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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Factory supply Tetrabutylammonium perchlorate Cas 1923-70-2 with best purity Company profile Wuhan Fortuna Chemical Co.,Ltd established in 2006, is a big integrative chemical enterprise being engaged in Pharmaceutical & its intermediates, Fo

Factory supply Tetrabutylammonium perchlorate Cas 1923-70-2 with best purity

Cas:1923-70-2

Min.Order:10 Kilogram

FOB Price: $10.0

Type:Trading Company

inquiry

Chemwill Asia Co., Ltd.

Tetrabutylammonium perchlorate -- CHemwill

Cas:1923-70-2

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Tetrabutylammonium perchlorate Basic information Product Name: Tetrabutylammonium perchlorate Synonyms: TETRA-N-BUTYLAMMONIUM PERCHLORATE;TETRABUTYLAMMONIUM PERCHLORATE;n,n,n-tributyl-1-

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

Tetrabutylammonium perchlorate CAS 1923-70-2

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Pharmaceutical Grade CAS 1923-70-2 with competitive price

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developmen

tetrabutylazanium,perchlorate CAS NO.1923-70-2

Cas:1923-70-2

Min.Order:20 Kilogram

FOB Price: $10.0 / 100.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Chemical Name Tetrabutyl ammonium perchlorate Synonyms TBAHS CAS No. 1923-70-2 Molecular formula C16H36NClO4 Molecular weight

Tetrabutyl ammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Tetrabutylammonium perchlorate 1923-70-2

Cas:1923-70-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Fandachem Co.,Ltd

Hangzhou Fanda Chemical Co.,Ltd (FandaChem) , a China-based chemical company, specialize in exporting Tetrabutylammonium perchlorate 98%, CAS No.:1923-70-2;Please contact us by email freely. We are leading exporter in China. If you

Tetrabutylammonium perchlorate 98%, CAS No.:1923-70-2 from Fandachem

Cas:1923-70-2

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

Tetrabutyl ammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chemlyte Solutions

Chemlyte Solutions believe that customers and suppliers deserve much more than what traditional distributors can offer. To grow in today s fast-paced and increasingly competitive market it is essential to be able to quickly adapt to market forces eff

Featured products Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:100 Gram

Negotiable

Type:Other

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:white crystal powder Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum, or as per your request. Application:Used as Pharmaceutical Intermed

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Other

inquiry

Siwei Development Group Ltd.

Product name: Tetrabutylammonium Perchlorate CAS No.: 1923-70-2 Molecule Formula:C16H36N·ClO4 Molecule Weight:341.92 Purity: 99.0% Package: 25kg/drum Description:White to off-white solid Manufacture Standards:Enterprise Standard

Lower Price Tetrabutylammonium Perchlorate on stock

Cas:1923-70-2

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages High purity, all above 98.5%, no impurities after dissolution We will test each batch to ensure quality OEM and private brand services designed for free Various cap colors available We can also provide MT1 peptide powd

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $100.0 / 102.0

Type:Trading Company

inquiry

Shanghai Minstar Chemical Co., Ltd

Tetrabutylammonium perchlorate Basic information Product Name: Tetrabutylammonium perchlorate Synonyms: TETRABUTYLAMMONIUM PERCHLORATE ELECTRO-C HEMICAL GRADE;Tetrabutylammonium perchlorate, contains max. 10% water, 99%;n,n,n-tributyl-1-butana

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

SAGECHEM is a chemical R&D, manufacturing and distribution company in China since 2009, including pharmaceutical intermediates, agrochemical, dyestuff intermediates, organosilicone, API and etc. We also offer a full range of services in custom synthe

Tetrabutylammonium perchlorate

Cas:1923-70-2

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);95%
With perchloric acid
With perchloric acid
With perchloric acid
(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2
74436-10-5

(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2

silver perchlorate

silver perchlorate

cis-[Pd(pentafluorophenyl)2(THF)2]

cis-[Pd(pentafluorophenyl)2(THF)2]

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;A 90%
B n/a
N-n-Bu4{Au(C6Cl5)2}

N-n-Bu4{Au(C6Cl5)2}

silver perchlorate

silver perchlorate

A

[{Au(C6Cl5)2}Ag]n

[{Au(C6Cl5)2}Ag]n

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.;A 90%
B n/a
NBu4[Ag(C6F5)2]

NBu4[Ag(C6F5)2]

{Ag(CH2P(C6H5)3)2}(1+)*ClO4(1-)={Ag(CH2P(C6H5)3)2}ClO4

{Ag(CH2P(C6H5)3)2}(1+)*ClO4(1-)={Ag(CH2P(C6H5)3)2}ClO4

A

{Ag(C6F5)(CH2P(C6H5)3)}

{Ag(C6F5)(CH2P(C6H5)3)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.;A 85%
B n/a
(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2
86392-02-1

(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2

silver perchlorate

silver perchlorate

cis-[Pd(C6Cl5)2(thf)2]

cis-[Pd(C6Cl5)2(thf)2]

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;A 80%
B n/a
{NBu4}{Pt(pentafluorophenyl)4}

{NBu4}{Pt(pentafluorophenyl)4}

[Ag(OClO3)(tetrahydrothiophene)]
1020072-44-9, 132018-77-0

[Ag(OClO3)(tetrahydrothiophene)]

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.;A 80%
B n/a
{NBu4}{Pt(pentafluorophenyl)4}

{NBu4}{Pt(pentafluorophenyl)4}

{Ag(tetrahydrothiophene)}ClO4
137400-80-7

{Ag(tetrahydrothiophene)}ClO4

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.;A 79%
B n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(tetrahydrothiophene)}

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(tetrahydrothiophene)}

(C4H8S)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

(C4H8S)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.;A 78%
B n/a
(NBu4)2{trans-PtCl2(C6Cl5)2}

(NBu4)2{trans-PtCl2(C6Cl5)2}

perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

A

N(C4H9)4(1+)*PtAgCl2(C6Cl5)2(P(C6H5)3)(1-) = (N(C4H9)4){PtAgCl2(C6Cl5)2(P(C6H5)3)}

N(C4H9)4(1+)*PtAgCl2(C6Cl5)2(P(C6H5)3)(1-) = (N(C4H9)4){PtAgCl2(C6Cl5)2(P(C6H5)3)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.;A 77%
B n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)(C6Cl5)2(triphenylphosphine)}

{(C4H9)4N}{cis-Pt(C6F5)(C6Cl5)2(triphenylphosphine)}

((C6H5)3P)(C6Cl5)2(C6F5)PtAg(P(C6H5)3)

((C6H5)3P)(C6Cl5)2(C6F5)PtAg(P(C6H5)3)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 77%
B n/a
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
116349-58-7

(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

silver perchlorate

silver perchlorate

A

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}
95674-06-9

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 1:1) and stirring of mixt. (exclusion of light, room temp., 1 h).; Evapn. of soln. to dryness and treatment of resulting oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.;A 76%
B n/a
(NBu4)2{platinum(pentafluorophenyl)3Cl}
90621-02-6

(NBu4)2{platinum(pentafluorophenyl)3Cl}

silver perchlorate

silver perchlorate

A

(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
116349-58-7

(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

C

silver(I) chloride

silver(I) chloride

Conditions
ConditionsYield
In dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl, evapn. of resulting yellow soln. to dryness and treatment of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.;A 76%
B n/a
C n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{Pt(C6Cl5)3(pyridine)}

{(C4H9)4N}{Pt(C6Cl5)3(pyridine)}

{(pyridine)(C6Cl5)3PtAg(triphenylphosphine)}

{(pyridine)(C6Cl5)3PtAg(triphenylphosphine)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 75%
B n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(triphenylphosphine)}

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(triphenylphosphine)}

((C6H5)3P)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

((C6H5)3P)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 73%
B n/a
(NBu4)2{platinum(pentafluorophenyl)3Cl}
90621-02-6

(NBu4)2{platinum(pentafluorophenyl)3Cl}

silver perchlorate

silver perchlorate

A

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}
95674-06-9

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

C

silver(I) chloride

silver(I) chloride

Conditions
ConditionsYield
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 2:1) and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl and of excess of AgClO4, evapn. of resulting yellow soln. to dryness and washing of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Partial evapn. of yellow soln. and addn. of n-hexane gives a solid.;A 72%
B n/a
C n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(pyridine)}

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(pyridine)}

(C5H5N)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

(C5H5N)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 72%
B n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{Pt(C6Cl5)3(triphenylphosphine)}

{(C4H9)4N}{Pt(C6Cl5)3(triphenylphosphine)}

(triphenylphosphine)(C6Cl5)3PtAg(triphenylphosphine)

(triphenylphosphine)(C6Cl5)3PtAg(triphenylphosphine)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 70%
B n/a
triphenylphosphinesilver perchlorate

triphenylphosphinesilver perchlorate

(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}
116349-58-7

(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

A

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(PPh3)}
116349-60-1

(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(PPh3)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane Addn. of O3ClOAgPPh3 to a soln. of Pt-compd. (CH2Cl2, -30°C) and stirring of mixt. (30 min, -30°C, exclusion of light).; Pumping of soln. to dryness (-30°C) and treatment of residue with O(C2H5)2 (-30°C). Evapn. of soln. to dryness and addn. of n-hexane after sepn. of insoluble NBu4ClO4.;A 69%
B n/a
{NBu4}{Pt(pentafluorophenyl)4}

{NBu4}{Pt(pentafluorophenyl)4}

perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-triphenylphosphine-2κP-platinumargentate (Ag-Pt)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-triphenylphosphine-2κP-platinumargentate (Ag-Pt)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;A 68%
B n/a
perchlorato(triphenylphosphane)silver(I)
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{Pt(C6Cl5)3(tetrahydrothiophene)}

{(C4H9)4N}{Pt(C6Cl5)3(tetrahydrothiophene)}

(tetrahydrothiophene)(C6Cl5)3PtAg(triphenylphosphine)}

(tetrahydrothiophene)(C6Cl5)3PtAg(triphenylphosphine)}

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 68%
B n/a
trans-dichlorobis(pyridine)platinum(II)
14024-97-6, 14872-21-0, 15227-42-6

trans-dichlorobis(pyridine)platinum(II)

{NBu4}{Pt(C6F5)3(OCMe2)}

{NBu4}{Pt(C6F5)3(OCMe2)}

[NBu4]2[Pt2(μ-pentafluorophenyl)2(pentafluorophenyl)4]

[NBu4]2[Pt2(μ-pentafluorophenyl)2(pentafluorophenyl)4]

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane; acetone addn. of trans-(PtCl2(py)2) to soln. of Pt-complex in CH2Cl2/acetone (2:1), stirring (1 h); evapn. to dryness, washing (diethyl ether, 2.product solid), evapn. of washings to dryness, treatment with i-PrOH/hexane;A 58%
B n/a
[μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

[μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

silver perchlorate

silver perchlorate

A

Au(1+)*Ag(1+)*2C6F3H2(1-)=AuAg(C6F3H2)2

Au(1+)*Ag(1+)*2C6F3H2(1-)=AuAg(C6F3H2)2

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In diethyl ether equimolar amt. of AgClO4 was added to soln. of Au-compound in Et2O, stirred for 1 h; filtered, filtrate evapd., hexane added; elem. anal.;A 56%
B >99
O3ClOAg(P(C2H5)3)
107556-35-4

O3ClOAg(P(C2H5)3)

(NBu4)2{trans-PtCl2(C6Cl5)2}

(NBu4)2{trans-PtCl2(C6Cl5)2}

Pt(C6Cl5)2((μ-Cl)Ag(PEt3))2

Pt(C6Cl5)2((μ-Cl)Ag(PEt3))2

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 2 h); evapn., treatment with MeOH, filtn., washing (MeOH); elem. anal.;A 51%
B n/a
{NBu4}{Pt(pentafluorophenyl)4}

{NBu4}{Pt(pentafluorophenyl)4}

Ag(OClO3)(O(C2H5)2)

Ag(OClO3)(O(C2H5)2)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;A 50%
B n/a
{NBu4}{Pt(pentafluorophenyl)4}

{NBu4}{Pt(pentafluorophenyl)4}

silver perchlorate

silver perchlorate

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
With diethyl ether In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;A 50%
B n/a
perchlorato(methyldiphenylphosphane)silver(I)
110373-27-8

perchlorato(methyldiphenylphosphane)silver(I)

(NBu4)2{trans-PtCl2(C6Cl5)2}

(NBu4)2{trans-PtCl2(C6Cl5)2}

Pt(C6Cl5)2((μ-Cl)Ag(PPh2Me))2

Pt(C6Cl5)2((μ-Cl)Ag(PPh2Me))2

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.;A 39%
B n/a
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.;A 73-77
B n/a
Didodecyl-(3-methyl-2-butenyl)-sulfonium perchlorate

Didodecyl-(3-methyl-2-butenyl)-sulfonium perchlorate

tetrabutylammonium dihydrogen phosphate

tetrabutylammonium dihydrogen phosphate

A

didodecyl sulfide
2469-45-6

didodecyl sulfide

B

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

C

(methyl-2 butene-3 yl-2) phosphate de potassium
110071-93-7

(methyl-2 butene-3 yl-2) phosphate de potassium

Conditions
ConditionsYield
With Potassium benzoate; copper(I) bromide In dichloromethaneA n/a
B n/a
C 17%
tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

boron trichloride
10294-34-5

boron trichloride

tetrabutylammonium trichloroperchloratoborate
54775-46-1

tetrabutylammonium trichloroperchloratoborate

Conditions
ConditionsYield
In chloroform introducing of gaseous BCl3 to soln. of <(C4H9)4N> in CHCl3 at 20°C; distn. and drying in vac.;100%
In neat (no solvent) Bu4NClO4 reacted slowly with excess of BCl3 at 20°C; elem. anal.;
In chloroform Bu4NClO4 reacted slowly with BCl3 in CHCl3 at 20°C; elem. anal.;
In chloroform
4,5-dimethylethylene (trans,trans) sulphate
4440-89-5

4,5-dimethylethylene (trans,trans) sulphate

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

A

trans-2-Butene
624-64-6

trans-2-Butene

B

C4H8O8S2(2-)*2K(1+)

C4H8O8S2(2-)*2K(1+)

C

2C16H36N(1+)*C6H12O8S2(2-)

2C16H36N(1+)*C6H12O8S2(2-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 20℃; Product distribution; electrolysis, oth. solvent, var. cathodes;A 99%
B 42%
C n/a
boron trifluoride
7637-07-2

boron trifluoride

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

tetrabutylammonium trifluoroperchloratoborate

tetrabutylammonium trifluoroperchloratoborate

Conditions
ConditionsYield
In chloroform Bu4NClO4 reacted with BF3 in CHCl3 at 20°C;99%
Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)
1007838-83-6

Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
1007838-97-2

[Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions
ConditionsYield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;99%
Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)
1007838-80-3

Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
1007838-95-0

[Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions
ConditionsYield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;99%
Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)
1007838-78-9

Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
1007838-91-6

[Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions
ConditionsYield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;99%
Ru(N,N'-bis(4'-chlorophenyl)pyridine-2,6-dicarboxamide)(2,2',2''-terpyridine)
1007838-85-8

Ru(N,N'-bis(4'-chlorophenyl)pyridine-2,6-dicarboxamide)(2,2',2''-terpyridine)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Ru(2,6-(ClC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
1007838-99-4

[Ru(2,6-(ClC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions
ConditionsYield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;99%
Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)
1007838-88-1

Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4
1007839-01-1

[Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions
ConditionsYield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;99%
Au3(MeN=COMe)3

Au3(MeN=COMe)3

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Au3(MeN=COMe)3](ClO4)0.34

[Au3(MeN=COMe)3](ClO4)0.34

Conditions
ConditionsYield
In dichloromethane Electrolysis;99%
pyridine
110-86-1

pyridine

Vanadium (III) chloride-(tris-tetrahydrofuran)
131063-11-1, 16997-51-6, 19559-06-9

Vanadium (III) chloride-(tris-tetrahydrofuran)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

water
7732-18-5

water

sodium acetate
127-09-3

sodium acetate

[V3O(O2CMe)6(pyridine)3](ClO4)
178882-95-6

[V3O(O2CMe)6(pyridine)3](ClO4)

Conditions
ConditionsYield
In pyridine; acetic acid; acetonitrile byproducts: NaCl; N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/pyridine=2:1:2v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.;95%
ammonium thiocyanate

ammonium thiocyanate

ammonium hexabromotechnetate

ammonium hexabromotechnetate

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

{(n-C4H9)4N}3{Tc(NCS)6}

{(n-C4H9)4N}3{Tc(NCS)6}

Conditions
ConditionsYield
With N2H4*H2O In methanol NH4SCN and (NH4)2TcBr6 refluxed in methanol under N2 or Ar for 24 h, system cooled to room temp., N2H4*H2O added, mixt. filtered under inert atm., filtrate treated with n-Bu4NClO4 in methanol; solid filtered under inert atm., washed with water, methanol, dried in vac.; elem. anal.;93%
picoline
108-89-4

picoline

Vanadium (III) chloride-(tris-tetrahydrofuran)
131063-11-1, 16997-51-6, 19559-06-9

Vanadium (III) chloride-(tris-tetrahydrofuran)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

water
7732-18-5

water

sodium acetate
127-09-3

sodium acetate

[V3O(O2CMe)6(4-picoline)3](ClO4)

[V3O(O2CMe)6(4-picoline)3](ClO4)

Conditions
ConditionsYield
In acetic acid; acetonitrile N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/4-picoline=2:1:2.2 v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.;91%
(tetrahydrothiophene)gold(I) chloride
39929-21-0

(tetrahydrothiophene)gold(I) chloride

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

lithium-2,4,6-trifluorophenyl
53732-49-3

lithium-2,4,6-trifluorophenyl

[μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

[μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

Conditions
ConditionsYield
In diethyl ether byproducts: Au; mixing soln. of Au-complex and ligand (-78°C), stirring for 20 min, warming to room temp., stirring (30 min), filtration, addn. to Bu4N(ClO4) soln. (pptn.); recrystn. (CH2Cl2/EtOH);90%
osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)
129264-47-7

osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

{osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)}perchlorate

{osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)}perchlorate

Conditions
ConditionsYield
In methanol; dichloromethane stirred in air at room temp. for 24h; cooled in a refrigerator; elem. anal.;90%
potassium cyanide

potassium cyanide

[platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2
400654-03-7

[platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

acetonitrile
75-05-8

acetonitrile

[(n-butyl)4N][platinum(II)(CN)2(2-( p-tolyl)-pyridine(-H))]*0.5(acetonitrile)

[(n-butyl)4N][platinum(II)(CN)2(2-( p-tolyl)-pyridine(-H))]*0.5(acetonitrile)

Conditions
ConditionsYield
Stage #1: [platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2 With silver perchlorate In acetonitrile for 7h; Darkness;
Stage #2: potassium cyanide In methanol for 2h;
Stage #3: tetrabutylammonium perchlorate; acetonitrile Further stages;
90%
2-(1,8-naphthyridin-2-yl)thiazole
170439-30-2

2-(1,8-naphthyridin-2-yl)thiazole

tetraacetatodiruthenium chloride

tetraacetatodiruthenium chloride

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

water
7732-18-5

water

cis-[Ru2(2-(2-thiazolyl)-1,8-naphthyridine)2(OAc)2][ClO4]2(H2O)0.5

cis-[Ru2(2-(2-thiazolyl)-1,8-naphthyridine)2(OAc)2][ClO4]2(H2O)0.5

Conditions
ConditionsYield
Stage #1: 2-(2-thiazolyl)-1,8-naphthyridine; tetraacetatodiruthenium chloride; tetrabutylammonium perchlorate In methanol Inert atmosphere; Schlenk technique; Reflux;
Stage #2: water Inert atmosphere; Schlenk technique;
90%
tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

C78H55Co5N24O(3+)*3BF4(1-)*3.75C2H3N*0.33H2O

C78H55Co5N24O(3+)*3BF4(1-)*3.75C2H3N*0.33H2O

acetonitrile
75-05-8

acetonitrile

C78H55Co5N24O(2+)*2ClO4(1-)*2C2H3N

C78H55Co5N24O(2+)*2ClO4(1-)*2C2H3N

Conditions
ConditionsYield
Glovebox; Inert atmosphere; Electrochemical reaction;90%
tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

sodium N,N-dimethyldithiocarbamate dihydrate
128-04-1

sodium N,N-dimethyldithiocarbamate dihydrate

N(C4H9)4(1+)*Au(C6F5)3(S2CN(CH3)2)(1-) = {N(C4H9)4}{Au(C6F5)3(S2CN(CH3)2)}

N(C4H9)4(1+)*Au(C6F5)3(S2CN(CH3)2)(1-) = {N(C4H9)4}{Au(C6F5)3(S2CN(CH3)2)}

Conditions
ConditionsYield
In dichloromethane; acetone byproducts: NaClO4; to soln. of Au complex in acetone added Na(S2CNMe2)*2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;89%
tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

sodium N,N-dimethyldithiocarbamate dihydrate
128-04-1

sodium N,N-dimethyldithiocarbamate dihydrate

N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(CH3)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(CH3)2)}

N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(CH3)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(CH3)2)}

Conditions
ConditionsYield
In dichloromethane; acetone to soln. of Au complex in acetone added Na(S2CNMe2)*2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (2*5 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;89%
1,4,8,11-Tetraazacyclotetradecane
295-37-4

1,4,8,11-Tetraazacyclotetradecane

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

acetonitrile
75-05-8

acetonitrile

[Fe(1,4,8,11-tetraazacyclotetradecane)(CH3CN)2](ClO4)2

[Fe(1,4,8,11-tetraazacyclotetradecane)(CH3CN)2](ClO4)2

Conditions
ConditionsYield
With trifluorormethanesulfonic acid In acetonitrile Ar-atmosphere; refluxing excess Fe with CF3SO3H for 4 h, filtration, mixing with cyclam, refluxing for 30 min, addn. of Bu4NClO4, refluxing for 30 min; cooling in ice bath, Et2O addn. (pptn.);88%
potassium cyanide

potassium cyanide

[Pt(2-phenylpyridinate)(NCMe)2]ClO4
1048673-03-5

[Pt(2-phenylpyridinate)(NCMe)2]ClO4

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

tetrabutylammonium dicyano[(2-pyridyl)phenyl-2-ido]platinate(II)
167647-56-5

tetrabutylammonium dicyano[(2-pyridyl)phenyl-2-ido]platinate(II)

Conditions
ConditionsYield
In methanol KCN was added to suspn. Pt complex in MeOH at room temp. and stirred for1 h, soln. was filtered through Celite and evapd. to dryness, Bu4NClO4 and acetone were added and stirred for 1 h; soln. was filtered through Celite, soln. was evapd. to dryness, residue was treated with water, filtered, dried (110°C) and recrystd. from CH2Cl2-Et2O; elem. anal.;88%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

[NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

[NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[Pd2(μ-PPh2)(C6F5)4(bipy)2][ClO4]
195203-54-4

[Pd2(μ-PPh2)(C6F5)4(bipy)2][ClO4]

Conditions
ConditionsYield
In isopropyl alcohol; acetone stirring Pd-complex with bipy (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.;87%
[NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

[NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

1,10-phenanthroline hydrate
5144-89-8

1,10-phenanthroline hydrate

[Pd2(μ-PPh2)(C6F5)4(phen)2][ClO4]
195203-56-6

[Pd2(μ-PPh2)(C6F5)4(phen)2][ClO4]

Conditions
ConditionsYield
In isopropyl alcohol; acetone stirring Pd-complex with phen (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.;87%
potassium cyanide

potassium cyanide

[(C6F5)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CH3CN)2]

[(C6F5)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CH3CN)2]

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

[NBu4]2[(RF)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CN)2]

[NBu4]2[(RF)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CN)2]

Conditions
ConditionsYield
In acetone at 20℃; for 12h;87%
tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

sodium diethyldithiocarbamate trihydrate
20624-25-3

sodium diethyldithiocarbamate trihydrate

N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(C2H5)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(C2H5)2)}

N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(C2H5)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(C2H5)2)}

Conditions
ConditionsYield
In dichloromethane; acetone appropriated choice of molar ratio of educts; to soln. of Au complex in acetone added Na(S2CNEt2)*3H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (2*5 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;84%
1,4-diiodo-2,3,5,6-tetrafluorobenzene
392-57-4

1,4-diiodo-2,3,5,6-tetrafluorobenzene

tetrabutylammonium perchlorate
1923-70-2

tetrabutylammonium perchlorate

1.5C6F4I2*C16H36N(1+)*ClO4(1-)

1.5C6F4I2*C16H36N(1+)*ClO4(1-)

Conditions
ConditionsYield
In methanol at 20℃;84%

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