Tetrabutylammonium perchlorate supplier

Name
Tetrabutylammonium perchlorate
EINECS 217-655-5
CAS No. 1923-70-2
Article Data22
CAS DataBase
Density 1.0387 (rough estimate)
Solubility acetonitrile: 0.1 g/mL, clear, colorless
Melting Point 211-215 °C
Formula C₁₆H₃₆N^.ClO₄
Boiling Point
Molecular Weight 341.919
Flash Point
Transport Information UN 1479 5.1/PG 2
Appearance white powder
Safety 17-26-36-36/37/39
Risk Codes 5-8-36/37/38
Molecular Structure
Hazard Symbols O, Xi
Synonyms Ammonium, tetrabutyl-, perchlorate;1-Butanaminium, N,N,N-tributyl-, perchlorate;Tetrabutyl ammonium perchlorate;Tetra-n-butylammonium perchlorate;
PSA 74.27000
LogP 5.21790

Synthetic route

: 1643-19-2
tetrabutylammomium bromide

: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);	95%
With perchloric acid
With perchloric acid
With perchloric acid

: 74436-10-5
(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2

: silver perchlorate

: cis-[Pd(pentafluorophenyl)2(THF)2]

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;	A 90% B n/a

...Expand

: N-n-Bu4{Au(C6Cl5)2}

: silver perchlorate

A: [{Au(C6Cl5)2}Ag]n

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.;	A 90% B n/a

...Expand

: NBu4[Ag(C6F5)2]

: {Ag(CH2P(C6H5)3)2}(1+)*ClO4(1-)={Ag(CH2P(C6H5)3)2}ClO4

A: {Ag(C6F5)(CH2P(C6H5)3)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.;	A 85% B n/a

...Expand

: 86392-02-1
(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2

: silver perchlorate

: cis-[Pd(C6Cl5)2(thf)2]

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;	A 80% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: 1020072-44-9, 132018-77-0
[Ag(OClO3)(tetrahydrothiophene)]

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.;	A 80% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: 137400-80-7
{Ag(tetrahydrothiophene)}ClO4

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.;	A 79% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(tetrahydrothiophene)}

: (C4H8S)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.;	A 78% B n/a

...Expand

: (NBu4)2{trans-PtCl2(C6Cl5)2}

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

A: N(C4H9)4(1+)*PtAgCl2(C6Cl5)2(P(C6H5)3)(1-) = (N(C4H9)4){PtAgCl2(C6Cl5)2(P(C6H5)3)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.;	A 77% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)(C6Cl5)2(triphenylphosphine)}

: ((C6H5)3P)(C6Cl5)2(C6F5)PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 77% B n/a

...Expand

: 116349-58-7
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

: silver perchlorate

A: 95674-06-9
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 1:1) and stirring of mixt. (exclusion of light, room temp., 1 h).; Evapn. of soln. to dryness and treatment of resulting oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.;	A 76% B n/a

...Expand

: 90621-02-6
(NBu4)2{platinum(pentafluorophenyl)3Cl}

: silver perchlorate

A: 116349-58-7
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

B: 1923-70-2
tetrabutylammonium perchlorate

C: silver(I) chloride

Conditions

Conditions	Yield
In dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl, evapn. of resulting yellow soln. to dryness and treatment of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Evapn. of ether soln. to dryness gives a solid.;	A 76% B n/a C n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{Pt(C6Cl5)3(pyridine)}

: {(pyridine)(C6Cl5)3PtAg(triphenylphosphine)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 75% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(triphenylphosphine)}

: ((C6H5)3P)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 73% B n/a

...Expand

: 90621-02-6
(NBu4)2{platinum(pentafluorophenyl)3Cl}

: silver perchlorate

A: 95674-06-9
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(diethyl ether)}

B: 1923-70-2
tetrabutylammonium perchlorate

C: silver(I) chloride

Conditions

Conditions	Yield
In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 2:1) and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl and of excess of AgClO4, evapn. of resulting yellow soln. to dryness and washing of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Partial evapn. of yellow soln. and addn. of n-hexane gives a solid.;	A 72% B n/a C n/a

Yield

In diethyl ether; dichloromethane Addn. of AgClO4 to a CH2Cl2 soln. of Pt-complex (molar ratio 2:1) and stirring of mixt. (exclusion of light, room temp., 2 h).; Filtn. of formed AgCl and of excess of AgClO4, evapn. of resulting yellow soln. to dryness and washing of obtained oily residue with O(C2H5)2 to separate the insoluble org. compd. Partial evapn. of yellow soln. and addn. of n-hexane gives a solid.;

A 72%
B n/a
C n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(pyridine)}

: (C5H5N)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 72% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{Pt(C6Cl5)3(triphenylphosphine)}

: (triphenylphosphine)(C6Cl5)3PtAg(triphenylphosphine)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 70% B n/a

...Expand

: triphenylphosphinesilver perchlorate

: 116349-58-7
(NBu4)2{platinum2(μ-pentafluorophenyl)2(pentafluorophenyl)4}

A: 116349-60-1
(NBu4){platinum2(silver)(μ-pentafluorophenyl)2(pentafluorophenyl)4(PPh3)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane Addn. of O3ClOAgPPh3 to a soln. of Pt-compd. (CH2Cl2, -30°C) and stirring of mixt. (30 min, -30°C, exclusion of light).; Pumping of soln. to dryness (-30°C) and treatment of residue with O(C2H5)2 (-30°C). Evapn. of soln. to dryness and addn. of n-hexane after sepn. of insoluble NBu4ClO4.;	A 69% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-triphenylphosphine-2κP-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;	A 68% B n/a

...Expand

: 73165-02-3, 623171-38-0
perchlorato(triphenylphosphane)silver(I)

: {(C4H9)4N}{Pt(C6Cl5)3(tetrahydrothiophene)}

: (tetrahydrothiophene)(C6Cl5)3PtAg(triphenylphosphine)}

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;	A 68% B n/a

...Expand

: 14024-97-6, 14872-21-0, 15227-42-6
trans-dichlorobis(pyridine)platinum(II)

: {NBu4}{Pt(C6F5)3(OCMe2)}

: [NBu4]2[Pt2(μ-pentafluorophenyl)2(pentafluorophenyl)4]

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane; acetone addn. of trans-(PtCl2(py)2) to soln. of Pt-complex in CH2Cl2/acetone (2:1), stirring (1 h); evapn. to dryness, washing (diethyl ether, 2.product solid), evapn. of washings to dryness, treatment with i-PrOH/hexane;	A 58% B n/a

...Expand

: [μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

: silver perchlorate

A: Au(1+)*Ag(1+)*2C6F3H2(1-)=AuAg(C6F3H2)2

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In diethyl ether equimolar amt. of AgClO4 was added to soln. of Au-compound in Et2O, stirred for 1 h; filtered, filtrate evapd., hexane added; elem. anal.;	A 56% B >99

...Expand

: 107556-35-4
O3ClOAg(P(C2H5)3)

: (NBu4)2{trans-PtCl2(C6Cl5)2}

: Pt(C6Cl5)2((μ-Cl)Ag(PEt3))2

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 2 h); evapn., treatment with MeOH, filtn., washing (MeOH); elem. anal.;	A 51% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: Ag(OClO3)(O(C2H5)2)

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;	A 50% B n/a

...Expand

: {NBu4}{Pt(pentafluorophenyl)4}

: silver perchlorate

: tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-diethyl ether-2κO-platinumargentate (Ag-Pt)

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
With diethyl ether In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, addn. of Et2O, filtration, evapn. to dryness, treated with hexane, drying in vac., elem. anal.;	A 50% B n/a

...Expand

: 110373-27-8
perchlorato(methyldiphenylphosphane)silver(I)

: (NBu4)2{trans-PtCl2(C6Cl5)2}

: Pt(C6Cl5)2((μ-Cl)Ag(PPh2Me))2

B: 1923-70-2
tetrabutylammonium perchlorate

Conditions

Conditions	Yield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.;	A 39% B n/a
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:2), stirring (room temp., 1 h); filtn., evapn., treatment with MeOH; elem. anal.;	A 73-77 B n/a

...Expand

: Didodecyl-(3-methyl-2-butenyl)-sulfonium perchlorate

: tetrabutylammonium dihydrogen phosphate

A: 2469-45-6
didodecyl sulfide

B: 1923-70-2
tetrabutylammonium perchlorate

C: 110071-93-7
(methyl-2 butene-3 yl-2) phosphate de potassium

Conditions

Conditions	Yield
With Potassium benzoate; copper(I) bromide In dichloromethane	A n/a B n/a C 17%

...Expand

: 1923-70-2
tetrabutylammonium perchlorate

: 10294-34-5
boron trichloride

: 54775-46-1
tetrabutylammonium trichloroperchloratoborate

Conditions

Conditions	Yield
In chloroform introducing of gaseous BCl3 to soln. of <(C4H9)4N> in CHCl3 at 20°C; distn. and drying in vac.;	100%
In neat (no solvent) Bu4NClO4 reacted slowly with excess of BCl3 at 20°C; elem. anal.;
In chloroform Bu4NClO4 reacted slowly with BCl3 in CHCl3 at 20°C; elem. anal.;
In chloroform

: 4440-89-5
4,5-dimethylethylene (trans,trans) sulphate

: 1923-70-2
tetrabutylammonium perchlorate

A: 624-64-6
trans-2-Butene

B: C4H8O8S2(2-)*2K(1+)

C: 2C16H36N(1+)*C6H12O8S2(2-)

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; Product distribution; electrolysis, oth. solvent, var. cathodes;	A 99% B 42% C n/a

...Expand

: 7637-07-2
boron trifluoride

: 1923-70-2
tetrabutylammonium perchlorate

: tetrabutylammonium trifluoroperchloratoborate

Conditions

Conditions	Yield
In chloroform Bu4NClO4 reacted with BF3 in CHCl3 at 20°C;	99%

: 1007838-83-6
Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)

: 1923-70-2
tetrabutylammonium perchlorate

: 1007838-97-2
[Ru(2,6-(C6H5NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions

Conditions	Yield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;	99%

: 1007838-80-3
Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)

: 1923-70-2
tetrabutylammonium perchlorate

: 1007838-95-0
[Ru(2,6-(4-CH3C6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions

Conditions	Yield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;	99%

: 1007838-78-9
Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)

: 1923-70-2
tetrabutylammonium perchlorate

: 1007838-91-6
[Ru(2,6-(4-CH3OC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions

Conditions	Yield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;	99%

: 1007838-85-8
Ru(N,N'-bis(4'-chlorophenyl)pyridine-2,6-dicarboxamide)(2,2',2''-terpyridine)

: 1923-70-2
tetrabutylammonium perchlorate

: 1007838-99-4
[Ru(2,6-(ClC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions

Conditions	Yield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;	99%

: 1007838-88-1
Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)

: 1923-70-2
tetrabutylammonium perchlorate

: 1007839-01-1
[Ru(2,6-(O2NC6H4NCO)2C5H3N)(2,2',2''-terpyridine)]ClO4

Conditions

Conditions	Yield
In dichloromethane; acetonitrile Electrolysis; 1:9 CH2Cl2:MeCN (0.1 M TBAP), 0.4 V vs. SCE, 298 K; layering over toluene, slow diffusion, elem. anal.;	99%

: Au3(MeN=COMe)3

: 1923-70-2
tetrabutylammonium perchlorate

: [Au3(MeN=COMe)3](ClO4)0.34

Conditions

Conditions	Yield
In dichloromethane Electrolysis;	99%

: 110-86-1
pyridine

: 131063-11-1, 16997-51-6, 19559-06-9
Vanadium (III) chloride-(tris-tetrahydrofuran)

: 1923-70-2
tetrabutylammonium perchlorate

: 7732-18-5
water

: 127-09-3
sodium acetate

: 178882-95-6
[V3O(O2CMe)6(pyridine)3](ClO4)

Conditions

Conditions	Yield
In pyridine; acetic acid; acetonitrile byproducts: NaCl; N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/pyridine=2:1:2v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.;	95%

...Expand

: ammonium thiocyanate

: ammonium hexabromotechnetate

: 1923-70-2
tetrabutylammonium perchlorate

: {(n-C4H9)4N}3{Tc(NCS)6}

Conditions

Conditions	Yield
With N2H4H2O In methanol NH4SCN and (NH4)2TcBr6 refluxed in methanol under N2 or Ar for 24 h, system cooled to room temp., N2H4H2O added, mixt. filtered under inert atm., filtrate treated with n-Bu4NClO4 in methanol; solid filtered under inert atm., washed with water, methanol, dried in vac.; elem. anal.;	93%

...Expand

: 108-89-4
picoline

: 131063-11-1, 16997-51-6, 19559-06-9
Vanadium (III) chloride-(tris-tetrahydrofuran)

: 1923-70-2
tetrabutylammonium perchlorate

: 7732-18-5
water

: 127-09-3
sodium acetate

: [V3O(O2CMe)6(4-picoline)3](ClO4)

Conditions

Conditions	Yield
In acetic acid; acetonitrile N2-atmosphere; stirring V-complex with AcONa in MeCN/AcOH/4-picoline=2:1:2.2 v/v/v for 24 h, filtration off of NaCl, Bu4NClO4 addn.; further educt: acetic acid; vol. reduction (vac.), pptn. on Et2O addn., collection (filtration), washing (Et2O), drying (vac.); elem. anal.;	91%

...Expand

: 39929-21-0
(tetrahydrothiophene)gold(I) chloride

: 1923-70-2
tetrabutylammonium perchlorate

: 53732-49-3
lithium-2,4,6-trifluorophenyl

: [μ-nitrido-bis(triphenylphosphorus)][Au(2,4,6-CC6F3H2)2]

Conditions

Conditions	Yield
In diethyl ether byproducts: Au; mixing soln. of Au-complex and ligand (-78°C), stirring for 20 min, warming to room temp., stirring (30 min), filtration, addn. to Bu4N(ClO4) soln. (pptn.); recrystn. (CH2Cl2/EtOH);	90%

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: 129264-47-7
osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)

: 1923-70-2
tetrabutylammonium perchlorate

: {osmium(2,2'-bipyridine)2(3,5-di-tert-butylcatechol)}perchlorate

Conditions

Conditions	Yield
In methanol; dichloromethane stirred in air at room temp. for 24h; cooled in a refrigerator; elem. anal.;	90%

: potassium cyanide

: 400654-03-7
[platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2

: 1923-70-2
tetrabutylammonium perchlorate

: 75-05-8
acetonitrile

: [(n-butyl)4N][platinum(II)(CN)2(2-( p-tolyl)-pyridine(-H))]*0.5(acetonitrile)

Conditions

Conditions	Yield
Stage #1: [platinum(II)(μ-chloride)(2-( p-tolyl)-pyridine(-H))]2 With silver perchlorate In acetonitrile for 7h; Darkness; Stage #2: potassium cyanide In methanol for 2h; Stage #3: tetrabutylammonium perchlorate; acetonitrile Further stages;	90%

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: 170439-30-2
2-(1,8-naphthyridin-2-yl)thiazole

: tetraacetatodiruthenium chloride

: 1923-70-2
tetrabutylammonium perchlorate

: 7732-18-5
water

: cis-[Ru2(2-(2-thiazolyl)-1,8-naphthyridine)2(OAc)2][ClO4]2(H2O)0.5

Conditions

Conditions	Yield
Stage #1: 2-(2-thiazolyl)-1,8-naphthyridine; tetraacetatodiruthenium chloride; tetrabutylammonium perchlorate In methanol Inert atmosphere; Schlenk technique; Reflux; Stage #2: water Inert atmosphere; Schlenk technique;	90%

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: 1923-70-2
tetrabutylammonium perchlorate

: C78H55Co5N24O(3+)*3BF4(1-)*3.75C2H3N*0.33H2O

: 75-05-8
acetonitrile

: C78H55Co5N24O(2+)*2ClO4(1-)*2C2H3N

Conditions

Conditions	Yield
Glovebox; Inert atmosphere; Electrochemical reaction;	90%

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: tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

: 1923-70-2
tetrabutylammonium perchlorate

: 128-04-1
sodium N,N-dimethyldithiocarbamate dihydrate

: N(C4H9)4(1+)*Au(C6F5)3(S2CN(CH3)2)(1-) = {N(C4H9)4}{Au(C6F5)3(S2CN(CH3)2)}

Conditions

Conditions	Yield
In dichloromethane; acetone byproducts: NaClO4; to soln. of Au complex in acetone added Na(S2CNMe2)*2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;	89%

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: tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

: 1923-70-2
tetrabutylammonium perchlorate

: 128-04-1
sodium N,N-dimethyldithiocarbamate dihydrate

: N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(CH3)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(CH3)2)}

Conditions

Conditions	Yield
In dichloromethane; acetone to soln. of Au complex in acetone added Na(S2CNMe2)2H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (25 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;	89%

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: 295-37-4
1,4,8,11-Tetraazacyclotetradecane

: 1923-70-2
tetrabutylammonium perchlorate

: 7439-89-6
iron

: 75-05-8
acetonitrile

: [Fe(1,4,8,11-tetraazacyclotetradecane)(CH3CN)2](ClO4)2

Conditions

Conditions	Yield
With trifluorormethanesulfonic acid In acetonitrile Ar-atmosphere; refluxing excess Fe with CF3SO3H for 4 h, filtration, mixing with cyclam, refluxing for 30 min, addn. of Bu4NClO4, refluxing for 30 min; cooling in ice bath, Et2O addn. (pptn.);	88%

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: potassium cyanide

: 1048673-03-5
[Pt(2-phenylpyridinate)(NCMe)2]ClO4

: 1923-70-2
tetrabutylammonium perchlorate

: 167647-56-5
tetrabutylammonium dicyano[(2-pyridyl)phenyl-2-ido]platinate(II)

Conditions

Conditions	Yield
In methanol KCN was added to suspn. Pt complex in MeOH at room temp. and stirred for1 h, soln. was filtered through Celite and evapd. to dryness, Bu4NClO4 and acetone were added and stirred for 1 h; soln. was filtered through Celite, soln. was evapd. to dryness, residue was treated with water, filtered, dried (110°C) and recrystd. from CH2Cl2-Et2O; elem. anal.;	88%

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: 366-18-7
[2,2]bipyridinyl

: [NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

: 1923-70-2
tetrabutylammonium perchlorate

: 195203-54-4
[Pd2(μ-PPh2)(C6F5)4(bipy)2][ClO4]

Conditions

Conditions	Yield
In isopropyl alcohol; acetone stirring Pd-complex with bipy (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.;	87%

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: [NBu4]2[Pd4(μ-Cl)4(μ-PPh2)2(C6F5)4]

: 1923-70-2
tetrabutylammonium perchlorate

: 5144-89-8
1,10-phenanthroline hydrate

: 195203-56-6
[Pd2(μ-PPh2)(C6F5)4(phen)2][ClO4]

Conditions

Conditions	Yield
In isopropyl alcohol; acetone stirring Pd-complex with phen (in Me2CO) for 10 min, partial evapn., add. if i-PrOH and Bu4NClO4; pptn. on partial evapn.., collection (filtration), washing (i-PrOH), drying in air; elem. anal.;	87%

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: potassium cyanide

: [(C6F5)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CH3CN)2]

: 1923-70-2
tetrabutylammonium perchlorate

: [NBu4]2[(RF)2Pt(μ-PPh2)2Pt(μ-PPh2)2Pt(CN)2]

Conditions

Conditions	Yield
In acetone at 20℃; for 12h;	87%

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: tris(pentafluorophenyl)(tetrahydrothiophene)gold(III)

: 1923-70-2
tetrabutylammonium perchlorate

: 20624-25-3
sodium diethyldithiocarbamate trihydrate

: N(C4H9)4(1+)*{Au(C6F5)3}2(S2CN(C2H5)2)(1-) = {N(C4H9)4}{{Au(C6F5)3}2(S2CN(C2H5)2)}

Conditions

Conditions	Yield
In dichloromethane; acetone appropriated choice of molar ratio of educts; to soln. of Au complex in acetone added Na(S2CNEt2)3H2O, stirred for 2 h at room temp., evapd. to dryness, soln. of (NBu4)ClO4 in CH2Cl2 added, stirred for 1h at room temp.; filtered, washed (25 ml) with CH2Cl2, filtrate and washings were evapd. in vac. to ca. 5 ml, upon addition of n-hexane pptd. product; elem. anal.;	84%

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: 392-57-4
1,4-diiodo-2,3,5,6-tetrafluorobenzene

: 1923-70-2
tetrabutylammonium perchlorate

: 1.5C6F4I2*C16H36N(1+)*ClO4(1-)

Conditions

Conditions	Yield
In methanol at 20℃;	84%

Tetrabutylammonium perchlorate Specification

The Tetrabutylammonium perchlorate is an organic compound with the formula C₁₆H₃₆N^.ClO₄. The systematic name of this chemical is N,N,N-tributylbutan-1-aminium perchlorate. With the CAS registry number 1923-70-2, it is also named as Ammonium, tetrabutyl-, perchlorate. The product's categories are Ammonium Polyhalides, etc. (Quaternary); Oxidation; Quaternary Ammonium Compounds; Synthetic Organic Chemistry; Detergents A to ZSynthetic Reagents; Detergents; Perchlorates; Ammonium SaltsSynthetic Reagents; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Ammonium SaltsAnalytical Reagents; Electrochemistry; Supporting Electrolytes for Electrochemistry. Besides, it should be stored in a closed cool and dry place.

Physical properties about Tetrabutylammonium perchlorate are: (1)ACD/LogP: -1.72; (2)ACD/LogD (pH 5.5): -1.72; (3)ACD/LogD (pH 7.4): -1.72; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.78; (7)ACD/KOC (pH 7.4): 2.78; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 12.

When you are using this chemical, please be cautious about it as the following:
It contacts with combustible material may cause fire. Please keep away from combustible material. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(3)InChIKey: KBLZDCFTQSIIOH-REWHXWOFAG
(4)Std. InChI: InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(5)Std. InChIKey: KBLZDCFTQSIIOH-UHFFFAOYSA-M

Product Name

Tetrabutylammonium perchlorate

Synthetic route

Tetrabutylammonium perchlorate Specification

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