Iron(II) EDTA complex supplier

Name
Ferrate(2-),[[N,N'-1,2-ethanediylbis[N-[(carboxy-kO)methyl]glycinato-kN,kO]](4-)]-, hydrogen (1:2), (OC-6-21)-
EINECS
CAS No. 21393-59-9
Article Data16
CAS DataBase
Density
Solubility
Melting Point
Formula C10H12 Fe N2 O8 . 2 H
Boiling Point
Molecular Weight 346.077
Flash Point
Transport Information
Appearance
Safety Poison by intraperitoneal route. When heated to decomposition it emits toxic fumes of NO_x. See also IRON COMPOUNDS.
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Ferrate(2-),[(ethylenedinitrilo)tetraacetato]-, dihydrogen (8CI); Ferrate(2-),[[N,N'-1,2-ethanediylbis[N-(carboxymethyl)glycinato]](4-)-N,N',O,O',ON,ON']-,dihydrogen, (OC-6-21)-; Ferrate(2-), [[N,N'-1,2-ethanediylbis[N-[(carboxy-kO)methyl]glycinato-kN,kO]](4-)]-, dihydrogen, (OC-6-21)- (9CI); Hydrogen[(ethylenedinitrilo)tetraacetato]ferrate(II) (6CI,7CI); Dihydrogen[ethylenediaminetetraacetato(4-)]ferrate(2-); Ferrous EDTA; Ferrousethylenediaminetetraacetate; Fetrilon; Iron EDTA; Ironethylenediaminetetraacetate; Iron(II) EDTA; Sequestrene H 2FE; [Dihydrogen(ethylenedinitrilo)tetraacetato]iron
PSA 161.34000
LogP -4.74310

Synthetic route

: iron(II) chloride tetrahydrate

: 64-02-8, 139-33-3, 150-38-9, 7379-28-4, 17421-79-3, 71705-16-3, 116229-67-5
disodium ethylenediamine tetraacetic acid

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
With citrate buffer In water stoich. amt. of Fe-salt addn. to deaerated Na-salt soln. buffered at pH 4.8;

: iron(II) sulfate

: 64-02-8, 139-33-3, 150-38-9, 7379-28-4, 17421-79-3, 71705-16-3, 116229-67-5
disodium ethylenediamine tetraacetic acid

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water prepared in the absence of O2;;

: 64-02-8, 139-33-3, 150-38-9, 7379-28-4, 17421-79-3, 71705-16-3, 116229-67-5
disodium ethylenediamine tetraacetic acid

: iron(II) chloride

A: 21393-59-9
iron(II) ethylenediaminetetraacetate

B: Fe(II)(Hedta)

Conditions

Conditions	Yield
In water product ratio depending on pH;;

...Expand

: iron(II) ethylenediaminetetraacetic acid*NO

A: 21393-59-9
iron(II) ethylenediaminetetraacetate

B: [Fe(ethylenediaminetetraacetate)](1-)

C: 10102-43-9
nitrogen(II) oxide

Conditions

Conditions	Yield
With borax; potassium dihydrogenphosphate; sodium sulfite In water Kinetics; at various temps. and over pH range of 5.74-8.00, ionic strength adjusted with KCl, pH controlled with buffer soln., equilibrium react.; detected by UV absorption;

...Expand

: iron(III) ammonium sulfate dodecahydrate

: disodium ethylenediaminetetraacetate dihydrate

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water Kinetics; byproducts: Fe2O3, ethylenediaminetriacetic acid, iminodiacetic acid; 1:1.5 ratio of Fe(III) to EDTA in H2O heated at 175°C at pH 9.3 (NaOH or NH3 controll) under inert atm.; Fe2O3 filtered, product detected by NMR, if 1:1 ratio of reagents used Fe2O3 formed;

: Ammonium iron sulfate

: disodium ethylenediaminetetraacetate dihydrate

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water
In water Hodges, H. L., Holwerda, R. A., Gray, H. B., J. Am. Chem. Soc., 1974, 98, 3132; through aq. soln. of Na2H2(EDTA)2H2O bubbled N2 for 1 h, addedair-free (NH4)2Fe(SO4)26H2O; not isolated from soln.;

: ferrous(II) sulfate heptahydrate

: 60-00-4
ethylenediaminetetraacetic acid

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water reaction in deoxygenized solns.;

: 19052-44-9
hexaamineruthenium(II)

: [Fe(ethylenediaminetetraacetate)](1-)

A: 18943-33-4
hexaammineruthenium(III)

B: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water Kinetics; soln. of Fe complex, 0.10 M TrisH(1+), 0.90 M NaClO4 (or LiClO4) adjusted with HClO4 (pH 4.5-6.5), soln. of Ru complex, 0.1 M TrisH(1+), 0.9 MNaClO4 adjusted with HCl; at 5.0-35.0 °C; not isolated, monitored by UV;

...Expand

: [Fe(ethylenediaminetetraacetate)](1-)

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
With sodium sulfide In water Kinetics; byproducts: Fe(OH)EDTA, Fe(OH)2EDTA, S; reaction at 23°C in an aq. alkaline soln. of Na2S (0.76E-3, 1.52E-3, 3.04E-3, 6.08E-3 or 12.16E-3 M), FeEDTA: 0.11E-3 M at pH = 8; existence of an intermediate complex discussed; variation of pH discussed;; detn. of the change of optical density (depending on time) at 500 nm;;
With ethanethiol In water Kinetics; byproducts: C2H5SSC2H5, Fe(OH)EDTA, Fe(OH)2EDTA; reaction at 14°C, pH = 9.0 with an excess of FeEDTA(1-) (7.67E-2 M); concentration of C2H5SH 0.0075, 0.00568 or 0.00372 M in a glass reactor (apparatus described);; determination of the change of optical density (depending on time) at 540 .+-. 10 nm;;
With ethanethiol In water Kinetics; byproducts: C2H5SSC2H5, Fe(OH)EDTA, Fe(OH)2EDTA; reaction at 21°C, pH = 9.0 with an excess of C2H5SH (0.0198 M); concentration of FeEDTA(1-) 0.005, 0.0025, 0.00125 or 0.625E-3 M in a closed cuvette; variation of pH discussed; formation of an intermediate complex discussed;; determination of the change of optical density (depending on time) at 540 .+-. 10 nm;;
With sodium sulfide In water Kinetics; byproducts: Fe(OH)EDTA, Fe(OH)2EDTA, S; reaction at 23°C in an aq. alkaline soln. of Na2S (2.8E-3 M), FeEDTA: 0.22E-3 M at pH = 8 in presence of sulfur (0.3E-4, 0.6E-4, 1.2E-4, 2.4E-4 or 4.8E-4 M); existence of an intermediate complex discussed; variation of pH discussed;; detn. of the change of optical density (depending on time) at 500 nm;;

: ferrous ammonium sulphate

: 2001-94-7, 5964-35-2, 7379-27-3, 16645-74-2, 17572-97-3, 53404-51-6, 116257-07-9
EDTA (dipotassium salt)

: 21393-59-9
iron(II) ethylenediaminetetraacetate

Conditions

Conditions	Yield
In water a potassium salt of EDTA was dissolved in H2O at pH 7, Fe-salt was added;

: 60-00-4
ethylenediaminetetraacetic acid

: 7439-89-6
iron(II)

A: 21393-59-9
iron(II) ethylenediaminetetraacetate

B: Fe(2+)*NCH2CH2N(CH2COO)3(CH2COOH)(3-)=Fe(NCH2CH2N(CH2COO)3(CH2COOH))(1-)

Conditions

Conditions	Yield
With hydrogen cation In water under Ar; Fe(EDTA)(2-) formed from about p{H} 4 to 12; FeHEDTA(1-) formation at low p{H};;

...Expand

: 21393-59-9
iron(II) ethylenediaminetetraacetate

: 7632-00-0
sodium nitrite

A: [Fe(ethylenediaminetetraacetate)](1-)

B: Fe(II)(edta)NO

Conditions

Conditions	Yield
In water Kinetics; product ratio depending on pH and concn. of O2 present in the soln.;; followed by UV-vis-spectroscopy;;

...Expand

: 21393-59-9
iron(II) ethylenediaminetetraacetate

A: 7439-89-6
iron(II)

B: 150-43-6
ethylenediaminetetraacetate

Conditions

Conditions	Yield
In ethanol; water 75% ethanol and 25% water (by vol.), μ=0.100 M (KCl), 25.0°C; stability const. for the complex detd.;

: 21393-59-9
iron(II) ethylenediaminetetraacetate

: [Fe(ethylenediaminetetraacetate)](1-)

Conditions

Conditions	Yield
With oxygen In water Kinetics; liquid-phase oxidation at 25°C, O2-pressure 0.09atm; influence of pH investigated (ph 5-9); proposal of react. mechanism;; chromatometrical determination of concentration of Fe(2+)-complex by titration with K2Cr2O7 (in acid soln. in presence of Na-diphenylaminosulfonate indicator);;
With O2 In water rapid oxidation;;

: 21393-59-9
iron(II) ethylenediaminetetraacetate

: 10102-43-9
nitrogen(II) oxide

A: [Fe(ethylenediaminetetraacetate)](1-)

B: Fe(II)(edta)NO

Conditions

Conditions	Yield
In water Kinetics; O2-free NO gas was passed through an evacuated soln. of Fe(II)(edta) within a few minutes; formation of Fe(III)(edta) not onserved;; followed by UV-vis-spectroscopy;;	A 0% B n/a

...Expand

: 21393-59-9
iron(II) ethylenediaminetetraacetate

: 7782-77-6
cis-nitrous acid

: Fe(II)(edta)NO

Conditions

Conditions	Yield
In water Kinetics; followed by UV-vis-spectroscopy;;

Iron(II) EDTA complex Chemical Properties

Empirical Formula of Iron(II) EDTA complex (CAS NO.21393-59-9): C₁₀H₁₄FeN₂O₈
Molecular Weight: 346.0718 g/mol
EINECS: 244-356-7
Flash Point: 325.2 °C
Enthalpy of Vaporization: 99.5 kJ/mol
Boiling Point: 614.2 °C at 760 mmHg
Vapour Pressure: 1.15E-16 mmHg at 25 °C
Structure of Iron(II) EDTA complex (CAS NO.21393-59-9):

IUPAC Name: 2-[2-[Bis(2-oxido-2-oxoethyl)amino]ethyl-(2-oxido-2-oxoethyl)amino]acetate ; Hydron ; Iron(2+)
Canonical SMILES: [H+].[H+].C(CN(CC(=O)[O-])CC(=O)[O-])N(CC(=O)[O-])CC(=O)[O-].[Fe+2]
InChI: InChI=1S/C10H16N2O8.Fe/c13-7(14)3-11(4-8(15)16)1-2-12(5-9(17)18)6-10(19)
20;/h1-6H2,(H,13,14)(H,15,16)(H,17,18)(H,19,20);/q;+2/p-2
InChIKey: JVXHQHGWBAHSSF-UHFFFAOYSA-L

Iron(II) EDTA complex Toxicity Data With Reference

ipr-mus LD50:40 mg(Fe)/kg

PABIAQ Pathologie et Biologie. 11 (1963),853.

Iron(II) EDTA complex Consensus Reports

Reported in EPA TSCA Inventory.

Iron(II) EDTA complex Safety Profile

Poison by intraperitoneal route. When heated to decomposition Iron(II) EDTA complex (CAS NO.21393-59-9) emits toxic fumes of NO_x. See also IRON COMPOUNDS.

Iron(II) EDTA complex Specification

Iron(II) EDTA complex , its cas register number is 21393-59-9. It also can be called Iron(II): EDTA ; Dihydrogen ((N,N'-ethylenebis(N-(carboxymethyl)glycinato))(4-)-N,N',O,O',ON,ON')ferrate(2-) ; and Ferrate(2-), ((N,N'-1,2-ethanediylbis(N-((carboxy-kappaO)methyl)glycinato-kappaN,kappaO))(4-))-, hydrogen (1:2), (OC-6-21)- .

Product Name

Ferrate(2-),[[N,N'-1,2-ethanediylbis[N-[(carboxy-kO)methyl]glycinato-kN,kO]](4-)]-, hydrogen (1:2), (OC-6-21)-

Synthetic route

Iron(II) EDTA complex Chemical Properties

Iron(II) EDTA complex Toxicity Data With Reference

Iron(II) EDTA complex Consensus Reports

Iron(II) EDTA complex Safety Profile

Iron(II) EDTA complex Specification

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