Hexamethylolmelamine supplier

Name
1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol
EINECS
CAS No. 531-18-0
Article Data17
CAS DataBase
Density 1.821g/cm³
Solubility
Melting Point 150℃
Formula C9H18 N6 O6
Boiling Point 669°Cat760mmHg
Molecular Weight 306.279
Flash Point 358.4°C
Transport Information
Appearance
Safety A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Methanol,(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- (9CI); Methanol, (s-triazine-2,4,6-triyltrinitrilo)hexa-(6CI,7CI,8CI); 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)-;2,4,6-Tris[di(hydroxymethyl)amino]-1,3,5-triazine; Cilag 61;Hexa(hydroxymethyl)melamine; Hexakis(hydroxymethyl)melamine;Hexamethylolmelamine; NSC 118741; Resloom M 75
PSA 169.77000
LogP -4.01040

Synthetic route

: 50-00-0
formaldehyd

: 108-78-1
2,4,6-triamino-s-triazine

: 531-18-0
hexa(hydroxymethyl)melamine

Conditions

Conditions	Yield
In water pH=7.5; Heating;	86%
With hydrogenchloride
With sodium hydroxide

: 50-00-0
formaldehyd

: 108-78-1
2,4,6-triamino-s-triazine

A: 1017-56-7
[1,3,5]triazine-2,4,6-triyltriamino-tris-methanol

B: 531-18-0
hexa(hydroxymethyl)melamine

...Expand

: 60-33-3
linoleic acid

: 531-18-0
hexa(hydroxymethyl)melamine

: hexa(linoleoylhydroxymethyl)melamine

Conditions

Conditions	Yield
With dmap; dicyclohexyl-carbodiimide In dichloromethane at 20℃; for 24h; Inert atmosphere;	95%

: 531-18-0
hexa(hydroxymethyl)melamine

: 35948-25-5
9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

: 66499-32-9
N,N,N',N',N'',N''-Hexakis-(10-oxo-10H-9-oxa-10λ5-phospha-phenanthren-10-ylmethyl)-[1,3,5]triazine-2,4,6-triamine

Conditions

Conditions	Yield
With benzenesulfonic acid at 165 - 240℃;	89%

: 67-56-1
methanol

: 531-18-0
hexa(hydroxymethyl)melamine

: 3089-11-0
hexakis-N-methoxymethyl-[1,3,5]triazine-2,4,6-triamine

Conditions

Conditions	Yield
With hydrogenchloride
With nitric acid In water at 45 - 55℃; for 1.5h; pH=1.5 - 3.8; Product distribution / selectivity;
With hydrogenchloride In water at 35℃; for 2h; pH=2.5; pH-value; Temperature;

: 531-18-0
hexa(hydroxymethyl)melamine

: 50693-84-0
hexakis-N-chloromethyl-[1,3,5]triazine-2,4,6-triamine

Conditions

Conditions	Yield
With phosphorus trichloride In N,N-dimethyl-formamide at 0℃;

: 531-18-0
hexa(hydroxymethyl)melamine

: 75-57-0
tetramethlyammonium chloride

: 106-89-8
epichlorohydrin

: 71-36-3
butan-1-ol

: Hexamethylolmelamineglycidyl Ether

Conditions

Conditions	Yield
With sodium hydroxide In water
With sodium hydroxide In water

...Expand

: 531-18-0
hexa(hydroxymethyl)melamine

: C9H24N12

Conditions

Conditions	Yield
With ammonia In methanol at 50 - 60℃; under 1140.08 Torr; for 2h; Inert atmosphere; Autoclave;

: 531-18-0
hexa(hydroxymethyl)melamine

: 111-42-2
2,2'-iminobis[ethanol]

: 1609117-63-6
C33H72N12O12

Conditions

Conditions	Yield
In ethanol at 60 - 80℃; for 3h;

: 531-18-0
hexa(hydroxymethyl)melamine

: 111-42-2
2,2'-iminobis[ethanol]

: C17H36N8O8

Conditions

Conditions	Yield
In ethanol at 30 - 60℃; for 3h;

: 21132-76-3
docosanoyl chloride

: 531-18-0
hexa(hydroxymethyl)melamine

: C97H184N6O16S2(2-)*2Na(1+)

Conditions

Conditions	Yield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine With chlorosulfonic acid In tetrahydrofuran at 30 - 70℃; for 2h; Stage #2: With sodium hydrogencarbonate In tetrahydrofuran

: 21132-76-3
docosanoyl chloride

: 531-18-0
hexa(hydroxymethyl)melamine

: C97H184N6O16P2(4-)*4Na(1+)

Conditions

Conditions	Yield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine With chlorophosphonic acid In tetrahydrofuran at 30 - 70℃; for 2h; Stage #2: With sodium hydrogencarbonate In tetrahydrofuran

: 21132-76-3
docosanoyl chloride

: 531-18-0
hexa(hydroxymethyl)melamine

: 144-62-7
oxalic acid

: C101H184N6O16(2-)*2Na(1+)

Conditions

Conditions	Yield
Stage #1: docosanoyl chloride; hexa(hydroxymethyl)melamine; oxalic acid In tetrahydrofuran at 30 - 70℃; for 2h; Stage #2: With sodium hydrogencarbonate In tetrahydrofuran

...Expand

: N,N-dimethylheneicosylamine

: 531-18-0
hexa(hydroxymethyl)melamine

: C147H306N12(6+)*6HO(1-)

Conditions

Conditions	Yield
In methanol at 30℃; for 2h;

: 67-56-1
methanol

: 531-18-0
hexa(hydroxymethyl)melamine

: C12H24N6O6

Conditions

Conditions	Yield
With hydrogenchloride In water at 38 - 42℃; pH=5; pH-value;

: 67-56-1
methanol

: antimony(III) trioxide

: 531-18-0
hexa(hydroxymethyl)melamine

: 71-36-3
butan-1-ol

: C16H31N6O7Sb

Conditions

Conditions	Yield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With nitric acid at 65℃; for 0.5h; pH=5.5; Stage #2: With potassium hydroxide at 50℃; pH=9; Stage #3: antimony(III) trioxide In water at 110℃; for 0.5h;

...Expand

: 67-56-1
methanol

: sodium molybdate

: 531-18-0
hexa(hydroxymethyl)melamine

: 71-36-3
butan-1-ol

: C19H36MoN6O8

Conditions

Conditions	Yield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 55℃; for 1.5h; pH=4.5; Stage #2: at 50℃; pH=8.6; Alkaline conditions; Stage #3: sodium molybdate In water at 100℃; for 1.5h;

...Expand

: 67-56-1
methanol

: sodium molybdate

: 531-18-0
hexa(hydroxymethyl)melamine

: 71-36-3
butan-1-ol

: C52H102MoN12O14

Conditions

Conditions	Yield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 65℃; for 1.66667h; pH=4.5; Stage #2: With sodium hydrogencarbonate at 50℃; pH=8.2; Stage #3: sodium molybdate In water at 100℃; for 1.5h;

...Expand

: 67-56-1
methanol

: Sodium borate

: 531-18-0
hexa(hydroxymethyl)melamine

: 71-36-3
butan-1-ol

: C34H67BN12O13

Conditions

Conditions	Yield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 55℃; for 1.66667h; pH=3.5; Stage #2: With sodium hydrogencarbonate at 50℃; pH=8.6; Stage #3: Sodium borate In water at 105℃; for 1h;

...Expand

: 67-56-1
methanol

: 531-18-0
hexa(hydroxymethyl)melamine

: 71-36-3
butan-1-ol

Sodium octoborate tetrahydrate: Sodium octoborate tetrahydrate

: C19H37BN6O7

Conditions

Conditions	Yield
Stage #1: methanol; hexa(hydroxymethyl)melamine; butan-1-ol With hydrogenchloride In water at 35℃; for 2h; pH=2.5; Stage #2: With sodium hydroxide at 50℃; pH=8; Stage #3: Sodium octoborate tetrahydrate In water at 100℃; for 2h;

...Expand

: antimony(III) trioxide

: 104-76-7
2-Ethylhexyl alcohol

: 531-18-0
hexa(hydroxymethyl)melamine

: C41H81N6O7Sb

Conditions

Conditions	Yield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With nitric acid at 65℃; for 0.5h; pH=5.5; Large scale; Stage #2: antimony(III) trioxide In water at 110℃; for 0.5h; Large scale;

...Expand

: sodium molybdate

: 104-76-7
2-Ethylhexyl alcohol

: 531-18-0
hexa(hydroxymethyl)melamine

: C98H194MoN12O14

Conditions

Conditions	Yield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 55℃; for 1.66667h; pH=4.5; Large scale; Stage #2: sodium molybdate In water at 105℃; for 1.5h; Large scale;

...Expand

: sodium molybdate

: 104-76-7
2-Ethylhexyl alcohol

: 531-18-0
hexa(hydroxymethyl)melamine

: C41H80MoN6O8

Conditions

Conditions	Yield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 55℃; for 1.33333h; pH=4.5; Large scale; Stage #2: sodium molybdate In water at 100℃; for 1.5h; Large scale;

...Expand

: Sodium borate

: 104-76-7
2-Ethylhexyl alcohol

: 531-18-0
hexa(hydroxymethyl)melamine

: C98H195BN12O13

Conditions

Conditions	Yield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 65℃; for 1.5h; pH=5.5; Large scale; Stage #2: Sodium borate In water at 105℃; for 1h; Large scale;

...Expand

: 104-76-7
2-Ethylhexyl alcohol

: disodium octaborate tetrahydrate

: 531-18-0
hexa(hydroxymethyl)melamine

: C41H81BN6O7

Conditions

Conditions	Yield
Stage #1: 2-Ethylhexyl alcohol; hexa(hydroxymethyl)melamine With hydrogenchloride In water at 35℃; for 2h; pH=2.5; Large scale; Stage #2: disodium octaborate tetrahydrate In water at 100℃; for 2h; Large scale;

...Expand

: sodium molybdate

: 531-18-0
hexa(hydroxymethyl)melamine

: 504-63-2
trimethyleneglycol

: C48H94MoN12O24

Conditions

Conditions	Yield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 55℃; for 1h; pH=4; Acidic conditions; Large scale; Stage #2: sodium molybdate In water at 105℃; for 1.5h; Large scale;

...Expand

: Sodium borate

: 531-18-0
hexa(hydroxymethyl)melamine

: 504-63-2
trimethyleneglycol

: C48H95BN12O23

Conditions

Conditions	Yield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 40℃; for 1.5h; pH=3.5; Acidic conditions; Large scale; Stage #2: Sodium borate In water at 105℃; for 1h; Large scale;

...Expand

: disodium octaborate tetrahydrate

: 531-18-0
hexa(hydroxymethyl)melamine

: 504-63-2
trimethyleneglycol

: C21H41BN6O11

Conditions

Conditions	Yield
Stage #1: hexa(hydroxymethyl)melamine; trimethyleneglycol at 35℃; for 2h; pH=2.5; Acidic conditions; Large scale; Stage #2: disodium octaborate tetrahydrate In water at 100℃; for 2h; Large scale;

...Expand

Hexamethylolmelamine Chemical Properties

IUPAC Name: [[4,6-Bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol
The MF of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is C₉H₁₈N₆O₆.

The MW of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0) is 306.27582.
Synonyms of 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol (CAS NO.531-18-0): Hexamethylolmelamine ; (1,3,5-Triazine-2,4,6-triyltrinitrilo)hexakismethanol ; Methanol, 1,1',1'',1''',1'''',1'''''-(1,3,5-triazine-2,4,6-triyltrinitrilo)hexakis- ; (s-Triazine-2,4,6-triyltrinitrilo)hexamethanol ; 1,3,5-Triazine-2,4,6-triamine, hexakis(hydroxymethyl)- ; 1,3,5-Triazine-2,4,6-triyltrinitrilohexamethanol
Index of Refraction: 1.812
EINECS: 208-503-9
Density: 1.821 g/ml
Flash Point: 358.4 °C
Boiling Point: 669 °C

Hexamethylolmelamine Toxicity Data With Reference

1.	skn-rbt 20 mg/24H MOD	85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,876.
2.	eye-rbt 100 mg/24H MOD	28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,154.
3.	ivn-mus LD50:180 mg/kg	CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems Laboratory, NIOSH Exchange Chemicals. (Aberdeen Proving Ground, MD 21010) NX#04006 .

Hexamethylolmelamine Consensus Reports

Reported in EPA TSCA Inventory.

Hexamethylolmelamine Safety Profile

A poison by intravenous route. A skin and eye irritant. When heated to decomposition it emits toxic fumes of NO_x.

Product Name

1,3,5-triazine-2,4,6-triyltrinitrilohexamethanol

Synthetic route

Hexamethylolmelamine Chemical Properties

Hexamethylolmelamine Toxicity Data With Reference

Hexamethylolmelamine Consensus Reports

Hexamethylolmelamine Safety Profile

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