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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

Vinyl chloride

Cas:75-01-4

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Chloroethylene

Cas:75-01-4

Min.Order:1

Negotiable

Type:Other

inquiry

Baoji Guokang Healthchem co.,ltd

Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

VINYL CHLORIDE Hydrocarbons halides

Cas:75-01-4

Min.Order:1 Kilogram

FOB Price: $10.0 / 15.0

Type:Trading Company

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High Purity Chloroethylene; Vinyl chloride

Cas:75-01-4

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless gas Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:25kg/drum;200kg/drum as per your request Application:The important raw material for

Ethene, chloro-

Cas:75-01-4

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

vinyl chloride pressure tin with 250 ml ~225 G net

Cas:75-01-4

Min.Order:0

Negotiable

Type:Other

inquiry

Wuhan Fortuna Chemical Co.,Ltd

Best service,high quality and cheap price. Storage:Keep away from heat,sparks and flames. Package:25kg/50kg/200kg drum or Customer demand Application:Used as pharmaceutical intermediates Transportation:BY sea/air or by courier

Vinyl chloride pressure tin with 250 ml ~225 G net

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Henan Tianfu Chemical Co., Ltd.

1.Our services:A.Supply sampleB.The packing also can be according the customers` requirmentC.Any inquiries will be replied within 24 hoursD.we provide Commerical Invoice, Packing List, Bill of loading, COA , Health certificate and Origin certificate.

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory directly supply CAS 75-01-4 with competitive price

Cas:75-01-4

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

1.High purity, like 99%, 99.9%, 99.95%, 99.99%, 99.999%2.Quality control, test sample before shipping and keep sample for 3 years after shipping;3. Prompt shipment with professional documents;4. Packing as your request, with photo before shipment;5.

Vinyl chloride

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

Our Services 1.Certificate Of Analysis (COA) 2.Material Safety Data Sheet (MSDS) 3.Route of synthesis (ROS) 4.Method of Aanlysis (MOA) 5.Nuclear Magnetic Resonance (NMR) 6.Packing pictures and loading video before loading 7.Free Sampl

Better product Vinyl chloride CAS NO.75-01-4

Cas:75-01-4

Min.Order:1 Metric Ton

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Chloroethylene

Cas:75-01-4

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HuBei Ipure Biotech CO.,ltd

HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl

Vinyl chloride CAS NO.75-01-4

Cas:75-01-4

Min.Order:1 Kilogram

FOB Price: $1.0 / 2.0

Type:Trading Company

inquiry

ORCHID CHEMICAL SUPPLIES LTD

Vinyl chloride CAS#75-01-4 Storage:Keep container tightly closed in a dry, cool and well-ventilated place. Package:25Kg/drum, 150Kg/drum, 200kg/drum, According to request. Transportation:By sea, by air.

Vinyl chloride

Cas:75-01-4

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai AngewChem Co., Ltd.

Shanghai AngewChemCo., Ltd. is an innovative enterprise on fine chemicals and pharmaceuticals. Based on Shanghai R&D center and Hunan chemical manufacturing plant, we offer chemical research, process development, and large-scale production. Complete

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Nanjing Raymon Biotech Co., Ltd.

Vinyl chloride Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Vinyl chloride

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the Chloroethene, CAS:75-01-4 with the most competitive price and the best quality. We ca

Chloroethene

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuxi Morality Chemical Co., Ltd

Do best quality products, erect the morality model Application:Please email us, thanks

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Other

inquiry

Shanghai Yanchu chemicals Co., Ltd

low price and good quality Application:It is an important raw material and intermediate used in Organic Synthesis, Pharmaceuticals, Agrochemicals and D

Ethene, chloro-

Cas:75-01-4

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Ruishun Trade Co.,Ltd

Supply top quality products with a reasonable price Application:api

75-01-4

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Changzhou Foreign Trade Corp

CFTC?PharmaChem?is?a?service?based?company?in?China,?a?pharmachem?division?of?Changzhou?Foreign?Trade?Corp.,supplying?raw?materials,?intermediates,?APIs?and?fine?chemicals?for?the?pharmaceutical?and?specialty?chemical?industries?worldwide. Applicatio

chloroethylene

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

NovaChemistry

High purity Application:Pharmaceutical intermediates, Material synthesis and analyzing the expectant ingredients

Chloroethene

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Sigma-Aldrich Chemie GmbH

Package:500ml high pressure aluminum cylinder equipped with a stainless steel valve according to DIN 477-1.

Vinyl chloride

Cas:75-01-4

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

acetylene
74-86-2

acetylene

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With hydrogenchloride; oxygen at 199.84℃; under 750.075 Torr; for 12h; Reagent/catalyst; Flow reactor; Inert atmosphere;100%
With hydrogenchloride at 180℃; Reagent/catalyst;99.9%
With hydrogenchloride In water at 250℃; under 825.083 - 900.09 Torr; Temperature; Reagent/catalyst;68%
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

A

hydrogenchloride
7647-01-0

hydrogenchloride

B

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
at 450 - 550℃; under 10501.1 - 26252.6 Torr; for 0.00416667 - 0.00833333h;A n/a
B 99.52%
at 362 - 485℃; eine nahezu homogene Reaktion erster Ordnung, die wahrscheinlich von Chloratomen und 1.2-Dichlor-aethyl-Radikalen unterhalten wird.Thermolysis;
at 600℃; Conversion of starting material;
at 615℃; Rate constant;
at 650℃; Rate constant;
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With triethylbenzylammonium ethanolate at -20 - 20℃;99%
75%
With polyacrylonitrile-based active carbon fiber at 350℃; under 760 Torr; for 2h; other catalyst, var. reaction time;57%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

A

chloroethylene
75-01-4

chloroethylene

B

dichloro(butoxy)phenylsilane
17887-35-3

dichloro(butoxy)phenylsilane

Conditions
ConditionsYield
at 20℃; for 24h;A n/a
B 96%
methylchlorodiazirine
4222-21-3

methylchlorodiazirine

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
In n-heptane Quantum yield; Irradiation;90%
β-chlorovinyl(methyl)dichlorosilane
13852-29-4

β-chlorovinyl(methyl)dichlorosilane

A

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

B

1,1-dichloroethane
75-34-3

1,1-dichloroethane

C

chloroethylene
75-01-4

chloroethylene

D

dichloro-(2,2-dichloro-ethyl)-methyl-silane

dichloro-(2,2-dichloro-ethyl)-methyl-silane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 25 - 31℃; for 4h; Product distribution; Further Variations:; Temperatures; reaction time, reagent concentration; Addition; elimination;A n/a
B n/a
C n/a
D 89%
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

A

ethene
74-85-1

ethene

B

chloroethane
75-00-3

chloroethane

C

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With hydrogen; Ni on pumice at 350℃; Product distribution; other temperature;A 83.7%
B 0.6%
C 0.7%
Trichloroethylene
79-01-6

Trichloroethylene

A

cis-1,2-Dichloroethylene
156-59-2

cis-1,2-Dichloroethylene

B

chloroethylene
75-01-4

chloroethylene

C

acetylene
74-86-2

acetylene

Conditions
ConditionsYield
With iron sulfide In water for 2922h; pH=8.3; Kinetics; Product distribution; Dehydrochlorination;A 6%
B 1%
C 65%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

(chloromethyl)trichlorosilane
1558-25-4

(chloromethyl)trichlorosilane

A

chloroethylene
75-01-4

chloroethylene

B

dichloro(chloromethyl)butoxysilane

dichloro(chloromethyl)butoxysilane

Conditions
ConditionsYield
at 20℃; for 24h;A n/a
B 57%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

-butyl vinyl ether
111-34-2

-butyl vinyl ether

A

chloroethylene
75-01-4

chloroethylene

B

dichloro(butoxy)methylsilane
1825-78-1

dichloro(butoxy)methylsilane

Conditions
ConditionsYield
at 20℃; for 24h;A n/a
B 45%
(tris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)(CH3)H

(tris(3,5-dimethylpyrazolyl)borate)Rh(PMe3)(CH3)H

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

A

ethene
74-85-1

ethene

B

chloroethylene
75-01-4

chloroethylene

C

(η(3)-tris(3,5-dimethylpyrazolyl)borato)Rh(PMe3)(Cl)2

(η(3)-tris(3,5-dimethylpyrazolyl)borato)Rh(PMe3)(Cl)2

D

[(HB(N2C3H(CH3)2)3)RhH(P(CH3)3)Cl]

[(HB(N2C3H(CH3)2)3)RhH(P(CH3)3)Cl]

Tp’RhCl(PMe3)(η1-CH=CH2)

Tp’RhCl(PMe3)(η1-CH=CH2)

Conditions
ConditionsYield
at 22℃; for 72h; Sealed tube; Inert atmosphere;A Ca. 10 %Spectr.
B Ca. 15 %Spectr.
C 41%
D 44%
E 15%
methylene chloride
74-87-3

methylene chloride

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With oxygen at 600℃; Reagent/catalyst;42%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

A

chloroethylene
75-01-4

chloroethylene

B

n-butoxytrichlorosilane
1825-85-0

n-butoxytrichlorosilane

Conditions
ConditionsYield
With tetrachlorosilane at 20℃; for 24h;A n/a
B 37%
-butyl vinyl ether
111-34-2

-butyl vinyl ether

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

A

chloroethylene
75-01-4

chloroethylene

B

chloro(butoxy)(methyl)phenylsilane
18001-27-9

chloro(butoxy)(methyl)phenylsilane

Conditions
ConditionsYield
at 20℃; for 24h;A n/a
B 32%
dichloromethane
75-09-2

dichloromethane

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With hydrogen at 500℃; under 1520.1 Torr; Reagent/catalyst; Temperature; Pressure;23.2%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

ethene
74-85-1

ethene

A

chloroethane
75-00-3

chloroethane

B

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With calcium sulfate at 260℃; under 14710.2 Torr;
1,1-dichloroethane
75-34-3

1,1-dichloroethane

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With sodium ethanolate
With pumice stone
With Y-type zeolite In chloroform at 125℃; under 760.051 Torr; Temperature;
With aluminum oxide at 300℃;
cis-dichloro(2-chlorovinyl) arsine
34461-56-8

cis-dichloro(2-chlorovinyl) arsine

1-methyl-4-nitrosobenzene
623-11-0

1-methyl-4-nitrosobenzene

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
at 40℃;
ethane
74-84-0

ethane

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With aluminum oxide; chlorine at 400℃;
at 380℃; bei der thermischen Chlorieren;
bei der photochemischen Chlorierung;
With chlorine at 500℃;
With hydrogenchloride In neat (no solvent, gas phase) at 400℃; Kinetics; Catalytic behavior; Temperature; Reagent/catalyst;
ethene
74-85-1

ethene

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With chlorine at 400℃;
With chlorine anschl. HCl-Abspaltung ueber Aktivkohle bei 400grad-450grad;
With chlorine
1-chloro-1-fluoroethane
1615-75-4

1-chloro-1-fluoroethane

A

1-fluoroethylene
75-02-5

1-fluoroethylene

B

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
at 600℃;
1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With sodium amalgam; nickel(I)octaethylisobacteriochlorin In N,N-dimethyl-formamide at 23℃; Rate constant;
With water; iron at 100 - 120℃; unter Druck;
With water; zinc at 50 - 60℃;
2-chloro-1-acetoxyethane
542-58-5

2-chloro-1-acetoxyethane

A

chloroethylene
75-01-4

chloroethylene

B

acetic acid
64-19-7

acetic acid

Conditions
ConditionsYield
Erhitzen;
2-chloroethyl benzenesulfonate
16670-48-7

2-chloroethyl benzenesulfonate

A

chloroethylene
75-01-4

chloroethylene

B

acetaldehyde
75-07-0

acetaldehyde

C

benzenesulfonic acid
98-11-3

benzenesulfonic acid

Conditions
ConditionsYield
at 285 - 290℃;
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

acetylene
74-86-2

acetylene

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With mercury(I) chloride; potassium chloride at 375℃;
With mercury dichloride; barium(II) chloride at 350 - 450℃;
ethylene dibromide
106-93-4

ethylene dibromide

A

2-fluoroethyl bromide
762-49-2

2-fluoroethyl bromide

B

chloroethylene
75-01-4

chloroethylene

Conditions
ConditionsYield
With potassium fluoride; ethylene glycol at 150℃;
With potassium fluoride at 200℃;
3-oxa-1,5-dichloropentane
111-44-4

3-oxa-1,5-dichloropentane

A

chloroethylene
75-01-4

chloroethylene

B

2-chloroetyl vinyl ether
110-75-8

2-chloroetyl vinyl ether

Conditions
ConditionsYield
at 450℃;
chlorobenzene
108-90-7

chlorobenzene

chloroethylene
75-01-4

chloroethylene

chloroethylene
75-01-4

chloroethylene

bis-trifluoromethyl-aminooxyl
2154-71-4

bis-trifluoromethyl-aminooxyl

1,2-bischloroethane
67329-57-1

1,2-bischloroethane

Conditions
ConditionsYield
for 0.833333h; Ambient temperature;99%
chloroethylene
75-01-4

chloroethylene

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
6141-72-6

perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)

O-[2-(Bis-trifluoromethyl-amino)-1-chloro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

O-[2-(Bis-trifluoromethyl-amino)-1-chloro-ethyl]-N,N-bis-trifluoromethyl-hydroxylamine

Conditions
ConditionsYield
for 120h; Ambient temperature; in vacuo;98%
chloroethylene
75-01-4

chloroethylene

1-chloro-1,3-bis(2,4,6-trichlorophenyl)triazene
187464-05-7

1-chloro-1,3-bis(2,4,6-trichlorophenyl)triazene

1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

1,3-bis(2,4,6-trichlorophenyl)-1,2,3-triazolium hexachloroantimonate

Conditions
ConditionsYield
With antimonypentachloride In dichloromethane at -60 - 23℃; for 1.75h;98%
3-[2-(7-chloro-2-quinolinyl)ethenyl]benzaldehyde
115104-40-0

3-[2-(7-chloro-2-quinolinyl)ethenyl]benzaldehyde

chloroethylene
75-01-4

chloroethylene

1‐[3‐(2‐(7-chloro‐2‐quinolinyl)vinyl)phenyl]‐2-propen-1-ol

1‐[3‐(2‐(7-chloro‐2‐quinolinyl)vinyl)phenyl]‐2-propen-1-ol

Conditions
ConditionsYield
With ammonium acetate In toluene at -2 - 5℃; Reagent/catalyst; Inert atmosphere;97.2%
methanol
67-56-1

methanol

chloroethylene
75-01-4

chloroethylene

chloroacetaldehyde dimethyl acetal
97-97-2

chloroacetaldehyde dimethyl acetal

Conditions
ConditionsYield
With sodium methylate; chlorine at 25 - 27℃; for 5.5h; pH=3 - 7; Temperature; Large scale;97.2%
chloroethylene
75-01-4

chloroethylene

1,2-dibromo-1-chloroethane
598-20-9

1,2-dibromo-1-chloroethane

Conditions
ConditionsYield
With bromine at 20℃; for 17h; Cooling;97%
With bromine
With bromine In tetrachloromethane
With bromine; dinitrogen tetraoxide In chloroform
With bromine; Nitrogen dioxide at 325℃;
tetrachloromethane
56-23-5

tetrachloromethane

chloroethylene
75-01-4

chloroethylene

1,1,1,3,3-pentachloropropane
23153-23-3

1,1,1,3,3-pentachloropropane

Conditions
ConditionsYield
With iron; orthoformic acid triethyl ester at 130℃; under 2250.23 Torr; for 0.5h; Temperature; Pressure; Reagent/catalyst;96.6%
With iron(III) chloride; phosphoric acid tributyl ester under 1125.11 Torr; for 100h; Flow reactor; Large scale;95.6%
Stage #1: tetrachloromethane With N,N,N,N,N,N-hexamethylphosphoric triamide; chloroform; iron at 140℃; for 0.5h; Autoclave; Inert atmosphere;
Stage #2: chloroethylene at 140℃; for 3h; Reagent/catalyst; Autoclave; Inert atmosphere;
93.1%
benzophenone
119-61-9

benzophenone

chloroethylene
75-01-4

chloroethylene

1,1-diphenylprop-2-en-1-ol
3923-51-1

1,1-diphenylprop-2-en-1-ol

Conditions
ConditionsYield
Stage #1: chloroethylene; zinc(II) chloride In tetrahydrofuran at 20℃; for 1h;
Stage #2: benzophenone In tetrahydrofuran at 0℃; for 2h;
96%
chloroethylene
75-01-4

chloroethylene

[Li(Et2O)2.8][B(C6F5)4]

[Li(Et2O)2.8][B(C6F5)4]

chloro(4,4'-di-tert-butyl-2,2'-bipyridine)methylpalladium(II)
524936-75-2

chloro(4,4'-di-tert-butyl-2,2'-bipyridine)methylpalladium(II)

carbon monoxide
201230-82-2

carbon monoxide

[(4,4'-di-tert-butyl-2,2'-bipyridine)Pd(CHClCH2COMe)][B(C6F5)4]
524936-99-0

[(4,4'-di-tert-butyl-2,2'-bipyridine)Pd(CHClCH2COMe)][B(C6F5)4]

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: LiCl, Et2O; stirring of ((t-Bu)2bipy)PdMeCl, (Li(Et2O)2.8)B(C6F5)4 (1 eqiuv.) and CH2Cl2 in Schlenk flask at -78°C for 10 min, exposure to CO (1 atm)at -78°C for 30 min, freezing to -196°C, evacuating, addn . of CH2CHCl, stirring at 23°C; filtration, drying of filtrate under vac., elem. anal.;96%
chloroethylene
75-01-4

chloroethylene

1,8-diazabicyclo[5.4.0]undec-7-ene
6674-22-2

1,8-diazabicyclo[5.4.0]undec-7-ene

6-vinyl DBU
1268387-98-9

6-vinyl DBU

Conditions
ConditionsYield
Stage #1: 1,8-diazabicyclo[5.4.0]undec-7-ene With n-butyllithium In tetrahydrofuran; hexane at -78℃; for 1h;
Stage #2: chloroethylene In tetrahydrofuran; hexane at -78 - 20℃;
96%
chloroethylene
75-01-4

chloroethylene

4-(Methylthio)benzaldehyde
3446-89-7

4-(Methylthio)benzaldehyde

1-[4-(methylsulfanyl)phenyl]-2-propen-1-ol
701935-64-0

1-[4-(methylsulfanyl)phenyl]-2-propen-1-ol

Conditions
ConditionsYield
Stage #1: chloroethylene With magnesium In tetrahydrofuran at 0 - 20℃; for 0.5h; Inert atmosphere;
Stage #2: 4-(Methylthio)benzaldehyde In tetrahydrofuran at 0 - 20℃; Grignard reaction;
Stage #3: With water; ammonium chloride In tetrahydrofuran Grignard reaction;
96%
chloroethylene
75-01-4

chloroethylene

9H-carbazole
86-74-8

9H-carbazole

9-vinyl-9H-carbazole
1484-13-5

9-vinyl-9H-carbazole

Conditions
ConditionsYield
With bis(η3-allyl-μ-chloropalladium(II)); sodium hydroxide; tri tert-butylphosphoniumtetrafluoroborate In toluene at 100℃; for 10h; Reagent/catalyst; Inert atmosphere;96%
tertiary butyl chloride
507-20-0

tertiary butyl chloride

chloroethylene
75-01-4

chloroethylene

1,1-dichloro-3,3-dimethylbutane
6130-96-7

1,1-dichloro-3,3-dimethylbutane

Conditions
ConditionsYield
With aluminium trichloride In dichloromethane at -40 - -10℃; for 0.5h;95%
With iron(III) chloride unter Stickstoffdruck;
With aluminium trichloride at -25℃;
With iron(III) chloride
With aluminium trichloride
chloroethylene
75-01-4

chloroethylene

rac-(EBI)Zr(Me)(μ-Me)B(C6F5)3

rac-(EBI)Zr(Me)(μ-Me)B(C6F5)3

oligopropylene, atactic, Mn = 500

oligopropylene, atactic, Mn = 500

Conditions
ConditionsYield
In dichloromethane-d2 at 25℃; for 24h; Polymerization; dechlorination; methylation;95%
chloroethylene
75-01-4

chloroethylene

carbon monoxide
201230-82-2

carbon monoxide

dimethyl amine
124-40-3

dimethyl amine

3-(dimthylamino)-N,Ndimethylpropanamide hydrochloride
110570-37-1

3-(dimthylamino)-N,Ndimethylpropanamide hydrochloride

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) at 100℃; Product distribution; Mechanism; other substituted vinyl chlorides, other amines and NH3, var. temp.;94%
chloroethylene
75-01-4

chloroethylene

bis-(3,5-dimethylphenyl)chlorophosphine
74289-57-9

bis-(3,5-dimethylphenyl)chlorophosphine

vinyl bis(3,5-dimethylphenyl)phosphine

vinyl bis(3,5-dimethylphenyl)phosphine

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 10h; Inert atmosphere;94%
chloroethylene
75-01-4

chloroethylene

N-phenylbenzohydrazonoyl chloride
15424-14-3

N-phenylbenzohydrazonoyl chloride

1,3-diphenyl-1H-pyrazole
4492-01-7

1,3-diphenyl-1H-pyrazole

Conditions
ConditionsYield
With triethylamine; hydroquinone In benzene for 48h; Ambient temperature;93%
chloroethylene
75-01-4

chloroethylene

1,1,2,2,3,3-Hexafluoro-cyclopropane
931-91-9

1,1,2,2,3,3-Hexafluoro-cyclopropane

A

polytetrafluoroethylene
116-14-3

polytetrafluoroethylene

B

Octafluorocyclobutane
115-25-3

Octafluorocyclobutane

C

1,1-difluoro-2-chlorocyclopropane
54944-21-7

1,1-difluoro-2-chlorocyclopropane

Conditions
ConditionsYield
at 294℃; for 1h; sealed tube in vacuo;A 91%
B 19%
C 55%
chloroethylene
75-01-4

chloroethylene

[Li(Et2O)2.8][B(C6F5)4]

[Li(Et2O)2.8][B(C6F5)4]

[(4,4'-dimethyl-2,2'-bipyridine)Pd(Me)Cl]
524936-74-1

[(4,4'-dimethyl-2,2'-bipyridine)Pd(Me)Cl]

carbon monoxide
201230-82-2

carbon monoxide

[(4,4'-dimethyl-2,2'-bipyridine)Pd(CHClCH2COMe)][B(C6F5)4]
524936-97-8

[(4,4'-dimethyl-2,2'-bipyridine)Pd(CHClCH2COMe)][B(C6F5)4]

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: LiCl, Et2O; stirring of (Me2bipy)PdMeCl, (Li(Et2O)2.8)(B(C6F5)4) (1 equiv.) and CH2Cl2 in Schlenk flask at -78°C for 10 min, exposure to CO (1 atm) at -78°C for 30 min, freezing to -196°C, evacuating, addn. of CH2CHCl, stirring at 23°C; filtration, drying of filtrate under vac., elem. anal.;91%
chloroethylene
75-01-4

chloroethylene

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane
16801-24-4

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane - vinyl chloride copolymer, vinyl chloride 74.24 mol percent; monomer(s): 1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane; vinyl chloride

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane - vinyl chloride copolymer, vinyl chloride 74.24 mol percent; monomer(s): 1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane; vinyl chloride

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In dimethyl sulfoxide at 70℃;88.9%
chloroethylene
75-01-4

chloroethylene

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane
16801-24-4

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane - vinyl chloride copolymer, vinyl chloride 77.78 mol percent; monomer(s): 1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane; vinyl chloride

1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane - vinyl chloride copolymer, vinyl chloride 77.78 mol percent; monomer(s): 1-{2-[2-(2-vinyloxyethoxy)ethoxy]ethoxy}-2,3-epoxypropane; vinyl chloride

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile) In acetone at 70℃;88.6%
[PdCl(CH3)(bis(diphenylphosphino)propane)]
139168-06-2

[PdCl(CH3)(bis(diphenylphosphino)propane)]

chloroethylene
75-01-4

chloroethylene

[Li(Et2O)2.8][B(C6F5)4]

[Li(Et2O)2.8][B(C6F5)4]

carbon monoxide
201230-82-2

carbon monoxide

[(1,3-bis(diphenylphosphino)propane)Pd(CHClCH2COMe)][B(C6F5)4]
524937-01-7

[(1,3-bis(diphenylphosphino)propane)Pd(CHClCH2COMe)][B(C6F5)4]

Conditions
ConditionsYield
In dichloromethane-d2 byproducts: LiCl, Et2O; stirring of (dppp)PdMeCl, (Li(Et2O)2.8)B(C6F5)4 (1 eqiuv.) and CH2Cl2 inSchlenk flask at -78°C for 10 min, exposure to CO (1 atm) at -78 °C for 30 min, freezing to -196°C, evacuating, addn. of CH2CHCl, stirring at 23°C; filtration, drying of filtrate under vac., elem. anal.;88%
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