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Henan Allgreen Chemical Co.,Ltd

he company has advanced technology, as well as a large number of excellent R & D team, to provide customers from the grams to one hundred kilograms and tons of high-quality products, competitive prices and quality se T rvice Appearance:

Dichlorophenylborane

Cas:873-51-8

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Borane, dichlorophenyl-

Cas:873-51-8

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Dichlorophenylborane

Cas:873-51-8

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufacturin

PHENYLBORON DICHLORIDE

Cas:873-51-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 873-51-8 with best quality

Cas:873-51-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Hubei Langyou International Trading Co., Ltd

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8 1. Guaranteed purity; 2. Large quantity in stock; 3. Largest manufacturer; 4. Best service after shipment with email; 5. High quality & competitive price; Appear

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:10 Metric Ton

Negotiable

Type:Other

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Borane, dichlorophenyl-

Cas:873-51-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Borane, dichlorophenyl-

Cas:873-51-8

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Borane, dichlorophenyl-

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Phenylboron dichloride

Cas:873-51-8

Min.Order:0 Metric Ton

Negotiable

Type:Other

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phenylborondichloride

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality Appearance:clear colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Used as Pharmaceutical Intermediates Transporta

PHENYLBORON DICHLORIDE

Cas:873-51-8

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

873-51-8

Cas:873-51-8

Min.Order:1 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

Type:Trading Company

inquiry

Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:1 Metric Ton

FOB Price: $1.5

Type:Trading Company

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

Dichlorophenylborane

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Trading Company

inquiry

Shanghai Acmec Biochemical Technology Co., Ltd.

Acmec is a leading manufacturer and supplier of biochemical reagents and life science products. We have over 40,000 items in stock (real-time inventory) and offer discounted prices to registered members of the online store ( www.acmec.com.cn ) Appea

Acmec Phenylboron Dichloride 1g

Cas:873-51-8

Min.Order:1 bottle

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages? High purity, all above 98.5%, no impurities after dissolution? We will test each batch to ensure quality? OEM and private brand services designed for free? Various cap colors available? We can also provide MT1 peptide powder2.

PHENYLBORON DICHLORIDE

Cas:873-51-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Borane, dichlorophenyl-

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

We are a trading company aiming at providing high-quality services to customers. Established for many years, with good reputation in the industry Storage:Sealed and preserved Application:Fine chemical intermediates, used as the main raw material for

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

PHENYLBORON DICHLORIDE CAS No.873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

Borane, dichlorophenyl- cas 873-51-8Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

Borane, dichlorophenyl- cas 873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

low price and high purityAppearance:solid or liquid Storage:in sealed air resistant place Package:As customer require Application:Pharma;Industry;Agricultural Transportation:by sea or by airplane Port:any port in China

Dichlorophenylborane, 96% 873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers2. Produce products of different specifications and sizes according to your requirements.3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures sta

PHENYLBORON DICHLORIDE

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8Appearance:white powder Storage:Shading, sealed, dry place. Package:foil bags, drums or bottles Application:Reagents / Pharmaceutical Intermediates / Active Pharmaceutical Ingredient

Phenylboron Dichloride High Purity Reagent in Low Price CAS 873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

873-51-8

Cas:873-51-8

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

trimethylphenylsilane
768-32-1

trimethylphenylsilane

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: ClSi(CH3)3; 60°C, 12h, ampul;98%
In dichloromethane byproducts: ClSi(CH3)3; in inert atmosphere, dropwise addn. of trimethylphenylsilane to a stirred soln. of BCl3 at -78°C, stirring (-78°C, 1 h), slow warming to room temp.; evapn. in vac. at 30°C.;92%
boron trichloride
10294-34-5

boron trichloride

diborane
19287-45-7

diborane

benzene
71-43-2

benzene

A

phenylborondichloride
873-51-8

phenylborondichloride

B

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: boron hydride; High Pressure; under N2; diborane and trihalogen-borane was added to benzene at -130°C, then in a closed autoclave the mixture was heated to 130°C for 90 min; at -195.8°C H2 was removed, at room temp. the residue of trihalogen-borane and diborane were removed;A 46%
B 77%
triphenylboroxine
3262-89-3

triphenylboroxine

aluminium trichloride
7446-70-0

aluminium trichloride

A

2,2,8,8,13-pentachloro-4,6,10,12-tetraphenyl-1,3,5,7,9,11-hexaoxa-4,6,10,12-tetrabora-2,8,13-trialuminatetracyclo{7.3.1.0(3,13)0(7,13)}tridecane

2,2,8,8,13-pentachloro-4,6,10,12-tetraphenyl-1,3,5,7,9,11-hexaoxa-4,6,10,12-tetrabora-2,8,13-trialuminatetracyclo{7.3.1.0(3,13)0(7,13)}tridecane

B

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
In octane boroxine was added under Ar to a soln. of AlCl3, the mixt was heated at about 100 °C for 10 h (stirring);; filtration, residue washed with hexane, dried in vac. at 20°C, recrystd. from benzene; elem. anal.;;A 68%
B n/a
ethylbenzene
100-41-4

ethylbenzene

boron trichloride
10294-34-5

boron trichloride

diborane
19287-45-7

diborane

A

ethyl-dichloro-borane
1739-53-3

ethyl-dichloro-borane

B

phenylborondichloride
873-51-8

phenylborondichloride

C

(3-ethylphenyl)dichloroborane
76782-86-0

(3-ethylphenyl)dichloroborane

D

(4-ethylphenyl)dichloroborane
4250-50-4

(4-ethylphenyl)dichloroborane

E

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
With sodium hydroxide byproducts: benzene, boron hydride, CH3CH2C6H5; High Pressure; under N2; diborane and trihalogen-borane was added to ethylbenzene at -130°C, then in a closed autoclave the mixture was heated to 125°C for 85 min; at -195.8°C H2 was removed, at room temp. the residue of trihalogen-borane and diborane were removed;A 16%
B 4.5%
C n/a
D n/a
E 68%
diethyl phenylboronate
31044-59-4

diethyl phenylboronate

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
iron(III) chloride In dichloromethane byproducts: BCl2(OC2H5); slow addn. of boronate to BCl3 soln. contg. FeCl3 under N2, 0°C, within 10 min; stirring at 0°C, 1 h and at 25°C, 1 h; evapn.; extn. (CH2Cl2); evapn.; distn.;67%
Isopropylbenzene
98-82-8

Isopropylbenzene

boron trichloride
10294-34-5

boron trichloride

diborane
19287-45-7

diborane

A

dichloro-isopropyl-borane
7680-99-1

dichloro-isopropyl-borane

B

m-Dichlor(isopropylphenyl)boran
76782-87-1

m-Dichlor(isopropylphenyl)boran

C

p-Dichlor(isopropylphenyl)boran
76782-88-2

p-Dichlor(isopropylphenyl)boran

D

phenylborondichloride
873-51-8

phenylborondichloride

E

hydrogen
1333-74-0

hydrogen

Conditions
ConditionsYield
byproducts: boron hydride, benzene, C3H8; High Pressure; under N2; diborane and trihalogen-borane was added to cumene at -130°C, then in a closed autoclave the mixture was heated to 130°C for 90 min; at -195.8°C H2 was removed, at room temp. the residue of trihalogen-borane and diborane were removed, unseparable isomers; elem. anal.;A 4%
B n/a
C n/a
D 20%
E 61%
tetraphenyltin(IV)
595-90-4

tetraphenyltin(IV)

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
In benzene BCl3 cooled at -78°C and quickly added to Sn(C6H5)4, cooled at 5°C while stirring; warming at ambient temp., boiled for 3.5 h using back-flow; best lab. method; solvent must be distd. below 140°C (immersion thermometer!); crude product distd. between 150-200°C; fractional vac. distn.;56%
In benzene BCl3 cooled at -78°C and quickly added to Sn(C6H5)4, cooled at 5°C while stirring; warming at ambient temp., boiled for 3.5 h using back-flow; best lab. method; solvent must be distd. below 140°C (immersion thermometer!); crude product distd. between 150-200°C; fractional vac. distn.;56%
bis(chlorophenylboryl)phenylamine

bis(chlorophenylboryl)phenylamine

A

phenylborondichloride
873-51-8

phenylborondichloride

B

hexaphenylborazine
16672-48-3

hexaphenylborazine

Conditions
ConditionsYield
In neat (no solvent, solid phase) N2 atmosphere, (room temp., 1E-3 Torr); pptn. (petroleum ether, room temp., 2 d), recrystn. (decane); elem. anal.;A n/a
B 26%
(μ-H)3Os3(CO)9{μ3-η2-C(OB(Ph)Cl)B(Cl)}

(μ-H)3Os3(CO)9{μ3-η2-C(OB(Ph)Cl)B(Cl)}

A

(μ-H)3(CO)9Os3(μ3-CH)

(μ-H)3(CO)9Os3(μ3-CH)

B

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With hydrogenchloride In dichloromethane-d2 byproducts: B3Cl3O3; under N2, stirred at room temp. for 2 h; decanted in an NMR tube, cooled to -196°C and sealed; NMR, IR, mass spectra;A 25%
B n/a
triphenylboroxine
3262-89-3

triphenylboroxine

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride
With phosphorus pentachloride
bis(s-butyloxy)phenyl borane
98109-89-8

bis(s-butyloxy)phenyl borane

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride
diphenylboronchloride
3677-81-4

diphenylboronchloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride at 200℃;
diethyl phenylboronate
31044-59-4

diethyl phenylboronate

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride
dibutoxyphenylborane
7330-48-5

dibutoxyphenylborane

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride
With phosphorus pentachloride
diisobutyl phenylborate
59024-15-6

diisobutyl phenylborate

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With phosphorus pentachloride
chloro-phenoxy-phenyl-borane
100123-15-7

chloro-phenoxy-phenyl-borane

A

phenylborondichloride
873-51-8

phenylborondichloride

B

diphenyl phenylboronate
2938-75-2

diphenyl phenylboronate

Conditions
ConditionsYield
at 155 - 160℃; under 0.05 Torr;
diphenylmercury(II)
587-85-9

diphenylmercury(II)

A

triphenylboroxine
3262-89-3

triphenylboroxine

B

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride; benzene at 180 - 200℃; ueber mehrere Stufen;
diphenylmercury(II)
587-85-9

diphenylmercury(II)

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride at 180 - 200℃;
benzene
71-43-2

benzene

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With boron trichloride; aluminium
With aluminium trichloride; boron trichloride
With iodine; boron trichloride
boron trichloride
10294-34-5

boron trichloride

benzene
71-43-2

benzene

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With Al(I2,AlCl3)
With aluminium trichloride; iodine for tech. application;
With palladium thermally;
aluminium trichloride
7446-70-0

aluminium trichloride

boron trichloride
10294-34-5

boron trichloride

benzene
71-43-2

benzene

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
In octane
In octane
diboron tetrachloride
13701-67-2

diboron tetrachloride

benzene
71-43-2

benzene

phenylborondichloride
873-51-8

phenylborondichloride

triphenylboroxine
3262-89-3

triphenylboroxine

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

triphenylboroxine
3262-89-3

triphenylboroxine

phosphorus trichloride
7719-12-2, 52843-90-0

phosphorus trichloride

phenylborondichloride
873-51-8

phenylborondichloride

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
With (dialkoxy)phenylborane
sodium tetraphenyl borate
143-66-8

sodium tetraphenyl borate

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

boron trichloride
10294-34-5

boron trichloride

diphenylmercury(II)
587-85-9

diphenylmercury(II)

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
byproducts: H2O; distn.;;
iodobenzene
591-50-4

iodobenzene

boron trichloride
10294-34-5

boron trichloride

phenylborondichloride
873-51-8

phenylborondichloride

Conditions
ConditionsYield
Irradiation (UV/VIS);
Irradiation (UV/VIS);
boron trichloride
10294-34-5

boron trichloride

phenylmercury(II) chloride
100-56-1

phenylmercury(II) chloride

phenylborondichloride
873-51-8

phenylborondichloride

phenylborondichloride
873-51-8

phenylborondichloride

dimethyl amine
124-40-3

dimethyl amine

Bis-(dimethylamino)-phenylboran
1201-45-2

Bis-(dimethylamino)-phenylboran

Conditions
ConditionsYield
In pentane at -78 - 20℃; Inert atmosphere;100%
In hexane87%
In hexane87%
nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)
158789-52-7

nitrido(tetra-tert-butylphthalocyaninato)rhenium(V)

phenylborondichloride
873-51-8

phenylborondichloride

((CH3)3CC8H3NN)4ReNBCl2C6H5
582295-88-3

((CH3)3CC8H3NN)4ReNBCl2C6H5

Conditions
ConditionsYield
In dichloromethane Re compd. dissolved in CH2Cl2 and cooled to -5°C, electrophile added dropwise to this soln., stirred for 6 h at -5°C; solvent removed at -5°C, elem. anal.;100%
4-phenyl-1,2,3-selenadiazole
25660-64-4

4-phenyl-1,2,3-selenadiazole

phenylborondichloride
873-51-8

phenylborondichloride

4-phenyl-1,2,3-selenadiazole phenyldichloroborane complex
1047719-64-1

4-phenyl-1,2,3-selenadiazole phenyldichloroborane complex

Conditions
ConditionsYield
In benzene at 20℃; for 1h;100%
5,5-dimethyl-5H-dibenzo[b,f]stannepine
1189139-25-0

5,5-dimethyl-5H-dibenzo[b,f]stannepine

phenylborondichloride
873-51-8

phenylborondichloride

5-phenyl-5H-dibenzo[b,f]borepin
1237745-14-0

5-phenyl-5H-dibenzo[b,f]borepin

Conditions
ConditionsYield
In toluene at -78 - 20℃; for 18h; Inert atmosphere;100%
In toluene Schlenk air-free techniques; react. of Sn compound and PhBCl2 at -78°C;99%
phenylborondichloride
873-51-8

phenylborondichloride

5,5-dimethyl-5H-dibenzo[b,d]stannole
5565-85-5

5,5-dimethyl-5H-dibenzo[b,d]stannole

5-phenyl-5H-dibenzo[b,d]borole
14010-93-6

5-phenyl-5H-dibenzo[b,d]borole

Conditions
ConditionsYield
In toluene byproducts: Me2SnCl2; (Ar); using Schlenk techniques; vac. transferring of toluene into flask with C12H8SnMe2 at -78°C; addn. dropwise via syringe of soln. of C6H5BCl2 at -78°C, slowly warming to room temp., stirring overnight; removal of solvent under vac., transferring to a sublimator, removal of Me2SnCl2 under static vac. at 40°C for 2 days, elem. anal.;99%
In water; toluene at -78 - 20℃; for 12h; Inert atmosphere; Schlenk technique;
In toluene at -78 - 20℃; Inert atmosphere;
Tl(C5H3(Si(CH3)3)2)

Tl(C5H3(Si(CH3)3)2)

phenylborondichloride
873-51-8

phenylborondichloride

bis(bis(trimethylsilyl)cyclopentadienyl)phenylborane
192649-53-9

bis(bis(trimethylsilyl)cyclopentadienyl)phenylborane

Conditions
ConditionsYield
In pentane byproducts: TlCl; Ar-atmosphere; dropwise addn. of B-compd. to 2 equiv. of Tl-compd. at room temp., stirring overnight; filtration off of TlCl, washing (pentane), slow evapn. (below 30°C), solidified on cooling, recrystn. (pentane);99%
phenylborondichloride
873-51-8

phenylborondichloride

1-ethyl-2-aminonaphthalene

1-ethyl-2-aminonaphthalene

2‐phenyl‐1,2‐dihydro‐1‐aza‐2‐boraphenanthrene

2‐phenyl‐1,2‐dihydro‐1‐aza‐2‐boraphenanthrene

Conditions
ConditionsYield
With triethylamine In chlorobenzene at 130℃; for 12h; Glovebox;99%
phenylborondichloride
873-51-8

phenylborondichloride

1‐vinylnaphthalen‐2‐amine

1‐vinylnaphthalen‐2‐amine

2‐phenyl‐1,2‐dihydro‐1‐aza‐2‐boraphenanthrene

2‐phenyl‐1,2‐dihydro‐1‐aza‐2‐boraphenanthrene

Conditions
ConditionsYield
With triethylamine In chlorobenzene at 130℃; for 14h; Inert atmosphere;99%
phenylborondichloride
873-51-8

phenylborondichloride

diphenylsilyl dichloride
80-10-4

diphenylsilyl dichloride

{((C6H5)2Si)4(B(C6H5))(CH2)5}

{((C6H5)2Si)4(B(C6H5))(CH2)5}

Conditions
ConditionsYield
With sodium; 1,2-dibromomethane In xylene Ar; to suspension of Na were added at 138°C during 1.5 h silane and borane (4:1) and CH2Br2; 30 min reflux; filtration; evapn. of solvent and drying at 100°C for 20 h (vacuo); elem. anal.;98.8%
phenylborondichloride
873-51-8

phenylborondichloride

2,4,6-triphenylborazine
976-28-3

2,4,6-triphenylborazine

Conditions
ConditionsYield
With 1,1,1,3,3,3-hexamethyl-disilazane In dichloromethane at 55℃; for 240h;98%
With ammonia96%
With NH396%
phenylborondichloride
873-51-8

phenylborondichloride

1,1,1,3,3,3-hexamethyl-disilazane
999-97-3

1,1,1,3,3,3-hexamethyl-disilazane

2,4,6-triphenylborazine
976-28-3

2,4,6-triphenylborazine

Conditions
ConditionsYield
In dichloromethane (Ar), (Me3Si)2NH in CH2Cl2 cooled to -78°C, treated with PhBCl2 under stirring, kept at 55°C for 10 d; evapd.(vac.), crystd.(Et2O);98%
In benzene byproducts: Me3SiCl; absence of moisture; addn. of silylamine to borane derivative (during 4h, cooling in ice/EtOH, stirring), slow warming to room temp. (overnight); distn. of Me3SiCl (50-55°C, atmospheric pressure), repeated fractional distn.;78%
1,1-chloro(methyl)-1-sila-[1]ferrocenophane
174872-97-0

1,1-chloro(methyl)-1-sila-[1]ferrocenophane

phenylborondichloride
873-51-8

phenylborondichloride

(C5H4B(C6H5)Cl)Fe(C5H4SiCl2(CH3))
627099-07-4

(C5H4B(C6H5)Cl)Fe(C5H4SiCl2(CH3))

Conditions
ConditionsYield
In hexane under Ar; Fe complex dissolved in hexane; added dropwise at 0°C to soln. of PhBCl2 (5 equiv.) in hexane; stirred at room temp. for 3 h; volatiles removed in vac.; taken up in hexane; soln. filtered over Na2SO4; solvent removed; detd. by (1)H NMR spectra;98%
bis-valine N,N'-sulfone
1104867-77-7

bis-valine N,N'-sulfone

phenylborondichloride
873-51-8

phenylborondichloride

C22H26B2N2O6S
1104867-78-8

C22H26B2N2O6S

Conditions
ConditionsYield
Stage #1: bis-valine N,N'-sulfone; phenylborondichloride In toluene for 0.5h;
Stage #2: With polymer-bound 2,6-di-tert-butylpyridine In toluene for 0.25h;
98%
8-((trimethylsilyl)oxy)quinoline
23111-13-9

8-((trimethylsilyl)oxy)quinoline

phenylborondichloride
873-51-8

phenylborondichloride

2-chloro-2-phenyl-2H-2l4,3l4-[1,3,2]oxazaborolo[5,4,3-ij]quinoline

2-chloro-2-phenyl-2H-2l4,3l4-[1,3,2]oxazaborolo[5,4,3-ij]quinoline

Conditions
ConditionsYield
In dichloromethane at 20℃; for 1h;98%
In dichloromethane98%
N-(1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)-1,1,1-trimethylsilanamine

N-(1,3-bis(2,6-diisopropylphenyl)-1H-imidazol-2(3H)-ylidene)-1,1,1-trimethylsilanamine

phenylborondichloride
873-51-8

phenylborondichloride

C33H41BClN3

C33H41BClN3

Conditions
ConditionsYield
In toluene at -35 - 20℃; for 1.5h;98%
(trimethylsilyl)(trimethylstannyl)cyclopentadiene

(trimethylsilyl)(trimethylstannyl)cyclopentadiene

phenylborondichloride
873-51-8

phenylborondichloride

bis(trimethylsilylcyclopentadienyl)phenylborane

bis(trimethylsilylcyclopentadienyl)phenylborane

Conditions
ConditionsYield
In toluene Ar-atmosphere; refluxing (overnight); evapn. (vac.);97.7%
1,1-dichloro-1-sila-[1]ferrocenophane

1,1-dichloro-1-sila-[1]ferrocenophane

phenylborondichloride
873-51-8

phenylborondichloride

(C5H4B(C6H5)Cl)Fe(C5H4SiCl3)
627099-29-0

(C5H4B(C6H5)Cl)Fe(C5H4SiCl3)

Conditions
ConditionsYield
In hexane under Ar; Fe complex dissolved in hexane; added dropwise at 0°C to soln. of PhBCl2 (5 equiv.) in hexane; stirred at room temp. for 3 h; volatiles removed in vac.; taken up in hexane; soln. filtered over Na2SO4; solvent removed; detd. by (1)H NMR spectra;97%
phenylborondichloride
873-51-8

phenylborondichloride

2,6-di(prop-1-en-2-yl)aniline

2,6-di(prop-1-en-2-yl)aniline

C18H18BN

C18H18BN

Conditions
ConditionsYield
In toluene at 0℃; for 2.5h; Inert atmosphere; Reflux;97%
trimethylsilylazide
4648-54-8

trimethylsilylazide

phenylborondichloride
873-51-8

phenylborondichloride

diazido(phenyl)borane
168281-51-4

diazido(phenyl)borane

Conditions
ConditionsYield
In benzene byproducts: Me3SiCl; cooling (0°C), stirring (12 h, room temp.); evapn. (vac.), distn. (50°C, 1 torr);96.5%
phenylborondichloride
873-51-8

phenylborondichloride

Bis-(dimethylamino)-phenylboran
1201-45-2

Bis-(dimethylamino)-phenylboran

chloro(dimethylamino)phenylborane
1196-44-7

chloro(dimethylamino)phenylborane

Conditions
ConditionsYield
(dichloro)phenylborane was added to bis(dimethylamino)phenylborane keeping the temp. at 60-70°C, stirred for 30 min; destn.;96%
In neat (no solvent) mixed and set aside for 3 h; distd. in vac.;90%
phenylborondichloride
873-51-8

phenylborondichloride

dicyclohexyl-carbodiimide
538-75-0

dicyclohexyl-carbodiimide

C6H5BCl2N(C6H11)CN(C6H11)
874162-18-2

C6H5BCl2N(C6H11)CN(C6H11)

Conditions
ConditionsYield
In hexane PhBCl2 in hexane treated with equiv. of ligand at ambient temp.; isolated, crystd.;96%
trimethylsilyl trifluoromethanesulfonate
27607-77-8

trimethylsilyl trifluoromethanesulfonate

phenylborondichloride
873-51-8

phenylborondichloride

1-(1,2,4-triazol-4-yl)-2,4,6-trimethylbenzene
54893-29-7

1-(1,2,4-triazol-4-yl)-2,4,6-trimethylbenzene

tris(1-mesityl-1,3,4-triazolium)phenylborane bis(triflate)

tris(1-mesityl-1,3,4-triazolium)phenylborane bis(triflate)

Conditions
ConditionsYield
Stage #1: phenylborondichloride; 1-(1,2,4-triazol-4-yl)-2,4,6-trimethylbenzene In toluene for 8h;
Stage #2: trimethylsilyl trifluoromethanesulfonate In toluene at 110℃; for 24h;
96%
phenylborondichloride
873-51-8

phenylborondichloride

C25H30BFePSn

C25H30BFePSn

A

(methyl)(phenyl)chloroborane
13272-66-7

(methyl)(phenyl)chloroborane

C24H27BClFePSn

C24H27BClFePSn

Conditions
ConditionsYield
Stage #1: phenylborondichloride; C25H30BFePSn In benzene-d6 at 20℃; for 2h; Inert atmosphere; Schlenk technique; Glovebox;
Stage #2: In benzene-d6 at 50℃; Inert atmosphere; Schlenk technique; Glovebox;
A n/a
B 96%
phenylborondichloride
873-51-8

phenylborondichloride

N-methyl-N,N-di(3-thienyl)amine

N-methyl-N,N-di(3-thienyl)amine

4-methyl-8-phenyl-4,8-dithieno[3,2-b:2',3'-e][1,4]azaborine

4-methyl-8-phenyl-4,8-dithieno[3,2-b:2',3'-e][1,4]azaborine

Conditions
ConditionsYield
With triethylamine In chlorobenzene at 135℃; for 48h;96%
phenylborondichloride
873-51-8

phenylborondichloride

2,2’-(2,5-dimethoxy-1,4-phenylene)dithiophene

2,2’-(2,5-dimethoxy-1,4-phenylene)dithiophene

C26H16B2O2S2

C26H16B2O2S2

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; triethylamine In chlorobenzene at 135℃; for 24h;96%
phenylborondichloride
873-51-8

phenylborondichloride

2,2'-(4,6-dimethoxy-1,3-phenylene)dithiophene

2,2'-(4,6-dimethoxy-1,3-phenylene)dithiophene

C26H16B2O2S2

C26H16B2O2S2

Conditions
ConditionsYield
With tetra-(n-butyl)ammonium iodide; triethylamine In chlorobenzene at 135℃; for 24h;96%
phenylborondichloride
873-51-8

phenylborondichloride

dimethyl amine
124-40-3

dimethyl amine

({(CH3)2NH}2B(Cl)C6H5)(1+)*Cl(1-)=({(CH3)2NH}2B(Cl)C6H5)Cl
94947-35-0

({(CH3)2NH}2B(Cl)C6H5)(1+)*Cl(1-)=({(CH3)2NH}2B(Cl)C6H5)Cl

Conditions
ConditionsYield
In benzene95.5%
In benzene95.5%
6,16-dimesityl-11-phenyl-subpyriporphyrin

6,16-dimesityl-11-phenyl-subpyriporphyrin

phenylborondichloride
873-51-8

phenylborondichloride

[6,16-dimesityl-11-phenyl-subpyriporphyrin-phenylboron] tetrafluoroborate

[6,16-dimesityl-11-phenyl-subpyriporphyrin-phenylboron] tetrafluoroborate

Conditions
ConditionsYield
Stage #1: 6,16-dimesityl-11-phenyl-subpyriporphyrin; phenylborondichloride In toluene for 1.5h;
Stage #2: With silver tetrafluoroborate In toluene Further stages.;
95%
1,1-di-n-butyl-2,3,4,5-tetraphenylstannol
75632-74-5

1,1-di-n-butyl-2,3,4,5-tetraphenylstannol

phenylborondichloride
873-51-8

phenylborondichloride

A

dibutyltin chloride
683-18-1

dibutyltin chloride

B

1,2,3,4,5-pentaphenyl-1H-borole
20195-59-9

1,2,3,4,5-pentaphenyl-1H-borole

Conditions
ConditionsYield
In toluene To a cooled toluene soln. of stannol was added PhBCl2, stirred for 3 h at room temp. (inert atm.);; filtered, ppt. was washed with toluene, dried in high vac.; elem. anal.;;A n/a
B 95%

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