Lithium metaborate supplier | CasNO.13453-69-5

Name
Lithium metaborate
EINECS 236-631-5
CAS No. 13453-69-5
Article Data7
CAS DataBase
Density 1.4 g/cm³
Solubility
Melting Point 845 °C(lit.)
Formula LiBO₂
Boiling Point
Molecular Weight 49.7508
Flash Point
Transport Information
Appearance white powder
Safety 24/25
Risk Codes 20/21/22-41
Molecular Structure
Hazard Symbols
Synonyms lithium,oxido(oxo)borane;Boric acid lithium salt;Lithium metaborate;
PSA 40.13000
LogP -0.88610

Synthetic route

: Li(1+)*{(C6H5)B(OH)3}(1-)=Li{(C6H5)B(OH)3}

A: 13453-69-5
lithium metaborate

B: 7732-18-5
water

C: 71-43-2
benzene

Conditions

Conditions	Yield
thermal decompn. in air at 115°C and in N2 atmosphere at 120°C;

...Expand

: Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

A: 13453-69-5
lithium metaborate

B: 7732-18-5
water

Conditions

Conditions	Yield
With oxygen byproducts: CO2; oxisative decompn. on heating;
With O2 byproducts: CO2; oxisative decompn. on heating;

: cobalt lithium orthoborate

A: cobalt(II,III) oxide

B: 13453-69-5
lithium metaborate

Conditions

Conditions	Yield
In neat (no solvent, solid phase) heating in air (800°C);

: lithium borohydride

: 7732-18-5
water

A: 13453-69-5
lithium metaborate

B: 1333-74-0
hydrogen

Conditions

Conditions	Yield
With cobalt(II) chloride at 20℃;

...Expand

: 7782-49-2
selenium

: lithium borohydride

: 1310-65-2
lithium hydroxide

A: 13453-69-5
lithium metaborate

B: dilithium diselenide

Conditions

Conditions	Yield
In water at 20℃; for 1h; Schlenk technique; Inert atmosphere; Sonication;

...Expand

: 67-56-1
methanol

: 13453-69-5
lithium metaborate

A: 7732-18-5
water

B: 6867-35-2
lithium tetramethanolatoborate

Conditions

Conditions	Yield
In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing;
In methanol with exclusion of air in excess anhydrous methanol; between room temp. and boiling; by refluxing;

...Expand

: 13453-69-5
lithium metaborate

: 69-65-8
mannitol

: Li(1+)*BO2(1-)*2C6H14O6*2H2O=LiBO2*2C6H14O6*2H2O

Conditions

Conditions	Yield
In water in concd.soln.; pptd. with alcohol;
In water in concd.soln.; pptd. with alcohol;

: 77-85-0
2-(hydroxymethyl)-2-methylpropane-1,3-diol

: 13453-69-5
lithium metaborate

: 7732-18-5
water

: Lithium-hydroxy-{2-(hydroxymethyl)-2-methyl-1,3-propandiolato(3-)-O,O'O''}-borat(1-) * 1.5H2O

...Expand

: 67-56-1
methanol

: 13453-69-5
lithium metaborate

: Li-tetrakis(methoxy)borate *2CH3OH

Conditions

Conditions	Yield
with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.;
with anhydrous CH3OH; reflux; exclusion of air; addn. of dimethyl ether to filtrate; drying at room temp.;

: 13453-69-5
lithium metaborate

: calcium borate

: beryllium oxide

: beryllium calcium diborate

Conditions

Conditions	Yield
In neat (no solvent) melting, cooling from 1198 K to 698 K (6 K/h); washing (hot distd. water);

...Expand

: strontium(II) oxide

: boron trioxide

: indium(III) oxide

: 13453-69-5
lithium metaborate

: strontium lithium indium pyroborate

Conditions

Conditions	Yield
In neat (no solvent) melting SrO, In2O3, LiBO2 and B2O3 in Pt-crucible at 1303 K, cooling slow to 1003 K (10 K/h), cooling to 300 K (88 K/h); washing (hot distd. water);

...Expand

: boron trioxide

: 13453-69-5
lithium metaborate

: lithium catena-poly{3,4-dihydroxypentaborate-1:5-μ-oxo}

Conditions

Conditions	Yield
In formic acid aq. formic acid; 573 K, 10 MPa, 8 d;

: dysprosium((III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiDy6O5(9+)*3BO3(3-)=LiDy6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: erbium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiEr6O5(9+)*3BO3(3-)=LiEr6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: 13453-69-5
lithium metaborate

: europium(III) oxide

: 11113-50-1
boric acid

: LiEu6O5(9+)*3BO3(3-)=LiEu6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: gadolinium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiGd6O5(9+)*3BO3(3-)=LiGd6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: holmium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiHo6O5(9+)*3BO3(3-)=LiHo6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: neodymium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiNd6O5(9+)*3BO3(3-)=LiNd6O5(BO3)3

Conditions

Conditions	Yield
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);

...Expand

: samarium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiSm6O5(9+)*3BO3(3-)=LiSm6O5(BO3)3

Conditions

Conditions	Yield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);

...Expand

: 13453-69-5
lithium metaborate

: thulia

: 11113-50-1
boric acid

: LiTm6O5(9+)*3BO3(3-)=LiTm6O5(BO3)3

Conditions

Conditions	Yield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);

...Expand

: 13453-69-5
lithium metaborate

: terbium(III) oxide

: 11113-50-1
boric acid

: LiTb6O5(9+)*3BO3(3-)=LiTb6O5(BO3)3

Conditions

Conditions	Yield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);

...Expand

: yttrium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiY6O5(9+)*3BO3(3-)=LiY6O5(BO3)3

Conditions

Conditions	Yield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);

...Expand

: praseodymium(III) oxide

: 13453-69-5
lithium metaborate

: 11113-50-1
boric acid

: LiPr6O5(9+)*3BO3(3-)=LiPr6O5(BO3)3

Conditions

Conditions	Yield
In nitric acid aq. HNO3; solubilization in diluted HNO3, coprecipitation, drying (100°C), heating (800°C, 24 h);
In neat (no solvent) preheating (700°C, 3 h), grinding, sintering (900°C, 22 h,under O2, Ar, or H2 atm.);

...Expand

: niobium(V) oxide

: 13453-69-5
lithium metaborate

: (LiBO2)0.90(Nb2O5)010

Conditions

Conditions	Yield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);

: niobium(V) oxide

: 13453-69-5
lithium metaborate

: (LiBO2)0.80(Nb2O5)020

Conditions

Conditions	Yield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);

: niobium(V) oxide

: 13453-69-5
lithium metaborate

: (LiBO2)0.95(Nb2O5)005

Conditions

Conditions	Yield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);

: niobium(V) oxide

: 13453-69-5
lithium metaborate

: (LiBO2)0.85(Nb2O5)015

Conditions

Conditions	Yield
In melt calcd. amts. of compd. mixed, melted in covered Pt crucible, temp. raised to 1373 K (5 K/min) and maintained at this temp. for 1 h; melt poured onto preheated (400 K) stainless steel plate, quickly pressed by another plate, heated at 573 K for 6 h (heating and cooling rates 50 K/h);

: 13453-69-5
lithium metaborate

: 7732-18-5
water

: lithium metaborate dihydrate

Conditions

Conditions	Yield
at 90℃;

Lithium metaborate Specification

The Lithium metaborate, also known as Lithium Tetraborate, is an chemical compound with the formula LiBO₂. It belongs to the product categories of Inorganics; ACS Grade Synthetic Reagents; Essential Chemicals; Inorganic Salts; Lithium; Routine Reagents; Lithium Salts; Metal and Ceramic Science; Salts. Its EINECS registry number is 236-631-5. With the CAS registry number 13453-69-5, its IUPAC name is lithium oxido(oxo)borane.

Physical properties of Lithium metaborate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 50.015139; (5)MonoIsotopic Mass: 50.015139; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 4; (8)Formal Charge: 0; (9)Complexity: 13.5; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 2.

Preparation of Lithium metaborate: This chemical can be prepared by fused lithium hydroxide or lithium carbonate and boric acid in right chemistry proportion.

B₂O + Li₂CO₃ = 2LiBO₂ + CO₂

Uses of Lithium metaborate: It can be used in borate fusion sample preparation of various samples for analysis by XRF, AAS, ICP-OES, ICP-AES and ICP-MS.

When you are using this chemical, please be cautious about it as the following:
This chemical is harmful by inhalation, in contact with skin and if swallowed. In addition, there will be a risk of serious damage to eyes. When using it, you must avoid contact with skin and eyes.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: [Li+].B(=O)[O-]
(2)InChI: InChI=1S/BO2.Li/c2-1-3;/q-1;+1
(3)InChIKey: HZRMTWQRDMYLNW-UHFFFAOYSA-N

Product Name

Lithium metaborate

Synthetic route

Lithium metaborate Specification

Related Products

Hot Products