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Hubei CuiRan Biotechnology Co., Ltd

Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)

Phytol

Cas:150-86-7

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

Phytol Manufacturer/High quality/Best price/In stock

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Sinoway Industrial Co., Ltd.

Why is SINOWAY: 1) Specialized in pharmaceutical and healthcare industrial for 34 years. 2) ISO 9001:2015 & SGS audited supplier . 3) Accept various payment terms : T.T 30-60 days. 4) We have warehouse in USA with quickly shipment . 5) We c

Phytol / Vitamin K1 Intermediate 150-86-7

Cas:150-86-7

Min.Order:25 Kilogram

Negotiable

Type:Trading Company

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Hangzhou Dingyan Chem Co., Ltd

Items Standard Result Appearance Yellow viscous liquid Conform Taste & odor Characte

Top purity Phytol with high quality and best price cas:150-86-7

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $105.0 / 150.0

Type:Manufacturers

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality Natural Phytol with high purity

Cas:150-86-7

Min.Order:1 Kilogram

Negotiable

Type:Manufacturers

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Jinan Finer Chemical Co., Ltd

Product Description

Phytol

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $5.0 / 30.0

Type:Lab/Research institutions

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

High Content Natural Extract Phytol HACCP manufacturer

Cas:150-86-7

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

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Xi`an Eastling Biotech Co., Ltd.

Phytol CAS: 150-86-7;102608-53-7 Molecular Formula: C20H40O Home Product Category Organic raw materials Alcohols 150-86-7 150-86-7 - Names and Identifiers Name Phytol Synonyms Phytol PHYTOL Natural Phytol

Top Quality Natural Phytol Chlorophyll150-86-7

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $35.0 / 49.0

Type:Trading Company

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Shanghai Seasonsgreen Chemical Co.,Ltd

Shanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu

lower price High quality Phytol

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

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COLORCOM LTD.

Colorcom is a global leader in industrial chemical manufacturing and is continuously innovating and transforming to exceed client expectations and industry standards. Colorcom prides itself on superior customer and technical focus, while focusing on

Natural Phytol

Cas:150-86-7

Min.Order:1 Metric Ton

Negotiable

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Phytol CAS 150-86-7 In stock

Cas:150-86-7

Min.Order:1 Metric Ton

FOB Price: $1.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

CHENGDU YANXI is a comprehensive manufacturer and an international distribution of products throughout the world. Specialized in Scrap metal, Chemical raw materials, Paper products and color industry. We aim to become leading position in global dis

PHYTOL; 150-86-7; Vitamin K1. Vitamin E intermediates

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Trading Company

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LIDE PHARMACEUTICALS LIMITED

Advantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&amp

2-Hexadecen-1-ol,3,7,11,15-tetramethyl-, (2E,7R,11R)- / LIDE PHARMA- Factory supply / Best price

Cas:150-86-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

150-86-7 Phytol

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $15.0 / 50.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

New production CAS 150-86-7 with best quality

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

Top purity Phytol with high quality and best price cas:150-86-7

Cas:150-86-7

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

PHYTOL CAS150-86-7

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $290.0 / 499.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

2-Hexadecen-1-ol,3,7,11,15-tetramethyl-, (2E,7R,11R)- 150-86-7

Cas:150-86-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Xi'an Faithful Biotech Co., Ltd.

We are the manufacturers and suppliers of API in China, and warehouse in Germany and USA of California, which can quickly and safely deliver to your address 1.High quality and competitive price. 2.Free sample for your evaluation. 3.Promptly delivery

Manufacturers Supply High Quality 98% Natural Phytol Raw Material with Best Price Phytol

Cas:150-86-7

Min.Order:10 Gram

FOB Price: $3.5

Type:Trading Company

inquiry

Qingdao Beluga Import and Export Co., LTD

PHYTOL CAS:150-86-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, stero

PHYTOL CAS:150-86-7

Cas:150-86-7

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

2-Hexadecen-1-ol,3,7,11,15-tetramethyl-, (2E,7R,11R)-

Cas:150-86-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

CAS 150-86-7 PHYTOL

Cas:150-86-7

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

About Product Details

China Biggest Factory Manufacturer Supply PHYTOL CAS 150-86-7

Cas:150-86-7

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

2-Hexadecen-1-ol,3,7,11,15-tetramethyl-, (2E,7R,11R)-

Cas:150-86-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Miheng Trading Co., Ltd.

Phytol CAS 150-86-7 Our advantage 1.Top quality: Using high quality material and establishing a strict quality control system,assigning specific persons in charge of each part of production,from raw material purchase to assembly. 2 Professi

Phytol CAS 150-86-7

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $10.0 / 50.0

Type:Trading Company

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Phytol

Cas:150-86-7

Min.Order:1 Kilogram

FOB Price: $80.0 / 100.0

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

PHYTOL

Cas:150-86-7

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Phytol

Cas:150-86-7

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

High quality Natural Phytol

Cas:150-86-7

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

Synthetic route

2-methyl-3,4-epoxy-1-butene
7437-61-8

2-methyl-3,4-epoxy-1-butene

(3R,7R)-3,7,11-Trimethyldodecylmagnesium-bromid
130627-55-3

(3R,7R)-3,7,11-Trimethyldodecylmagnesium-bromid

phytol
150-86-7

phytol

Conditions
ConditionsYield
With copper(l) iodide In tetrahydrofuran at -20 - 0℃; for 24h;95%
(2E,7R,11R)-Phytyl-(2'-tetrahydropyranyl)aether
66432-63-1

(2E,7R,11R)-Phytyl-(2'-tetrahydropyranyl)aether

phytol
150-86-7

phytol

Conditions
ConditionsYield
With pyridinium p-toluenesulfonate In ethanol at 55℃; for 1.5h;94%
(E)-(7R,11R)-1-(1'-ethoxy)ethoxy-3,7,11,15-tetramethyl-2-hexadecene
92116-50-2

(E)-(7R,11R)-1-(1'-ethoxy)ethoxy-3,7,11,15-tetramethyl-2-hexadecene

phytol
150-86-7

phytol

Conditions
ConditionsYield
With hydrogenchloride; ammonium chloride In tetrahydrofuran at 0 - 20℃; for 3h;68%
2',4'-dimethylpent-3'-yl (7R,11R)-3,7,11,15-tetramethyl-5-methanesulfonyloxyhexadec-2-enoate
679841-68-0

2',4'-dimethylpent-3'-yl (7R,11R)-3,7,11,15-tetramethyl-5-methanesulfonyloxyhexadec-2-enoate

phytol
150-86-7

phytol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether Heating;67%
(2E,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid methyl ester
13853-16-2

(2E,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid methyl ester

phytol
150-86-7

phytol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; diethyl ether
With lithium aluminium tetrahydride In diethyl ether at 0℃;
(2Z,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid ethyl ester
101541-51-9

(2Z,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid ethyl ester

phytol
150-86-7

phytol

Conditions
ConditionsYield
With lithium aluminium tetrahydride; aluminium trichloride
chlorophyll

chlorophyll

phytol
150-86-7

phytol

Conditions
ConditionsYield
With lithium hydroxide
With tetramethyl ammoniumhydroxide
formaldehyd
50-00-0

formaldehyd

trimethylaluminum
75-24-1

trimethylaluminum

6,10,14-Trimethyl-pentadec-1-yne
179991-80-1

6,10,14-Trimethyl-pentadec-1-yne

A

(2E,7S,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol

(2E,7S,11R)-3,7,11,15-tetramethylhexadec-2-en-1-ol

B

phytol
150-86-7

phytol

Conditions
ConditionsYield
Stage #1: trimethylaluminum; 6,10,14-Trimethyl-pentadec-1-yne With zirconocene dichloride In 1,2-dichloro-ethane
Stage #2: With n-butyllithium In tetrahydrofuran
Stage #3: formaldehyd In tetrahydrofuran Further stages.;
(3R,7R,5E)-3,7,11-trimethyldodecan-1-al
105470-79-9

(3R,7R,5E)-3,7,11-trimethyldodecan-1-al

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
2: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
3: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
3-Methylbutenoic acid
541-47-9

3-Methylbutenoic acid

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1.1: 81 percent / DMAP; DCC / CH2Cl2 / 3 h / 20 °C
2.1: (i-Pr)2NLi / hexane; tetrahydrofuran / 1 h / -78 °C
2.2: 99 percent / hexane; tetrahydrofuran / 1 h / -78 - 20 °C
3.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
4.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
5.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(R)-5-methyl-cyclohex-2-enone
54307-74-3, 15466-88-3

(R)-5-methyl-cyclohex-2-enone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 13 steps
1.1: 74 percent / Et2AlI / hexane; CH2Cl2 / 0.5 h / 0 °C
2.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 - 0 °C
2.2: 95 percent / hexane; tetrahydrofuran / 2 h / 0 - 20 °C
3.1: Li / tetrahydrofuran / 26 h
3.2: CuI / tetrahydrofuran / 0.33 h / -20 °C
3.3: 169 mg / tetrahydrofuran / 1 h / -20 °C
4.1: Li / tetrahydrofuran
4.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
4.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
5.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
6.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
7.1: 54 percent / pyridine / CH2Cl2 / 4 h
8.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
9.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
10.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
11.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
12.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
13.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
1-(2',4'-dimethylpent-3'-yloxy)-3-methyl-1-trimethylsilyloxybuta-1,3-diene
73311-67-8

1-(2',4'-dimethylpent-3'-yloxy)-3-methyl-1-trimethylsilyloxybuta-1,3-diene

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 3 steps
1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
2: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
3: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
1-bromo-5-methylpentane
626-88-0

1-bromo-5-methylpentane

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 10 steps
1.1: Li / tetrahydrofuran
1.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
1.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
2.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
3.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
4.1: 54 percent / pyridine / CH2Cl2 / 4 h
5.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
6.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
7.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
8.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
9.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
10.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(3R,5S,1'Z)-2-ethylidene-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
679841-33-9

(3R,5S,1'Z)-2-ethylidene-3-dimethyl(phenyl)silyl-5-methylcyclohexanone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 10 steps
1.1: Li / tetrahydrofuran
1.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
1.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
2.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
3.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
4.1: 54 percent / pyridine / CH2Cl2 / 4 h
5.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
6.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
7.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
8.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
9.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
10.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
2,4-dimethylpent-3-yl 3-methylbut-2-enoate
73311-65-6

2,4-dimethylpent-3-yl 3-methylbut-2-enoate

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1.1: (i-Pr)2NLi / hexane; tetrahydrofuran / 1 h / -78 °C
1.2: 99 percent / hexane; tetrahydrofuran / 1 h / -78 - 20 °C
2.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
3.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
4.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(5R)-2-(1'-hydroxyethyl)-5-methylcyclohex-2-enone
679841-37-3

(5R)-2-(1'-hydroxyethyl)-5-methylcyclohex-2-enone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 12 steps
1.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 - 0 °C
1.2: 95 percent / hexane; tetrahydrofuran / 2 h / 0 - 20 °C
2.1: Li / tetrahydrofuran / 26 h
2.2: CuI / tetrahydrofuran / 0.33 h / -20 °C
2.3: 169 mg / tetrahydrofuran / 1 h / -20 °C
3.1: Li / tetrahydrofuran
3.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
3.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
4.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
5.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
6.1: 54 percent / pyridine / CH2Cl2 / 4 h
7.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
8.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
9.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
10.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
11.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
12.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(5R)-2-(1'-methoxycarbonyloxyethyl)-5-methylcyclohex-2-enone
679841-58-8

(5R)-2-(1'-methoxycarbonyloxyethyl)-5-methylcyclohex-2-enone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 11 steps
1.1: Li / tetrahydrofuran / 26 h
1.2: CuI / tetrahydrofuran / 0.33 h / -20 °C
1.3: 169 mg / tetrahydrofuran / 1 h / -20 °C
2.1: Li / tetrahydrofuran
2.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
2.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
3.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
4.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
5.1: 54 percent / pyridine / CH2Cl2 / 4 h
6.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
7.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
8.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
9.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
10.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
11.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(3R,7R,5E)-3,7,11-trimethyldodec-5-en-1-al
679841-66-8

(3R,7R,5E)-3,7,11-trimethyldodec-5-en-1-al

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
2: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
3: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
4: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(3R,7R,5E)-3,7,11-trimethyldodec-5-enonitrile
679841-42-0

(3R,7R,5E)-3,7,11-trimethyldodec-5-enonitrile

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
2: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
3: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
4: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
5: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(2R,3R,5S)-2-(1'-hydroxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
679841-36-2

(2R,3R,5S)-2-(1'-hydroxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 12 steps
1.1: 92 percent / N,N-4-dimethylaminopyridine; pyridine / CH2Cl2 / 12 h / 0 °C
2.1: 98 percent / DBU / dimethylformamide / 5 h / 100 °C
3.1: Li / tetrahydrofuran
3.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
3.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
4.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
5.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
6.1: 54 percent / pyridine / CH2Cl2 / 4 h
7.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
8.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
9.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
10.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
11.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
12.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(2R,3R,5S)-2-(1'-acetoxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
679841-55-5

(2R,3R,5S)-2-(1'-acetoxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 11 steps
1.1: 98 percent / DBU / dimethylformamide / 5 h / 100 °C
2.1: Li / tetrahydrofuran
2.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C
2.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C
3.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
4.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
5.1: 54 percent / pyridine / CH2Cl2 / 4 h
6.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
7.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
8.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
9.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
10.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
11.1: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
679841-40-8

(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 8 steps
1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
2: 54 percent / pyridine / CH2Cl2 / 4 h
3: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
4: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
5: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
6: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
7: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
8: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(2R,3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)cyclohexanone oxime
679841-64-6

(2R,3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)cyclohexanone oxime

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 7 steps
1: 54 percent / pyridine / CH2Cl2 / 4 h
2: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
3: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
4: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
5: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
6: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
7: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
2',4'-dimethylpent-3'-yl-(7R,11R)-3,7,11,15-tetramethyl-5-hydroxyhexadec-2-enoate
679841-43-1

2',4'-dimethylpent-3'-yl-(7R,11R)-3,7,11,15-tetramethyl-5-hydroxyhexadec-2-enoate

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
2: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)-1-trimethysilyloxylcyclohexene
679841-63-5

(3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)-1-trimethysilyloxylcyclohexene

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 9 steps
1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C
2: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating
3: 54 percent / pyridine / CH2Cl2 / 4 h
4: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
5: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
6: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
7: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
8: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
9: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(E)-(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone oxime acetate
679841-41-9

(E)-(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone oxime acetate

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 6 steps
1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C
2: 59 percent / DIBAl / hexane / 2.5 h / 20 °C
3: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C
4: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C
5: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C
6: 67 percent / LiAlH4 / diethyl ether / Heating
View Scheme
(E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol
24529-80-4

(E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 5 steps
1: 73 percent / Ba(OH)2 / methanol
2: POCl3 / 0.5 h
3: dimethylformamide / 3 h / 80 °C
4: 72 percent / Mg / Li2CuCl4 / tetrahydrofuran / 10 min, -78 deg C then 2 h, 0 deg C then 15 h, r.t.
5: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 5 steps
1: 73 percent / Ba(OH)2 / methanol
2: POCl3 / 0.5 h
3: dimethylformamide / 3 h / 80 °C
4: 57 percent Chromat. / Mg / CuI / tetrahydrofuran
5: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 4 steps
1: 73 percent / Ba(OH)2 / methanol
2: POCl3 / 0.5 h
3: 48 percent Chromat. / Mg / CuCl / tetrahydrofuran
4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 4 steps
1: 73 percent / Ba(OH)2 / methanol
2: POCl3 / 0.5 h
3: 33.7 percent / Li2CuCl4 / tetrahydrofuran / 2 h / 0 °C
4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
(E)-4-chloro-3-methyl-2-buten-1-ol
53170-97-1

(E)-4-chloro-3-methyl-2-buten-1-ol

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 4 steps
1: POCl3 / 0.5 h
2: dimethylformamide / 3 h / 80 °C
3: 72 percent / Mg / Li2CuCl4 / tetrahydrofuran / 10 min, -78 deg C then 2 h, 0 deg C then 15 h, r.t.
4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 4 steps
1: POCl3 / 0.5 h
2: dimethylformamide / 3 h / 80 °C
3: 57 percent Chromat. / Mg / CuI / tetrahydrofuran
4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 3 steps
1: POCl3 / 0.5 h
2: 48 percent Chromat. / Mg / CuCl / tetrahydrofuran
3: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
Multi-step reaction with 3 steps
1: POCl3 / 0.5 h
2: 33.7 percent / Li2CuCl4 / tetrahydrofuran / 2 h / 0 °C
3: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
racemic Hexahydrofarnesylmagnesium bromid
42933-01-7

racemic Hexahydrofarnesylmagnesium bromid

phytol
150-86-7

phytol

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 84 percent Chromat. / Li2CuCl4 / tetrahydrofuran
2: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C
View Scheme
phytol
150-86-7

phytol

(3RS,7R,11R)-3,7,11,15-tetramethylhexadecan-1-ol
189302-44-1

(3RS,7R,11R)-3,7,11,15-tetramethylhexadecan-1-ol

Conditions
ConditionsYield
With hydrogen; nickel In ethanol for 72h;100%
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 72h;100%
With platinum(IV) oxide; hydrogen In tetrahydrofuran at 20℃; under 750.075 Torr; for 4h;96%
phytol
150-86-7

phytol

(3R,7R,11R)-3,7,11,15-tetramethyl-1-hexadecanol (dihydrophytol)
18654-63-2

(3R,7R,11R)-3,7,11,15-tetramethyl-1-hexadecanol (dihydrophytol)

Conditions
ConditionsYield
With hydrogen; <(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl>diacetatoruthenium(II) In methanol under 77572.2 Torr; for 24h;100%
Phenyl glycidyl ether
122-60-1

Phenyl glycidyl ether

phytol
150-86-7

phytol

C29H50O3

C29H50O3

Conditions
ConditionsYield
With potassium methanolate at 110℃; for 18.0833h; Inert atmosphere;99.5%
phytol
150-86-7

phytol

3,7,11,15-tetramethyl-hexadecanol
645-72-7

3,7,11,15-tetramethyl-hexadecanol

Conditions
ConditionsYield
With hydrogen In ethanol; water at 20℃; for 72h;99%
With platinum(IV) oxide hydrate; hydrogen; sodium hydrogencarbonate In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;90%
With hydrogen In ethanol82.3%
With hydrogen; nickel In ethanol for 5h; Hydrogenation;
phytol
150-86-7

phytol

((2R,3R)-3-methyl-3-((4R,8R)-4,8,12-trimethyltridecyl)-oxiran-2-yl)methanol
14237-72-0

((2R,3R)-3-methyl-3-((4R,8R)-4,8,12-trimethyltridecyl)-oxiran-2-yl)methanol

Conditions
ConditionsYield
With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate In nonane; dichloromethane at -20℃; for 3h; Sharpless epoxidation; Molecular sieve; Inert atmosphere;96%
With titanium(IV) isopropylate; Dimethyl D-tartrate; Trimethylacetic acid In dichloromethane at -20℃;85%
With 3-chloro-benzenecarboperoxoic acid In dichloromethane
phytol
150-86-7

phytol

n-hexadecanoyl chloride
112-67-4

n-hexadecanoyl chloride

trans-palmitoylphytol

trans-palmitoylphytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;96%
With triethylamine In hexane at 80℃; for 2h;85%
With pyridine; dmap at 30 - 35℃; for 14h;
pivaloyl chloride
3282-30-2

pivaloyl chloride

phytol
150-86-7

phytol

1-O-pivaloylphytol
127951-52-4

1-O-pivaloylphytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;96%
With pyridine; dmap at 30 - 35℃; for 14h;
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

aqueous 3N-K2 CO3

aqueous 3N-K2 CO3

di-tert-butyl peroxide
110-05-4

di-tert-butyl peroxide

water
7732-18-5

water

phytol
150-86-7

phytol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

Conditions
ConditionsYield
silica gel In diethyl ether; dichloromethane95%
acetyl chloride
75-36-5

acetyl chloride

phytol
150-86-7

phytol

(R,R,E)-phytyl acetate
10236-16-5

(R,R,E)-phytyl acetate

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;95%
With pyridine; dmap at 30 - 35℃; for 14h;
phytol
150-86-7

phytol

(5R,9R)-5,9,13-trimethyltetradecanoic acid

(5R,9R)-5,9,13-trimethyltetradecanoic acid

Conditions
ConditionsYield
Stage #1: phytol With ozone
Stage #2: With potassium tribromide; sodium hydroxide
94%
With potassium tribromide; ozone; sodium hydroxide94%
undecanoyl chloride
17746-05-3

undecanoyl chloride

phytol
150-86-7

phytol

phytyl dodecanoate

phytyl dodecanoate

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;94%
m-anisoyl chloride
1711-05-3

m-anisoyl chloride

phytol
150-86-7

phytol

1-O-(m-anisoyl)phytol

1-O-(m-anisoyl)phytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;93%
With pyridine; dmap at 30 - 35℃; for 14h;
benzoyl chloride
98-88-4

benzoyl chloride

phytol
150-86-7

phytol

1-O-benzoylphytol

1-O-benzoylphytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;92%
3,4,5-Trimethoxybenzoyl chloride
4521-61-3

3,4,5-Trimethoxybenzoyl chloride

phytol
150-86-7

phytol

1-O-(3,4,5-trimethoxybenzoyl)phytol
127951-49-9

1-O-(3,4,5-trimethoxybenzoyl)phytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;92%
With pyridine; dmap at 30 - 35℃; for 14h;
titanium(IV) isopropylate
546-68-9

titanium(IV) isopropylate

1,1-dichloroethane
75-34-3

1,1-dichloroethane

Diethyl tartrate
408332-88-7

Diethyl tartrate

phytol
150-86-7

phytol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

(2S,3S)-epoxy-(3S,7R,11R)-3,7,11,15-tetramethylhexadecane-1-ol

Conditions
ConditionsYield
With tert.-butylhydroperoxide; sodium hydroxide In CHCl3 -benzene; diethyl ether; dichloromethane91.3%
N-ethyl-N-phenylamine
103-69-5

N-ethyl-N-phenylamine

phytol
150-86-7

phytol

N-ethyl-N-(3,7,11,15-tetramethylhexadecyl)aniline

N-ethyl-N-(3,7,11,15-tetramethylhexadecyl)aniline

Conditions
ConditionsYield
With formic acid; C28H28Cl2O3PRuS In toluene at 150℃; for 16h; Inert atmosphere; chemoselective reaction;90%
With tricarbonyl(η(4)-cycloocta-1,5-diene)iron In ethanol at 50℃; for 20h; Inert atmosphere; Schlenk technique; Irradiation;65%
phytol
150-86-7

phytol

3,7,11,15-tetramethylhexadecan-1-ol
1257631-81-4

3,7,11,15-tetramethylhexadecan-1-ol

Conditions
ConditionsYield
With hydrogen; nickel In ethanol at 20℃; under 760.051 Torr; for 6h;88%
cinnamoyl chloride
102-92-1

cinnamoyl chloride

phytol
150-86-7

phytol

1-O-cinnamoylphytol

1-O-cinnamoylphytol

Conditions
ConditionsYield
With pyridine; dmap at 30 - 35℃; for 14h;88%
With pyridine; dmap at 30 - 35℃; for 14h;
phytol
150-86-7

phytol

phytyl bromide
4444-13-7

phytyl bromide

Conditions
ConditionsYield
With pyridine; phosphorus tribromide In benzene at 4 - 35℃; for 3.5h;86%
With phosphorus tribromide In benzene at 4 - 35℃; for 4.5h;86%
With phosphorus tribromide In pyridine
Triethyl orthoacetate
78-39-7

Triethyl orthoacetate

phytol
150-86-7

phytol

ethyl 3,7,11,15-tetramethyl-3-vinylhexadecanoate

ethyl 3,7,11,15-tetramethyl-3-vinylhexadecanoate

Conditions
ConditionsYield
With acetic acid at 138℃; Johnson-Claisen Rearrangement;86%
6-Chloro-pyridin-3-ylamine
5350-93-6

6-Chloro-pyridin-3-ylamine

phytol
150-86-7

phytol

N-(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl-5-amino-2-chloropyridine

N-(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl-5-amino-2-chloropyridine

Conditions
ConditionsYield
With potassium hydrogensulfate; iron(II) bromide In toluene at 120℃; for 24h;86%
phytol
150-86-7

phytol

(2’E,7’R,11‘R)-3,7,11,15-tetramethylhexadec-2-enal
13754-69-3

(2’E,7’R,11‘R)-3,7,11,15-tetramethylhexadec-2-enal

Conditions
ConditionsYield
With manganese(IV) oxide In dichloromethane for 24h; Reflux;85%
With pyridine; chromium(VI) oxide In dichloromethane75%
With pyridinium chlorochromate In dichloromethane for 6h; Reflux;74%
phytol
150-86-7

phytol

(3-methyl-3-((4R,8R)-4,8,12-trimethyltridecyl)oxiran-2-yl)methanol

(3-methyl-3-((4R,8R)-4,8,12-trimethyltridecyl)oxiran-2-yl)methanol

Conditions
ConditionsYield
With 3-chloro-benzenecarboperoxoic acid In chloroform for 0.75h;85%
With methyl hexanoate; CpLIP2 Y179F (ipase/acyltransferase) from Candida parapsilosis; dihydrogen peroxide In aq. phosphate buffer; water at 20℃; pH=6.5; Enzymatic reaction;55%
With dihydrogen peroxide; methyltrioxorhenium(VII) In aq. phosphate buffer at 20℃; for 3h; pH=2.0;
phytol
150-86-7

phytol

2-chloro-3,7,11,15-tetramethylhexadecan-1,3-diol

2-chloro-3,7,11,15-tetramethylhexadecan-1,3-diol

Conditions
ConditionsYield
With 1,3,5-trichloro-2,4,6-triazine; 4-methylmorpholine N-oxide In chloroform at -10 - 20℃;83%
phytol
150-86-7

phytol

methyl iodide
74-88-4

methyl iodide

(2E,7R,11R)-Phytyl-methylaether
66432-64-2

(2E,7R,11R)-Phytyl-methylaether

Conditions
ConditionsYield
With sodium hydride In N,N-dimethyl-formamide Ambient temperature;82%
8-amino quinoline
578-66-5

8-amino quinoline

phytol
150-86-7

phytol

N-(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl-8-quinolinamine

N-(2E,7R,11R)-3,7,11,15-tetramethyl-2-hexadecenyl-8-quinolinamine

Conditions
ConditionsYield
With potassium hydrogensulfate; iron(II) bromide In toluene at 120℃; for 24h;81%
phytol
150-86-7

phytol

3,7,11,15-tetramethylhexadecane-1,3-diol

3,7,11,15-tetramethylhexadecane-1,3-diol

Conditions
ConditionsYield
With iron(III)-acetylacetonate; methyl 4-nitrobenzenesulfonate; phenylsilane; sodium hydrogencarbonate In methanol at 0 - 20℃; for 12h; Schlenk technique; Inert atmosphere; regioselective reaction;81%
Trimethylhydroquinone
700-13-0

Trimethylhydroquinone

phytol
150-86-7

phytol

(2RS,4R,8R)-α-tocopherol
186537-56-4

(2RS,4R,8R)-α-tocopherol

Conditions
ConditionsYield
With scandium tris(trifluoromethanesulfonate) In toluene at 110℃; for 0.5h; Friedel-Crafts Alkylation; Microwave irradiation; Green chemistry;77%
With hydrogenchloride; diethyl ether
With ethanol; phosphorus pentoxide

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