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Dayang Chem (Hangzhou) Co.,Ltd.

Dayangchem’s R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. DayangChem can provide different quantiti

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply Dichloro(methyl)(phenyl)silane

Cas:149-74-6

Min.Order:1

Negotiable

Type:Other

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 5 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

Dichloromethylphenylsilane --

Cas:149-74-6

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Hunan chemfish Pharmaceutical co.,Ltd.located in Lugu High-tech industral park ,Hunan province . with its own R&D center and more than 10000㎡manufacture plant . Chemfish owns 40 reactors from 1000L to 8000L. With complete auxiliary equipment as

Methylphenyldichlorosilane

Cas:149-74-6

Min.Order:1 Gram

Negotiable

Type:Manufacturers

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

English name:Methylphenyldichlorosilane CAS RN: 149-74-6 Molecular formula: C7H8Cl2Si Molecular weight: 191 Appearance and properties: Colorless and transparent liquid. Boiling point (℃): 206~207 Density(g/cm3): 1.19 Purity:≥99% Uses: &

Methylphenyldichlorosilane

Cas:149-74-6

Min.Order:100 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Massive Chemical Technology Co., Ltd.

Massive Chemical is certified with ISO9001 and ISO14001 manufacturer for this product. We will offer all documents as requirement for the materials which includes, Certificate of Analysis, Material Safety Data Sheet, and Method of Analysis and

Dichloromethylphenylsilane/High quality/Best price

Cas:149-74-6

Min.Order:1 Gram

FOB Price: $1.0

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:10 Gram

FOB Price: $100.0

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

moderate price & quick delivery. Appearance:clear colourless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:100g/bottle,1kg/bottle,25kg/drum or as per your request Application:Used for polymeri

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Kono Chem Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou

Trimethyl orthoformate

Cas:149-74-6

Min.Order:0

Negotiable

Type:Other

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Methylphenyldichlorosilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

high purity, manufacturer Application:Intermediate

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

Dichloro(Methyl)phenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard

factory supply CAS 149-74-6 with competitive price

Cas:149-74-6

Min.Order:1 Kilogram

FOB Price: $112.0

Type:Trading Company

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Benzene,(dichloromethylsilyl)-

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Ocean Chemical Co., Ltd.

1.High purity, like 99%, 99.9%, 99.95%, 99.99%, 99.999%2.Quality control, test sample before shipping and keep sample for 3 years after shipping;3. Prompt shipment with professional documents;4. Packing as your request, with photo before shipment;5.

Dichloro(methyl)phenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hubei Langyou International Trading Co., Ltd

Dichloromethylphenylsilane Application:Dichloromethylphenylsilane

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Other

inquiry

Hunan Longxianng Runhui Trading Co.,Ltd

DichloromethylphenylsilaneAppearance:liquid Storage:Store below +30°C. Application:Used to make other chemicals. Transportation:By express (Door to door) such as FEDEX, DHL, EMS for small amount. By air(airport to airport) or by sea LCL/FCL for large

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hunan Russell Chemicals Technology Co.,Ltd

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:any port in China

Dichloromethylphenylsilane 149-74-6

Cas:149-74-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Chemsigma International Co.,Ltd.

bulk?production Application:Pharmaceutical intermediates

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

HWRK Chem

in store Package:25ml Application:Organic Chemicals

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Dongguan Albiya Energy Science and Technology Co.,Ltd

1. Introduction ofDichloromethylphenylsilane The Dichloromethylphenylsilane, with its CAS NO149-7…Appearance:Colorless Transparent Liquid Storage:20℃ Package:25kg/plastic drum,200Kg/iron drum Application:silane and other Transp

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Manufacturers

inquiry

Yurui(Shanghai)Chemical Co.,Ltd

How May We Serve You UIV CHEM 4-Bromotriphenylamine 36809-26-4 in stock We can Supply HPLC\HMMR\MS report for you ,pls feel free to contact us! Capability on chemical synthesis ● Shanghai High-Tech Enterprises ● Strong R&D Team from U

UIV CHEM CM8930 CAS NO.149-74-6 Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:1 Kilogram

FOB Price: $160.0 / 180.0

Type:Lab/Research institutions

inquiry

Amadis Chemical Co., Ltd.

1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G

Methyldichlorophenylsilane

Cas:149-74-6

Min.Order:10 Milligram

Negotiable

Type:Lab/Research institutions

inquiry

HENAN SUNLAKE ENTERPRISE CORPORATION

HENAN SUNLAKE ENTERPRISE CORPORATION Our company advantages: 1、The highest quality with the competitive price. 2、Professional human services. 3、The fastest and safest delivery service. 4、The faster and safest delivery service. 5、The hig

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Changzhou Extraordinary Pharmatech co.,LTD

Changzhou Extraordinary Pharmatech co., LTD. As a leading chemical manufacturer and supplier in China.DAS authentication is passed.We can provide the popular precursor chemicals, we have our own strong R & D team, have our own laboratories and fa

Methylphenyldichlorosilane

Cas:149-74-6

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Changzhou Pesan Chemical Co.,Ltd

Strong R&D strength and team We have a R&D team with around 30 R&D personnel.All of our employees have chemical backgrounds and have worked in the chemical industry for many years.Our laboratory can synthesize target products with wei

Dichloro(methyl)phenylsilane 149-74-6

Cas:149-74-6

Min.Order:1 Kilogram

FOB Price: $1.0 / 9999.0

Type:Other

inquiry

Zhengzhou Kingorgchem Chemical Technology Co., Ltd.

1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

Dichloromethylphenylsilane

Cas:149-74-6

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

methylphenylsilane
766-08-5

methylphenylsilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With trichloroisocyanuric acid In dichloromethane Heating;95.5%
With copper(l) iodide; copper dichloride In diethyl ether at 20℃; for 3h; Inert atmosphere;94.2%
With tellurium tetrachloride In benzene for 4.5h; Heating;90%
With hydrogenchloride; ether adduct of tris(pentafluorophenyl)boron In toluene at 20℃; for 16h; Schlenk technique; Inert atmosphere; Cooling with liquid nitrogen;99 %Spectr.
With dichloromethane; eosin y at 20℃; for 8h; Reagent/catalyst; Sealed tube; Inert atmosphere; Irradiation; Green chemistry;99 %Spectr.
Dichloromethylsilane
75-54-7

Dichloromethylsilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With benzene In neat (no solvent) CH3SiHCl2 and C6H6 with a silylboron acid ester as catalyst at 200-210°C;;46%
With C6H6; tris(trimethylsilyl)borate In neat (no solvent) (CH3)SiHCl2 and benzene at 200°C;;46%
With benzene; tris(trimethylsilyl)borate In neat (no solvent) (CH3)SiHCl2 and benzene at 200°C;;46%
tetramethylsilane
75-76-3

tetramethylsilane

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
aluminium trichloride at 120℃; for 3h; in autoclave;25%
tetramethylsilane
75-76-3

tetramethylsilane

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

A

chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
aluminium trichloride at 120℃; for 3h; Product distribution; in autoclave;A 25%
B 25%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

tetraphenylsilane
1048-08-4

tetraphenylsilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With zirconium(IV) chloride
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

phenylmagnesium bromide

phenylmagnesium bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With diethyl ether
In tetrahydrofuran at 20℃; Kinetics; Further Variations:; Solvents; Reaction partners;
In tetrahydrofuran at 20℃; Kinetics; Further Variations:; Reaction partners;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

chlorobenzene
108-90-7

chlorobenzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
at 400℃; unter Druck;
at 20 - 540℃; under 750.075 Torr; for 0.00138889h; Product distribution / selectivity; Gas phase;
With cleavable disilane at 540 - 590℃; under 750.075 Torr; for 0.00138889h; Product distribution / selectivity; Gas phase;
With dicumene at 590℃; under 750.075 Torr; for 0.00138889h; Product distribution / selectivity; Gas phase;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

benzene
71-43-2

benzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

bromobenzene
108-86-1

bromobenzene

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

A

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With magnesium 1) ether, 2) ether; Multistep reaction;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

triphenylphosphine
603-35-0

triphenylphosphine

A

phenylphosphane
638-21-1

phenylphosphane

B

diphenylphosphane
829-85-6

diphenylphosphane

C

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
nickel Heating;A n/a
B n/a
C 1.6 mol
1,2,3,4,5,7-hexaphenyl-7-methyl-7-silanorbornadiene

1,2,3,4,5,7-hexaphenyl-7-methyl-7-silanorbornadiene

A

pentaphenylbenzene
18631-82-8

pentaphenylbenzene

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In tetrachloromethane for 1.66667h; Irradiation;
chloro(methyl)phenylsilane
1631-82-9

chloro(methyl)phenylsilane

A

methylphenylsilane
766-08-5

methylphenylsilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With tetrabutylammomium bromide at 120℃; for 24h; Equilibrium constant; Further Variations:; Temperatures; Disproportionation;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

metaboric acid
13460-50-9

metaboric acid

benzene
71-43-2

benzene

A

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
at 250℃; under 58840.6 Torr;
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; Kinetics; Further Variations:; Solvents; Reaction partners;
In diethyl ether
In diethyl ether; toluene
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

chlorobenzene
108-90-7

chlorobenzene

A

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In diethyl ether at 64℃; for 0.166667h; Product distribution / selectivity; Grignard Reaction;
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

A

diphenylsilyl chloride
1631-83-0

diphenylsilyl chloride

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In diethyl ether; toluene at 58℃; for 0.225h; Product distribution / selectivity; Grignard Reaction;A 17.5 %Chromat.
B 5.7 %Chromat.
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

diethyl ether
60-29-7

diethyl ether

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

A

dichloro(ethyl)methylsilane
4525-44-4

dichloro(ethyl)methylsilane

B

biphenyl
92-52-4

biphenyl

C

ethoxy(methyl)dichlorosilane
1825-75-8

ethoxy(methyl)dichlorosilane

D

methyldiphenylsilane
776-76-1

methyldiphenylsilane

E

chloro(methyl)phenylsilane
1631-82-9

chloro(methyl)phenylsilane

F

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

G

chlorobenzene
108-90-7

chlorobenzene

H

benzene
71-43-2

benzene

I

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In toluene at 61 - 62℃; for 0.316667 - 0.35h; Product distribution / selectivity;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

diethyl ether
60-29-7

diethyl ether

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

A

biphenyl
92-52-4

biphenyl

B

methyldiphenylsilane
776-76-1

methyldiphenylsilane

C

chloro(methyl)phenylsilane
1631-82-9

chloro(methyl)phenylsilane

D

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

E

chlorobenzene
108-90-7

chlorobenzene

F

toluene
108-88-3

toluene

G

benzene
71-43-2

benzene

H

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
In n-heptane at 58 - 59℃; for 0.35 - 0.366667h; Product distribution / selectivity;
Dichloromethylsilane
75-54-7

Dichloromethylsilane

A

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With chlorobenzene In neat (no solvent) (CH3)SiHCl2 and C6H5Cl at 450°C;;
With chlorobenzene In neat (no solvent) (CH3)SiHCl2 and C6H5Cl at 450°C;;
methyl pentachlorodisilane
26980-40-5

methyl pentachlorodisilane

A

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With chlorobenzene In neat (no solvent) passing (CH3)Cl2SiSiCl3 and C6H5Cl through a tube at 520°C;;
silicon
7440-21-3

silicon

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With methylene chloride; benzene; copper In neat (no solvent) Si-Cu and a mixt. of CH3Cl and C6H6 at 350°C;;
With methylene chloride; benzene; copper In neat (no solvent) Si-Cu and a mixt. of CH3Cl and C6H6 at 350°C;;
chloro-trimethyl-silane
75-77-4

chloro-trimethyl-silane

Phenyltrichlorosilane
98-13-5

Phenyltrichlorosilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
aluminium trichloride In neat (no solvent) (CH3)3SiCl and (C6H5)SiCl3 at 325°C;;
aluminium trichloride In neat (no solvent) (CH3)3SiCl and (C6H5)SiCl3 at 325°C;;
tetrachlorosilane
10026-04-7, 53609-55-5

tetrachlorosilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With CH3MgBr; C6H5MgBr In not given
bromobenzene
108-86-1

bromobenzene

1,1,2,2-tetrachloro-1,2-dimethyldisilane
4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

A

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

B

diphenylsilyl dichloride
80-10-4

diphenylsilyl dichloride

C

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) at 160℃; for 24h; Inert atmosphere; neat (no solvent);
1,1,2,2-tetrachloro-1,2-dimethyldisilane
4518-98-3

1,1,2,2-tetrachloro-1,2-dimethyldisilane

chlorobenzene
108-90-7

chlorobenzene

A

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

B

diphenylsilyl dichloride
80-10-4

diphenylsilyl dichloride

C

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0) at 160℃; for 24h; Inert atmosphere; neat (no solvent);
Dichloromethylsilane
75-54-7

Dichloromethylsilane

benzene
71-43-2

benzene

A

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

B

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With 20percent Boria / 80percent Alumina - Graphite Binder at 250℃; under 77.5728 Torr; for 4h; Pressure; Reagent/catalyst; Time; Sealed tube;A 6.74 %Chromat.
B 25.44 %Chromat.
phenyl(chloromethyl)dihydrosilane
42976-56-7

phenyl(chloromethyl)dihydrosilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
With dichloromethane; eosin y at 20℃; for 4h; Reagent/catalyst; Inert atmosphere; Green chemistry;99 %Spectr.
bromobenzene
108-86-1

bromobenzene

Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

Conditions
ConditionsYield
Stage #1: bromobenzene With magnesium In tetrahydrofuran at 20℃; for 4h; Inert atmosphere;
Stage #2: Methyltrichlorosilane In tetrahydrofuran at -78 - 20℃; for 12h; Inert atmosphere; Schlenk technique;
iodobenzene
591-50-4

iodobenzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

biphenyl
92-52-4

biphenyl

Conditions
ConditionsYield
With potassium hydroxide; palladium on activated charcoal In water at 100℃;100%
With potassium hydroxide; palladium on activated charcoal In water Heating;100%
p-nitrobenzene iodide
636-98-6

p-nitrobenzene iodide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

1-phenyl-4-nitrobenzene
92-93-3

1-phenyl-4-nitrobenzene

Conditions
ConditionsYield
With potassium hydroxide; palladium on activated charcoal In water Heating;100%
m-iodonitrobenzene
645-00-1

m-iodonitrobenzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

3-nitro-1,1'-biphenyl
2113-58-8

3-nitro-1,1'-biphenyl

Conditions
ConditionsYield
With potassium hydroxide; palladium on activated charcoal In water Heating;100%
o-nitroiodobenzene
609-73-4

o-nitroiodobenzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

2-nitrobiphenyl
86-00-0

2-nitrobiphenyl

Conditions
ConditionsYield
With potassium hydroxide; palladium on activated charcoal In water Heating;100%
2-hydroxybromobenzene
95-56-7

2-hydroxybromobenzene

1-bromo-2-(phenylethenyl)benzene
21375-88-2

1-bromo-2-(phenylethenyl)benzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

(2-bromophenoxy)(methyl)(phenyl)(2-(phenylethynyl)phenyl)silane

(2-bromophenoxy)(methyl)(phenyl)(2-(phenylethynyl)phenyl)silane

Conditions
ConditionsYield
Stage #1: 1-bromo-2-(phenylethenyl)benzene With tert.-butyl lithium In tetrahydrofuran; pentane at -70℃; for 0.416667h; Schlenk technique; Inert atmosphere;
Stage #2: dichloromethylphenylsilane In tetrahydrofuran; pentane at -70 - 20℃; for 7.58333h; Schlenk technique; Inert atmosphere;
Stage #3: 2-hydroxybromobenzene In tetrahydrofuran; pentane at 35℃; for 48h; Schlenk technique; Inert atmosphere;
100%
tert-butylamine
75-64-9

tert-butylamine

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

N-tert-butyl-1-chloro-1-methyl-1-phenylsilaneamine

N-tert-butyl-1-chloro-1-methyl-1-phenylsilaneamine

Conditions
ConditionsYield
In dichloromethane at 20℃;99%
In hexane for 12h; Inert atmosphere;94.2%
n-octyne
629-05-0

n-octyne

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

methyldi(oct-1-yn-1-yl)(phenyl)silane
1422469-25-7

methyldi(oct-1-yn-1-yl)(phenyl)silane

Conditions
ConditionsYield
Stage #1: n-octyne With n-butyllithium In tetrahydrofuran-d8 at -78℃; for 0.5h; Inert atmosphere;
Stage #2: dichloromethylphenylsilane In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;
99%
allyl bromide
106-95-6

allyl bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

diallyl(methyl)(phenyl)silane
2633-60-5

diallyl(methyl)(phenyl)silane

Conditions
ConditionsYield
Stage #1: allyl bromide With indium In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: dichloromethylphenylsilane In N,N-dimethyl-formamide at 20℃; for 3h;
98%
With zinc In tetrahydrofuran for 0.166667h; Inert atmosphere; Sonication;78%
4-but-1-enylmagnesium bromide
7103-09-5

4-but-1-enylmagnesium bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

C15H22Si

C15H22Si

Conditions
ConditionsYield
In tetrahydrofuran at 0 - 20℃; for 19h; Inert atmosphere;98%
tert-butyl alcohol
75-65-0

tert-butyl alcohol

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

tert-butoxychloromethylphenylsilane

tert-butoxychloromethylphenylsilane

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In toluene at 110℃; for 1.5h; Solvent; Reagent/catalyst; Temperature; Inert atmosphere;98%
1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

dibenzhydryloxymethylphenylsilane

dibenzhydryloxymethylphenylsilane

Conditions
ConditionsYield
With pyridine In diethyl ether for 8h; Heating;97%
5-bromo-1-methyl-1H-pyrrole-2-carboxylic acid
56454-27-4

5-bromo-1-methyl-1H-pyrrole-2-carboxylic acid

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

bis(1-methylpyrrol-2-yl)methylphenylsilane

bis(1-methylpyrrol-2-yl)methylphenylsilane

Conditions
ConditionsYield
With tetrabutylammomium bromide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide at 20℃; Silylation; Electrochemical reaction;97%
ethyl cinnamate
4192-77-2

ethyl cinnamate

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

3,3-diphenyl-propionic acid ethyl ester
7476-18-8

3,3-diphenyl-propionic acid ethyl ester

Conditions
ConditionsYield
Stage #1: dichloromethylphenylsilane With potassium carbonate In toluene at 20℃; for 2h;
Stage #2: ethyl cinnamate With water; [Rh(OH)(cod)]2 In toluene at 120℃; for 41h;
97%
allylsamarium bromide
346713-20-0

allylsamarium bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

diallyl(methyl)(phenyl)silane
2633-60-5

diallyl(methyl)(phenyl)silane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 2h;97%
3-Bromo-but-1-yne
113647-42-0, 18668-72-9

3-Bromo-but-1-yne

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

di-(buta-1,2-dienyl)methylphenylsilane
1097204-68-6

di-(buta-1,2-dienyl)methylphenylsilane

Conditions
ConditionsYield
Stage #1: 3-Bromo-but-1-yne With indium In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: dichloromethylphenylsilane In N,N-dimethyl-formamide at 20℃; for 3h;
97%
propargyl bromide
106-96-7

propargyl bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

diallenylmethylphenylsilane
1097204-63-1

diallenylmethylphenylsilane

Conditions
ConditionsYield
Stage #1: propargyl bromide With indium In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: dichloromethylphenylsilane In N,N-dimethyl-formamide at 20℃; for 3h;
97%
1-Heptyne
628-71-7

1-Heptyne

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

di(hept-1-yn-1-yl)(methyl)(phenyl)silane
1267750-09-3

di(hept-1-yn-1-yl)(methyl)(phenyl)silane

Conditions
ConditionsYield
Stage #1: 1-Heptyne With n-butyllithium In tetrahydrofuran-d8 at -78℃; for 0.5h; Inert atmosphere;
Stage #2: dichloromethylphenylsilane In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;
97%
disodium salicylhydroxamate

disodium salicylhydroxamate

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

6-Methyl-6-phenyl-5,7-dioxa-8-aza-6-sila-benzocyclohepten-9-one

6-Methyl-6-phenyl-5,7-dioxa-8-aza-6-sila-benzocyclohepten-9-one

Conditions
ConditionsYield
In methanol; benzene Heating;96%
1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine
63226-47-1

1,3-diallyl-4-(trimethylsilyloxy)-2,6-dioxo-1,3,5-triazine

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

C25H28N6O6Si

C25H28N6O6Si

Conditions
ConditionsYield
at 120 - 160℃;95%
phenylacetylene
536-74-3

phenylacetylene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

bis(phenylethynylene)methylphenylsilane
23024-19-3

bis(phenylethynylene)methylphenylsilane

Conditions
ConditionsYield
With [{Ir(μ-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine; lithium iodide at 90℃; for 24h; Schlenk technique; Inert atmosphere;95%
Stage #1: phenylacetylene With n-butyllithium In tetrahydrofuran-d8 at -78℃; for 0.5h; Inert atmosphere;
Stage #2: dichloromethylphenylsilane In tetrahydrofuran at 20℃; for 12h; Inert atmosphere;
85%
In various solvent(s) electrolysis;56%
Stage #1: phenylacetylene With n-butyllithium
Stage #2: dichloromethylphenylsilane
With n-butyllithium In tetrahydrofuran at -78℃;
cyclohexenone
930-68-7

cyclohexenone

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

3-phenylcyclohexanone
20795-53-3

3-phenylcyclohexanone

Conditions
ConditionsYield
With air; sodium fluoride; rhodium(I)-bis(1,5-cyclooctadiene) tetrafluoroborate at 100℃; for 12h;95%
Stage #1: dichloromethylphenylsilane With potassium carbonate In toluene at 20℃; for 2h;
Stage #2: cyclohexenone With water; [Rh(OH)(cod)]2 In toluene at 120℃; for 24h;
70%
allylsamarium bromide
346713-20-0

allylsamarium bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

allylchloro(methyl)phenylsilane
112945-35-4

allylchloro(methyl)phenylsilane

Conditions
ConditionsYield
In tetrahydrofuran at 20℃; for 1h;95%
trimethylsilylacetylene
1066-54-2

trimethylsilylacetylene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

bis(trimethylsilylethynyl)phenyl(methyl)silane
1290083-26-9

bis(trimethylsilylethynyl)phenyl(methyl)silane

Conditions
ConditionsYield
With [{Ir(μ-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine; lithium iodide at 90℃; for 24h; Schlenk technique; Inert atmosphere;95%
Methyltrichlorosilane
75-79-6

Methyltrichlorosilane

phenylmagnesium chloride
100-59-4

phenylmagnesium chloride

chlorobenzene
108-90-7

chlorobenzene

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

chloromethyldiphenylsilane
144-79-6

chloromethyldiphenylsilane

Conditions
ConditionsYield
In diethyl ether at 67℃; for 0.166667h; Product distribution / selectivity; Grignard Reaction;94.11%
dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

methyldifluorophenylsilane
328-57-4

methyldifluorophenylsilane

Conditions
ConditionsYield
With sodium tetrafluoroborate In various solvent(s) for 0.75h; Heating;94%
With zinc(II) fluoride
With potassium hydrogen bifluoride
sodium salicylhydroxamate

sodium salicylhydroxamate

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

2-(Chloro-methyl-phenyl-silanyloxy)-N-hydroxy-benzamide

2-(Chloro-methyl-phenyl-silanyloxy)-N-hydroxy-benzamide

Conditions
ConditionsYield
In methanol; benzene Heating;94%
2-bromofuran
584-12-3

2-bromofuran

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

di(2-furyl)(methyl)phenylsilane
217322-06-0

di(2-furyl)(methyl)phenylsilane

Conditions
ConditionsYield
With tetrabutylammomium bromide In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide 2:1 substrate/PhMeSiCl2 ratio, electrochemical conditions (Mg anode, 2.2 F.mol-1);94%
1-Bromo-2-butyne
3355-28-0

1-Bromo-2-butyne

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

di-(1-methylallenyl)methylphenylsilane
1097204-67-5

di-(1-methylallenyl)methylphenylsilane

Conditions
ConditionsYield
Stage #1: 1-Bromo-2-butyne With indium In N,N-dimethyl-formamide at 20℃; for 1h;
Stage #2: dichloromethylphenylsilane In N,N-dimethyl-formamide at 20℃; for 3h;
94%
2-bromo-1-(trimethylsilylethynyl)benzene
38274-16-7

2-bromo-1-(trimethylsilylethynyl)benzene

allylmagnesium bromide
1730-25-2

allylmagnesium bromide

dichloromethylphenylsilane
149-74-6

dichloromethylphenylsilane

C18H18Si

C18H18Si

Conditions
ConditionsYield
Stage #1: 2-bromo-1-(trimethylsilylethynyl)benzene With n-butyllithium In tetrahydrofuran at -78℃; for 1h;
Stage #2: dichloromethylphenylsilane In tetrahydrofuran at -78 - 50℃; for 6h;
Stage #3: allylmagnesium bromide Further stages;
94%

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