichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

Hangzhou Dingyan Chem is a leading manufacturer and supplier of chemicals in China.We develop,produce and distribute high quality pharmaceuticals, intermediates, special chemicals and other fine chemicals. We could give you: 1.Best qualit

Boron trichloride

Cas:10294-34-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 10294-34-5 with competitive price

Cas:10294-34-5

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Borane, trichloro-

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Supply top quality products with a reasonable price Application:api

10294-34-5

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Borontrichloride 10294-34-5

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#10294-34-5;CAT#A855825

Cas:10294-34-5

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Boron trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Boron trichloride

Cas:10294-34-5

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Xiamen BaiFuchem Co.,Ltd

BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

High Purity Boron Trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

Negotiable

Type:Other

inquiry

Shanghai Wechem Chemical Co Ltd

Boron Trichloride is a colorless, corrosive, nonflammable toxic gas with an irritating, acrid odor, it forms dense fumes in humid air . Boron Trichloride is irritating to the mucous membranes . It hydrolyses in moist air to form hydrogen chloride .

Boron Trichloride - ( BCL3 )

Cas:10294-34-5

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

hangzhou verychem science and technology co.ltd

Product name: Boron trichloride Cas No: 10294-34-5 Assay: 99%min Hangzhou Verychem Science And Technology Co. Ltd. was set up in year 2004, it’s a young but fast growing company. In the twelve

Boron trichloride

Cas:10294-34-5

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hongkong wechem chemical co., ltd

Boron Trichloride is a colorless, corrosive, nonflammable toxic gas with an irritating, acrid odor, it forms dense fumes in humid air . Boron Trichloride is irritating to the mucous membranes . It hydrolyses in moist air to form hydrogen chloride .

Boron Trifluoride - ( BF3 )

Cas:10294-34-5

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Cerametek Materials(ShenZhen)Co., Ltd.

sub/micron to mesh powders (near/spheres, whiskers, flake, fiber, porous) and grain/ball, thin/ thick metal / alloys pieces / parts, thin and thick (particle) film materials /target, and custom-made crystals, substrates/parts. In the industries and a

Boron tri-chloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Other

inquiry

U-Chemo Holding Co.,Limited

U-CHEMO is a high-tech enterprise taking pharmaceutical intermediates and fine chemicals as main products. We pay high attention on product quality and apply quality management in the whole manufacturing process from research to production. In additi

Boron trichloride

Cas:10294-34-5

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

boron

boron

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
In melt Electrolysis; electrolysis in a chloride melt (400-500°C);100%
With chlorine 400°C;; 6-8 times vac. distn. spect. purity product obtained;
With silver(I) chloride
cyclotriboric acid trimethyl ester
102-24-9

cyclotriboric acid trimethyl ester

chlorine
7782-50-5

chlorine

A

boron trioxide

boron trioxide

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
byproducts: HCl, ClCOCl; at room temp.;;A n/a
B 96%
C10H20BCl2N2(1+)*BCl4(1-)=[C10H20BCl2N2]BCl4

C10H20BCl2N2(1+)*BCl4(1-)=[C10H20BCl2N2]BCl4

A

boron trichloride
10294-34-5

boron trichloride

B

1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole
64486-90-4

1,3-di-tert-butyl-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole

Conditions
ConditionsYield
With sodium amalgam In hexane Ar atmosphere, stiring (overnight in the dark); decantation, filtration, removement of volatiles (vacuum), sublimation (40 to 60°C, 0.01 Torr);A n/a
B 91%
dichloroborane
10325-39-0

dichloroborane

A

boron trichloride
10294-34-5

boron trichloride

B

diborane
19287-45-7

diborane

Conditions
ConditionsYield
With hydrogen condensation of HBCl2/BCl3/B2H6 mixt. on molecular sieve, heating in H2 stream, BCl3 not adsorbed, B2H6 easily desorbed, strongly adsorbed HBCl2 slowly symmetrysied;A n/a
B 90%
With H2 condensation of HBCl2/BCl3/B2H6 mixt. on molecular sieve, heating in H2 stream, BCl3 not adsorbed, B2H6 easily desorbed, strongly adsorbed HBCl2 slowly symmetrysied;A n/a
B 90%
equil. const. Kx determined at 273 K;

A

octaboron octachloride
32915-80-3

octaboron octachloride

B

B9Cl9
31304-34-4

B9Cl9

C

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
In tetrachloromethane 100°C, 2 weeks; NMR monitoring; not isolated, detected by NMR;A 88%
B n/a
C n/a
aluminium trichloride
7446-70-0

aluminium trichloride

boron trifluoride
7637-07-2

boron trifluoride

A

aluminum(III) fluoride
7784-18-1

aluminum(III) fluoride

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
heating with excess of BF3; condensation of BCl3 in an U-tube cooled the mixt. of CO2 and alcohol; fractionated distn.;A n/a
B 80%
heating with excess of BF3; condensation of BCl3 in an U-tube cooled the mixt. of CO2 and alcohol; fractionated distn.;A n/a
B 80%
1,3-bis(dichloroboryl)propane
89033-11-4

1,3-bis(dichloroboryl)propane

boron triiodide
13517-10-7

boron triiodide

A

1,3-bis(diiodoboryl)propane
157426-91-0

1,3-bis(diiodoboryl)propane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
removal of BCl3 in vacuo;; distillation in vacuo after 4 h;;A 78%
B n/a
pentaborane(9)

pentaborane(9)

diboron tetrachloride
13701-67-2

diboron tetrachloride

A

monochlorodiborane
17927-57-0

monochlorodiborane

B

1-(dichloroboryl)pentaborane

1-(dichloroboryl)pentaborane

C

dichloroborane
10325-39-0

dichloroborane

D

boron trichloride
10294-34-5

boron trichloride

E

diborane
19287-45-7

diborane

Conditions
ConditionsYield
In neat (no solvent) reaction carried out in Pyrex tubes to which Teflon valves had been sealed or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1:3 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 20 min at ambient temp.,; fractionation, yield of 1-BCl2B5H8 based upon amt. of B2Cl4 employed: 73%, based upon amt. of B5H9 consumed: 95%; small amts. of B2H6, BCl2H, B2H5Cl, also material insufficiently volatileto move into vac. line formed;;A n/a
B 73%
C n/a
D n/a
E n/a
diphenylboronchloride
3677-81-4

diphenylboronchloride

boron triiodide
13517-10-7

boron triiodide

A

(diphenyl)iodoborane
17933-05-0

(diphenyl)iodoborane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
heating at 130-140°C for 4 h; distn.;A 72%
B n/a
boron trioxide

boron trioxide

sodium chloride
7647-14-5

sodium chloride

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
800-1000°C; ratio B2O3:NaCl=3:1;60%
800-1000°C; ratio B2O3:NaCl=1:1;30%
0%
dichloro(pentafluorophenyl)borane
830-48-8

dichloro(pentafluorophenyl)borane

A

bis(pentafluorophenyl)boron chloride
2720-03-8

bis(pentafluorophenyl)boron chloride

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
In neat (no solvent) pyrolysis at 220°C within 25 hours;;A 59%
B n/a
heating;
heating;
C18H20BCl2N2(1+)*Cl(1-)=[C18H20BCl2N2]Cl

C18H20BCl2N2(1+)*Cl(1-)=[C18H20BCl2N2]Cl

A

1,3-bis(2,6-dimethylphenyl)-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole
212375-81-0

1,3-bis(2,6-dimethylphenyl)-2-chloro-2,3-dihydro-1H-1,3,2-diazaborole

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
With sodium amalgam In hexane Ar atmosphere, stiring (room temp., 5 d); decantation, removement volatiles (vacuum);A 55%
B n/a
Cl2BNCl(C2H5)
74686-73-0

Cl2BNCl(C2H5)

diboron tetrachloride
13701-67-2

diboron tetrachloride

A

N-ethylbis(dichloroboryl)amine
74686-75-2

N-ethylbis(dichloroboryl)amine

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
under N2, with exclusion of moisture, reagents in 8/4.4 mmol ratio, condensed at -196°C, gently warmed to room temp. for 15 min; BCl3 sepd. by distn.; elem. anal.;A 37.5%
B n/a
2,4-dicarba-closo-heptaborane
20693-69-0

2,4-dicarba-closo-heptaborane

1,6-dicarba-closo-decaborane(10)
23704-81-6

1,6-dicarba-closo-decaborane(10)

A

5-Cl-closo-2,4-C2B5H6
28347-92-4

5-Cl-closo-2,4-C2B5H6

B

1,6-C2B8H9-2-(or-3-)Cl

1,6-C2B8H9-2-(or-3-)Cl

C

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
With aluminium trichloride; chlorine In neat (no solvent) byproducts: CH3BCl2, CH2(BCl2)2; addn. of mixt. of B-compds. to NMR tube contg. freshly sublimed AlCl3, addn. of Cl2 gas, warmed from -190°C to room temp. for 3 h; not isolated; detected by NMR;A 36%
B 32%
C 4%
5-Cl-closo-2,4-C2B5H6
28347-92-4

5-Cl-closo-2,4-C2B5H6

A

C2B5H4(CH3)2Cl

C2B5H4(CH3)2Cl

B

C2B5H4(CH3)2Cl

C2B5H4(CH3)2Cl

C

5-CH3-6-Cl-closo-2,4-C2B5H5
79550-11-1

5-CH3-6-Cl-closo-2,4-C2B5H5

D

1,1-bis(dichloroboryl)methane
40710-68-7

1,1-bis(dichloroboryl)methane

E

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
With chloroform In chloroform heating of 5-Cl-2,4-C2B5H6 and CH3Cl in a react. vessel at 126°Cfor 21.0 h; further products; cold-column vac. fractionation at -104 to -29°C; identification by (11)B-NMR;A n/a
B n/a
C 34%
D n/a
E n/a
tris(dichloroboryl)methane
40710-69-8

tris(dichloroboryl)methane

A

boron trichloride
10294-34-5

boron trichloride

B

hexachloro hexaboraadamantane
54573-10-3

hexachloro hexaboraadamantane

Conditions
ConditionsYield
450°C, sealed tube; cooling to room temp. over 12 h yields crystals, evapn. of volatile products, boraadamantane is sublimated in vac., elem. anal.;A n/a
B 28%
pentaborane(9)

pentaborane(9)

diboron tetrachloride
13701-67-2

diboron tetrachloride

A

1-(dichloroboryl)pentaborane

1-(dichloroboryl)pentaborane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
In neat (no solvent) reaction carried out in pyrex tubes to which Teflon valves had been sealed or N2 filled glovebox; reaction of B2Cl4 with excess B5H9 in a 1.0:1.4 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 25 min at ambient temp.,; fractionation,;A 26%
B n/a
In neat (no solvent) reaction carried out in a Pyrex tubes to which Teflon valves had been sealed, or in a N2-filled glovebox; reaction of B2Cl4 with excess B5H9 in a 2.9:1.0 mole ratio; vessel allowed to warm from -196 ° C to ambient temp., 12 min at ambient temp.,; fractionation, nonvolatile material remained within the vessel, yield of BCl2B5H8 was 8% based upon amt. of B2Cl4, 34% based upon unrecovered b5H9;A 8%
B n/a
1,1-bis(dichloroboryl)methane
40710-68-7

1,1-bis(dichloroboryl)methane

A

boron trichloride
10294-34-5

boron trichloride

B

hexachloro hexaboraadamantane
54573-10-3

hexachloro hexaboraadamantane

Conditions
ConditionsYield
byproducts: HCl; 450°C, sealed tube; cooling to room temp. over 12 h yields crystals, evapn. of volatile products, boraadamantane is sublimated in vac,, elem. anal.;A n/a
B 24%
(azido)dichloroborane
35226-75-6

(azido)dichloroborane

A

hexachlorborazine
19087-72-0

hexachlorborazine

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
byproducts: N2; 200°C, in bomb tube;A n/a
B 24%
byproducts: N2; 200°C, in bomb tube;A n/a
B 24%
1-I-B5H8
30624-33-0

1-I-B5H8

A

1-chloro-pentaborane(9)
19469-13-7

1-chloro-pentaborane(9)

B

boron trichloride
10294-34-5

boron trichloride

C

diborane
19287-45-7

diborane

Conditions
ConditionsYield
With mercury dichloride byproducts: H2, HCl; heating in closed react. tube at 105°C, 70 min;;A 7%
B n/a
C n/a
With mercury dichloride byproducts: H2, HCl; in bomb tube at temp. >= 100°C;;
diboron tetrabromide
14355-29-4

diboron tetrabromide

A

boron trichloride
10294-34-5

boron trichloride

B

BBrCl2

BBrCl2

C

Dibromochloroborane

Dibromochloroborane

Conditions
ConditionsYield
With tetrachloromethane Vac.-distn. of B2Br4 to CCl4, heating in an oil-bath (96°C, 5.75 h).; Monitored by (11)B-NMR.;A 5.5%
B 4.5%
C 1.3%
dichloro-methyl-borane
7318-78-7

dichloro-methyl-borane

A

boron trichloride
10294-34-5

boron trichloride

B

hexachloro hexaboraadamantane
54573-10-3

hexachloro hexaboraadamantane

Conditions
ConditionsYield
byproducts: HCl; 450°C, sealed tube; cooling to room temp. over 12 h yields crystals, evapn. of volatile products, boraadamantane is sublimated in vac., elem. anal.;A n/a
B 5%
diboron tetrachloride
13701-67-2

diboron tetrachloride

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

A

closo-1,7-P2B10Cl10
244036-47-3

closo-1,7-P2B10Cl10

B

closo-3,4,5,6-tetrachloro-1,2-diphosphahexaborane(4)
112897-10-6

closo-3,4,5,6-tetrachloro-1,2-diphosphahexaborane(4)

C

closo-1,10-P2B8Cl8
263152-14-3

closo-1,10-P2B8Cl8

D

conjuncto-3,3'-(1,2-P2B4Cl3)2
263152-13-2

conjuncto-3,3'-(1,2-P2B4Cl3)2

E

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
In neat (no solvent) (vac. or inert gas); B2Cl4 and PCl3 condensed in vac., sealed, heated at 400°C for 1 h, allowed to cool over 20 h; vac.-evapd. at 0°C, extd. with BCl3, evapd. at 0°C, fractionated by sublimation in vac.;A 5%
B n/a
C n/a
D n/a
E n/a
ethyl 1,1-dichloroacetate
535-15-9

ethyl 1,1-dichloroacetate

molecular compound of dichloroacetic acid ethyl ester with 1 mol boron chloride

molecular compound of dichloroacetic acid ethyl ester with 1 mol boron chloride

A

dichloroacethyl chloride
79-36-7

dichloroacethyl chloride

B

chloroethane
75-00-3

chloroethane

C

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
at 45℃;
butoxy-dichloro-borane
16339-30-3

butoxy-dichloro-borane

A

dibutoxy-chloro-borane
18379-65-2

dibutoxy-chloro-borane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
at 20℃; under 14 Torr; Disproportionierung;
dichloro(neopentyloxy)borane
34456-12-7

dichloro(neopentyloxy)borane

A

bis(neopentyloxy)chloroborane
115001-74-6

bis(neopentyloxy)chloroborane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
at 20℃; Zersetzung;
(2-chloroethoxy)dichloroborane
16339-31-4

(2-chloroethoxy)dichloroborane

A

tris(2-chloroethoxy)borane
22238-19-3

tris(2-chloroethoxy)borane

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
at 70℃; under 14 Torr;
bis(n-octyloxy)chloroborane
93314-06-8

bis(n-octyloxy)chloroborane

A

tri-n-octyl borate
2467-12-1

tri-n-octyl borate

B

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
under 0.01 Torr;
(n-octyloxy)dichloroborane
98561-14-9

(n-octyloxy)dichloroborane

A

1-Chlorooctane
111-85-3

1-Chlorooctane

B

tri-n-octyl borate
2467-12-1

tri-n-octyl borate

C

boron trichloride
10294-34-5

boron trichloride

Conditions
ConditionsYield
Erwaermen unter vermindertem Druck;
butoxy-dichloro-borane
16339-30-3

butoxy-dichloro-borane

A

n-Butyl chloride
109-69-3

n-Butyl chloride

B

boron trichloride
10294-34-5

boron trichloride

C

boroxide

boroxide

Conditions
ConditionsYield
Disproportionierung bei Normaldruck;
monochlorodiborane
17927-57-0

monochlorodiborane

boron trichloride
10294-34-5

boron trichloride

dichloroborane
10325-39-0

dichloroborane

Conditions
ConditionsYield
in presence of fluid BCl3; 100 % conversion at 20°C in 1 week; more than 60 % B2H5Cl reacts at 30°C in 4 h;100%
100°C; 20 min.;>99
100°C; 20 min; BCl3 in excess;>99
boron trichloride
10294-34-5

boron trichloride

sodium triethylborohydride

sodium triethylborohydride

diborane
19287-45-7

diborane

Conditions
ConditionsYield
ambient temp.;100%
ambient temp.;100%
trifluorormethanesulfonic acid
1493-13-6

trifluorormethanesulfonic acid

boron trichloride
10294-34-5

boron trichloride

tris(trifluoromethanesulfonyloxy)boron
64371-01-3

tris(trifluoromethanesulfonyloxy)boron

Conditions
ConditionsYield
at 10 - 20℃; for 4h;100%
In 1,1,2-Trichloro-1,2,2-trifluoroethane soln. of the components stirred at -78 ° C for 4-6 h; SO2ClF may also be used as solvent instead of Freon-113; soln. warmed to room temp.; white solid obtained after removal of the solvent; prduct purified by distn. (68-73 ° C, 0.5 Torr); elem. anal.;;
nitrogen trichloride
10025-85-1

nitrogen trichloride

boron trichloride
10294-34-5

boron trichloride

hexachlorborazine
19087-72-0

hexachlorborazine

Conditions
ConditionsYield
100%
100%
tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

boron trichloride
10294-34-5

boron trichloride

tetrabutylammonium trichloroperchloratoborate
54775-46-1

tetrabutylammonium trichloroperchloratoborate

Conditions
ConditionsYield
In chloroform introducing of gaseous BCl3 to soln. of <(C4H9)4N> in CHCl3 at 20°C; distn. and drying in vac.;100%
In neat (no solvent) Bu4NClO4 reacted slowly with excess of BCl3 at 20°C; elem. anal.;
In chloroform Bu4NClO4 reacted slowly with BCl3 in CHCl3 at 20°C; elem. anal.;
In chloroform
Cp(CO)2Fe(P(O)(OMe)(NEt2))

Cp(CO)2Fe(P(O)(OMe)(NEt2))

boron trichloride
10294-34-5

boron trichloride

(η5-C5H5)Fe(CO)2P(OBCl3)(Cl)(NEt2)

(η5-C5H5)Fe(CO)2P(OBCl3)(Cl)(NEt2)

Conditions
ConditionsYield
In hexane; dichloromethane (N2); a soln. of BCl3 in hexane added to a soln. of Fe-complex at -78°C; stirred for 1 h at room temp.; evapd.; added CH2Cl2; filtered; evapd.; recrystd. from CH2Cl2/hexane;100%
[(AlH)6(AlN(CH3)3)2(CCH2CH2Si(CH3)3)6]*2CH3C6H5

[(AlH)6(AlN(CH3)3)2(CCH2CH2Si(CH3)3)6]*2CH3C6H5

boron trichloride
10294-34-5

boron trichloride

[(AlCl)6(AlN(CH3)3)2(CCH2CH2Si(CH3)3)6]

[(AlCl)6(AlN(CH3)3)2(CCH2CH2Si(CH3)3)6]

Conditions
ConditionsYield
In hexane; toluene byproducts: B2H6; (N2); using Schlenk techniques; addn. dropwise of soln. BCl3 (2 equiv.) in hexane to soln. of (AlH3)6(AlNMe3)2(CCH2CH2SiMe3)6 (1 equiv.) in toluene at -78°C, stirring for 0.5 h at this temp., stirring for 0.5 h at 0°C and 2 h at room temp.; removal of volatiles in vac. at 30°C, recrystn. from toluene (50°C/4°C), drying in vac., elem. anal.;100%
nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)
158789-52-7

nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)

boron trichloride
10294-34-5

boron trichloride

((CH3)3CC8H3NN)4ReNBCl3
582295-87-2

((CH3)3CC8H3NN)4ReNBCl3

Conditions
ConditionsYield
In dichloromethane Re compd. dissolved in CH2Cl2 and cooled to -5°C, electrophile added dropwise to this soln., stirred for 6 h at -5°C; solvent removed at -5°C, elem. anal.;100%
boron trichloride
10294-34-5

boron trichloride

rhenium(VII) oxide

rhenium(VII) oxide

rhenium trichloride dioxide

rhenium trichloride dioxide

Conditions
ConditionsYield
In neat (no solvent) (Ar); Re2O7 put into glass ampoule; BCl3 condensed onto it at -196°C; warmed slowly to -40°C then to room temp.; slowly cooled to -60°C;100%
5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide
955084-10-3

5,5-difluoro-10-(p-tolyl)-5H-dipyrrolo[1,2-c:2',1'-f][1,3,2]diazaborinin-4-ium-5-uide

boron trichloride
10294-34-5

boron trichloride

4,4-dichloro-8-p-tolyl-4-bora-3a,4a-diaza-s-indacene

4,4-dichloro-8-p-tolyl-4-bora-3a,4a-diaza-s-indacene

Conditions
ConditionsYield
In dichloromethane for 0.25h; Inert atmosphere; UV-irradiation;100%
2,2'-biquinoline
119-91-5

2,2'-biquinoline

boron trichloride
10294-34-5

boron trichloride

C18H12BCl2N2(1+)*Cl(1-)

C18H12BCl2N2(1+)*Cl(1-)

Conditions
ConditionsYield
In n-heptane; dichloromethane at -78 - 25℃; for 20h; Inert atmosphere;100%
boron trichloride
10294-34-5

boron trichloride

4-n-butyl-1-trimethylsilylbenzene
81631-74-5

4-n-butyl-1-trimethylsilylbenzene

4-n-butylphenyldichloroborane

4-n-butylphenyldichloroborane

Conditions
ConditionsYield
In dichloromethane at 20℃; Inert atmosphere;100%
chlorosulfonic acid
7790-94-5

chlorosulfonic acid

boron trichloride
10294-34-5

boron trichloride

B(SO3Cl)3

B(SO3Cl)3

Conditions
ConditionsYield
at 6 - 20℃; for 4h;100%
boron trichloride
10294-34-5

boron trichloride

3,3',5,5'-tetraphenyl-ms-aza-2,2'-dipyrrolylmethene difluoroborate

3,3',5,5'-tetraphenyl-ms-aza-2,2'-dipyrrolylmethene difluoroborate

4,4-dichloro-1,3,5,7-tetraphenyl-4-bora-3a,4a,8-triaza-s-indacene

4,4-dichloro-1,3,5,7-tetraphenyl-4-bora-3a,4a,8-triaza-s-indacene

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.333333h; Glovebox; Inert atmosphere; Schlenk technique;100%
N,N-difluoroboryl-[N-(3-phenyl-2H-isoindol-1-yl)-N-(3-phenyl-1H-isoindol-1-ylidene)amine]
1073151-42-4

N,N-difluoroboryl-[N-(3-phenyl-2H-isoindol-1-yl)-N-(3-phenyl-1H-isoindol-1-ylidene)amine]

boron trichloride
10294-34-5

boron trichloride

N,N-dichloroboryl-[N-(3-phenyl-2H-isoindol-1-yl)-N-(3-phenyl1H-isoindol-1-ylidene)amine]

N,N-dichloroboryl-[N-(3-phenyl-2H-isoindol-1-yl)-N-(3-phenyl1H-isoindol-1-ylidene)amine]

Conditions
ConditionsYield
In dichloromethane at 20℃; for 0.333333h; Glovebox; Inert atmosphere; Schlenk technique;100%
C27H24BFN4

C27H24BFN4

boron trichloride
10294-34-5

boron trichloride

C27H24BClN4

C27H24BClN4

Conditions
ConditionsYield
In n-heptane; dichloromethane at 21℃; for 1h; Inert atmosphere;100%
lithium aluminium tetrahydride
16853-85-3

lithium aluminium tetrahydride

boron trichloride
10294-34-5

boron trichloride

diborane
19287-45-7

diborane

Conditions
ConditionsYield
In diethyl ether byproducts: LiCl, AlCl3; distn. of BCl3 to water free etheric soln. of LiAlH4, cooled with liq. N2; heating up to room temp.; fractionated condensation;99.4%
In diethyl ether byproducts: LiCl, AlCl3; distn. of BCl3 to water free etheric soln. of LiAlH4, cooled with liq. N2; heating up to room temp.; fractionated condensation;99.4%
bis(trifluoromethyl)mercury
371-76-6

bis(trifluoromethyl)mercury

boron trichloride
10294-34-5

boron trichloride

boron trifluoride
7637-07-2

boron trifluoride

Conditions
ConditionsYield
In neat (no solvent) (N2); BCl3 was condensed above Hg compd. in an evacuated tube, mixt. was warmed up to room temp. with stirring, after 35 min was cooled to 0°C and all volatiles removed in vac.; fractionation at -160°C yielded BF3; identified by (19)F- and (11)B-NMR and mass spect.;99%
triethyl borane
97-94-9

triethyl borane

boron trichloride
10294-34-5

boron trichloride

diethylchloroborane
5314-83-0

diethylchloroborane

Conditions
ConditionsYield
With ethene; tetraethyldiborane(6) react. of two equiv of B(C2H5)3 with one equiv of BCl3 at room temp., decompn. of catalyst with ethylene; distn.;99%
With ethylene; tetraethyldiborane(6) react. of two equiv of B(C2H5)3 with one equiv of BCl3 at room temp., decompn. of catalyst with ethylene; distn.;99%
tetraethyldiborane(6)
tetraethyldiborane(6)
12081-54-8

tetraethyldiborane(6)

tripropylborane
1116-61-6

tripropylborane

boron trichloride
10294-34-5

boron trichloride

dipropylchloroborane
22086-53-9

dipropylchloroborane

Conditions
ConditionsYield
With decene-1 introduction of BCl3 in mixt. of B(n-C3H7) and (C2H5)2B2H2 for 15 min, addn. of decene-1; distn.;99%
(benzyl alcohol)tricarbonylchromium(0)
12116-45-9

(benzyl alcohol)tricarbonylchromium(0)

boron trichloride
10294-34-5

boron trichloride

(η6-benzyl chloride)tricarbonylchromium(0)
12170-17-1

(η6-benzyl chloride)tricarbonylchromium(0)

Conditions
ConditionsYield
In dichloromethane stirring at -78°C for 1 h, quenching (satd. aq. NaHCO3), warming to room temp.; addn. of H2O, extn. (Et2O), drying (MgSO4), filtration, concn.;99%
C5H4Si(CH3)3Sn(CH3)3

C5H4Si(CH3)3Sn(CH3)3

boron trichloride
10294-34-5

boron trichloride

ClB(C5H4Si(CH3)3)2

ClB(C5H4Si(CH3)3)2

Conditions
ConditionsYield
In toluene under N2 atm. to soln. BCl3 in toluene was added C5H4(SiMe3)(SnMe3), react. mixt. was heated to reflux for 5 h; volatiles were removed at 0.1 mm Hg, 50°C;99%
(C6F5)2(CH3)2C3HN2Si(CH3)3

(C6F5)2(CH3)2C3HN2Si(CH3)3

boron trichloride
10294-34-5

boron trichloride

(C6F5)2(CH3)2C3HN2BCl2

(C6F5)2(CH3)2C3HN2BCl2

Conditions
ConditionsYield
In hexane; toluene (under Ar, Schlenk); soln. of BCl3 in hexane added to soln. of ligand intoluene at ambient temp., stirred overnight; solvent removed under reduced pressure;99%
tetrakis(2,6-diisopropylphenylimino)pyracene

tetrakis(2,6-diisopropylphenylimino)pyracene

boron trichloride
10294-34-5

boron trichloride

[(C14H4(NC6H3(C3H7)2)4)(BCl2)2](2+)*2BCl4(1-)=[(C14H4(NC6H3(C3H7)2)4)(BCl2)2][BCl4]2

[(C14H4(NC6H3(C3H7)2)4)(BCl2)2](2+)*2BCl4(1-)=[(C14H4(NC6H3(C3H7)2)4)(BCl2)2][BCl4]2

Conditions
ConditionsYield
In hexane; dichloromethane BCl3 (4 equiv.) and ligand at 25°C for 12 h;99%
5,5-dimethyl-5H-dibenzo[b,f]stannepine
1189139-25-0

5,5-dimethyl-5H-dibenzo[b,f]stannepine

(2,4,6-triisopropylphenyl)tin(Bu)3
1237745-13-9

(2,4,6-triisopropylphenyl)tin(Bu)3

boron trichloride
10294-34-5

boron trichloride

5-(2,4,6-tri-iso-propylphenyl)-5H-dibenzo[b,f]borepin
1237745-15-1

5-(2,4,6-tri-iso-propylphenyl)-5H-dibenzo[b,f]borepin

Conditions
ConditionsYield
In toluene Schlenk air-free technique; react. of Sn(CH3)2(C2H2(C6H4)2), tripyl-Sn(Bu)3 and BCl3 at -78°C;99%
boron trichloride
10294-34-5

boron trichloride

borondipyrromethene

borondipyrromethene

4,4-dichloro-4-bora-3a,4a-diaza-s-indacene
1417726-65-8

4,4-dichloro-4-bora-3a,4a-diaza-s-indacene

Conditions
ConditionsYield
In dichloromethane at 22℃; for 1h; Inert atmosphere;99%
2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene

2,6-diethyl-4,4-difluoro-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene

boron trichloride
10294-34-5

boron trichloride

4,4-dichloro-2,6-diethyl-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene
1355045-95-2

4,4-dichloro-2,6-diethyl-1,3,5,7-tetramethyl-8H-4-bora-3a,4a-diaza-s-indacene

Conditions
ConditionsYield
In dichloromethane at 22℃; for 1h;99%
In hexane; dichloromethane for 1h; Inert atmosphere;
1',2',3',4',5'-pentamethylazaferrocene
183619-19-4

1',2',3',4',5'-pentamethylazaferrocene

boron trichloride
10294-34-5

boron trichloride

C14H19BCl3FeN
1610052-27-1

C14H19BCl3FeN

Conditions
ConditionsYield
In dichloromethane for 0.5h; Inert atmosphere;99%
1,3-bis-(2,4,6-trimethylphenyl)-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene
1237706-56-7

1,3-bis-(2,4,6-trimethylphenyl)-4,6-diketo-5,5-dimethylpyrimidin-2-ylidene

boron trichloride
10294-34-5

boron trichloride

C24H28BCl3N2O2

C24H28BCl3N2O2

Conditions
ConditionsYield
In hexane; benzene at 20℃; for 1h; Inert atmosphere; Glovebox;99%
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