Lithium trifluoromethanesulfonate supplier

Name
Lithium triflate
EINECS 251-528-5
CAS No. 33454-82-9
Article Data10
CAS DataBase
Density 1,9 g/cm3
Solubility soluble in water
Melting Point >300 °C(lit.)
Formula CHF₃LiO₃S
Boiling Point 162 °C at 760 mmHg
Molecular Weight 156.011
Flash Point
Transport Information
Appearance white powder
Safety 26-36-37/39
Risk Codes 36/37/38
Molecular Structure
Hazard Symbols Xi
Synonyms Methanesulfonicacid, trifluoro-, lithium salt (8CI,9CI);AQ 75T;Fluorad FC 122;LiTFS;Lithium triflate;Lithium trifluoromethanesulfonate;Lithiumtrifluoromethanesulfonate (LiSO3CF3);Lithium trifluoromethylsulfonate;PFM-Li;Sankonol AQ 50T;Sankonol AQ 75T;Sankonol EAc 30T;Trifluoromethanesulfonicacid lithium salt;
PSA 65.58000
LogP 1.13220

Synthetic route

: 1493-13-6
trifluorormethanesulfonic acid

: lithium chloride

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In water at 100℃; for 1h;	93.3%

: 4167-85-5
LiSn(C6H5)2CH3

: 135580-50-6
{(CH3)3C}{(CH3)2CH}Si(OSO2CF3)2

: 1493-13-6
trifluorormethanesulfonic acid

: 124-40-3
dimethyl amine

A: 135580-44-8
{(CH3)3C}{(CH3)2CH}{(CH3)2N}SiSn{N(CH3)2}(C6H5)CH3

B: 33454-82-9
lithium trifluoromethanesulfonate

C: 79430-76-5
[Me2NH2]OTf

Conditions

Conditions	Yield
In diethyl ether; toluene byproducts: C6H6; Ar-atmosphere; addn. of LiSnPh2Me to Si-derivative in ether (-&0°C), toluene addn., addn. of triflic acid (-70°C), stirring (3 h, -70°C), addn. of Me2NH (-40°C); sepn. of Me2NH2OSO2CF3, filtration, evapn. (vac.), fractional distn.; mixt. of stereoisomers (1 : 1) not sepd.; elem. anal.;	A 54% B n/a C n/a

...Expand

: 2794-60-7
barium trifluoromethanesulfonate

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
With lithium sulfate In water for 24h;

: 72971-96-1
bis(trifluoromethyl)sulfone

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
With lithium hydroxide In methanol at 0℃; for 0.5h;

: 2794-60-7
barium trifluoromethanesulfonate

: 1310-65-2
lithium hydroxide

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
With sulfuric acid In water
With dild. H2SO4 In water

: 1493-13-6
trifluorormethanesulfonic acid

: 1310-65-2
lithium hydroxide

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
byproducts: H2O;

: 335-05-7
Trifluoromethanesulfonyl fluoride

: 1310-65-2
lithium hydroxide

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
byproducts: HF;

: 675825-21-5
Lithium enolate of the acetaldehyde

: 34946-82-2
copper(II) bis(trifluoromethanesulfonate)

: 33454-82-9
lithium trifluoromethanesulfonate

: 34946-82-2
copper(II) bis(trifluoromethanesulfonate)

: 27557-78-4
1,2,2-triphenyl-ethanone; lithium enolate

: 33454-82-9
lithium trifluoromethanesulfonate

(C6H5)2Sn(OSO2CF3)2: 27607-86-9
(C6H5)2Sn(OSO2CF3)2

: 4039-32-1
lithium hexamethyldisilazane

A: 135580-43-7
(C6H5)2Sn{N(Si(CH3)3)2}(OSO2CF3)

B: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In diethyl ether Ar-atmosphere; mixing at -50°C, warming to room temp. (during 2 h); evapn. (vac., room temp.), toluene addn. filtration off of Li-triflate, evapn. (vac.); elem. anal.;	A >95 B n/a

...Expand

: 27607-86-9
(C6H5)2Sn(OSO2CF3)2

: 4440-01-1
lithium phenylacetylide

A: 135580-42-6
(C6H5)2Sn(CCC6H5)OSO2CF3

B: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In diethyl ether Ar-atmosphere; mixing at -50°C, warming to room temp. (during 2 h); evapn. (vac., room temp.), toluene addn. filtration off of Li-triflate, evapn. (vac.); elem. anal.;	A >95 B n/a

...Expand

: 27607-78-9
bis(trifluoromethanesulfonyloxy)dimethylsilane

: 3839-32-5
triphenylgermyl lithium

A: 135580-38-0
(CH3)2SiGe(C6H5)3(OSO2CF3)

B: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In diethyl ether Ar-atmosphere; mixing at -70°C, stirring and warming to 0°C (3 h); evapn. (vac., 0°C), toluene addn., filtration off of Li-triflate (cooling), evapn. (vac.); elem. anal.;	A >95 B n/a

...Expand

: 27607-78-9
bis(trifluoromethanesulfonyloxy)dimethylsilane

: 4167-90-2
lithium triphenylstannide

A: 135580-39-1
(CH3)2SiSn(C6H5)3(OSO2CF3)

B: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In diethyl ether Ar-atmosphere; mixing at -70°C, stirring and warming to 0°C (3 h); evapn. (vac., 0°C), toluene addn., filtration off of Li-triflate (cooling), evapn. (vac.); elem. anal.;	A >95 B n/a

...Expand

: 27607-86-9
(C6H5)2Sn(OSO2CF3)2

: 65567-06-8, 4541-02-0
lithium diphenylphosphide

A: 135604-57-8
(C6H5)2Sn{P(C6H5)2}(OSO2CF3)

B: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
In diethyl ether Ar-atmosphere; mixing at -50°C, warming to room temp. (during 2 h); evapn. (vac., room temp.), toluene addn. filtration off of Li-triflate, evapn. (vac.); elem. anal.;	A >95 B n/a

...Expand

: 335-05-7
Trifluoromethanesulfonyl fluoride

: 33454-82-9
lithium trifluoromethanesulfonate

Conditions

Conditions	Yield
With calcium oxide; lithium hydroxide In water for 9.5h;	1001 g

: (4'-formyl-1,1'-biphenyl-4-yl)(triphenyl)phosphonium bromide

: 33454-82-9
lithium trifluoromethanesulfonate

(4'-formyl-1,1'-biphenyl-4-yl)(triphenyl)phosphonium trifluoromethanesulfonate: 1017241-87-0
(4'-formyl-1,1'-biphenyl-4-yl)(triphenyl)phosphonium trifluoromethanesulfonate

Conditions

Conditions	Yield
In dichloromethane; water; acetonitrile for 1h;	100%

: 395-25-5
bis(4-fluorophenyl)sulfoxide

: 33454-82-9
lithium trifluoromethanesulfonate

: 578-95-0
10H-acridin-9-one

: 1306757-09-4
CF3O3S(1-)*C25H16F2NOS(1+)

Conditions

Conditions	Yield
Stage #1: bis(4-fluorophenyl)sulfoxide; 10H-acridin-9-one With methanesulfonic acid; phosphorus pentoxide In chlorobenzene at 50℃; for 2h; Inert atmosphere; Stage #2: lithium trifluoromethanesulfonate In dichloromethane for 1h;	100%

...Expand

: 33454-82-9
lithium trifluoromethanesulfonate

: 2-[(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)methyl]-4,6-di-tert-butylphenol

: 1572037-31-0
C26H43F3LiNO8S

Conditions

Conditions	Yield
In diethyl ether at 20℃; Inert atmosphere; Schlenk technique;	100%

: 143-24-8
Tetraethylene glycol dimethyl ether

: 33454-82-9
lithium trifluoromethanesulfonate

: Li(1+)*C10H22LiO5(1+)*CF3O3S(1-)

Conditions

Conditions	Yield
at 79.84℃; for 0.5h;	100%

: 33454-82-9
lithium trifluoromethanesulfonate

: 1-benzyl-4-aza-1,4-diazoniabicyclo[2.2.2]octane triflate

: 1-benzyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane ditriflate

Conditions

Conditions	Yield
With fluorine In acetonitrile at -10 - 20℃; Inert atmosphere;	99%

: 1,2,3,4,5,6,7,8-octahydro-1,4;5,8-anti-dimethanoanthracene-9-iodonium(phenyl) tosylate

: 33454-82-9
lithium trifluoromethanesulfonate

: 1,2,3,4,5,6,7,8-octahydro-1,4;5,8-anti-dimethanoanthracene-9-iodonium(phenyl) triflate

Conditions

Conditions	Yield
In chloroform at 20℃; for 0.5h;	99%

: 33454-82-9
lithium trifluoromethanesulfonate

: 56-40-6
glycine

: Li(glycine)(CF3SO3)

Conditions

Conditions	Yield
In ethanol at 80℃; for 0.333333h; Irradiation;	99%

: C19H32N6O4(2+)*2Br(1-)

: 33454-82-9
lithium trifluoromethanesulfonate

: C19H32N6O4(2+)*2CF3O3S(1-)

Conditions

Conditions	Yield
In water at 20℃; for 2h;	99%

: C14H20NO4(1+)*I(1-)

: 33454-82-9
lithium trifluoromethanesulfonate

: N-[(methyl 5-deoxy-2,3-O-isopropylidene-β-D-ribofuranoside)-5-yl]pyridinium triflate

Conditions

Conditions	Yield
In water at 20℃; for 24h;	99%

: 1,1-(1,4-phenylenedimethylene)bis(3-methyl-1H-imidazolium-1-yl) dibromide

: 33454-82-9
lithium trifluoromethanesulfonate

: 1-(2-hydroxyethyl)-3-methylimidazolium trifluoromethanesulfonate

Conditions

Conditions	Yield
In ethanol; water at 20℃; for 4h;	98.6%

: 876610-32-1
1-(1-methyl-1-pyrrolidinio)propane-3-sulfonate

: 33454-82-9
lithium trifluoromethanesulfonate

: triflate lithium 1-methylpyrrolidinium-1-propanesulfonate

Conditions

Conditions	Yield
In methanol for 12h;	98%

: tri-n-butyl(4-vinylbenzyl)phosphonium chloride

: 33454-82-9
lithium trifluoromethanesulfonate

: tributyl-(4-vinylbenzyl)phosphonium triflate

Conditions

Conditions	Yield
In dichloromethane for 8h; Inert atmosphere;	98%
In dichloromethane	92%

: [Os(NH3)5(2,3-η2-4-methoxystyrene)] bis(trifluoromethanesulfonate)

: 33454-82-9
lithium trifluoromethanesulfonate

: 107-02-8
acrolein

: [Os(NH3)5(3,4-η2-8-formyl-2-methoxy-6,7,8,8a-tetrahydronaphthalene)] bis(trifluoromethanesulfonate)

Conditions

Conditions	Yield
In acetonitrile N2; org. compd. dissoln. in CH3CN containing Li-salt, this soln. addn. to Os-compd., soln. stirring for ca. 12 h, pptn. on adding to stirring Et2O; ppt. filtration off, rinsing (ether), vac. drying; elem. anal.;	97%

...Expand

: di(rhodium)tetracarbonyl dichloride

: C43H37N3P2

: 33454-82-9
lithium trifluoromethanesulfonate

: C43H36ClLiN4OP2Rh(1+)*CF3O3S(1-)

Conditions

Conditions	Yield
In dichloromethane for 0.166667h; Glovebox; Inert atmosphere;	97%

...Expand

: 1,1'-(pyridine-2,6-diylbis(methylene))bis(3-(2-(adamantan-1-yl)ethyl)-1H-benzo[d]imidazol-3-ium) dibromide

: 33454-82-9
lithium trifluoromethanesulfonate

: 1,1'-(pyridine-2,6-diylbis(methylene))bis(3-(2-(adamantan-1-yl)ethyl)-1H-benzo[d]imidazol-3-ium) bis(trifluoromethane)sulfonate

Conditions

Conditions	Yield
In methanol at 20℃; for 12h;	97%

: 33454-82-9
lithium trifluoromethanesulfonate

: 1493-13-6
trifluorormethanesulfonic acid

Conditions

Conditions	Yield
With sulfuric acid	96.8%

: 1122-54-9
methyl (4-pyridyl) ketone

: 33454-82-9
lithium trifluoromethanesulfonate

: 135182-95-5
N-Fluoro-4-acetylpyridinium triflate

Conditions

Conditions	Yield
With fluorine In acetonitrile at -40℃; for 3h;	96%

: 33454-82-9
lithium trifluoromethanesulfonate

: 79917-90-1
1-butyl-3-methylimidazolium chloride

: 174899-66-2
1-(n-butyl)-3-methylimidazolium triflate

Conditions

Conditions	Yield
In water	96%
In dichloromethane at 20℃; for 72h; Inert atmosphere;	86.7%
In acetonitrile Heating;	82.8%

: 872006-83-2
4-(1-methylpyrrolidinium-1-yl)butane-1-sulfonate

: 33454-82-9
lithium trifluoromethanesulfonate

: triflate lithium 1-methylpyrrolidinium-1-butanesulfonate

Conditions

Conditions	Yield
In methanol for 12h;	96%

: 42790-42-1
4-aza-1-benzylazoniabicyclo<2.2.2>octane chloride

: 33454-82-9
lithium trifluoromethanesulfonate

: 1-benzyl-4-aza-1,4-diazoniabicyclo[2.2.2]octane triflate

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 24h; Inert atmosphere;	96%

: 1,1'-(pyridine-2,6-diyl)bis(3-(4-(phenylethynyl)benzyl)-1H-benzo[d]imidazol-3-ium) dibromide

: 33454-82-9
lithium trifluoromethanesulfonate

: 1,1'-(pyridine-2,6-diyl)bis(3-(4-(phenylethynyl)benzyl)-1H-benzo[d]imidazol-3-ium) bis(trifluoromethane)sulfonate

Conditions

Conditions	Yield
Stage #1: 1,1'-(pyridine-2,6-diyl)bis(3-(4-(phenylethynyl)benzyl)-1H-benzo[d]imidazol-3-ium) dibromide; lithium trifluoromethanesulfonate In methanol; acetonitrile at 85℃; for 12h; Stage #2: In water at 100℃; for 12h;	96%

: 1243209-98-4
Br(1-)*C23H39N2(1+)

: 33454-82-9
lithium trifluoromethanesulfonate

: 1243210-02-7
CF3O3S(1-)*C23H39N2(1+)

Conditions

Conditions	Yield
In water for 1h;	95%

: C79H111N5O4(2+)*2Br(1-)

: 33454-82-9
lithium trifluoromethanesulfonate

: C79H111N5O4(2+)*2CF3O3S(1-)

Conditions

Conditions	Yield
In methanol at 20℃; for 12h;	95%

: 1,1’-(pyridine-2,6-diylbis(methylene))bis(3-octyl-1H-benzimidazol-3-ium) dibromide

: 33454-82-9
lithium trifluoromethanesulfonate

: 1,1'-(pyridine-2,6-diylbis(methylene))bis(3-octyl-1H-benzimidazol-3-ium) bis(trifluoromethane)sulfonate

Conditions

Conditions	Yield
In methanol at 20℃; for 12h;	95%

: C26H40N4(2+)*2Br(1-)

: 33454-82-9
lithium trifluoromethanesulfonate

: C26H40N4(2+)*2CF3O3S(1-)

Conditions

Conditions	Yield
In acetonitrile at 50 - 60℃; for 5h;	95%

: 100-48-1
pyridine-4-carbonitrile

: 33454-82-9
lithium trifluoromethanesulfonate

: 135182-97-7
N-Fluoro-4-cyanopyridinium triflate

Conditions

Conditions	Yield
With fluorine In acetonitrile at -40℃; for 3h;	94%

: 1210397-31-1, 1268524-46-4
((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2

: 33454-82-9
lithium trifluoromethanesulfonate

: 123-54-6
acetylacetone

: C26H26N5O3Ru(1+)*CF3O3S(1-)

Conditions

Conditions	Yield
Stage #1: ((2,6-bis(1-methylbenzimidazole-2-yl)pyridine)(Cl)Ru)2Cl2 With trifluorormethanesulfonic acid for 1h; Stage #2: acetylacetone With triethylamine In methanol for 3h; Inert atmosphere; Reflux; Stage #3: lithium trifluoromethanesulfonate In water	94%

...Expand

: C22H30N6O4(2+)*2Br(1-)

: 33454-82-9
lithium trifluoromethanesulfonate

: C22H30N6O4(2+)*2CF3O3S(1-)

Conditions

Conditions	Yield
In water at 20℃; for 2h;	94%

: C19H34N4(2+)*2Br(1-)

: C14H13ClN2Pt

: 33454-82-9
lithium trifluoromethanesulfonate

: C31H42N5Pt(1+)*CF3O3S(1-)

Conditions

Conditions	Yield
Stage #1: C19H34N4(2+)*2Br(1-); C14H13ClN2Pt With triethylamine In acetonitrile at 90℃; for 24h; Stage #2: lithium trifluoromethanesulfonate In acetonitrile at 20℃;	94%

...Expand

: 33454-82-9
lithium trifluoromethanesulfonate

: 99045-50-8
n-decyl-tri-n-butylphosphonium bromide

: tributyldecylphosphonium trifluoromethanesulfonate

Conditions

Conditions	Yield
In water; acetone at 20℃; for 15h;	93.4%

Lithium trifluoromethanesulfonate Specification

This chemical is called Methanesulfonic acid, 1,1,1-trifluoro-, lithium salt (1:1), and it's also named as Lithium trifluoromethanesulphonate. With the CAS registry number of 33454-82-9, its product categories are Organic-metal Salt; Catalysts for Organic Synthesis; Classes of Metal Compounds; Homogeneous Catalysts; Li (Lithium) Compounds; Metal Triflates; Synthetic Organic Chemistry; Typical Metal Compounds.

Other characteristics of the Methanesulfonic acid, 1,1,1-trifluoro-, lithium salt (1:1) can be summarised as followings: (1)H-Bond Donor: 1; (2)H-Bond Acceptor: 6; (3)Rotatable Bond Count: 0; (4)Exact Mass: 156.975853; (5)MonoIsotopic Mass: 156.975853; (6)Topological Polar Surface Area: 62.8; (7)Heavy Atom Count: 9; (8)Formal Charge: 0; (9)Complexity: 158; (10)Isotope Atom Count: 0.

Uses of this chemical: The Methanesulfonic acid, 1,1,1-trifluoro-, lithium salt (1:1) could react with pyridine, and obtain the 1-fluoropyridinium triflate. This reaction needs the reagent of 10 percent F₂-N₂, and the solvent of acetonitrile. The yield is 87 %. In addition, this reaction should be taken for 3 hours at the temperature of -40 °C.

The Methanesulfonic acid, 1,1,1-trifluoro-, lithium salt (1:1) could react with pyridine, and obtain the 1-fluoropyridinium triflate

When you are using this chemical, please be cautious about it as the following: This chemical is irritating to eyes, respiratory system and skin. You should wear suitable protective clothing if you use it. In case of contacting with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
1.SMILES: [Li].C(F)(F)(F)S(=O)(=O)O
2.InChI: InChI=1/CHF3O3S.Li/c2-1(3,4)8(5,6)7;/h(H,5,6,7);
3.InChIKey: WDGKXRCNMKPDSD-UHFFFAOYAM

Product Name

Lithium triflate

Synthetic route

Lithium trifluoromethanesulfonate Specification

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