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Hebei yanxi chemical co.,LTD.

hebei yanxi chemical co., LTD who registered capital of 10 million yuan, nearly to $2 million, we have a pharmaceutical raw materials factory production of pharmaceutical raw materials, and a reagent r&d center, and we do research and developm

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 3.0

Type:Trading Company

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Wholesale price CAS 593-74-8 with best price

Cas:593-74-8

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Upbio Tech Co.,Ltd

1.No Less 8 years exporting experience. Clients can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specialized

Mercury, dimethyl- 593-74-8

Cas:593-74-8

Min.Order:1 Kilogram

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Qingdao Beluga Import and Export Co., LTD

DIMETHYLMERCURY CAS: 593-74-8 Qingdao Belugas Import and Export Co., Ltd. is a scientific and technological company integrating research and development, production and trade of chemical intermediates, specializing in high quality organic intermedia

DIMETHYLMERCURY CAS: 593-74-8

Cas:593-74-8

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shandong Hanjiang Chemical Co., Ltd.

Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by emai

Mercury, dimethyl-

Cas:593-74-8

Min.Order:1 Kilogram

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Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Mercury, dimethyl-

Cas:593-74-8

Min.Order:0

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Changchun Artel lmport and Export trade company

Product Detail Minimum Order Qty. 10 Gram

dimethylmercury CAS NO.593-74-8 CAS NO.593-74-8

Cas:593-74-8

Min.Order:20 Metric Ton

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Wuhan Zenuo Biological Medicine Technology Co Ltd

Product Name: DIMETHYLMERCURY Synonyms: Methyl mercury ion;MERCURY DIMETHYL;DIMETHYLMERCURY;(CH3)2Hg;dimethyl-mercur;methylmercury II;MONOMETHYLMERCURY;5,7-Dinitro-8-hydroxyquinoline CAS: 593-74-8 MF: C2H6Hg MW: 230.66 EINECS: 209-805-3

DIMETHYLMERCURY big supplier with lower price

Cas:593-74-8

Min.Order:1 Kilogram

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Triumph International Development Limilted

Appearance:white powder/crystal Storage:Store in a cool,dry place and keep away from direct strong light Package:As customer request Application:Used for research and industrial manufacture. Transportation:Common products:Sea/A

2-Allyl-4,6-dibenzoylresorcinol

Cas:593-74-8

Min.Order:100 Metric Ton

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Type:Lab/Research institutions

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Wuhan Han Sheng New Material Technology Co.,Ltd

Our Advantage: high quality with competitive price High quality standard: BP/USP/EP Enterprise standard All purity customized Fast and safe delivery We have reliable forwarder who can help us deliver our goods more fast and safe. We

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:10 Kilogram

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Type:Trading Company

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Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Dimethylmercury

Cas:593-74-8

Min.Order:10 Gram

FOB Price: $100.0

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HANGZHOU YUNUO CHEMICAL CO.,LTD

Superior quality, moderate price & quick delivery. Appearance:colourless liquid Storage:Well-sealed and put in dry and cool conditions. Protected from direct sunlight or high temperature. Package:as per your request Application:Used as Pharma

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:1 Kilogram

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Type:Trading Company

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Zibo Dorne chemical technology co. LTD

Product Details Grade: pharmaceutical grade Purity:99%+ ProductionCapacity: 1000 Kilogram/Month Scope of use: For scientific research only(The product must be used legally) Our Advantage 1. Best quality with competitive price. 2. Quick shipping,

Mercury, dimethyl-

Cas:593-74-8

Min.Order:1 Gram

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Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

DIMETHYLMERCURY CAS593-74-8

Cas:593-74-8

Min.Order:1 Kilogram

FOB Price: $1.0 / 100.0

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Jiangsu Qianyu Molecular Technology Co., LTD.

Our Advantages A. International Top level TechnologyOur company owned biomedicine experts are famous at home and abroad with rich experience in research and development in the field of efficient chiral functional molecules research and development an

high purityDIMETHYLMERCURY

Cas:593-74-8

Min.Order:0

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EAST CHEMSOURCES LIMITED

factory?direct?saleAppearance:White Powder Storage:Store In Dry, Cool And Ventilated Place Package:25kg/drum, also according to the clients requirement Application:It is widely used as a thickener, emulsifier and stabilizer Transportation:By Sea Or B

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:1 Kilogram

FOB Price: $18.0 / 20.0

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TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:1 Kilogram

FOB Price: $2.0

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Henan Kanbei Chemical Co.,LTD

High quality, competitive price, fast delivery and first-class service we possesses have won the trust and praise of customers. Standard: BP/USP/EP The purity is equal or greater than 99%. As a supplier, we can provide high-quality produc

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:0

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Shandong Mopai Biotechnology Co., LTD

Shandong Mopai Biotechnology Co., LTD is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. W

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:1 Gram

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KAISA GROUP INC

1.Applied in food field.it can improve the immune system and prolong life. 2.Appliedin cosmetic field.it can improve the skin care. 3.Applied in pharmaceutical field.it can treat various dieases. 4.Our product quality assurance will make our customer

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:1 Metric Ton

FOB Price: $1.5

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Golden Pharma Co., Limited

GOLDEN PHARMA CO.,LIMITED.is a professional pharmaceutical company,our team have more than 20years expereince in pharmaceutical production and sales. we are a professional technical enterprise specializing in the R & D, production,QA regulation

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:1 Kilogram

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Type:Other

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Bluecrystal chem-union

We are a Union of chemistry in China, consists of chemists,engineers, laboratories,factories in China. We organize surplus capacity of R&D and production as well as custom synthesis for chemical products and chemical business project. We are supp

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:1 Metric Ton

FOB Price: $1.0

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Hebei Mojin Biotechnology Co.,Ltd

We produce carbomer by our own factory,carbomer 940 is our best seller.It is used for cosmetic and medical.And we also become agent for lubrizol.Our carbomer 940 get high viscosity and good transparency.The price will depond on the market,surely supp

Mercury, dimethyl-

Cas:593-74-8

Min.Order:0

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GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

Mercury, dimethyl-

Cas:593-74-8

Min.Order:0

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Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:0

Negotiable

Type:Manufacturers

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Wuhan Circle Star Chem-medical Technology co.,Ltd.

1,we produce and sell good chemicals around the world.2,our success rate is about 95%. this means, if customer order is accepted, the probability that the customer will obtain the ordered substances, is 95%.3,our staff consists of highly qualified in

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:0

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Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

Mercury, dimethyl-

Cas:593-74-8

Min.Order:0

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HANGZHOU TIANYE CHEMICALS CO., LTD.

We product this chemical more than 10 years . We are very experience to export it to many countries, Our superior & stable quality , competitive price gain warm reception from our customers. Application:intermediate

DIMETHYLMERCURY

Cas:593-74-8

Min.Order:0

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Hubei Langyou International Trading Co., Ltd

dimethylmercury CAS NO.593-74-8 Application:dimethylmercury CAS NO.593-74-8

dimethylmercury CAS NO.593-74-8

Cas:593-74-8

Min.Order:0

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Type:Other

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DB BIOTECH CO., LTD

best seller Application:API

DIMETHYLMERCURY

Cas:593-74-8

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Synthetic route

diphenylmercury(II)
587-85-9

diphenylmercury(II)

trimethyl gallium
1445-79-0

trimethyl gallium

A

methyl(diphenyl)gallium
1059626-80-0

methyl(diphenyl)gallium

B

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
In neat (no solvent) (CH3)3Ga was added to freshly sublimed diphenylmercury, the suspn. was heated at 100°C in a closed vessel for 3 h, cooled to room temp. without stiring; volatiles were removed in vac. (1E-2 mbar), crystals were washed with n-hexane and dried in vac. for 2 h: elem. anal.;A 98%
B n/a
bis(trifluoromethyl)mercury
371-76-6

bis(trifluoromethyl)mercury

Tetramethylblei-(IV)
75-74-1

Tetramethylblei-(IV)

A

dimethylmercury
593-74-8

dimethylmercury

B

methyl(trifluoromethyl)mercury
33327-63-8

methyl(trifluoromethyl)mercury

C

trimethyl(trifluoromethyl)lead
646-62-8

trimethyl(trifluoromethyl)lead

Conditions
ConditionsYield
In toluene absence of air and moisture; heating of PbMe4 with two-fold excess of Hg-compd. (sealed tube, 70°C, 2 weeks); gas chromy.;A 2%
B 94%
C 93%
diphenylmercury(II)
587-85-9

diphenylmercury(II)

trimethyl gallium
1445-79-0

trimethyl gallium

A

dimethyl(phenyl)gallium
1059626-77-5

dimethyl(phenyl)gallium

B

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
In neat (no solvent) in an Schlenk flask (CH3)3Ga was added to freshly sublimed (C6H5)2Hg, the vessel was tightly closed, the suspn. was heated at 100°C for 5h, cooled to room temp.; volatiles were removed under reduced pressure (10 mbar), the residue waswashed twice with n-hexane at -70°C; elem. anal.;A 90%
B n/a
pentakis(chloromercurio)(pentamethyl)ruthenocene

pentakis(chloromercurio)(pentamethyl)ruthenocene

methylmagnesium chloride
676-58-4

methylmagnesium chloride

A

Ru2(C5(CH3)5)2(C5Mg4Cl4)2Mg
178112-05-5

Ru2(C5(CH3)5)2(C5Mg4Cl4)2Mg

B

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
In tetrahydrofuran byproducts: methylchloride; 23°C, 12 equiv of methylmagnesiumchloride;A 85%
B n/a
[(C5H5)2Ti(C6H5)(CH3)]
75535-77-2

[(C5H5)2Ti(C6H5)(CH3)]

methylmercury(II) chloride
115-09-3

methylmercury(II) chloride

A

bis(cyclopentadienyl)methyltitanium(IV) chloride
1278-83-7

bis(cyclopentadienyl)methyltitanium(IV) chloride

B

Cp2Ti(Ph)Cl

Cp2Ti(Ph)Cl

C

dimethylmercury
593-74-8

dimethylmercury

D

methyl phenyl mercury
21392-61-0

methyl phenyl mercury

Conditions
ConditionsYield
In [(2)H6]acetone to cold (-78 °C) soln. of Ti complex (excess) in acetone-d6 added soln. of MeHgCl in acetone-d6 under N2, stirred at -78 °C for 2h, stirred at room temp. for 6 h; monitored by NMR;A 40%
B 60%
C 60%
D 40%
1-(2-hydroxyethyl)-3-methyl-(1H)-imidazole-2(3H)-selone
1451001-55-0

1-(2-hydroxyethyl)-3-methyl-(1H)-imidazole-2(3H)-selone

methylmercury(II) chloride
115-09-3

methylmercury(II) chloride

A

C12H20Cl2HgN4O2Se2

C12H20Cl2HgN4O2Se2

B

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
In water; acetonitrile at 23℃; for 168h; Kinetics; Schlenk technique;A 53%
B n/a
methylmercury-L-glutathionate

methylmercury-L-glutathionate

1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazole-2(3H)-thione

1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazole-2(3H)-thione

A

GLUTATHIONE
70-18-8

GLUTATHIONE

mercury sulfide

mercury sulfide

C

dimethylmercury
593-74-8

dimethylmercury

D

1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazol-2(3H)-one
2033-53-6

1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazol-2(3H)-one

Conditions
ConditionsYield
Stage #1: methylmercury-L-glutathionate; 1-(2-hydroxyethyl)-3-methyl-1H-benzo[d]imidazole-2(3H)-thione In water; acetonitrile at 37℃; for 1h;
Stage #2: With sodium hydrogencarbonate In water; acetonitrile at 37℃; for 5h;
A n/a
B 11 mg
C n/a
D 40%
methyl bromide
74-83-9

methyl bromide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With sodium amalgam; acetic acid methyl ester at -5 - -3℃;
methyl magnesium iodide
917-64-6

methyl magnesium iodide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With diethyl ether; mercury dichloride
methyl radical
2229-07-4

methyl radical

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With mercury
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

dimethylmercury
593-74-8

dimethylmercury

methylmagnesium bromide
75-16-1

methylmagnesium bromide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With diethyl ether; mercury dibromide
potassium cyanide
151-50-8

potassium cyanide

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

dimethylmercury
593-74-8

dimethylmercury

methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With pyridine; copper
With zinc
dimethyl sulfate
77-78-1

dimethyl sulfate

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With sodium amalgam; acetic acid methyl ester
methyl iodide
74-88-4

methyl iodide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With sodium amalgam; ethyl acetate at 10℃;
With sodium amalgam; acetic acid ester
acetic acid methyl ester
79-20-9

acetic acid methyl ester

dimethyl sulfate
77-78-1

dimethyl sulfate

sodium amalgam

sodium amalgam

dimethylmercury
593-74-8

dimethylmercury

aluminium carbide

aluminium carbide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With water; mercury dichloride in schwach saurer Loesung;
methylmercury(II) iodide
143-36-2

methylmercury(II) iodide

lime/chalk/

lime/chalk/

dimethylmercury
593-74-8

dimethylmercury

methylmercury acetate

methylmercury acetate

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With pyridine; water at 30 - 40℃; Electrolysis.An einer Platinakathode;
methylmercury chloride

methylmercury chloride

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With ammonia Electrolysis.man an der Kathode auftretenden Niederschlag sich auf Zimmertemperatur erwaermen laesst;
methylmercury halide

methylmercury halide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With sodium hydroxide; tin(ll) chloride
methylmercury sulfate

methylmercury sulfate

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
With sodium sulfate Electrolysis;
methylmercury sulfide

methylmercury sulfide

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
beim Erwaermen;
pyridine
110-86-1

pyridine

methylmercury(II) chloride
115-09-3

methylmercury(II) chloride

platinum

platinum

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
Aus einer 25prozentigen waessrigen Loesung des Acetats.Electrolysis;
pyridine
110-86-1

pyridine

methylmercury (1+); hydrosulfide
54277-95-1

methylmercury (1+); hydrosulfide

platinum

platinum

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
Aus einer 25prozentigen waessrigen Loesung des Acetats.Electrolysis;
pyridine
110-86-1

pyridine

methylmercury (1+); dicarbonate

methylmercury (1+); dicarbonate

platinum

platinum

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
Aus einer 25prozentigen waessrigen Loesung des Acetats.Electrolysis;
pyridine
110-86-1

pyridine

MeOCS2HgMe
435339-65-4

MeOCS2HgMe

platinum

platinum

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
Aus einer 25prozentigen waessrigen Loesung des Acetats.Electrolysis;
pyridine
110-86-1

pyridine

methylmercury (1+); ethyl xanthogenate
435339-66-5

methylmercury (1+); ethyl xanthogenate

platinum

platinum

dimethylmercury
593-74-8

dimethylmercury

Conditions
ConditionsYield
Aus einer 25prozentigen waessrigen Loesung des Acetats.Electrolysis;
dimethylmercury
593-74-8

dimethylmercury

bis(trifluoromethanesulfonyl)amide
82113-65-3

bis(trifluoromethanesulfonyl)amide

MeHg(NTf2)

MeHg(NTf2)

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; Schlenk technique; Inert atmosphere;100%
dimethylmercury
593-74-8

dimethylmercury

bis(fluorosulfonyl)amide
14984-73-7

bis(fluorosulfonyl)amide

MeHg(N(SO2F)2)

MeHg(N(SO2F)2)

Conditions
ConditionsYield
In dichloromethane at 0 - 20℃; Schlenk technique; Inert atmosphere;100%
([(η5-C5H4)CH2CH(μ3:η1-O)CH2OBu(n)]Yb)4*tetrahydrofuran

([(η5-C5H4)CH2CH(μ3:η1-O)CH2OBu(n)]Yb)4*tetrahydrofuran

dimethylmercury
593-74-8

dimethylmercury

[(η5-C5H4)CH2CH(η1-O)CH2OBu(n)]YbMe(tetrahydrofuran)
339184-76-8

[(η5-C5H4)CH2CH(η1-O)CH2OBu(n)]YbMe(tetrahydrofuran)

Conditions
ConditionsYield
In tetrahydrofuran byproducts: Hg; (vac.); refluxed for 60 h; decanted, crystd. by slow diffusion of hexane vapor into the soln.; elem. anal.;98%
N,N'-bis-methanesulfonyl-sulfur diimide
5636-09-9

N,N'-bis-methanesulfonyl-sulfur diimide

dimethylmercury
593-74-8

dimethylmercury

N-(Methylmercurio)-N,N'-bis(methylsulfonyl)methansulfinamidin

N-(Methylmercurio)-N,N'-bis(methylsulfonyl)methansulfinamidin

Conditions
ConditionsYield
In dichloromethane stirred at room temp. for 24 h; evapd. in vac., recrystd. (CH2Cl2, 5°C), filtered, dried in vac., elem. anal.;91%
2Pt(1+)*2N(CH2CH2CH3)4(1+)*4Cl(1-)*2CO=(N(CH2CH2CH3)4)2[Pt2Cl4(CO)2]

2Pt(1+)*2N(CH2CH2CH3)4(1+)*4Cl(1-)*2CO=(N(CH2CH2CH3)4)2[Pt2Cl4(CO)2]

dimethylmercury
593-74-8

dimethylmercury

tetra-n-propylammonium carbonyldichloromethylplatinate(II)
68422-17-3

tetra-n-propylammonium carbonyldichloromethylplatinate(II)

Conditions
ConditionsYield
In dichloromethane byproducts: Hg; addn. of stoich. amt. of Hg-compd. to Pt-complex, standing (overnight); treatment with charcoal, filtration, concn., crystn. on Et2O addn.; elem. anal.;91%
phenylpentacarbonylmanganese(I)
13985-77-8

phenylpentacarbonylmanganese(I)

dimethylmercury
593-74-8

dimethylmercury

η(2)-(2-acetylphenyl)tetracarbonylmanganese

η(2)-(2-acetylphenyl)tetracarbonylmanganese

Conditions
ConditionsYield
In toluene byproducts: Hg, benzene; reflux, 1 h; elem. anal.;82%
[Ir(acetylacetonate-C3)(η2-O,O-acetylacetonate)2(H2O)]
637744-14-0

[Ir(acetylacetonate-C3)(η2-O,O-acetylacetonate)2(H2O)]

dimethylmercury
593-74-8

dimethylmercury

[Ir(μ-acac-O,O,C3)(acac-O,O)(CH3)]2
678984-24-2

[Ir(μ-acac-O,O,C3)(acac-O,O)(CH3)]2

Conditions
ConditionsYield
In methanol (Schlenk), dimethylmercury was added to a soln. of complex in methanol, the flask was sealed, placed in a 60°C oil bath for 2 h, cooled to room temp.; the soln. was vac.-transferred, loaded on a silica gel column, eluted with THF; elem. anal;80%
tris(1,10-phenantholine)iron(III) perchlorate

tris(1,10-phenantholine)iron(III) perchlorate

dimethylmercury
593-74-8

dimethylmercury

A

(Fe(N2C12H8)2(N2C12H7CH3))(2+)*2ClO4(1-)=(Fe(N2C12H8)2(N2C12H7CH3))(ClO4)2

(Fe(N2C12H8)2(N2C12H7CH3))(2+)*2ClO4(1-)=(Fe(N2C12H8)2(N2C12H7CH3))(ClO4)2

B

methylmercury(II) bromide
506-83-2

methylmercury(II) bromide

Conditions
ConditionsYield
With sodium bromide In acetonitrile Me2Hg in CH3CN added to Fe(phen)3(ClO4)3 in CH3CN at 20°C under Ar and soln. stirred for 2 h, drop water added and Fe(II) complex filtered, filtrate dried with MgSO4 and treated NaBr;A n/a
B 78%
dimethylmercury
593-74-8

dimethylmercury

thianthrenium tetrafluoroborate
60896-34-6

thianthrenium tetrafluoroborate

5-methylthianthrenyliumyl tetrafluoroborate
32593-00-3

5-methylthianthrenyliumyl tetrafluoroborate

Conditions
ConditionsYield
In acetonitrile76%
tris(di-tert-butyphosphino)gallane
140194-63-4

tris(di-tert-butyphosphino)gallane

dimethylmercury
593-74-8

dimethylmercury

Quecksilber-bis-(di-tert.-butyl-phosphid)
40894-47-1

Quecksilber-bis-(di-tert.-butyl-phosphid)

Conditions
ConditionsYield
In toluene byproducts: {Me2Ga(μ-t-Bu2P)}2; excess of Me2Hg was added to frozen soln. of Ga compd. at 77 K and mixt. was slowly warmed to room temp.; volatiles were removed under vac., residue recrystd. from hexane at -30°C;76%
cis-[PdCl2(CNC6H4OMe-p)2]
40927-13-7

cis-[PdCl2(CNC6H4OMe-p)2]

dimethylmercury
593-74-8

dimethylmercury

trans-chloro-1,4-bis(p-methoxyphenyl)-1,4-diaza-3-methylbutadiene-2-yl-bis(triphenylphosphine)palladium(II)

trans-chloro-1,4-bis(p-methoxyphenyl)-1,4-diaza-3-methylbutadiene-2-yl-bis(triphenylphosphine)palladium(II)

Conditions
ConditionsYield
With P(C6H5)3 In benzene byproducts: MeHgCl; addn. of slight excess of HgMe2 to Pd-complex, stirring for 7-8 h, addn.of stoich. amt. of PPh3, 15 min; filtration (charcoal), concn. (reduced pressure), pptn. on Et2O addn., filtration, washing (ether), drying (vac.), sublimation off of MeHgCl (80-100°C, 0.01 Torr), repptn. from CH2Cl2 with Et2O; elem. anal.;75%
dimethylmercury
593-74-8

dimethylmercury

mercury(II) selenocyanate
5487-13-8, 53408-92-7

mercury(II) selenocyanate

methylmercury selenocyanate
2180-02-1

methylmercury selenocyanate

Conditions
ConditionsYield
In not given metathesis reaction; elem. anal.;75%
dimethylmercury
593-74-8

dimethylmercury

bis(p-toluenesulfonyl) sulfur diimide
851-06-9

bis(p-toluenesulfonyl) sulfur diimide

N-(Methylmercurio)-N,N'-bis(4-methylphenylsulfonyl)methansulfinamidin

N-(Methylmercurio)-N,N'-bis(4-methylphenylsulfonyl)methansulfinamidin

Conditions
ConditionsYield
In dichloromethane stirred for 48 h; evapd. in vac., dissolved in CH2Cl2 at room temp., pptd (petroether), elem. anal.;71%
dimethylmercury
593-74-8

dimethylmercury

tungsten(VI) chloride
13283-01-7

tungsten(VI) chloride

monomethyltungsten(VI) pentachloride
23830-77-5

monomethyltungsten(VI) pentachloride

Conditions
ConditionsYield
In dichloromethane byproducts: MeHgCl; Ar-atmosphere; dropwise addn. of equimolar amt. of HgMe2 to WCl6 (-45°C, stirring), standing for 1 h; addn. of cold pentane (-45°C), filtration off of MeHgCl, evapn. (-20°C), washing (pentane, -20°C), recrystn. (CH2Cl2/pentane=1:5, -40°C, 1 week); elem. anal.;66%
molybdenum(V) chloride
10241-05-1

molybdenum(V) chloride

dimethylmercury
593-74-8

dimethylmercury

1,2-bis-(diphenylphosphino)ethane
1663-45-2

1,2-bis-(diphenylphosphino)ethane

tetrachloro(methyl){bis(diphenylphosphino)ethane}molybdenum(V)

tetrachloro(methyl){bis(diphenylphosphino)ethane}molybdenum(V)

Conditions
ConditionsYield
In dichloromethane byproducts: HgCl2; dry Ar and oxygen-free atmosphere, dry and degassed solvents; addn. of CH2Cl2 soln. of HgMe2 to soln. of MoCl5 in CH2Cl2 at -45°C, stirring (5 h), filtration of react. mixt. onto dppe in CH2Cl2 at -45°C, stirring (2 h); addn. of pentane, filtration, washing (pentane) at -35°C, drying under vac.; elem. anal.;66%
all-trans-[Ru(CO)2(PMe2Ph)Cl2]
17141-01-4, 17141-04-7, 25165-53-1, 60426-65-5

all-trans-[Ru(CO)2(PMe2Ph)Cl2]

dimethylmercury
593-74-8

dimethylmercury

[RuCl(CO)2(CH3)(P(CH3)2C6H5)2]

[RuCl(CO)2(CH3)(P(CH3)2C6H5)2]

Conditions
ConditionsYield
In acetone N2-atmosphere; excess HgMe2, 313 K, 4 h; solvent removal (reduced pressure), chromy. (Al2O3, CHCl3), recrystn. (light petroleum); elem. anal.;A n/a
B 66%
N,N'-Bis(trifluoromethylsulfonyl)sulfur diimide
30227-02-2

N,N'-Bis(trifluoromethylsulfonyl)sulfur diimide

dimethylmercury
593-74-8

dimethylmercury

N-(Methylmercurio)-N,N'-bis(trifluormethylsulfonyl)methansulfinamidin

N-(Methylmercurio)-N,N'-bis(trifluormethylsulfonyl)methansulfinamidin

Conditions
ConditionsYield
In dichloromethane stirred at room temp. for 48 h; solvent removed, cooled to -15°C, filtered, dried in vac., elem.anal.;62%
cis-[PdCl2(CNC6H4OMe-p)2]
40927-13-7

cis-[PdCl2(CNC6H4OMe-p)2]

triphenyl-arsane
603-32-7

triphenyl-arsane

dimethylmercury
593-74-8

dimethylmercury

PdCl(As(C6H5)3)2(C(NC6H4OCH3)C(CH3)N(C6H4OCH3))

PdCl(As(C6H5)3)2(C(NC6H4OCH3)C(CH3)N(C6H4OCH3))

Conditions
ConditionsYield
In not given byproducts: HgCH3Cl; Pd-complex was reacted with HgMe2 for 7 h, AsPh3 was added, stood for 12 h; sublimated to eliminate HgMeCl, dissolved in C6H6, EtOH was added, concd., stored at -20°C; elem. anal.;60%
Trifluoromethylsulfonyliminosulfinyl dichloride
78438-05-8

Trifluoromethylsulfonyliminosulfinyl dichloride

dimethylmercury
593-74-8

dimethylmercury

A

Dimethylschwefel-(trifluormethylsulfonyl)imid
32461-73-7

Dimethylschwefel-(trifluormethylsulfonyl)imid

B

CH3HgCl

CH3HgCl

Conditions
ConditionsYield
In dichloromethane for 48h; Ambient temperature;A 57%
B n/a
tungsten oxytetrachloride
160797-03-5, 13520-78-0

tungsten oxytetrachloride

dimethylmercury
593-74-8

dimethylmercury

methyltungsten(VI) trichloride oxide-1,2-bis(diphenylphosphino)ethane (1/1)

methyltungsten(VI) trichloride oxide-1,2-bis(diphenylphosphino)ethane (1/1)

Conditions
ConditionsYield
With (C6H5)2PCH2CH2P(C6H5)2 In dichloromethane; pentane byproducts: MeHgCl; Ar-atmosphere; slow addn. of HgMe2 to suspn. of equimolar amt. of W-compd. (in CH2Cl2/pentane=2:1) at -80°C, stirring (-80°C, 1 h), filtration off of MeHgCl, evapn., stirring with pentane (-78°C), addn. of dppe;55%
dimethylmercury
593-74-8

dimethylmercury

mercury fulminate
92114-96-0

mercury fulminate

methylmercury fulminate
92114-94-8

methylmercury fulminate

Conditions
ConditionsYield
In tetrahydrofuran reflux, 1 h; evapn. in vac., extn. (acetone), crystn. from CHCl3;50%
cis-[bis(cyclohexylisocyanide)dichloropalladium(II)]
29827-46-1

cis-[bis(cyclohexylisocyanide)dichloropalladium(II)]

dimethylmercury
593-74-8

dimethylmercury

trans-[PdCl(C(NC6H11)CMeNC6H11)(PPh3)2]
63560-38-3, 69256-71-9

trans-[PdCl(C(NC6H11)CMeNC6H11)(PPh3)2]

Conditions
ConditionsYield
With P(C6H5)3 In benzene byproducts: MeHgCl; treatment of Pd-complex with HgMe2 (90 min), then addn. of PPh3; repptn. (CH2Cl2/hexane); elem. anal.;50%
dimethylmercury
593-74-8

dimethylmercury

thianthrene cation radical perchlorate
35787-71-4

thianthrene cation radical perchlorate

A

thianthrene-5-oxide
2362-50-7

thianthrene-5-oxide

B

methylmercury(II) chloride
115-09-3

methylmercury(II) chloride

C

5-Methylthianthreniumyl perchlorate
65886-47-7

5-Methylthianthreniumyl perchlorate

D

Thianthrene
92-85-3

Thianthrene

E

1-methyl-, 2-mehthyl-, and dimethylthianthrenes

1-methyl-, 2-mehthyl-, and dimethylthianthrenes

Conditions
ConditionsYield
With lithium chloride In acetonitrile Product distribution; Mechanism; other dialkylmercurials, other thianthren cation radical salt, other solvent;A 0.65%
B 42.5%
C 38.1%
D 48.9%
E n/a
silver tetrafluoroborate
14104-20-2

silver tetrafluoroborate

dimethylmercury
593-74-8

dimethylmercury

diphenylchloromethane
90-99-3

diphenylchloromethane

A

1,1-Diphenylmethanol
91-01-0

1,1-Diphenylmethanol

B

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

C

methylmercury(II) bromide
506-83-2

methylmercury(II) bromide

Conditions
ConditionsYield
With potassium bromide In nitromethane byproducts: N-(diphenylmethyl)acetamide; Ar atmosphere and absence of light and moisture; addn. of AgBF4 in nitromethane to soln. of alkylmercury, portionwise addn. of Ph2CHCl in nitromethane (20°C, TLC monitoring), washing with soln. of KBr; TLC;A 47%
B 35%
C 30%
With potassium bromide In acetonitrile byproducts: N-(diphenylmethyl)acetamide; Ar atmosphere and absence of light and moisture; addn. of AgBF4 in MeCNto soln. of alkylmercury, portionwise addn. of Ph2CHCl in MeCN (20°C, TLC monitoring), pouring into soln. of KBr; extn. (CH2Cl2), TLC;A 47%
B 35%
C 30%
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