Hubei CuiRan Biotechnology Co., Ltd is a leading company in the research, development, manufacture and marketing of High Quality Phytochemicals and Extracts(especially Active Ingredients from Traditional Chinese Medicine,Traditional Chinese Medicine)
Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti
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inquiryItems Standard Result Appearance Yellow viscous liquid Conform Taste & odor Characte
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inquiryProduct Description
The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
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inquiry1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s
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inquiryPhytol CAS: 150-86-7;102608-53-7 Molecular Formula: C20H40O Home Product Category Organic raw materials Alcohols 150-86-7 150-86-7 - Names and Identifiers Name Phytol Synonyms Phytol PHYTOL Natural Phytol
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inquiryShanghai Seasonsgreen Chemical is a high-tech research and development, production, sale and custom synthesis set in one high-tech chemical products enterprises. Our sales and marketing division is located in Shanghai, serving international pharmaceu
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inquiryAdvantage : LIDE PHARMACEUTICALS LTD. is a mid-small manufacturing-type enterprise, engaged in pharmaceutical intermediates of R&D, custom-made and production, and also involving trading chemicals for export. We have established the R&
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inquiryOur Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con
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inquiryPHYTOL CAS:150-86-7 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermediates, stero
Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai
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inquiryAbout Product Details
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inquiryHenan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod
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inquiry1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures
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J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
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inquiry2-methyl-3,4-epoxy-1-butene
(3R,7R)-3,7,11-Trimethyldodecylmagnesium-bromid
phytol
Conditions | Yield |
---|---|
With copper(l) iodide In tetrahydrofuran at -20 - 0℃; for 24h; | 95% |
(2E,7R,11R)-Phytyl-(2'-tetrahydropyranyl)aether
phytol
Conditions | Yield |
---|---|
With pyridinium p-toluenesulfonate In ethanol at 55℃; for 1.5h; | 94% |
(E)-(7R,11R)-1-(1'-ethoxy)ethoxy-3,7,11,15-tetramethyl-2-hexadecene
phytol
Conditions | Yield |
---|---|
With hydrogenchloride; ammonium chloride In tetrahydrofuran at 0 - 20℃; for 3h; | 68% |
2',4'-dimethylpent-3'-yl (7R,11R)-3,7,11,15-tetramethyl-5-methanesulfonyloxyhexadec-2-enoate
phytol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride In diethyl ether Heating; | 67% |
(2E,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid methyl ester
phytol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; diethyl ether | |
With lithium aluminium tetrahydride In diethyl ether at 0℃; |
(2Z,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid ethyl ester
phytol
Conditions | Yield |
---|---|
With lithium aluminium tetrahydride; aluminium trichloride |
phytol
Conditions | Yield |
---|---|
With lithium hydroxide | |
With tetramethyl ammoniumhydroxide |
formaldehyd
trimethylaluminum
6,10,14-Trimethyl-pentadec-1-yne
B
phytol
Conditions | Yield |
---|---|
Stage #1: trimethylaluminum; 6,10,14-Trimethyl-pentadec-1-yne With zirconocene dichloride In 1,2-dichloro-ethane Stage #2: With n-butyllithium In tetrahydrofuran Stage #3: formaldehyd In tetrahydrofuran Further stages.; |
(3R,7R,5E)-3,7,11-trimethyldodecan-1-al
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 2: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 3: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1.1: 81 percent / DMAP; DCC / CH2Cl2 / 3 h / 20 °C 2.1: (i-Pr)2NLi / hexane; tetrahydrofuran / 1 h / -78 °C 2.2: 99 percent / hexane; tetrahydrofuran / 1 h / -78 - 20 °C 3.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 4.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 5.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(R)-5-methyl-cyclohex-2-enone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 13 steps 1.1: 74 percent / Et2AlI / hexane; CH2Cl2 / 0.5 h / 0 °C 2.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 - 0 °C 2.2: 95 percent / hexane; tetrahydrofuran / 2 h / 0 - 20 °C 3.1: Li / tetrahydrofuran / 26 h 3.2: CuI / tetrahydrofuran / 0.33 h / -20 °C 3.3: 169 mg / tetrahydrofuran / 1 h / -20 °C 4.1: Li / tetrahydrofuran 4.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 4.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 5.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 6.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 7.1: 54 percent / pyridine / CH2Cl2 / 4 h 8.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 9.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 10.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 11.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 12.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 13.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
1-(2',4'-dimethylpent-3'-yloxy)-3-methyl-1-trimethylsilyloxybuta-1,3-diene
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 2: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 3: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 10 steps 1.1: Li / tetrahydrofuran 1.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 1.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 2.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 3.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 4.1: 54 percent / pyridine / CH2Cl2 / 4 h 5.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 6.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 7.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 8.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 9.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 10.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(3R,5S,1'Z)-2-ethylidene-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 10 steps 1.1: Li / tetrahydrofuran 1.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 1.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 2.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 3.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 4.1: 54 percent / pyridine / CH2Cl2 / 4 h 5.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 6.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 7.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 8.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 9.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 10.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
2,4-dimethylpent-3-yl 3-methylbut-2-enoate
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1.1: (i-Pr)2NLi / hexane; tetrahydrofuran / 1 h / -78 °C 1.2: 99 percent / hexane; tetrahydrofuran / 1 h / -78 - 20 °C 2.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 3.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 4.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(5R)-2-(1'-hydroxyethyl)-5-methylcyclohex-2-enone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 12 steps 1.1: n-BuLi / hexane; tetrahydrofuran / 1 h / -78 - 0 °C 1.2: 95 percent / hexane; tetrahydrofuran / 2 h / 0 - 20 °C 2.1: Li / tetrahydrofuran / 26 h 2.2: CuI / tetrahydrofuran / 0.33 h / -20 °C 2.3: 169 mg / tetrahydrofuran / 1 h / -20 °C 3.1: Li / tetrahydrofuran 3.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 3.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 4.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 5.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 6.1: 54 percent / pyridine / CH2Cl2 / 4 h 7.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 8.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 9.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 10.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 11.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 12.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(5R)-2-(1'-methoxycarbonyloxyethyl)-5-methylcyclohex-2-enone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 11 steps 1.1: Li / tetrahydrofuran / 26 h 1.2: CuI / tetrahydrofuran / 0.33 h / -20 °C 1.3: 169 mg / tetrahydrofuran / 1 h / -20 °C 2.1: Li / tetrahydrofuran 2.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 2.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 3.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 4.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 5.1: 54 percent / pyridine / CH2Cl2 / 4 h 6.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 7.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 8.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 9.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 10.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 11.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(3R,7R,5E)-3,7,11-trimethyldodec-5-en-1-al
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 2: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 3: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 4: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(3R,7R,5E)-3,7,11-trimethyldodec-5-enonitrile
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 2: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 3: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 4: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 5: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(2R,3R,5S)-2-(1'-hydroxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 12 steps 1.1: 92 percent / N,N-4-dimethylaminopyridine; pyridine / CH2Cl2 / 12 h / 0 °C 2.1: 98 percent / DBU / dimethylformamide / 5 h / 100 °C 3.1: Li / tetrahydrofuran 3.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 3.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 4.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 5.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 6.1: 54 percent / pyridine / CH2Cl2 / 4 h 7.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 8.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 9.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 10.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 11.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 12.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(2R,3R,5S)-2-(1'-acetoxyethyl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 11 steps 1.1: 98 percent / DBU / dimethylformamide / 5 h / 100 °C 2.1: Li / tetrahydrofuran 2.2: CuBr*Me2S / tetrahydrofuran / 0.5 h / -20 °C 2.3: 670 mg / tetrahydrofuran; diethyl ether / 1 h / -78 - 0 °C 3.1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 4.1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 5.1: 54 percent / pyridine / CH2Cl2 / 4 h 6.1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 7.1: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 8.1: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 9.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 10.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 11.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 8 steps 1: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 2: 54 percent / pyridine / CH2Cl2 / 4 h 3: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 4: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 5: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 6: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 7: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 8: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(2R,3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)cyclohexanone oxime
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 7 steps 1: 54 percent / pyridine / CH2Cl2 / 4 h 2: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 3: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 4: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 5: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 6: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 7: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
2',4'-dimethylpent-3'-yl-(7R,11R)-3,7,11,15-tetramethyl-5-hydroxyhexadec-2-enoate
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 2: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(3R,5S,2'R)-3-dimethyl(phenyl)silyl-5-methyl-2-(6'-methylhept-2'-yl)-1-trimethysilyloxylcyclohexene
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 9 steps 1: 96 percent / aq. HCl / tetrahydrofuran / 12 h / 20 °C 2: 66 percent / NH2OH*HCl; pyridine / ethanol / Heating 3: 54 percent / pyridine / CH2Cl2 / 4 h 4: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 5: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 6: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 7: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 8: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 9: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(E)-(2R,3R,5S,2'R)-2-(6'-methylhept-2'-yl)-3-dimethyl(phenyl)silyl-5-methylcyclohexanone oxime acetate
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 6 steps 1: 90 percent / Me3SiOTf / CH2Cl2 / 4 h / 0 °C 2: 59 percent / DIBAl / hexane / 2.5 h / 20 °C 3: 98 percent / H2 / Pd/C / ethyl acetate / 20 °C 4: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 5: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 6: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
(E)-1-O-acetyl-4-chloro-3-methyl-2-buten-1-ol
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 5 steps 1: 73 percent / Ba(OH)2 / methanol 2: POCl3 / 0.5 h 3: dimethylformamide / 3 h / 80 °C 4: 72 percent / Mg / Li2CuCl4 / tetrahydrofuran / 10 min, -78 deg C then 2 h, 0 deg C then 15 h, r.t. 5: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 5 steps 1: 73 percent / Ba(OH)2 / methanol 2: POCl3 / 0.5 h 3: dimethylformamide / 3 h / 80 °C 4: 57 percent Chromat. / Mg / CuI / tetrahydrofuran 5: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 4 steps 1: 73 percent / Ba(OH)2 / methanol 2: POCl3 / 0.5 h 3: 48 percent Chromat. / Mg / CuCl / tetrahydrofuran 4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 4 steps 1: 73 percent / Ba(OH)2 / methanol 2: POCl3 / 0.5 h 3: 33.7 percent / Li2CuCl4 / tetrahydrofuran / 2 h / 0 °C 4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme |
(E)-4-chloro-3-methyl-2-buten-1-ol
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 4 steps 1: POCl3 / 0.5 h 2: dimethylformamide / 3 h / 80 °C 3: 72 percent / Mg / Li2CuCl4 / tetrahydrofuran / 10 min, -78 deg C then 2 h, 0 deg C then 15 h, r.t. 4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 4 steps 1: POCl3 / 0.5 h 2: dimethylformamide / 3 h / 80 °C 3: 57 percent Chromat. / Mg / CuI / tetrahydrofuran 4: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 3 steps 1: POCl3 / 0.5 h 2: 48 percent Chromat. / Mg / CuCl / tetrahydrofuran 3: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme | |
Multi-step reaction with 3 steps 1: POCl3 / 0.5 h 2: 33.7 percent / Li2CuCl4 / tetrahydrofuran / 2 h / 0 °C 3: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme |
racemic Hexahydrofarnesylmagnesium bromid
phytol
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 84 percent Chromat. / Li2CuCl4 / tetrahydrofuran 2: 94 percent / pyridinium-p-toluolsulfonate / ethanol / 1.5 h / 55 °C View Scheme |
phytol
(3RS,7R,11R)-3,7,11,15-tetramethylhexadecan-1-ol
Conditions | Yield |
---|---|
With hydrogen; nickel In ethanol for 72h; | 100% |
With hydrogen In ethanol at 20℃; under 760.051 Torr; for 72h; | 100% |
With platinum(IV) oxide; hydrogen In tetrahydrofuran at 20℃; under 750.075 Torr; for 4h; | 96% |
phytol
(3R,7R,11R)-3,7,11,15-tetramethyl-1-hexadecanol (dihydrophytol)
Conditions | Yield |
---|---|
With hydrogen; <(S)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl>diacetatoruthenium(II) In methanol under 77572.2 Torr; for 24h; | 100% |
Conditions | Yield |
---|---|
With potassium methanolate at 110℃; for 18.0833h; Inert atmosphere; | 99.5% |
Conditions | Yield |
---|---|
With hydrogen In ethanol; water at 20℃; for 72h; | 99% |
With platinum(IV) oxide hydrate; hydrogen; sodium hydrogencarbonate In tetrahydrofuran at 20℃; for 12h; Inert atmosphere; | 90% |
With hydrogen In ethanol | 82.3% |
With hydrogen; nickel In ethanol for 5h; Hydrogenation; |
phytol
((2R,3R)-3-methyl-3-((4R,8R)-4,8,12-trimethyltridecyl)-oxiran-2-yl)methanol
Conditions | Yield |
---|---|
With titanium(IV) isopropylate; tert.-butylhydroperoxide; diethyl (2S,3S)-tartrate In nonane; dichloromethane at -20℃; for 3h; Sharpless epoxidation; Molecular sieve; Inert atmosphere; | 96% |
With titanium(IV) isopropylate; Dimethyl D-tartrate; Trimethylacetic acid In dichloromethane at -20℃; | 85% |
With 3-chloro-benzenecarboperoxoic acid In dichloromethane |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 96% |
With triethylamine In hexane at 80℃; for 2h; | 85% |
With pyridine; dmap at 30 - 35℃; for 14h; |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 96% |
With pyridine; dmap at 30 - 35℃; for 14h; |
titanium(IV) isopropylate
di-tert-butyl peroxide
DIPT
water
phytol
Conditions | Yield |
---|---|
silica gel In diethyl ether; dichloromethane | 95% |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 95% |
With pyridine; dmap at 30 - 35℃; for 14h; |
phytol
Conditions | Yield |
---|---|
Stage #1: phytol With ozone Stage #2: With potassium tribromide; sodium hydroxide | 94% |
With potassium tribromide; ozone; sodium hydroxide | 94% |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 94% |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 93% |
With pyridine; dmap at 30 - 35℃; for 14h; |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 92% |
3,4,5-Trimethoxybenzoyl chloride
phytol
1-O-(3,4,5-trimethoxybenzoyl)phytol
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 92% |
With pyridine; dmap at 30 - 35℃; for 14h; |
titanium(IV) isopropylate
1,1-dichloroethane
Diethyl tartrate
phytol
Conditions | Yield |
---|---|
With tert.-butylhydroperoxide; sodium hydroxide In CHCl3 -benzene; diethyl ether; dichloromethane | 91.3% |
Conditions | Yield |
---|---|
With formic acid; C28H28Cl2O3PRuS In toluene at 150℃; for 16h; Inert atmosphere; chemoselective reaction; | 90% |
With tricarbonyl(η(4)-cycloocta-1,5-diene)iron In ethanol at 50℃; for 20h; Inert atmosphere; Schlenk technique; Irradiation; | 65% |
phytol
3,7,11,15-tetramethylhexadecan-1-ol
Conditions | Yield |
---|---|
With hydrogen; nickel In ethanol at 20℃; under 760.051 Torr; for 6h; | 88% |
Conditions | Yield |
---|---|
With pyridine; dmap at 30 - 35℃; for 14h; | 88% |
With pyridine; dmap at 30 - 35℃; for 14h; |
Conditions | Yield |
---|---|
With pyridine; phosphorus tribromide In benzene at 4 - 35℃; for 3.5h; | 86% |
With phosphorus tribromide In benzene at 4 - 35℃; for 4.5h; | 86% |
With phosphorus tribromide In pyridine |
Conditions | Yield |
---|---|
With acetic acid at 138℃; Johnson-Claisen Rearrangement; | 86% |
Conditions | Yield |
---|---|
With potassium hydrogensulfate; iron(II) bromide In toluene at 120℃; for 24h; | 86% |
phytol
(2’E,7’R,11‘R)-3,7,11,15-tetramethylhexadec-2-enal
Conditions | Yield |
---|---|
With manganese(IV) oxide In dichloromethane for 24h; Reflux; | 85% |
With pyridine; chromium(VI) oxide In dichloromethane | 75% |
With pyridinium chlorochromate In dichloromethane for 6h; Reflux; | 74% |
phytol
Conditions | Yield |
---|---|
With 3-chloro-benzenecarboperoxoic acid In chloroform for 0.75h; | 85% |
With methyl hexanoate; CpLIP2 Y179F (ipase/acyltransferase) from Candida parapsilosis; dihydrogen peroxide In aq. phosphate buffer; water at 20℃; pH=6.5; Enzymatic reaction; | 55% |
With dihydrogen peroxide; methyltrioxorhenium(VII) In aq. phosphate buffer at 20℃; for 3h; pH=2.0; |
phytol
Conditions | Yield |
---|---|
With 1,3,5-trichloro-2,4,6-triazine; 4-methylmorpholine N-oxide In chloroform at -10 - 20℃; | 83% |
Conditions | Yield |
---|---|
With sodium hydride In N,N-dimethyl-formamide Ambient temperature; | 82% |
Conditions | Yield |
---|---|
With potassium hydrogensulfate; iron(II) bromide In toluene at 120℃; for 24h; | 81% |
phytol
Conditions | Yield |
---|---|
With iron(III)-acetylacetonate; methyl 4-nitrobenzenesulfonate; phenylsilane; sodium hydrogencarbonate In methanol at 0 - 20℃; for 12h; Schlenk technique; Inert atmosphere; regioselective reaction; | 81% |
Conditions | Yield |
---|---|
With scandium tris(trifluoromethanesulfonate) In toluene at 110℃; for 0.5h; Friedel-Crafts Alkylation; Microwave irradiation; Green chemistry; | 77% |
With hydrogenchloride; diethyl ether | |
With ethanol; phosphorus pentoxide |
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