Product Name

  • Name

    Methyl mercury

  • EINECS
  • CAS No. 22967-92-6
  • Article Data8
  • CAS DataBase
  • Density g/cm3
  • Solubility
  • Melting Point
  • Formula CH3 Hg
  • Boiling Point °Cat760mmHg
  • Molecular Weight 215.625
  • Flash Point °C
  • Transport Information
  • Appearance
  • Safety A poison. An experimental teratogen. Experimental reproductive effects. Mutation data reported. Used as a fungicide. When heated to decomposition it emits toxic fumes of Hg. See also MERCURY COMPOUNDS, ORGANIC.
  • Risk Codes
  • Molecular Structure Molecular Structure of 22967-92-6 (Methyl mercury)
  • Hazard Symbols
  • Synonyms Mercury(1+),methyl-, ion (8CI); Methylmercury; Methylmercury cation; Methylmercury ion(1+);Methylmercury(1+); Methylmercury(II) cation; Monomethylmercury cation
  • PSA 0.00000
  • LogP 0.58130

Synthetic route

hydrogen cation

hydrogen cation

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

A

methylmercury(II)
22967-92-6

methylmercury(II)

B

mercury(II) iodide

mercury(II) iodide

Conditions
ConditionsYield
In water byproducts: CH4; impact of H2SO4, HClO4 or CH3COOH on 5E-3 molar soln.;;
In methanol byproducts: CH4; impact of H2SO4, HClO4 or CH3COOH on 5E-3 molar soln.;;
In water-d2 byproducts: CH4; impact of H2SO4, HClO4 or CH3COOH on 5E-3 molar soln.;;
In 1,4-dioxane byproducts: CH4; impact of H2SO4, HClO4 or CH3COOH on 5E-3 molar soln.;;
methylcobalamine

methylcobalamine

mercury ion

mercury ion

A

dimethylmercury
593-74-8

dimethylmercury

B

methylmercury(II)
22967-92-6

methylmercury(II)

mercury ion

mercury ion

methylmercury(II)
22967-92-6

methylmercury(II)

Conditions
ConditionsYield
With cobaloxime
With cobaloxime
dimethylsulfide
75-18-3

dimethylsulfide

methylmercury(II)
22967-92-6

methylmercury(II)

CH3HgS(CH3)2(1+)
44209-58-7

CH3HgS(CH3)2(1+)

Conditions
ConditionsYield
In water
methylmercury(II)
22967-92-6

methylmercury(II)

acetic acid
64-19-7

acetic acid

methyl mercury acetate
108-07-6

methyl mercury acetate

Conditions
ConditionsYield
With nitric acid In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 4-5; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

methylmercury(II) hydroxide
1184-57-2

methylmercury(II) hydroxide

Conditions
ConditionsYield
With sodium hydroxide In water 1 M aq. soln. of CH3Hg(1+) was diluted by water to final concn. 0.33 M at pH 8.39 adjusting with 4 M NaOH; not isolated, detected by Raman spectrum;
(2-aminoethanethiolato-N,S)bis(1,2-diaminoethane)cobalt(III) perchlorate

(2-aminoethanethiolato-N,S)bis(1,2-diaminoethane)cobalt(III) perchlorate

methylmercury(II)
22967-92-6

methylmercury(II)

Co(NH2CH2CH2NH2)2(SCH2CH2NH2)(2+)*CH3Hg(1+)=Co(NH2CH2CH2NH2)2(SCH2CH2NH2)(CH3Hg)(3+)

Co(NH2CH2CH2NH2)2(SCH2CH2NH2)(2+)*CH3Hg(1+)=Co(NH2CH2CH2NH2)2(SCH2CH2NH2)(CH3Hg)(3+)

Conditions
ConditionsYield
In not given Kinetics; CH3Hg(1+) was added to Co-complex at 85°C; monitored by spectrophotometry;
(H2O)5CrCH2CH2SO3(1+)
114185-94-3

(H2O)5CrCH2CH2SO3(1+)

methylmercury(II)
22967-92-6

methylmercury(II)

A

chromium(III) hexahydrate cation
14873-01-9

chromium(III) hexahydrate cation

B

H3CHgCH2CH2SO3(1-)

H3CHgCH2CH2SO3(1-)

Conditions
ConditionsYield
In not given Kinetics;
lysine hydrobromide
61686-24-6

lysine hydrobromide

methylmercury(II)
22967-92-6

methylmercury(II)

methylmercury(II) bromide
506-83-2

methylmercury(II) bromide

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
{Ni(SCH2CH2(SHCH2CH2)2P)2}

{Ni(SCH2CH2(SHCH2CH2)2P)2}

methylmercury(II)
22967-92-6

methylmercury(II)

Ni(2+)*2SCH2CH2P(CH2CH2SHgCH3)2(1-)

Ni(2+)*2SCH2CH2P(CH2CH2SHgCH3)2(1-)

methylmercury(II)
22967-92-6

methylmercury(II)

CH3HgOH2(1+)

CH3HgOH2(1+)

Conditions
ConditionsYield
With nitric acid In water 1 M aq. soln. of CH3Hg(1+) was diluted by water to final concn. 0.33 M at pH <2 adjusting with 4 M HNO3; not isolated, detected by Raman spectrum;
formic acid
64-18-6

formic acid

methylmercury(II)
22967-92-6

methylmercury(II)

methylmercury (1+); formate
40187-67-5

methylmercury (1+); formate

Conditions
ConditionsYield
With nitric acid In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 3-4; not isolated, detected by Raman spectrum;
Glutamic acid
617-65-2

Glutamic acid

methylmercury(II)
22967-92-6

methylmercury(II)

(CH3Hg)2OCOCH2CH2CHNH2COO

(CH3Hg)2OCOCH2CH2CHNH2COO

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed and the solvent was evapd.; detected by Raman spectrum;
In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylammonium cation
17000-00-9

methylammonium cation

methylmercury(II)
22967-92-6

methylmercury(II)

H3CHgNH2(CH3)(1+)

H3CHgNH2(CH3)(1+)

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

(CH3Hg)2OH(1+)
40695-98-5

(CH3Hg)2OH(1+)

Conditions
ConditionsYield
With nitric acid In water 1 M aq. soln. of CH3Hg(1+) was diluted by water to final concn. 0.33 M at pH 4.5 adjusting with 4 M HNO3; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

aspartic Acid
617-45-8

aspartic Acid

CH3HgOCOCH2CHNH2COOH

CH3HgOCOCH2CHNH2COOH

Conditions
ConditionsYield
With nitric acid In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 3-4; not isolated, detected by Raman spectrum;
serin
302-84-1

serin

methylmercury(II)
22967-92-6

methylmercury(II)

HOCH2CHNH2(COO)HgCH3

HOCH2CHNH2(COO)HgCH3

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed and the solvent was evapd.; detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

rac-Pro-OH
609-36-9

rac-Pro-OH

CH3HgC4H7NCOO

CH3HgC4H7NCOO

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
ASPARAGINE
3130-87-8

ASPARAGINE

methylmercury(II)
22967-92-6

methylmercury(II)

CH3HgNH2COCH2CHNH2COO

CH3HgNH2COCH2CHNH2COO

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

CH3HgNH2(CH2)4CHNH2(COO)HgCH3(1+)

CH3HgNH2(CH2)4CHNH2(COO)HgCH3(1+)

Conditions
ConditionsYield
In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
Conditions
ConditionsYield
In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

DL-methionine
59-51-8

DL-methionine

(DL-methioninato)(methyl)mercury(II)

(DL-methioninato)(methyl)mercury(II)

Conditions
ConditionsYield
In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

DL-methionine
59-51-8

DL-methionine

CH3SCH2CH2CHNH2(COO)HgCH3(1+)

CH3SCH2CH2CHNH2(COO)HgCH3(1+)

Conditions
ConditionsYield
With nitric acid In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH <2; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

histidine hydrochloride
6459-59-2

histidine hydrochloride

CH3HgNCHNHCHCCH2CHNH2(COO)HgCH3(1+)

CH3HgNCHNHCHCCH2CHNH2(COO)HgCH3(1+)

Conditions
ConditionsYield
In water aq. solns. of stoich. amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

dl-arginine hydrochloride
220144-84-3

dl-arginine hydrochloride

CH3HgNH3C(NH)NHCH2CH2CHNH2COO(1+)

CH3HgNH3C(NH)NHCH2CH2CHNH2COO(1+)

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

(CH3Hg)2C8H5NCH2CHNH2COO(1+)

(CH3Hg)2C8H5NCH2CHNH2COO(1+)

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed and the solvent was evapd.; detected by Raman spectrum;
ammonium sulfate

ammonium sulfate

methylmercury(II)
22967-92-6

methylmercury(II)

CH3HgNH3(1+)

CH3HgNH3(1+)

Conditions
ConditionsYield
In water aq. solns. of equimolar amts. of reagents were mixed at a final concn. 0.33 M at pH 7; not isolated, detected by Raman spectrum;
methylmercury(II)
22967-92-6

methylmercury(II)

captopril
62571-86-2

captopril

A

cis-methylmercury(II)-captopril

cis-methylmercury(II)-captopril

B

trans-methylmercury(II)-captopril

trans-methylmercury(II)-captopril

Conditions
ConditionsYield
In water-d2 Kinetics; not isolated, detected by NMR spectroscopy;;

Methyl mercury Chemical Properties

Chemistry informtion about  Methyl mercury (22967-92-6) is:
IUPAC Name: Methylmercury(1+)
Synonyms: Methylmercury ; Methylhydridemercury(Ii)
MF: CH3Hg
MW: 215.62
Following is the molecular structure of  Methyl mercury (22967-92-6) is:

Methyl mercury Uses

 Methyl mercury (22967-92-6) can be used in organic synthesis and environmental monitoring and analytical testing of the quality assurance and quality control. It can also be used for ICP-AES, AAS, AFS, ICP-MS, ion chromatography and for instrument calibration, method validation and technical arbitration.

Methyl mercury Toxicity Data With Reference

Toxic

Methyl mercury Specification

 Methyl mercury (22967-92-6) is a colorless liquid and it has volatile.It can soluble in ether and ethanol, but insoluble in water.
First aid measures:
Skin: Remove contaminated clothing, rinse thoroughly with plenty of water flow. Medical treatment.
Eye:  Immediately turn over the upper and lower eyelids, with large flows of water or saline flushing. Medical treatment.
Inhalation: Rapidly from the scene to fresh air. To maintain airway patency. To the oxygen breathing difficulties. Breathing stops, artificial respiration immediately. Medical treatment.
Inhalation: Coverage to blues or egg white. Gastric lavage as soon as possible. Medical treatment.

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