Product Name

  • Name

    Titanium tetrafluoride

  • EINECS 232-017-6
  • CAS No. 7783-63-3
  • Article Data63
  • CAS DataBase
  • Density 2.798g/cm3
  • Solubility Insoluble in water.
  • Melting Point >400ºC
  • Formula F4Ti
  • Boiling Point 284ºC
  • Molecular Weight 123.874
  • Flash Point
  • Transport Information UN 3260
  • Appearance white powder
  • Safety 26-27-28-36/37/39-45
  • Risk Codes R20/21/22;R34   
  • Molecular Structure Molecular Structure of 7783-63-3 (Titanium tetrafluoride)
  • Hazard Symbols CorrosiveC
  • Synonyms Titaniumfluoride (TiF4) (6CI,8CI);Titanium tetrafluoride;Titanium(4+) fluoride;Titanium(IV) fluoride;
  • PSA 0.00000
  • LogP 1.68080

Synthetic route

stannous fluoride

stannous fluoride

titanium
7440-32-6

titanium

A

tin
7440-31-5

tin

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In melt Kinetics; placing of mixt. of Ti with SnF2 (molar ratio SnF2:Ti=4.04) in Fluoroplast-4 ampule, closing by screwed stopper, exposition for 1.00 h at 230°C; various product ratio yields for various conditions; cooling, stirring up in water, collection, drying;A 13.8%
B n/a
titanium
7440-32-6

titanium

chlorine trifluoride
7790-91-2

chlorine trifluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride reaction of ClF3 with Ti in HF-suspension at -78°C;;
In hydrogen fluoride HF (liquid); reaction of ClF3 with Ti in HF-suspension at -78°C;;
titanium
7440-32-6

titanium

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With hydrogen fluoride In water byproducts: H2; at room temp.;
With fluorine gentle heating;
With hydrogen fluoride byproducts: H2; at red heat;
hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride
100-120°C;
HF free of water;;
titanium(III) fluoride
13470-08-1

titanium(III) fluoride

hydrogen fluoride
7664-39-3

hydrogen fluoride

A

hydrogen
1333-74-0

hydrogen

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In water Kinetics;
titanium(IV) oxyfluoride

titanium(IV) oxyfluoride

hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
Kinetics; 220 to 400°C, 0.2 to 1 atm HF;
hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) oxide

titanium(IV) oxide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
Kinetics; byproducts: oxide, fluorides; => 200°C;
With sulfuric acid In water0%
antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: HCl; vigorous reaction;
byproducts: HCl; vigorous reaction;
titanium(IV) oxide

titanium(IV) oxide

A

fluoroboroxine
13703-95-2

fluoroboroxine

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With boron trifluoride at 500°C;
With BF3 at 500°C;
Dichlorodifluoromethane
75-71-8

Dichlorodifluoromethane

titanium(IV) oxide

titanium(IV) oxide

A

TiCl2F2

TiCl2F2

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C

titanium tetrachloride
7550-45-0

titanium tetrachloride

Conditions
ConditionsYield
In neat (no solvent) reaction at 700-750°C;;
titanium
7440-32-6

titanium

hydrogen fluoride
7664-39-3

hydrogen fluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: H2; red heat;
titanium
7440-32-6

titanium

fluorine
7782-41-4

fluorine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With Ar In neat (no solvent) at 150°C for 2 d;
In neat (no solvent)
(O2)2Ti7F30

(O2)2Ti7F30

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With F2; Ar In hydrogen fluoride HF (liquid); 300°C, 1 d, cooling (20°C/d to room temp., 3 weeks);
barium fluorotitanate
31252-79-6

barium fluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: BaF2; glowing;
chloryl fluoride
13637-83-7

chloryl fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

2ClO2(1+)*TiF6(2-)=(ClO2)2TiF6

2ClO2(1+)*TiF6(2-)=(ClO2)2TiF6

B

chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

C

chlorine
7782-50-5

chlorine

D

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In neat (no solvent) at -100°C;;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2; UF6 in excess;
byproducts: Cl2; UF6 in excess;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

C

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2; TiCl4 in excess;
byproducts: Cl2; TiCl4 in excess;
uranium hexafluoride
7783-81-5

uranium hexafluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: Cl2, UF4; TiCl4 in excess;
byproducts: Cl2, UF4; TiCl4 in excess;
β-uranium(V) fluoride
13775-07-0

β-uranium(V) fluoride

titanium tetrachloride
7550-45-0

titanium tetrachloride

A

uranium hexachloride
13763-23-0

uranium hexachloride

B

uranium(IV) tetrafluoride
10049-14-6

uranium(IV) tetrafluoride

C

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

ammonium hexafluorotitanate

ammonium hexafluorotitanate

A

ammonium fluoride

ammonium fluoride

B

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
heating in N2-stream, NH4F evolution above 100°C, TiF4-loss from 150°C;
heating in N2-stream, NH4F evolution above 100°C, TiF4-loss from 150°C;
titanium oxyfluoride
13537-16-1

titanium oxyfluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: TiO2; by heating;
titanium oxyfluoride
13537-16-1

titanium oxyfluoride

A

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

B

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
decompn. at 600°C;
titanium(IV) oxide

titanium(IV) oxide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With boron trifluoride 500°C;
With BF3
lithium hexafluorotitanate

lithium hexafluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: F2; above 900°C;
byproducts: F2; above 900°C;
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: C5H5N; heating in moist. air;
Ba(2+)*TiF6(2-)*0.5H2O=Ba{TiF6}*0.5H2O

Ba(2+)*TiF6(2-)*0.5H2O=Ba{TiF6}*0.5H2O

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
very strong heating;
very strong heating;
ammonium pentafluoroperoxotitanate

ammonium pentafluoroperoxotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
With hydrogen fluoride In water byproducts: H2O2;
With HF In water
magnesium hexafluorotitanate

magnesium hexafluorotitanate

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
byproducts: H2O; at 300°C;
byproducts: H2O; at 300°C;
titanium
7440-32-6

titanium

fluorine
7782-41-4

fluorine

A

titanium(III) fluoride
13470-08-1

titanium(III) fluoride

B

TiF

TiF

C

titanium(II) fluoride

titanium(II) fluoride

D

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In solid matrix Irradiation (UV/VIS); Ti atoms evapd., trapped in F2/Ar matrix at ca 10 K, photolyzed using Hg-Xe, annealed to 25 K; not isolated, detected by IR;
titanium(III) fluoride
13470-08-1

titanium(III) fluoride

fluorine
7782-41-4

fluorine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Conditions
ConditionsYield
In hydrogen fluoride HF (liquid);
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

trimethylsilylazide
4648-54-8

trimethylsilylazide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C10H8N14Ti

C10H8N14Ti

Conditions
ConditionsYield
In acetonitrile at -196 - 20℃; for 8h;100%
1,10-Phenanthroline
66-71-7

1,10-Phenanthroline

trimethylsilylazide
4648-54-8

trimethylsilylazide

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

C12H8N14Ti

C12H8N14Ti

Conditions
ConditionsYield
In acetonitrile at -196 - 20℃; for 16h;100%
1,2-bis(dimethylphosphanyl)ethane
23936-60-9

1,2-bis(dimethylphosphanyl)ethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

(TiF4((CH3)2PCH2CH2P(CH3)2))
1258515-14-8

(TiF4((CH3)2PCH2CH2P(CH3)2))

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 2 h; solvent was removed in vacuo, residue was washed with hexane, filtered off and dried in vacuo; elem. anal.;91%
15-crown-5
33100-27-5

15-crown-5

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[(titanium)(fluorine)2([15]crown-5][(titanium)4(fluorine)18]*0.5MeCN

[(titanium)(fluorine)2([15]crown-5][(titanium)4(fluorine)18]*0.5MeCN

Conditions
ConditionsYield
In acetonitrile soln. of (15)crown-5 in MeCN added to soln. of TiF4 in MeCN; concd., stored at room temp. for several h; elem. anal.;90%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

1,3,4,5-tetramethylimidazol-2-ylidene
141556-40-3

1,3,4,5-tetramethylimidazol-2-ylidene

trans-TiF4(1,3,4,5-tetramethylimidazol-2-ylidene)2

trans-TiF4(1,3,4,5-tetramethylimidazol-2-ylidene)2

Conditions
ConditionsYield
In tetrahydrofuran (N2); addn. of THF soln. of titanium fluoride to THF soln. of imidazole deriv. at -79°C, stiring for 30 min at -79°C, warming to room temp., stirring for 6 h at room temp.; filtration, washing with THF, drying in vac., recrystn. (CH2Cl2), elem. anal.;90%
dichloromethane
75-09-2

dichloromethane

1,2-bis(dimethylphosphino)benzene
7237-07-2

1,2-bis(dimethylphosphino)benzene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[TiF4(o-C6H4(PMe3)2)]*CH2Cl2

[TiF4(o-C6H4(PMe3)2)]*CH2Cl2

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 1 h; solvent was removed in vacuo, residue was triturated with hexane and stirred for 2 h, ppt. was filtered off and dried in vacuo; elem. anal.;85%
2,2,6,6-tetramethylheptane-3,5-dione
1118-71-4

2,2,6,6-tetramethylheptane-3,5-dione

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(dipivaloylmethanide)2F2

Ti(dipivaloylmethanide)2F2

Conditions
ConditionsYield
In dichloromethane dry N2-atmosphere; refluxing for 6 h; elem. anal.;84%
1,1,1-trifluoro-4-(2-thienyl)butane-2,4-dione

1,1,1-trifluoro-4-(2-thienyl)butane-2,4-dione

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

difluorobis[1,1,1-trifluoro-4-(2'-thienyl)butane-2,4-dionato] titanium(IV)

difluorobis[1,1,1-trifluoro-4-(2'-thienyl)butane-2,4-dionato] titanium(IV)

Conditions
ConditionsYield
In dichloromethane TiF4 refluxed in CH2Cl2 with the organic compound for 12 h, soln. cooled; filtered, concentrated under a stream of N2, hexane added, recrystd. from CH2Cl2-hexane; elem. anal.;83%
bis(acetylacetonate)oxidovanadium(IV)

bis(acetylacetonate)oxidovanadium(IV)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(CH3COCHCOCH3)2F2
16986-93-9

Ti(CH3COCHCOCH3)2F2

B

oxo difluoro vanadium (IV)

oxo difluoro vanadium (IV)

Conditions
ConditionsYield
In n-heptane; 1,2-dichloro-ethane at 20℃; Schlenk technique; Inert atmosphere;A 81%
B n/a
15-crown-5
33100-27-5

15-crown-5

antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

trans-difluoro(15-crown-5)titanium(IV) hexafluoroantimonate(V)

trans-difluoro(15-crown-5)titanium(IV) hexafluoroantimonate(V)

Conditions
ConditionsYield
In acetonitrile under N2; solns. of TiF4 in MeCN, 15-crown-5 in MeCN and SbF5 (molar ratio 1:1:2.4) in MeCN mixed at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;80%
1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol
718-64-9

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Conditions
ConditionsYield
With BuLi In hexane; toluene byproducts: LiF; (N2); addn. of soln. of BuLi in hexane to soln. of propanol deriv. in toluenen at -78°C, stirring at -78°C for 1 h and at room temp. for 1 h, addn. to suspn. of titanium compd. in toluene at room temp.,stirring for 2 h, refluxing for 1 d; filtration, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;80%
1,2-dimethoxyethane
110-71-4

1,2-dimethoxyethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(κ2-1,2-dimethoxyethane)tetrachlorotitanium(IV)
19289-14-6

(κ2-1,2-dimethoxyethane)tetrachlorotitanium(IV)

Conditions
ConditionsYield
In dichloromethane (Ar), TiF4 in CH2Cl2 treated with 1 equiv. of ligand, stirred at room temp. for 4 h; evapd.(vac.), elem. anal.;80%
titanium(IV) oxide bis(2,4-pentanedionate)

titanium(IV) oxide bis(2,4-pentanedionate)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

Ti(CH3COCHCOCH3)2F2
16986-93-9

Ti(CH3COCHCOCH3)2F2

B

OTi(2+)*2F(1-)

OTi(2+)*2F(1-)

Conditions
ConditionsYield
In 1,2-dichloro-ethane at 20℃; Schlenk technique; Inert atmosphere;A 78%
B 80%
tetrakis(dimethylamido)titanium(IV)

tetrakis(dimethylamido)titanium(IV)

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(TiF2(N(CH3)2)2)4
53787-11-4

(TiF2(N(CH3)2)2)4

Conditions
ConditionsYield
In acetonitrile under N2 atm. soln. TiF4 in MeCN was added soln. Ti(NMe2)4 in MeCN at room temp. and stirred for 30 min; ppt. was filtered, washed with MeCN, and dried in vacuo overnight; elem.anal.;75%
antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

fac-trifluorotris(acetonitrile)titanium(IV) hexafluoroantimonate(V)*(acetonitrile)
867253-68-7

fac-trifluorotris(acetonitrile)titanium(IV) hexafluoroantimonate(V)*(acetonitrile)

Conditions
ConditionsYield
In acetonitrile under N2; SbF5 (1 equiv.) distd. under vac.; MeCN condensed onto SbF5 at-79°C; warmed; added to soln. of TiF4 (1 equiv.) in MeCN at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;70%
In acetonitrile under N2; SbF5 (2 or 3 equiv.) distd. under vac.; MeCN condensed onto SbF5 at -79°C; warmed; added to soln. of TiF4 (1 equiv.) in MeCN atroom temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2;
tetrahydrofuran
109-99-9

tetrahydrofuran

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

cis-[(THF)2TiF4]
30116-61-1

cis-[(THF)2TiF4]

Conditions
ConditionsYield
In tetrahydrofuran (N2) soln. TiF4 in THF was stirred for 30 min; soln. was filtered, concd. in vacuo and refrigerated for 24 h, ppt. was filtered off and dried in vacuo; elem. anal.;69%
Schlenk technique; Glovebox; Inert atmosphere;
dichloromethane
75-09-2

dichloromethane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[TiF4(Et2P(CH2)2PEt2)]*CH2Cl2

[TiF4(Et2P(CH2)2PEt2)]*CH2Cl2

Conditions
ConditionsYield
In dichloromethane (N2) TiF4 was dissolved in MeCN, soln. was filtered and evapd. in vacuo,residue was dissolved in CH2Cl2, ligand was added dropwise, stirred for 2 h; solvent was removed in vacuo, residue was stirred overnight with hexane and CH2Cl2, ppt. was filtered off and dried in vacuo; elem. anal.;68%
5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene
189832-67-5

5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[(TiF)2(μ-F)(p-tert-butylcalix[6]arene(-5H))]2*6.5(acetonitrile)

[(TiF)2(μ-F)(p-tert-butylcalix[6]arene(-5H))]2*6.5(acetonitrile)

Conditions
ConditionsYield
Stage #1: 5,11,17,23,29,35-hexakis(tert-butyl)-37,38,39,40,41-hexakis(hydroxy)calix[6]arene; titanium(IV) fluoride In toluene for 12h; Reflux; Inert atmosphere;
Stage #2: acetonitrile at 0℃; for 48h; Inert atmosphere;
68%
Ti(O2CNEt2)4
62532-34-7

Ti(O2CNEt2)4

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

TiF2(O2CNEt2)2

TiF2(O2CNEt2)2

Conditions
ConditionsYield
In dichloromethane at 24.84℃; for 30h; Schlenk technique; Reflux; Inert atmosphere;66%
N-tris(pentafluorobenzyl)-B-trichloroborazine
14560-21-5

N-tris(pentafluorobenzyl)-B-trichloroborazine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

N-tris(pentafluorobenzyl)-B-trifluoroborazine
15057-92-8

N-tris(pentafluorobenzyl)-B-trifluoroborazine

Conditions
ConditionsYield
64%
64%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

lithium hexamethyldisilazane
4039-32-1

lithium hexamethyldisilazane

fluoro-tris(bis-trimethylsilyl-amido)titanum
157369-02-3

fluoro-tris(bis-trimethylsilyl-amido)titanum

Conditions
ConditionsYield
In tetrahydrofuran byproducts: LiF; Ar; stoichiometric amounts; room temperature; stirring for 1 d;; evapn. to dryness; addn. of hexane; filtration on celite; solvent concentration; crystn. upon cooling to -30 ° C; ekem. anal.;;60%
18-crown-6 ether
17455-13-9

18-crown-6 ether

antimony pentafluoride
7783-70-2

antimony pentafluoride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

trans-difluoro(18-crown-6)titanium(IV) hexafluoroantimonate(V)

trans-difluoro(18-crown-6)titanium(IV) hexafluoroantimonate(V)

Conditions
ConditionsYield
In acetonitrile under N2; solns. of TiF4 in MeCN, 18-crown-6 in MeCN and SbF5 (molar ratio 1:1:3) in MeCN mixed at room temp.; filtered; concd.; left at 5°C for 5 d; filtered; crystals washed with cold (-20 to -40°C) CH2Cl2; elem. anal.;60%
titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

2,8-dimethylnonane-4,6-dione
7307-08-6

2,8-dimethylnonane-4,6-dione

Ti(diisobutyrylmethanide)2F2

Ti(diisobutyrylmethanide)2F2

Conditions
ConditionsYield
In dichloromethane dry N2-atmosphere; refluxing for 5.5 h; elem. anal.;60%
p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene
1313016-01-1

p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

acetonitrile
75-05-8

acetonitrile

[Ti4F14(p-methyl-dimethyldiazacalix[6]arene)H2(H)2]·2.5MeCN

[Ti4F14(p-methyl-dimethyldiazacalix[6]arene)H2(H)2]·2.5MeCN

Conditions
ConditionsYield
Stage #1: p-methyl-N,N'-dimethyldiazacalix[3.1.1.3.1.1]arene; titanium(IV) fluoride In toluene for 12h; Inert atmosphere; Schlenk technique; Reflux;
Stage #2: acetonitrile Inert atmosphere; Schlenk technique;
56%
diphenylboronchloride
3677-81-4

diphenylboronchloride

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

(diphenyl)fluoroborane
36140-35-9

(diphenyl)fluoroborane

Conditions
ConditionsYield
stirring for 1 h; distn.;54%
stirring for 1 h; distn.;54%
B-trichloro-N-triphenylborazine
981-87-3

B-trichloro-N-triphenylborazine

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

2,4,6-trifluoro-1,3,5-triphenyl-borazine
1960-46-9

2,4,6-trifluoro-1,3,5-triphenyl-borazine

Conditions
ConditionsYield
52%
52%
titanium tetra-n-propoxide

titanium tetra-n-propoxide

cyanex-921
78-50-2

cyanex-921

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

titanium(IV) oxide

titanium(IV) oxide

Conditions
ConditionsYield
In further solvent(s) byproducts: FCH(CH3)2; addn. of phosphine oxide to soln. of Ti-halide in heptadecane, heating (N2-atmosphere, 300°C), rapid addn. of 1 equiv. of Ti-alkoxide, 5 min; centrifugation, washing (acetone); XRD pattern characterisation;50%
18-crown-6 ether
17455-13-9

18-crown-6 ether

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

[(cis-TiF4)2(18-crown-6)]
847836-02-6

[(cis-TiF4)2(18-crown-6)]

Conditions
ConditionsYield
In acetonitrile Schlenk techique, under N2; CH3CN condenced into mixt. of TiF4 (6.5 mmol) + 18-crown-6 (3.0 mmol) (-79°C); warmed to 50°C; filtered; concd.; kept (room temp., 5 d); crystals filtered; washed withCH2Cl2 (from -20 to -40°C); elem. anal.;50%
1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol
718-64-9

1,1,1,3,3,3-hexafluoro-2-phenylisopropyl alcohol

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

A

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)4

(THF)2Li(μ-F)2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Li(THF)2

(THF)2Li(μ-F)2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Ti(1,1,1,3,3,3-hexafluoro-2-phenyl-2-propanolate)2F2Li(THF)2

Conditions
ConditionsYield
With MeLi In tetrahydrofuran; diethyl ether byproducts: LiF; (N2); addn. of soln. of 2 equiv. of MeLi in ether to soln. of 2 equiv. of propanol deriv. in THF at -78°C, stirring at -78°C for 1h and at room temp., addn. to soln. of titanium compd. in THF at room t emp., stirring for 2 h; evapn., keeping at room temp. for 2 d; first product: filtration, washing with CH2Cl2, drying in vac., elem. anal.; second product: evapn. of filtrate, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;A n/a
B 50%
With MeLi In tetrahydrofuran; diethyl ether byproducts: LiF; (N2); addn. of soln. of 3 equiv. of MeLi in ether to soln. of 3 equiv. of propanol deriv. in THF at -78°C, stirring at -78°C for 1h and at room temp., addn. to soln. of titanium compd. in THF at room t emp., stirring for 2 h; evapn., keeping at room temp. for 2 d; first product: filtration, washing with CH2Cl2, drying in vac., elem. anal.; second product: evapn. of filtrate, extn. (hexane), filtration, concn., keeping for 5 d at 5°C, filtration, elem. anal.;A 40%
B 30%
dibromo(phenyl)borane
4151-77-3

dibromo(phenyl)borane

titanium(IV) fluoride
7783-63-3

titanium(IV) fluoride

difluoro-phenyl-borane
368-98-9

difluoro-phenyl-borane

Conditions
ConditionsYield
C6H5BBr2 + TiF4 mixed to a pulp, after 15 min stirring it liquefies, boiled using backflow for 2 h; distn.;49%

Titanium tetrafluoride Specification

The cas register number of Titanium tetrafluoride is 7783-63-3. It also can be called as tetrafluorotitanium and the Systematic name about this chemical is titanium(+2) cation tetrafluoride. And it Classification Code are Cariostatic agents and Protective Agents.

When you are using this chemical, please be cautious about it as the following:
It is harmful by inhalation, in contact with skin and if swallowed. And it may be causes burns. If it is in case of contact with eyes, rinse immediately with plenty of water and seek medical advice and must take off immediately all contaminated clothing. After contact with skin, wash immediately with plenty of soap-suds. So people must wear suitable protective clothing, gloves and eye/face protection. In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)

People can use the following data to convert to the molecule structure.
1.SMILES: [Ti+2].[Ti+2].[F-].[F-].[F-].[F-]
2.InChI: InChI=1/4FH.2Ti/h4*1H;;/q;;;;2*+2/p-4 
3.InChIKey: VHIAGHNQBFWVPM-XBHQNQODAO
4.Std. InChI: InChI=1S/4FH.2Ti/h4*1H;;/q;;;;2*+2/p-4
5.Std. InChIKey: VHIAGHNQBFWVPM-UHFFFAOYSA-J

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