Product Name

  • Name

    L(+)-Rhamnose monohydrate

  • EINECS 222-793-4
  • CAS No. 10030-85-0
  • Density 1.47 g/cm3
  • Solubility water: 0.1 g/mL, clear, colorless
  • Melting Point 90-95 °C(lit.)
  • Formula C6H14O6
  • Boiling Point 323.9 °C at 760 mmHg
  • Molecular Weight 182.174
  • Flash Point 149.7 °C
  • Transport Information
  • Appearance White crystals or crystalline powder
  • Safety 24/25-37/39-26
  • Risk Codes 36/38
  • Molecular Structure Molecular Structure of 10030-85-0 (L(+)-Rhamnose monohydrate)
  • Hazard Symbols IrritantXi
  • Synonyms (2R,3R,4S,5S)-2,3,4,5-Tetrahydroxyhexanal hydrate;(2R,3R,4S,5S)-2,3,4,5-Tetrahydroxyhexanalhydrat;6-Deoxy-L-mannose hydrate (1:1);6-Deoxy-L-mannose hydrate;
  • PSA 107.22000
  • LogP -2.41550

Synthetic route

1-Aminopiperidine
2213-43-6

1-Aminopiperidine

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

(2S,3S,4S,5S)-1-(piperidin-1-ylimino)hexane-2,3,4,5-tetrol

(2S,3S,4S,5S)-1-(piperidin-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 3.75h; Reflux;83%
L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

N-aminopyrrolidine
16596-41-1

N-aminopyrrolidine

(2S,3S,4S,5S)-1-(pyrrolidin-1-ylimino)hexane-2,3,4,5-tetrol

(2S,3S,4S,5S)-1-(pyrrolidin-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 2.5h; Reflux;80%
1-azepanylamine
5906-35-4

1-azepanylamine

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

(2S,3S,4S,5S)-1-(azepan-1-ylimino)hexane-2,3,4,5-tetrol

(2S,3S,4S,5S)-1-(azepan-1-ylimino)hexane-2,3,4,5-tetrol

Conditions
ConditionsYield
In methanol for 3.25h; Reflux;74%
L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

6-deoxy-L-arabino-2-hexulose
14807-05-7

6-deoxy-L-arabino-2-hexulose

Conditions
ConditionsYield
In pyridine for 5h; Heating;63%
2-hexyldecan-1-ol
2425-77-6

2-hexyldecan-1-ol

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

2-hexyldecyl 6-deoxy-L-mannopyranoside

2-hexyldecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
With sodium hydrogencarbonate In ethyl acetate48%
L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

A

6-deoxy-L-glucose
35867-45-9

6-deoxy-L-glucose

B

6-deoxy-L-arabino-2-hexulose
14807-05-7

6-deoxy-L-arabino-2-hexulose

C

6-deoxy-L-ribo-hexulose
1026722-79-1

6-deoxy-L-ribo-hexulose

Conditions
ConditionsYield
With pyridine for 5h; Product distribution; Heating; variation of time;A 5%
B 34%
C 3%
2-octyldodecan-1-ol
5333-42-6

2-octyldodecan-1-ol

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

2-octyldodecyl 6-deoxy-L-mannopyranoside

2-octyldodecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
10%
2-decylteradecanol
58670-89-6

2-decylteradecanol

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

2-decyltetradecyl 6-deoxy-L-mannopyranoside

2-decyltetradecyl 6-deoxy-L-mannopyranoside

Conditions
ConditionsYield
6%
L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

6-deoxy-L-fructose 2-nitrophenylhydrazone
72774-23-3, 72774-24-4

6-deoxy-L-fructose 2-nitrophenylhydrazone

Conditions
ConditionsYield
Multi-step reaction with 2 steps
1: 63 percent / pyridine / 5 h / Heating
2: H2O; ethanol / 0.17 h / Heating
View Scheme
4-aminophenylacetic acid
1197-55-3

4-aminophenylacetic acid

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

p-aminophenylacetic acid-N-L-rhamnoside

p-aminophenylacetic acid-N-L-rhamnoside

Conditions
ConditionsYield
With ammonium chloride In ethanol; nitrogen
3,6-diamino-10-methyl-acridine

3,6-diamino-10-methyl-acridine

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

3,6-Di-(α-L-rhamnopyranosyl-amino)-10-N-methylacridinium chloride
84208-01-5

3,6-Di-(α-L-rhamnopyranosyl-amino)-10-N-methylacridinium chloride

Conditions
ConditionsYield
With hydrogenchloride In water; ethyl acetate; acetone
proflavine hydrochloride
952-23-8

proflavine hydrochloride

L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

3,6-Di-(α-L-rhamnopyranosyl-amino)-acridine
84207-95-4

3,6-Di-(α-L-rhamnopyranosyl-amino)-acridine

Conditions
ConditionsYield
In ethanol; water
L-rhamnose monohydrate
10030-85-0

L-rhamnose monohydrate

methyl 6-deoxy-α-L-mannopyranoside
14917-55-6

methyl 6-deoxy-α-L-mannopyranoside

Conditions
ConditionsYield
In methanol

L(+)-Rhamnose monohydrate Specification

The L-Mannose, 6-deoxy-,hydrate (1:1) with the CAS registry number 10030-85-0 is also known as 6-Deoxy-L-mannosehydrat. Its EINECS registry number is 222-793-4. The IUPAC name is (2R,4S,5R)-6-methyloxane-2,3,4,5-tetrol hydrate. In addition, the molecular formula is C6H14O6 and molecular weight is 182.17. And it is a kind of white crystals or crystalline powder and belongs to the class of Arbohydrates.

Physical properties about L-Mannose, 6-deoxy-,hydrate (1:1) are: (1)# of Rule of 5 Violations: 1; (2)#H bond acceptors: 6; (3)#H bond donors: 6; (4)#Freely Rotating Bonds: 8; (5)Polar Surface Area: 97.99 Å2; (6)Flash Point: 250.5 °C; (7)Enthalpy of Vaporization: 87.23 kJ/mol; (8)Boiling Point: 490.6 °C at 760 mmHg; (9)Vapour Pressure: 1.1E-11 mmHg at 25°C.

Preparation and uses of L-Mannose, 6-deoxy-,hydrate (1:1): this chemical is prepared by sugar ligand which come from sweet orange and other Citrus Branch said extract. In addition, it can be used as biochemical reagents and edible sweeteners.

When you are using this chemical, please be cautious about it as the following:
This chemical is irritating to eyes, skin and may cause inflammation to the skin or other mucous membranes. Therefore, you should wear suitable gloves, eye/face protection and avoid contact with skin and eyes. In addition, in case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: O.O[C@@H]([C@H](C)O)[C@@H](O)[C@@H](O)C=O
(2)InChI: InChI=1/C6H12O5.H2O/c1-3(8)5(10)6(11)4(9)2-7;/h2-6,8-11H,1H3;1H2/t3-,4-,5-,6-;/m0./s1
(3)InChIKey: CBDCDOTZPYZPRO-DEZHIRTDBL

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