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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

N,N'-Diphenylbenzidine Manufacturer/High quality/Best price/In stock

Cas:531-91-9

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

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Henan Allgreen Chemical Co.,Ltd

Conventional product Service: 1. Quick Response :within 6 hours after receive your email. 2. Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Ital

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1 Metric Ton

FOB Price: $140.0 / 150.0

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualified

Factory Supply N,N'-Diphenylbenzidine Supplier Manufacturer Good Price

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

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HUBEI RISON CHEMICAL CO.,LTD.

Founded in 2005, Wuhan Rison Trading co.,ltd is engaged in supplying various speciality chemicals, which are used for electroplating, pharmaceuticals, Oled, paint ,plastic, rubber and other industry. Our customers got to used to request package produ

N,N'-Diphenylbenzidine CAS No:531-91-9

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Other

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Simagchem Corporation

Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

High quality N,N-Diphenylbenzidine supplier in China

Cas:531-91-9

Min.Order:0 Metric Ton

Negotiable

Type:Manufacturers

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Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi

Factory Supply N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1

Negotiable

Type:Other

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Wuhan Kemi-Works Chemical Co., Ltd

Top quality best price N,N'-Diphenylbenzidine 531-91-9 global trader ISO9001 Exporting Japan, Korea regularly. N,N'-Diphenylbenzidine MF: C24H20N2 Moisture: 0.1% max Impurities: 0.5% max. N,N'-Diphenylbenzidine CAS No.

Top quality best price N,N'-Diphenylbenzidine 531-91-9 global trader

Cas:531-91-9

Min.Order:1 Gram

FOB Price: $1.0

Type:Other

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Puyang Huicheng Electronic Material Co., Ltd

Puyang Huicheng Electronic Material Co., Ltd was founded in 2002, which is focus on high complex new type intermediates and fine chemical custom synthesis, LED&OLED materials and related intermediates, catalyst design and synthesi

made in China N,N-Diphenylbenzidine

Cas:531-91-9

Min.Order:100 Gram

Negotiable

Type:Manufacturers

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Xi'an Xszo Chem Co., Ltd.

1. Factory price and high quality must be guaranteed, base on 8 years of production and R&D experience2. Free samples will be provided,ensure specifications and quality are right for customer3. Customers will receive the most professional technical s

Factory Price OLED 99% 531-91-9 [1,1'-Biphenyl]-4,4'-diamine,N4,N4'-diphenyl- Manufacturer

Cas:531-91-9

Min.Order:1 Gram

FOB Price: $0.1

Type:Manufacturers

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Hebei yanxi chemical co.,LTD.

chengdu and import and export trade co., LTD., who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do res

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:10 Kilogram

FOB Price: $500.0

Type:Trading Company

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Jinan Finer Chemical Co., Ltd

Product Description Product website: http://www.finerchem.com/pro01en/id/1427.html Product Name N,N'-Diphenylbenzidine CAS No. 531-91-9

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1 Gram

FOB Price: $22.0

Type:Lab/Research institutions

inquiry

Henan Tianfu Chemical Co., Ltd.

N,N'-Diphenylbenzidine Basic information Product Name: N,N'-Diphenylbenzidine Synonyms: N,N'-DIPHENYLBENZIDINE;N,N'-DIPHENYL BIPHENYLAMINE;SYM-DIPHENYLBENZIDINE;TIMTEC-BB

99.5% N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:100 Kilogram

FOB Price: $172.0 / 180.0

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

With our good experience, we offer detailed technical support and advice to assist customers. We communicate closely with customers to establish their quality requirements. Consistent Quality Our plant has strict quality control in each manufactu

CAS 531-91-9 N, N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Top Purity CAS 531-91-9 with fast shipping

Cas:531-91-9

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

inquiry

Henan Sinotech Import&Export Corporation

Name: N,N'-Diphenylbenzidine Synonyms: N,N-Diphenyl Diphenylamine CAS:531-91-9 MF: C24H20N2 Appearance:White powder Storage:Store in cool and dry place, away from sun light. Package:25kg/drum Application: OLED Immediates Transportatio

N,N'-Diphenylbenzidine CAS:531-91-9

Cas:531-91-9

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

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Wuhan Fortuna Chemical Co.,Ltd

1.High quality : the purity is 99% min . through multiple producing procedures. 2.Competitive price : low price because of our skilled production technolpgy ,save the production cost at most , and give big profit room to our customers 3.Safe a

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:0 Metric Ton

Negotiable

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

N,N'-Diphenylbenzidine 531-91-9

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Qingdao Beluga Import and Export Co., LTD

N,N'-Diphenylbenzidine CAS: 531-91-9 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic

N,N'-Diphenylbenzidine CAS: 531-91-9

Cas:531-91-9

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Changchun Artel lmport and Export trade company

Minimum Order Qty. 10 Gram Supply Ability 500 Kilograms/Month Storage store in cool, dry, ventilated place 20℃ Delivery Time 3 business days after payment Payment Term TT,western union,Paypal,MoneyGram Package 10g,20g,50g,100g,500g,1KGS,

N,N'-Diphenylbenzidine supplier in China CAS NO.531-91-9

Cas:531-91-9

Min.Order:10 Gram

Negotiable

Type:Trading Company

inquiry

Hubei Jiutian Bio-medical Technology Co., Ltd

1,we produce and sell good chemicals around the world. 2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%. 3,our staff consists of highly qualifie

N,N'-Diphenylbenzidine CAS 531-91-9

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Leader Biochemical Group

About Product Details

China Biggest Factory Manufacturer Supply N,N'-Diphenylbenzidine CAS 531-91-9

Cas:531-91-9

Min.Order:500 Kilogram

FOB Price: $1.0 / 2.0

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

CAS NO.:531-91-9

Cas:531-91-9

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures s

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:1 Kilogram

FOB Price: $30.0 / 40.0

Type:Lab/Research institutions

inquiry

Shanxi Ankesi Biotechnology Co., Ltd

Our Advantage 1. Rich experience We specialize in this filed for many years, our APIs exported to all over the world and and we established long friendly relations of cooperation with our clients. 2. Great quality,purity and favorable Good qual

Top Purity N,N'-Diphenylbenzidine CAS 531-91-9 AKS

Cas:531-91-9

Min.Order:1 Kilogram

Negotiable

Type:Trading Company

inquiry

Xiamen Hisunny Chemical Co.,Ltd

Best quality & Attractive price & Professional service; Trial & Pilot & Commercial Hisunny Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality intermediates, specia

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Triumph International Development Limilted

Appearance:white or light yellow crystalline powder Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:By

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:100 Gram

Negotiable

Type:Lab/Research institutions

inquiry

HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:grey to brownish fine crystalline powder Storage:Keep containers tightly closed. Keep in original container. Keep away from heat Package:25kg/drum, with inner PE bag; or as per y

N,N'-Diphenylbenzidine

Cas:531-91-9

Min.Order:10 Kilogram

Negotiable

Type:Trading Company

inquiry

Synthetic route

chlorobenzene
108-90-7

chlorobenzene

p,p'-diaminobiphenyl
92-87-5

p,p'-diaminobiphenyl

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
With sodium t-butanolate; Ni(0)*2IPr In 1,4-dioxane at 100℃;95%
With palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium hydroxide In tetrahydrofuran; ethanol; water; toluene; tert-butyl alcohol at 100℃; for 16h; Glovebox; Inert atmosphere; Schlenk technique;116.5 mg
4-(4-bromophenyl)bromobenzene
92-86-4

4-(4-bromophenyl)bromobenzene

aniline
62-53-3

aniline

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Stage #1: 4-(4-bromophenyl)bromobenzene; aniline In 1-methyl-pyrrolidin-2-one; toluene at 20℃; for 0.25h;
Stage #2: With sodium t-butanolate In 1-methyl-pyrrolidin-2-one; toluene for 0.166667h;
Stage #3: tris-(dibenzylideneacetone)dipalladium(0); XPhos In 1-methyl-pyrrolidin-2-one; toluene at 20 - 60℃; for 24.5h; Product distribution / selectivity;
93.1%
With sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine In toluene at 90℃; for 3h;90%
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene at 90℃; for 3h;90%
4-(4-bromophenyl)bromobenzene
92-86-4

4-(4-bromophenyl)bromobenzene

N-trimethylsilylaniline
3768-55-6

N-trimethylsilylaniline

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Stage #1: N-trimethylsilylaniline With n-butyl magnesium bromide In dibutyl ether at 0 - 100℃; for 1h; Inert atmosphere;
Stage #2: 4-(4-bromophenyl)bromobenzene With lithium bromide; iron(II) chloride In dibutyl ether at 140℃; for 24h; Inert atmosphere;
87%
bromobenzene
108-86-1

bromobenzene

p,p'-diaminobiphenyl
92-87-5

p,p'-diaminobiphenyl

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 5h; Inert atmosphere; Reflux;80.2%
With tri-tert-butyl phosphine; palladium diacetate; sodium t-butanolate In toluene for 2h; Reflux;46.1 g
diphenylamine
122-39-4

diphenylamine

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Stage #1: diphenylamine With methanesulfonic acid In dichloromethane at 0℃;
Stage #2: With chloranil In dichloromethane at 0 - 20℃; for 24h;
38%
With aluminum (III) chloride In neat (no solvent) at 95℃; Reagent/catalyst; Temperature;14.9%
With pyridine; nitrosonium tetrafluoroborate In acetonitrile Mechanism;
tetraphenylhydrazine
632-52-0

tetraphenylhydrazine

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
With sulfuric acid; acetic acid
With sulfuric acid
With hydrogenchloride
N,N-diphenylhydroxylamine
1079-64-7

N,N-diphenylhydroxylamine

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
With sulfuric acid at -20℃;
N,N'-biphenyl-4,4'-diyl-di-anthranilic acid
53036-42-3

N,N'-biphenyl-4,4'-diyl-di-anthranilic acid

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
at 285℃;
at 285℃;
N,N'-dinitroso-N,N'-diphenyl-benzidine
40317-17-7

N,N'-dinitroso-N,N'-diphenyl-benzidine

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
With sulfuric acid; acetic acid Reduktion der entstandenen Loesung mit Zinkstaub;
tetrachloromethane
56-23-5

tetrachloromethane

1,2,15,16-tetraphenyl-1,2,15,16-tetraaza-[2.0.2.0]paracyclophane

1,2,15,16-tetraphenyl-1,2,15,16-tetraaza-[2.0.2.0]paracyclophane

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1,1-Diphenylhydrazine
530-50-7

1,1-Diphenylhydrazine

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

Conditions
ConditionsYield
With sulfuric acid at -16℃;
acetic acid
64-19-7

acetic acid

1,2,15,16-tetraphenyl-1,2,15,16-tetraaza-[2.0.2.0]paracyclophane

1,2,15,16-tetraphenyl-1,2,15,16-tetraaza-[2.0.2.0]paracyclophane

zinc

zinc

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

sulfuric acid
7664-93-9

sulfuric acid

diphenylamine
122-39-4

diphenylamine

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
elektrolytische Oxydation und Reduktion des entstandenen kristallinischen Produkts mit Zink;
sulfuric acid
7664-93-9

sulfuric acid

diphenylamine
122-39-4

diphenylamine

sodium dichromate

sodium dichromate

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
bei der Reduktion des entstandenen blauen Produkts mit NaHSO3 oder Zinkstaub;
sulfuric acid
7664-93-9

sulfuric acid

diphenylamine
122-39-4

diphenylamine

sodium nitrite

sodium nitrite

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

N,N'-dinitroso-N,N'-diphenyl-benzidine
40317-17-7

N,N'-dinitroso-N,N'-diphenyl-benzidine

C

N,N'-bis-(4-nitroso-phenyl)-benzidine
88855-71-4

N,N'-bis-(4-nitroso-phenyl)-benzidine

Conditions
ConditionsYield
bei folgendem Zusatz von Eis zum Reaktionsgemisch;
sulfuric acid
7664-93-9

sulfuric acid

sulfur trioxide
7446-11-9

sulfur trioxide

diphenylamine
122-39-4

diphenylamine

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

N.N'-diphenyl-benzidine sulfone

N.N'-diphenyl-benzidine sulfone

Conditions
ConditionsYield
at 80℃;
at 80℃;
sulfuric acid
7664-93-9

sulfuric acid

1,1-Diphenylhydrazine
530-50-7

1,1-Diphenylhydrazine

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

4-anilinophenol
122-37-2

4-anilinophenol

C

N-phenyl-1,2-benzenediamine
534-85-0

N-phenyl-1,2-benzenediamine

Conditions
ConditionsYield
at -16℃; anschl. Erwaermen auf 20grad;
sulfuric acid
7664-93-9

sulfuric acid

tetraphenylhydrazine
632-52-0

tetraphenylhydrazine

acetic acid
64-19-7

acetic acid

benzene
71-43-2

benzene

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
nachf. Reduktion mit Zinkstaub;
tetraphenylhydrazine
632-52-0

tetraphenylhydrazine

benzene
71-43-2

benzene

etheric hydrochloric acid

etheric hydrochloric acid

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

N-(4-chloro-phenyl)-N',N'-diphenyl-p-phenylenediamine
857468-42-9

N-(4-chloro-phenyl)-N',N'-diphenyl-p-phenylenediamine

C

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
in Kohlendioxyd-Atmosphaere;
sulfuric acid
7664-93-9

sulfuric acid

N,N-diphenylhydroxylamine
1079-64-7

N,N-diphenylhydroxylamine

A

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

B

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
at -20℃;
sulfuric acid
7664-93-9

sulfuric acid

N,N'-dinitroso-N,N'-diphenyl-benzidine
40317-17-7

N,N'-dinitroso-N,N'-diphenyl-benzidine

acetic acid
64-19-7

acetic acid

zinc

zinc

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

N-nitrosodiphenylamine
382165-80-2

N-nitrosodiphenylamine

A

tetraphenylhydrazine
632-52-0

tetraphenylhydrazine

B

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C

diphenylamine
122-39-4

diphenylamine

Conditions
ConditionsYield
With HY zeolite In dichloromethane at 20℃; Product distribution; Further Variations:; Reagents; Temperatures;
p,p'-diaminobiphenyl
92-87-5

p,p'-diaminobiphenyl

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; copper; amyl alcohol
2: 285 °C
View Scheme
ortho-chlorobenzoic acid
118-91-2

ortho-chlorobenzoic acid

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: potassium carbonate; copper; amyl alcohol
2: 285 °C
View Scheme
diphenylamine
122-39-4

diphenylamine

A

p,p'-(N,N'-diphenyl)diaminobis(phenyl)amine

p,p'-(N,N'-diphenyl)diaminobis(phenyl)amine

B

tetraphenylhydrazine
632-52-0

tetraphenylhydrazine

C

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
In N,N-dimethyl-formamide for 3h; Electrolysis;
aniline
62-53-3

aniline

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: triethylamine / cyclohexane / 2 h / 5 °C / Inert atmosphere
1.2: 18 h / 5 °C / Inert atmosphere
2.1: n-butyl magnesium bromide / dibutyl ether / 1 h / 0 - 100 °C / Inert atmosphere
2.2: 24 h / 140 °C / Inert atmosphere
View Scheme
4-chloro-aniline
106-47-8

4-chloro-aniline

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1.1: potassium acetate; tetrahydroxydiboron; dicyclohexyl(2',4',6'-triisopropyl-[1,1':3',1''-terphenyl]-2-yl)phosphane; Pd(Cy*Phine)2Cl2 / tert-butyl alcohol; ethanol / 80 °C / Glovebox; Inert atmosphere; Schlenk technique; Sealed tube
1.2: 3.5 h / 80 °C / Inert atmosphere; Glovebox; Schlenk technique
2.1: sodium hydroxide; palladium diacetate; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl / toluene; tetrahydrofuran; tert-butyl alcohol; ethanol; water / 16 h / 100 °C / Glovebox; Inert atmosphere; Schlenk technique
View Scheme
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1-bromo-3-(2-(2-methoxyethoxy)ethoxy)benzene

1-bromo-3-(2-(2-methoxyethoxy)ethoxy)benzene

C46H48N2O6

C46H48N2O6

Conditions
ConditionsYield
With di(tertbutyl)phenylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 3h; Inert atmosphere; Reflux;100%
1-bromo-3-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene
318261-63-1

1-bromo-3-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C50H56N2O8

C50H56N2O8

Conditions
ConditionsYield
With bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate; tri tert-butylphosphoniumtetrafluoroborate In toluene for 3h; Inert atmosphere; Reflux;100%
9-chloro-11,11-dimethylbenzo[a]fluorene
954137-80-5

9-chloro-11,11-dimethylbenzo[a]fluorene

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C62H48N2
954137-37-2

C62H48N2

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; tri-tert-butyl phosphine In xylene at 125℃; for 15h;99%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1-bromo-4-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene
125808-05-1

1-bromo-4-(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)benzene

C50H56N2O8

C50H56N2O8

Conditions
ConditionsYield
With di(tertbutyl)phenylphosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene for 3h; Inert atmosphere; Reflux;99%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole
2620-76-0

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

N,N'-diphenyl-N,N'-di-{4-(1,3-benzoxazol-2-yl)-phenyl}benzidine
1416621-06-1

N,N'-diphenyl-N,N'-di-{4-(1,3-benzoxazol-2-yl)-phenyl}benzidine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; sodium t-butanolate; bis(dibenzylideneacetone)-palladium(0) In hexane; xylene at 130℃; for 4.5h; Hartwig-Buchwald reaction; Inert atmosphere;96%
1-Bromonaphthalene
90-11-9

1-Bromonaphthalene

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

4,4'-bis[N-(1-naphthyl)-N-phenylamino] biphenyl

4,4'-bis[N-(1-naphthyl)-N-phenylamino] biphenyl

Conditions
ConditionsYield
With sodium t-butanolate; palladium diacetate; 1,3-bis[2,6-diisopropylphenyl]imidazolium chloride In toluene at 20 - 130℃; Inert atmosphere;95%
With tri-tert-butyl phosphine; sodium t-butanolate In toluene for 12h; Inert atmosphere; Reflux;70%
With 1,1'-bis-(diphenylphosphino)ferrocene; sodium t-butanolate; palladium diacetate In toluene for 72h; Heating;54%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

2-bromo-9,9'-spirobifluorene
171408-76-7

2-bromo-9,9'-spirobifluorene

4,4'-bis[N-(spiro-9,9'-bifluoren-2-yl)-N-phenylamino]-1,1'-biphenyl

4,4'-bis[N-(spiro-9,9'-bifluoren-2-yl)-N-phenylamino]-1,1'-biphenyl

Conditions
ConditionsYield
With sodium t-butanolate; tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0) In hexane; toluene at 80℃; for 6h;93%
With sodium t-butanolate; bis(dibenzylideneacetone)-palladium(0) In hexane; toluene at 80℃; for 6h;93%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

4-N,N-diphenylamino-1-bromobenzene
36809-26-4

4-N,N-diphenylamino-1-bromobenzene

N',N"-bis[4-(diphenylamino)phenyl]-N',N"-diphenyl biphenyl-4,4'-diamine
209980-53-0

N',N"-bis[4-(diphenylamino)phenyl]-N',N"-diphenyl biphenyl-4,4'-diamine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 50℃; for 7h; Inert atmosphere;91%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1,6-bis(4-iodophenoxy)hexane

1,6-bis(4-iodophenoxy)hexane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxyhexamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,6-bis(4-iodophenoxy)hexane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxyhexamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,6-bis(4-iodophenoxy)hexane

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene for 72h; Ullmann reaction; Heating;90%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1,12-bis(4-iodophenoxy)dodecane

1,12-bis(4-iodophenoxy)dodecane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxydodecamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,12-bis(4-iodophenoxy)dodecane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxydodecamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,12-bis(4-iodophenoxy)dodecane

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene Ullmann reaction; Heating;90%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

sodium benzenesulfonate
873-55-2

sodium benzenesulfonate

N,N′-diphenyl-3-(phenylsulfonyl)-[1,1′-biphenyl]-4,4′-diamine

N,N′-diphenyl-3-(phenylsulfonyl)-[1,1′-biphenyl]-4,4′-diamine

Conditions
ConditionsYield
In aq. phosphate buffer; acetonitrile Electrolysis; regioselective reaction;90%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

sodium 4-methylbenzenesulfinate
824-79-3

sodium 4-methylbenzenesulfinate

N,N′-diphenyl-3-tosyl-[1,1′-biphenyl]-4,4′-diamine

N,N′-diphenyl-3-tosyl-[1,1′-biphenyl]-4,4′-diamine

Conditions
ConditionsYield
In aq. phosphate buffer; acetonitrile Electrolysis; regioselective reaction;90%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C48H36N4

C48H36N4

Conditions
ConditionsYield
In perchloric acid; water; N,N-dimethyl-formamide Electrolysis;90%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C11H7BrN2O2

C11H7BrN2O2

C46H32N6O4

C46H32N6O4

Conditions
ConditionsYield
With potassium phosphate; copper(l) iodide; (1R,2R)-1,2-diaminocyclohexane In 1,4-dioxane for 24h; Reflux;88%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1,10-bis(4-iodophenoxy)decane

1,10-bis(4-iodophenoxy)decane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxydecamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,10-bis(4-iodophenoxy)decane

poly[1,4-phenylene(phenylimino)biphenyl-4,4-ylene(phenylimino)-1,4-phenyleneoxydecamethyleneoxy]; Monomer(s): N,N-diphenylbenzidine; 1,10-bis(4-iodophenoxy)decane

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene Ullmann reaction; Heating;87.5%
3-bromo-9-ethyl-9H-carbazole
57102-97-3

3-bromo-9-ethyl-9H-carbazole

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C52H42N4

C52H42N4

Conditions
ConditionsYield
With tri-tert-butyl phosphine; bis(dibenzylideneacetone)-palladium(0); sodium t-butanolate In toluene at 50℃; for 6.5h; Inert atmosphere;87%
4-tolyl iodide
624-31-7

4-tolyl iodide

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine
20441-06-9

N,N'-di(4''-methylphenyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 190℃; for 14h; Ullmann condensation;86%
C12H14BrN

C12H14BrN

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C48H46N4

C48H46N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium tert-butylate In N,N-dimethyl-formamide at 90℃; for 8h; Inert atmosphere;86%
1-iodo-2,4-dimethylbenzene
4214-28-2

1-iodo-2,4-dimethylbenzene

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

N,N'-diphenyl-N,N'-bis(2,4-dimethylphenyl)-(1,1'-biphenyl)-4,4'-diamine
122738-25-4

N,N'-diphenyl-N,N'-bis(2,4-dimethylphenyl)-(1,1'-biphenyl)-4,4'-diamine

Conditions
ConditionsYield
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 20 - 190℃; Inert atmosphere;85%
With 18-crown-6 ether; copper; potassium carbonate In 1,2-dichloro-benzene at 170℃; for 48h;50%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

1-bromo-4-(trifluorovinyloxy)benzene

1-bromo-4-(trifluorovinyloxy)benzene

N,N'-bis[(p-trifluorovinyloxy)phenyl]-N,N'-bis(phenyl)benzidine
1159606-87-7

N,N'-bis[(p-trifluorovinyloxy)phenyl]-N,N'-bis(phenyl)benzidine

Conditions
ConditionsYield
With tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine; sodium t-butanolate In toluene for 24h; Reflux; Inert atmosphere;85%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

sodium p-chlorobenzenesulphinate
14752-66-0

sodium p-chlorobenzenesulphinate

3-[(4-chlorophenyl)sulfonyl]-N,N′-diphenyl-[1,1′-biphenyl]-4,4′-diamine

3-[(4-chlorophenyl)sulfonyl]-N,N′-diphenyl-[1,1′-biphenyl]-4,4′-diamine

Conditions
ConditionsYield
In aq. phosphate buffer; acetonitrile Electrolysis; regioselective reaction;85%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

polymer; monomer(s): N-methyl-3,4-bis-(4-bromophenyl)maleimide; N,N\-diphenylbenzidine

polymer; monomer(s): N-methyl-3,4-bis-(4-bromophenyl)maleimide; N,N\-diphenylbenzidine

Conditions
ConditionsYield
With tri-tert-butyl phosphine; sodium t-butanolate; palladium diacetate In tetrahydrofuran for 48h; Heating;84%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

4-bromo-N-cyclohexylideneaniline
64456-62-8

4-bromo-N-cyclohexylideneaniline

C48H46N4

C48H46N4

Conditions
ConditionsYield
With tetrakis(triphenylphosphine) palladium(0); potassium tert-butylate In N,N-dimethyl-formamide at 90℃; for 6h; Inert atmosphere;84%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

C33H21Br

C33H21Br

C90H60N2

C90H60N2

Conditions
ConditionsYield
With bis(tri-t-butylphosphine)palladium(0); sodium t-butanolate In toluene at 95 - 100℃; for 2.5h;84%
bromobenzene
108-86-1

bromobenzene

N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
15546-43-7

N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl

Conditions
ConditionsYield
With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate In o-xylene; toluene at 110℃; for 24h; Inert atmosphere;82.62%
N,N'-diphenyl-p-phenylenediamine
531-91-9

N,N'-diphenyl-p-phenylenediamine

3-bromo-8,8-dimethyl-8H-indolo [3,2,1-de]acridine
1224892-52-7

3-bromo-8,8-dimethyl-8H-indolo [3,2,1-de]acridine

N4,N4'-Bis-(8,8-dimethyl-8H-indolo[3,2,1-de]acridin-3-yl)-N4,N4'-diphenylbiphenyl-4,4'-diamine
1319016-29-9

N4,N4'-Bis-(8,8-dimethyl-8H-indolo[3,2,1-de]acridin-3-yl)-N4,N4'-diphenylbiphenyl-4,4'-diamine

Conditions
ConditionsYield
Stage #1: N,N'-diphenyl-p-phenylenediamine; 3-bromo-8,8-dimethyl-8H-indolo [3,2,1-de]acridine In 1,4-dioxane for 1h; Hartwig-buchwald coupling reaction; Inert atmosphere;
Stage #2: With sodium t-butanolate; tri-tert-butyl phosphine; palladium diacetate In 1,4-dioxane for 18h; Reflux;
81%
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