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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem's R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantities

Ethane, 1,1-dichloro- Manufacturer/High quality/Best price/In stock

Cas:75-34-3

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,1-Dichloroethane

Cas:75-34-3

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

75-34-3 1,1-DICHLOROETHANE

Cas:75-34-3

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

Hangzhou Huarong Pharm Co., Ltd.

Hangzhou Huarong Pharm Co., Ltd.established since 2006 , has been actively developing specialty products for Finished Dosages, APIs, Intermediates, and Fine chemicals markets in North America, Europe, Korea, Japan, Mid-East and all over the World. Hu

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

1,1-dichloroethane

Cas:75-34-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

1,1-Dichloroethane (stabilized with NitroMethane)

Cas:75-34-3

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 75-34-3 with competitive price

Cas:75-34-3

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

1,1-Dichloroethane 75-34-3

Cas:75-34-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Amadis Chemical offer CAS#75-34-3;CAT#A838387

Cas:75-34-3

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

1,1-Dichloroethane

Cas:75-34-3

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai united Scientific Co.,Ltd.

United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Chungking Joyinchem Co., Ltd.

Joyinchem have been committed to chemical supply for several years and have built good cooperation records with multinational chemical corporations and importers from all over the world. Our services include:-Spot goods-Contract manufacturing-Custom

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Pure Chemistry Scientific Inc.

1,1-Dichloroethane Application:2024907

1,1-Dichloroethane

Cas:75-34-3

Min.Order:1 Gram

FOB Price: $500.0

Type:Trading Company

inquiry

Nanjing Raymon Biotech Co., Ltd.

Ethane, 1,1-dichloro- Storage:keep in dry and cool condition Package:25kg or according to cutomer's demand Application:Chemical research/pharma intermediate Transportation:By Sea,by Air,By courier like DHL or Fedx. Port:Shanghai/Shenzhen

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

Price, Purity Application:reagent

CSR081605-61150

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Sparrow Chemical Co.,Ltd

Our company provides the best service for our customers. Under the premise of ensuring quality and delivery date, give customers the best price. The company is more willing to meet our customers. If you want to visit our factories and warehouses, we

ethyldichloridE.D.C

Cas:75-34-3

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Wuhan Chemwish Technology Co., Ltd

High quality Products with prompt delivery Package:based on customer requirement Application:organic intermediates Transportation:By are or by sea Port:any port of China

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Trans Intl Chem Shop

99

1,1-Dichloroethane

Cas:75-34-3

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Ansell

Ethane, 1,1-dichloro-

Cas:75-34-3

Min.Order:0

Negotiable

Type:

inquiry

Synthetic route

β-chlorovinyl(methyl)dichlorosilane
13852-29-4

β-chlorovinyl(methyl)dichlorosilane

A

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

B

1,1-dichloroethane
75-34-3

1,1-dichloroethane

C

chloroethylene
75-01-4

chloroethylene

D

dichloro-(2,2-dichloro-ethyl)-methyl-silane

dichloro-(2,2-dichloro-ethyl)-methyl-silane

Conditions
ConditionsYield
With hydrogenchloride; iron(III) chloride at 25 - 31℃; for 4h; Product distribution; Further Variations:; Temperatures; reaction time, reagent concentration; Addition; elimination;A n/a
B n/a
C n/a
D 89%
chloroethylene
75-01-4

chloroethylene

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

Conditions
ConditionsYield
With chlorotrifluoromethane; hydrogen iodide Product distribution; Mechanism; Irradiation; var. pressure; labeling (38)Cl;A 0.76%
B 78%
1,1,1-trichloroethane
71-55-6

1,1,1-trichloroethane

A

(Z)-2-Butene
590-18-1

(Z)-2-Butene

B

1,1-dichloroethane
75-34-3

1,1-dichloroethane

C

ethane
74-84-0

ethane

D

ethene
74-85-1

ethene

Conditions
ConditionsYield
With Tris buffer; iron; sodium chloride pH=7.5; Kinetics; Product distribution; Further Variations:; Reagents; Dehalogenation; dimerization;A n/a
B 67%
C n/a
D n/a
1,1,1-trichloroethane
71-55-6

1,1,1-trichloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

ethane
74-84-0

ethane

Conditions
ConditionsYield
With Tris buffer; sodium chloride; zinc pH=7.5; Kinetics; Dehalogenation;A 25.8%
B n/a
ethylenebis(chloroformate)
124-05-0

ethylenebis(chloroformate)

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

Vinyl chloroformate
5130-24-5

Vinyl chloroformate

C

carbonochloridic acid 1-chloro-ethyl ester
50893-53-3

carbonochloridic acid 1-chloro-ethyl ester

D

2-Chloroethyl chloroformate
627-11-2

2-Chloroethyl chloroformate

Conditions
ConditionsYield
at 460℃; Produkt 5: 1.2-Dichlor-aethan.Pyrolysis;
ethane
74-84-0

ethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
bei der thermischen und photochemischen Chlorierung;
With chlorine at 400℃;
ethane
74-84-0

ethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

chloroethane
75-00-3

chloroethane

Conditions
ConditionsYield
With chlorine; pyrographite at 100 - 300℃;
With chlorine; pyrographite at 100 - 300℃;
With chlorine; pyrographite at 100 - 300℃;
chloroethane
75-00-3

chloroethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With chlorine
Chlorierung im Lichte;
With chlorine; pyrographite at 250 - 400℃;
With chlorine
With water Chlorierung;
chloroethane
75-00-3

chloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

2-Chloroethanesulfonyl chloride
1622-32-8

2-Chloroethanesulfonyl chloride

Conditions
ConditionsYield
With sulfur dioxide; chlorine unter Belichtung; Nebenprod.2:1,2-Dichlor-aethan;
chloroethane
75-00-3

chloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

Conditions
ConditionsYield
at 0℃; Einfluss des Loesungsmittels auf die Photochlorierung;
With chlorine In chlorobenzene Mechanism; Kinetics; other solvent; object of study: solvents effects vs. the reaction selectivity;
With chlorine In gas at 8 - 94℃; Kinetics; Thermodynamic data; Mechanism; ΔE(excit);
chloroethylene
75-01-4

chloroethylene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With hydrogenchloride; aluminium trichloride at 125℃;
With hydrogenchloride; aluminium trichloride; 1,2-dichloro-ethane
With hydrogenchloride; aluminium trichloride at 10 - 50℃; unter Druck;
carbonochloridic acid 1-chloro-ethyl ester
50893-53-3

carbonochloridic acid 1-chloro-ethyl ester

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With aluminium trichloride
phosgene
75-44-5

phosgene

acetaldehyde
75-07-0

acetaldehyde

1,1-dichloroethane
75-34-3

1,1-dichloroethane

acetaldehyde
75-07-0

acetaldehyde

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With phosphorus pentachloride
With tungsten(VI) chloride In dichloromethane at 20℃; for 168h; Sealed tube;
1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With aluminium trichloride at 350 - 500℃; im Eisenrohr; und Leiten des entstandenen Gemisches von Vinylchlorid und HCl ueber AlCl3 bei ca. 125grad;
With aluminium trichloride at 375℃; und Leiten des entstandenen Gemisches von Vinylchllorid und HCl ueber AlCl3 bei ca. 125grad;
phosgene
75-44-5

phosgene

paracetaldehyde
123-63-7

paracetaldehyde

1,1-dichloroethane
75-34-3

1,1-dichloroethane

acetylene
74-86-2

acetylene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With hydrogenchloride; silica gel; mercury dichloride at 75 - 175℃;
With hydrogenchloride; silica gel; zinc(II) chloride at 75 - 175℃;
1-Heptene
592-76-7

1-Heptene

1,1,1-trichloroethane
71-55-6

1,1,1-trichloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

2,2-dichlorononane
66250-04-2

2,2-dichlorononane

C

2,2,4-trichlorononane

2,2,4-trichlorononane

Conditions
ConditionsYield
With triethylsilane; bithionol at 130 - 140℃; for 5h;A 12.4 % Chromat.
B 32.2 % Chromat.
C 8.7 % Chromat.
With triethylsilane; bithionol at 130 - 140℃;A 12.4 % Chromat.
B 32.2 % Chromat.
C 8.7 % Chromat.
ethene
74-85-1

ethene

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

chloroethylene
75-01-4

chloroethylene

C

1,2-dichloro-ethane
107-06-2

1,2-dichloro-ethane

D

benzene
71-43-2

benzene

Conditions
ConditionsYield
aluminum oxide; hydrogen tetrachloropalladate; copper dichloride at 24.9 - 499.9℃; under 757.6 Torr; for 0.5h; Product distribution; other salts and supports as catalysts;
chloroethane
75-00-3

chloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

s-butyl chloride
78-86-4, 53178-20-4

s-butyl chloride

Conditions
ConditionsYield
With chlorine Mechanism; Irradiation; var. temperature, concns. of Cl2, O2, laser fluence;
1-bromo-1-chloroethane
593-96-4

1-bromo-1-chloroethane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

1,1-Dibromoethane
557-91-5

1,1-Dibromoethane

Conditions
ConditionsYield
copper and nickel chlorides at 170℃; Equilibrium constant; Thermodynamic data; 200 - 250 deg C, ΔH(excit.), ΔS(excit).;
(1,1-dichloroethyl)trimethylsilane
15990-16-6

(1,1-dichloroethyl)trimethylsilane

A

1,1-dichloroethane
75-34-3

1,1-dichloroethane

B

1,1-dichloro-1-deuterio-ethane
65284-20-0

1,1-dichloro-1-deuterio-ethane

Conditions
ConditionsYield
With methanol; deuteromethanol; sodium methylate at 21℃; Product distribution; value of product isotope effect;
α-chloroethyl radical
16520-13-1

α-chloroethyl radical

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With chlorine at 24.9℃; under 700 Torr; Rate constant; Irradiation; var. bath gas (He) density;
α,α-dichloroethyl radical
19468-97-4

α,α-dichloroethyl radical

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With hydrogen bromide at 183.9℃; Kinetics; Rate constant; ΔH-, ΔS-changes;
1,1,1-trichloroethane
71-55-6

1,1,1-trichloroethane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Conditions
ConditionsYield
With iron sulfide In water at 25℃; pH=8.3; Kinetics; Dehalogenation;
metaldehyde
108-62-3

metaldehyde

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

1,1-dichloroethane
75-34-3

1,1-dichloroethane

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

paracetaldehyde
123-63-7

paracetaldehyde

1,1-dichloroethane
75-34-3

1,1-dichloroethane

oxirane
75-21-8

oxirane

disulfur dichloride

disulfur dichloride

1,1-dichloroethane
75-34-3

1,1-dichloroethane

phosphorus pentachloride
10026-13-8, 874483-75-7

phosphorus pentachloride

acetaldehyde
75-07-0

acetaldehyde

1,1-dichloroethane
75-34-3

1,1-dichloroethane

4-Ethyl-5,8-dimethylthiochroman-6-carboxylic acid-1,1,dioxide
182426-32-0

4-Ethyl-5,8-dimethylthiochroman-6-carboxylic acid-1,1,dioxide

1,1-dichloroethane
75-34-3

1,1-dichloroethane

4-penten-3-one
1629-58-9

4-penten-3-one

2,5-dimethylthiophenol
4001-61-0

2,5-dimethylthiophenol

(2,5-dimethylphenyl)-3-oxopentylsulfide
182426-11-5

(2,5-dimethylphenyl)-3-oxopentylsulfide

Conditions
ConditionsYield
With triethylamine100%
1-methyl-pyrrolidin-2-one
872-50-4

1-methyl-pyrrolidin-2-one

2-chloro-6-nitrobenzonitrile
6575-07-1

2-chloro-6-nitrobenzonitrile

1,1-dichloroethane
75-34-3

1,1-dichloroethane

2,6-dichloro-benzonitrile
1194-65-6

2,6-dichloro-benzonitrile

Conditions
ConditionsYield
With lithium carbonate; aluminium trichloride98%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

1-Methylene-2-<(tetrahydropyran-2-yloxy)methyl>dispiro<2.0.2.1>heptane
137943-57-8

1-Methylene-2-<(tetrahydropyran-2-yloxy)methyl>dispiro<2.0.2.1>heptane

1-Chloro-1-methyl-9-<(tetrahydropyran-2-yloxy)methyl>trispiro<2.0.0.2.1.1>nonane
137943-46-5

1-Chloro-1-methyl-9-<(tetrahydropyran-2-yloxy)methyl>trispiro<2.0.0.2.1.1>nonane

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane at -40 - -35℃;97%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

1,1-difluoroethane
75-37-6

1,1-difluoroethane

Conditions
ConditionsYield
With hydrogen fluoride; chromium(III) oxide at 200℃; under 1500.15 Torr; for 10 - 200h; Product distribution / selectivity; Molecular sieve MS-13X;96.2%
With hydrogen fluoride; chromium(III) oxide at 200℃; under 1500.15 Torr; for 3 - 100h; Product distribution / selectivity;62%
With hydrogen fluoride; antimonypentachloride at 50℃; im Autoklaven;
methyl 4-amino-5-bromo-2-methoxybenzenecarboxylate

methyl 4-amino-5-bromo-2-methoxybenzenecarboxylate

thiophosgene
463-71-8

thiophosgene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

methyl 2-methoxy 4-isothiocyanato 5-bromo benzoate
111049-67-3

methyl 2-methoxy 4-isothiocyanato 5-bromo benzoate

Conditions
ConditionsYield
With calcium carbonate In water; Petroleum ether96%
thiophosgene
463-71-8

thiophosgene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

methyl 4-amino-5-chloro-2-methoxybenzoate
20896-27-9

methyl 4-amino-5-chloro-2-methoxybenzoate

methyl 2-methoxy 4-isothiocyanato 5-chloro benzoate
111049-64-0

methyl 2-methoxy 4-isothiocyanato 5-chloro benzoate

Conditions
ConditionsYield
With calcium carbonate In water; Petroleum ether95.8%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

<2-(Methoxymethyl)ethylidene>spiropentane
137943-52-3, 138008-29-4

<2-(Methoxymethyl)ethylidene>spiropentane

1-Chloro-1-methyl-2-(methoxymethyl)dispiro<2.0.2.1>heptane
137943-43-2, 138051-19-1, 138051-20-4, 138051-21-5

1-Chloro-1-methyl-2-(methoxymethyl)dispiro<2.0.2.1>heptane

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane at -40 - -35℃;95.5%
3-carboxy-1,1-dimethylindane
129948-78-3

3-carboxy-1,1-dimethylindane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1,1-dimethyl-3-hydroxymethylindane

1,1-dimethyl-3-hydroxymethylindane

Conditions
ConditionsYield
sulfuric acid In methanol95%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

4-chloro-3-ethylphenol
14143-32-9

4-chloro-3-ethylphenol

2,4-dichloro-3-ethyl-6-nitrophenol
99817-36-4

2,4-dichloro-3-ethyl-6-nitrophenol

Conditions
ConditionsYield
With hydrogenchloride; chlorosulfonic acid; aqueous nitric acid; dihydrogen peroxide95%
With hydrogenchloride; chlorosulfonic acid; aqueous nitric acid; dihydrogen peroxide94%
With hydrogenchloride; chlorosulfonic acid; dihydrogen peroxide In aqueous nitric acid92%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

2-(phenoxymethyl)benzoic acid
724-98-1

2-(phenoxymethyl)benzoic acid

O-ethylhydroxylamine hydrochloride
3332-29-4

O-ethylhydroxylamine hydrochloride

α-ethoxyimino-2-phenoxymethylbenzyl chloride

α-ethoxyimino-2-phenoxymethylbenzyl chloride

Conditions
ConditionsYield
With pyridine; thionyl chloride; triphenylphosphine In tetrachloromethane; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile93.2%
2-(3-butenyloxy)tetrahydropyran
59574-65-1

2-(3-butenyloxy)tetrahydropyran

1,1-dichloroethane
75-34-3

1,1-dichloroethane

2-[2-(1-chloro-1-methylcycloprop-2-yl)ethoxy]tetrahydro-2H-pyran
107616-97-7

2-[2-(1-chloro-1-methylcycloprop-2-yl)ethoxy]tetrahydro-2H-pyran

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; hexane at 25℃; for 12h;93%
With n-butyllithium In diethyl ether at -35℃;76%
With n-butyllithium In diethyl ether; hexane at 20℃; for 12h;61%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

A

1,1,1-trichloroethane
71-55-6

1,1,1-trichloroethane

B

1,1,2-trichloroethane
79-00-5

1,1,2-trichloroethane

Conditions
ConditionsYield
With chlorine at 25℃; for 0.05h; Irradiation;A 92.6%
B 4.8%
Chlorierung im Licht;
With chlorine In chlorobenzene at 20℃; Product distribution; Irradiation; var. conc., presence of chloroethane;
methyl 2-(t-butyldiphenylsiloxy)propanoate

methyl 2-(t-butyldiphenylsiloxy)propanoate

1,1-dichloroethane
75-34-3

1,1-dichloroethane

4-(tert-butyl-diphenyl-silanyloxy)-2,2-dichloro-pentan-3-one

4-(tert-butyl-diphenyl-silanyloxy)-2,2-dichloro-pentan-3-one

Conditions
ConditionsYield
Stage #1: 1,1-dichloroethane With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -100℃; for 0.5h; Metallation;
Stage #2: methyl 2-(t-butyldiphenylsiloxy)propanoate In diethyl ether at -78℃; for 0.75h; Alkylation;
92%
1-(2,2-dimethoxyethoxy)-2,3-dimethylbenzene

1-(2,2-dimethoxyethoxy)-2,3-dimethylbenzene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1-bromo-4-(2,2-dimethoxyethoxy)-2,3-dimethylbenzene

1-bromo-4-(2,2-dimethoxyethoxy)-2,3-dimethylbenzene

Conditions
ConditionsYield
With sodium hydroxide; bromine In methanol; water92%
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Diethyl tartrate
408332-88-7

Diethyl tartrate

phytol
150-86-7

phytol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium hydroxide In CHCl3 -benzene; diethyl ether; dichloromethane91.3%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

Methyl (2R,3R,5R,6S)-2,6-dibenzyloxy-3,7-bis(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4-dimethylheptanoate
163275-36-3

Methyl (2R,3R,5R,6S)-2,6-dibenzyloxy-3,7-bis(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4-dimethylheptanoate

(4R,5R,7R,8S)-4,8-bis(benzyloxy)-5,9-bis(t-butyldimethylsiloxy)-2-chloro-7-(4-methoxybenzyloxy)-6,6-dimethylnonan-3-one
253662-98-5

(4R,5R,7R,8S)-4,8-bis(benzyloxy)-5,9-bis(t-butyldimethylsiloxy)-2-chloro-7-(4-methoxybenzyloxy)-6,6-dimethylnonan-3-one

Conditions
ConditionsYield
With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -100 - -78℃; for 1h;91%
Stage #1: 1,1-dichloroethane With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -100℃; for 0.5h; Metallation;
Stage #2: Methyl (2R,3R,5R,6S)-2,6-dibenzyloxy-3,7-bis(tert-butyldimethylsiloxy)-5-(p-methoxybenzyloxy)-4,4-dimethylheptanoate In diethyl ether at -78℃; for 0.75h; Alkylation;
91%
benzoic acid methyl ester
93-58-3

benzoic acid methyl ester

1,1-dichloroethane
75-34-3

1,1-dichloroethane

2,2-dichloro-1-phenylpropan-1-one
57169-51-4

2,2-dichloro-1-phenylpropan-1-one

Conditions
ConditionsYield
Stage #1: 1,1-dichloroethane With N,N,N,N,N,N-hexamethylphosphoric triamide; n-butyllithium In tetrahydrofuran; diethyl ether; hexane at -100℃; for 0.5h; Metallation;
Stage #2: benzoic acid methyl ester In diethyl ether at -78℃; for 0.75h; Alkylation;
91%
1-methyl-piperazine
109-01-3

1-methyl-piperazine

9,10-dihydrodibenzazepine
494-19-9

9,10-dihydrodibenzazepine

1,1-dichloroethane
75-34-3

1,1-dichloroethane

N-methylpiperazinomethyl-2 dihydro-10,11 5H dibenzoazepine
64097-57-0

N-methylpiperazinomethyl-2 dihydro-10,11 5H dibenzoazepine

Conditions
ConditionsYield
With sodium chloride; acetic acid; paraformaldehyde91%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

1-methoxy-2,3-dihydro-1H-inden-2-ol
71720-52-0

1-methoxy-2,3-dihydro-1H-inden-2-ol

methanesulfonyl chloride
124-63-0

methanesulfonyl chloride

trans-2-methane sulfonyloxy-1-methoxy indane

trans-2-methane sulfonyloxy-1-methoxy indane

Conditions
ConditionsYield
With sodium carbonate; triethylamine In chloroform; water90.5%
2-(prop-2-en-1-yloxy)oxane
69161-61-1, 4203-49-0

2-(prop-2-en-1-yloxy)oxane

1,1-dichloroethane
75-34-3

1,1-dichloroethane

1-Chloro-1-methyl-2-(tetrahydropyranyloxymethyl)cyclopropane
136908-89-9

1-Chloro-1-methyl-2-(tetrahydropyranyloxymethyl)cyclopropane

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane -35 - -40 deg C -> rt;90%
1,4-dioxaspiro[4.4]non-6-ene
695-56-7

1,4-dioxaspiro[4.4]non-6-ene

1,1-dichloroethane
75-34-3

1,1-dichloroethane

6-methyl-6-chlorobicyclo<3.1.0>hex-2-one ethylene ketal
71946-87-7, 82536-58-1, 82536-61-6

6-methyl-6-chlorobicyclo<3.1.0>hex-2-one ethylene ketal

Conditions
ConditionsYield
With n-butyllithium In hexane; pentane at -40 - -30℃; for 0.666667h;90%
With n-butyllithium In hexane; pentane at -40 - -30℃;45%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

7-<2-(Tetrahydropyran-2-yloxy)ethylidene>dispiro<2.0.2.1>heptane
137943-59-0

7-<2-(Tetrahydropyran-2-yloxy)ethylidene>dispiro<2.0.2.1>heptane

1-Chloro-1-methyl-2-<(tetrahydropyran-2-yloxy)methyl>trispiro<2.0.2.0.2.0>nonane
137943-50-1

1-Chloro-1-methyl-2-<(tetrahydropyran-2-yloxy)methyl>trispiro<2.0.2.0.2.0>nonane

Conditions
ConditionsYield
With n-butyllithium In diethyl ether; pentane at -40 - -35℃;90%
With n-butyllithium
2,4-dimethyl-1H-pyrrole
625-82-1

2,4-dimethyl-1H-pyrrole

1,1-dichloroethane
75-34-3

1,1-dichloroethane

3,5-dimethylpyrrole-2-carbaldehyde
2199-58-8

3,5-dimethylpyrrole-2-carbaldehyde

Conditions
ConditionsYield
In N-methyl-acetamide; water90%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

tetrabutylammomium bromide
1643-19-2

tetrabutylammomium bromide

propargyl bromide
106-96-7

propargyl bromide

N,N,N'-tris-propargyl-p,p'-diamino diphenyl methane

N,N,N'-tris-propargyl-p,p'-diamino diphenyl methane

Conditions
ConditionsYield
With sodium hydroxide In water89%
nitrogen dioxide NO2

nitrogen dioxide NO2

1,1-dichloroethane
75-34-3

1,1-dichloroethane

adamantane
281-23-2

adamantane

nitrogen(II) oxide
10102-43-9

nitrogen(II) oxide

1-nitroadamantane
7575-82-8

1-nitroadamantane

Conditions
ConditionsYield
In acetonitrile88%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

ammonium chloride

ammonium chloride

p-aminoiodobenzene
540-37-4

p-aminoiodobenzene

N-(4'-iodophenyl)-2-amino octane

N-(4'-iodophenyl)-2-amino octane

Conditions
ConditionsYield
With sodium tris(acetoxy)borohydride; acetic acid88%
With acetic acid88%
hexadecylamine
143-27-1

hexadecylamine

1,1-dichloroethane
75-34-3

1,1-dichloroethane

N-hexadecyl-4-chloro-3-nitrobenzenesulfonamide
118938-20-8

N-hexadecyl-4-chloro-3-nitrobenzenesulfonamide

Conditions
ConditionsYield
With triethylamine In methanol88%
1,1-dichloroethane
75-34-3

1,1-dichloroethane

O,S-diethyl-dithiophosphoric acid
60899-79-8

O,S-diethyl-dithiophosphoric acid

8-Cyano-4-methyl-5,6,7,8-tetrahydroquinoline
83246-80-4

8-Cyano-4-methyl-5,6,7,8-tetrahydroquinoline

4-Methyl-5,6,7,8-tetrahydroquinoline-8-thiocarboxamide
56717-18-1

4-Methyl-5,6,7,8-tetrahydroquinoline-8-thiocarboxamide

Conditions
ConditionsYield
With hydrogenchloride88%
dilithium dicarbonyl(η5-cyclopentadienyl)(diphenylphosphido)molybdate(1-)
114133-29-8

dilithium dicarbonyl(η5-cyclopentadienyl)(diphenylphosphido)molybdate(1-)

1,1-dichloroethane
75-34-3

1,1-dichloroethane

2,2-dicarbonyl-2-(η5-cyclopentadienyl)-3-methyl-1,1-diphenyl-1-phospha-2-molybdacyclopropane
89738-64-7

2,2-dicarbonyl-2-(η5-cyclopentadienyl)-3-methyl-1,1-diphenyl-1-phospha-2-molybdacyclopropane

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiCl; (Ar or N2); to soln. of Mo complex was added dropwise CH3CHCl2 at 0°C within 2 h, mixt. was slowly warmed up to room temp. and solvent was removed in vac.; residue was extd. three times with diethylether/hexane (1:5), exts. were chromd. (Al2O3, diethylether/hexane 1:5); elem. anal.;88%

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