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Dayang Chem (Hangzhou) Co.,Ltd.

DayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe

1,1-Diphenylethane Manufacturer/High quality/Best price/In stock

Cas:612-00-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

1,1'-Ethylidenebisbenzene

Cas:612-00-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

inquiry

Henan Tianfu Chemical Co., Ltd.

TIANFUCHEM-- 612-00-0--High purity 6-ACETYLTETRAHYDRONAPHTHALENE factory price Our company was built in 2009 with an ISO certificate.In the past 10 years, we have grown up as a famous fine chemicals supplier in China And we had established

TIANFUCHEM-- 612-00-0--High purity 6-ACETYLTETRAHYDRONAPHTHALENE factory price

Cas:612-00-0

Min.Order:1 Metric Ton

FOB Price: $2000.0

Type:Lab/Research institutions

inquiry

Hebei Sankai Chemical Technology Co., Ltd

1. Product advantages ♦ High purity, all above 98.5%, no impurities after dissolution ♦ We will test each batch to ensure quality ♦ OEM and private brand services designed for free ♦ Various cap colors available ♦ W

1,1-Diphenylethane CAS612-00-0

Cas:612-00-0

Min.Order:1 Kilogram

FOB Price: $289.0 / 499.0

Type:Trading Company

inquiry

Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Benzene,1,1'-ethylidenebis-

Cas:612-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Benzene,1,1'-ethylidenebis-

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Keyingchem Co.,Ltd

Hangzhou KeyingChem Co., Ltd. exported this product to many countries and regions at best price. If you are looking for the material’s manufacturer or supplier in China, KeyingChem is your best choice. Pls contact with us freely for getting det

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0 Metric Ton

Negotiable

Type:Lab/Research institutions

inquiry

SHANGHAI T&W PHARMACEUTICAL CO., LTD.

A substitute for perfluorooctanoic acid, mainly used as a surfactant, dispersant, additive, etc Appearance:White solid or Colorless liquid Purity:99.3 % We will ship the goods in a timely manner as required We can provide relevant documents acc

1,1-Diphenylethane

Cas:612-00-0

Min.Order:4 Kilogram

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

Benzene,1,1'-ethylidenebis-

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

1,1-Diphenylethane

Cas:612-00-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

GIHI CHEMICALS CO.,LIMITED

Lower price, sample is available,SDS test documents are available,large stock in warehouseAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:Fine chemical intermediates, used as the main raw material for the synthe

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Antimex Chemical Limied

Ansciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Appearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

1,1-Diphenylethane CAS No.612-00-0

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:white crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

1,1-Diphenylethane cas 612-00-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

1,1-Diphenylethane cas 612-00-0

Cas:612-00-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Shanghai Chinqesen Biotechnology Co., Ltd.

Good Quality Package:1kg/bag Application:Medical or chemical Transportation:Air/Train/Sea Port:Shenzhen

612-00-0

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

ZHEJIANG JIUZHOU CHEM CO.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

LEAP CHEM Co., Ltd.

Best Seller, High Quality, Competitive Price, Fast Delivery, Quick ResponseAppearance:powder, or liquid Storage:Stored in room temperature, ventilated place Package:Bottle, barrel, cargo, container, etc. Application:Pharmaceuticals, intermediates, AP

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Jilin haofei import and export trade Co.,Ltd

Price, service, company and transport advantage: 1. Best service, place of origin China, high quality, and reasonable price. 2. It's customers' right to choose the package (EMS, DHL, FEDEX, UPS). 3. It's customers' right

CSR1608-836 CAS NO.612-00-0

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

suzhou BetterBioChem Co., Ltd.

Betterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in

1,1-DIPHENYLETHANE

Cas:612-00-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Finetech Industry Limited

FINETECH INDUSTRY LIMITED is a LONDON based CRO company providing drug discovery & development services to worldwide clients. FINETECH INDUSTRY LIMITED supplies the 1,1-Diphenylethane, CAS:612-00-0 with the most competitive price and the best quality

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Skyrun Industrial Co.,Ltd

Capacity, Prompt shipment Application:surface active agent

CSR1608-836

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Topbatt Chemical Co., Ltd.

Topbatt Chemical Co., Ltd., Established in 2019, located in Shenzhen, Guangdong Province, is a Manufacturer and Trading company which specialized in fine chemicals like Pharmaceutical Reference Standards and Stable Isotopes. Our Stable Isotopes produ

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Debye Scientific

Debyesci is here who supplied several kinds of chemical products to global pharmaceutical, drug discovery, agrochemical and biotechnology industries for four yearsOur key scientific leadership team has gained experience in top research and developmen

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

NovaChemistry

High purity Application:Pharmaceutical intermediates, Material synthesis and analyzing the expectant ingredients

1,1-Diphenylethane

Cas:612-00-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Synthetic route

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With C28H18Co(1-)*K(1+)*2C4H10O2; hydrogen In toluene at 60℃; under 7500.75 Torr; for 24h; Solvent; chemoselective reaction;100%
With water for 6h; Milling; Green chemistry;100%
With iPr-amboxCoCl2; hydrogen; sodium triethylborohydride In toluene at 0 - 20℃; Reagent/catalyst; Sealed tube;100%
1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With iodine; hypophosphorous acid In acetic acid at 60℃; for 24h;100%
With phosphonic Acid; methanesulfonic acid; sodium iodide In water at 95℃; for 24h; Inert atmosphere;99.6%
With formic acid; 5%-palladium/activated carbon; ammonium formate In methanol; water at 80℃; for 0.666667h;95%
1,1-bis(4-chlorophenyl)-2,2-dichloroethylene
72-55-9

1,1-bis(4-chlorophenyl)-2,2-dichloroethylene

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With hydrogen; triethylamine; palladium on activated charcoal In methanol at 20℃; for 0.5h;100%
With Pd(0)/HAP; hydrogen; caesium carbonate In isopropyl alcohol at 60℃; under 7600.51 Torr; for 1h;> 99 %Chromat.
diphenylmethyl p-tolyl sulfone
5433-78-3

diphenylmethyl p-tolyl sulfone

trimethylaluminum
75-24-1

trimethylaluminum

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
In dichloromethane; toluene at 25℃; for 2h; Inert atmosphere;100%
C13H15BrO2

C13H15BrO2

benzene
71-43-2

benzene

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With silica-supported sulfuric acid at 60℃; for 1h; Friedel-Crafts type alkylation;99%
With silica sulfuric acid at 60℃; for 1h;
benzhydryl methyl ether
1016-09-7

benzhydryl methyl ether

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With palladium dichloride In methanol at 40℃; for 12h; Inert atmosphere; Green chemistry; chemoselective reaction;99%
(1-(phenylsulfonyl)ethane-1,1-diyl)dibenzene
60702-29-6

(1-(phenylsulfonyl)ethane-1,1-diyl)dibenzene

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With N1,N1,N12,N12-tetramethyl-7,8-dihydro-6H-dipyrido[1,2-a:2,1'-c][1,4]diazepine-2,12-diamine In N,N-dimethyl-formamide at 100℃; Inert atmosphere;98%
With tetraazaethylene-type neutral organic super-electron donor In N,N-dimethyl-formamide at 110℃; for 18h;97%
Stage #1: (1-(phenylsulfonyl)ethane-1,1-diyl)dibenzene With C3H6C9H10N4 In N,N-dimethyl-formamide at 110℃; Inert atmosphere;
Stage #2: In water Inert atmosphere;
97%
With C24H32N8Ni(2+)*2I(1-); sodium amalgam In N,N-dimethyl-formamide at 20℃; for 18h; Inert atmosphere;70%
With 4-(dimethylamino)-1-methylpyridinium-2-carboxylate In N,N-dimethyl-formamide at 150℃; for 24h; Schlenk technique; Inert atmosphere;15%
2,2-diphenylpropionitrile
5558-67-8

2,2-diphenylpropionitrile

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With sodium hydride; lithium iodide In tetrahydrofuran; mineral oil at 85℃; for 7h; Reagent/catalyst; Inert atmosphere; Sealed tube;98%
(1-bromoethyl)benzne
585-71-7, 38661-81-3

(1-bromoethyl)benzne

phenylmagnesium bromide
100-58-3

phenylmagnesium bromide

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With dichloro bis(acetonitrile) palladium(II); 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In tetrahydrofuran at 20℃; for 14h; Kumada-Corriu reaction; Inert atmosphere;96%
dimethyl zinc(II)
544-97-8

dimethyl zinc(II)

diphenylchloromethane
90-99-3

diphenylchloromethane

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With titanium tetrachloride In dichloromethane at 0℃; for 2h;95%
styrene
292638-84-7

styrene

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

ethylbenzene
100-41-4

ethylbenzene

Conditions
ConditionsYield
With C28H18Co(1-)*K(1+)*2C4H10O2; hydrogen at 20℃; under 1500.15 Torr; for 3h;A 18%
B 95%
5-benzhydryl-2,2,5-trimethyl-1,3-dioxane-4,6-dione
87057-91-8

5-benzhydryl-2,2,5-trimethyl-1,3-dioxane-4,6-dione

trimethylaluminum
75-24-1

trimethylaluminum

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
In n-heptane; dichloromethane at 20℃; for 1h;92%
bromobenzene
108-86-1

bromobenzene

(1-chloroethyl)benzene
672-65-1

(1-chloroethyl)benzene

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With nickel(II) iodide; potassium fluoride; 4,4'-dimethyl-2,2'-bipyridines; zinc In N,N-dimethyl acetamide at 25℃; for 16h; Inert atmosphere; Glovebox; Schlenk technique;92%
styrene
292638-84-7

styrene

2-phenyl[1,3,2]dioxaborolane
4406-72-8

2-phenyl[1,3,2]dioxaborolane

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With potassium tert-butylate; oxygen; (-)-sparteine; imidazole-carbene-derived Pd complex In isopropyl alcohol at 55℃; for 24h;91%
With potassium tert-butylate; oxygen; isopropyl alcohol; [Pd(SiPr)Cl2]2; (-)-sparteine at 55℃; for 24h;91%
With di-μ-chlorobis[chloro(N,N'-bis-(2,6-(diisopropyl)phenyl)imidazolidine-2-ylidene)palladium]; potassium tert-butylate; oxygen; isopropyl alcohol; (-)-sparteine at 55℃; for 24h; regioselective reaction;91%
2,2-diphenylpropanoic acid
5558-66-7

2,2-diphenylpropanoic acid

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With methanol at 40℃; for 24h; Schlenk technique; Irradiation; Inert atmosphere;91%
With 10-phenyl-9-(2,4,6-trimethylphenyl)acridinium tetrafluoroborate; N-ethyl-N,N-diisopropylamine; diphenyldisulfane In 2,2,2-trifluoroethanol at 20℃; for 24h; Glovebox; Irradiation; Sealed tube;83%
O-diphenylmethyl 2,2,2-trichloroacetimidate
100865-93-8

O-diphenylmethyl 2,2,2-trichloroacetimidate

trimethylaluminum
75-24-1

trimethylaluminum

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

N-benzhydryl-trichloroacetamide
100865-92-7

N-benzhydryl-trichloroacetamide

Conditions
ConditionsYield
With aluminum (III) chloride In dichloromethane at 20℃; for 0.5h; Solvent; Temperature; Reagent/catalyst;A 91%
B 8%
O-diphenylmethyl 2,2,2-trichloroacetimidate
100865-93-8

O-diphenylmethyl 2,2,2-trichloroacetimidate

trimethylaluminum
75-24-1

trimethylaluminum

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
Stage #1: trimethylaluminum With aluminum (III) chloride In hexane; dichloromethane for 0.0833333h; Inert atmosphere;
Stage #2: O-diphenylmethyl 2,2,2-trichloroacetimidate In hexane; dichloromethane at 0 - 20℃; for 0.25h; Reagent/catalyst; Inert atmosphere;
91%
benzophenone
119-61-9

benzophenone

methyllithium
917-54-4

methyllithium

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
Stage #1: benzophenone; methyllithium In tetrahydrofuran at -50 - 0℃; for 2h; Inert atmosphere;
Stage #2: With hexylsilane; tris(pentafluorophenyl)borate In dichloromethane at 20℃; for 1h; Inert atmosphere; chemoselective reaction;
91%
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

2,2,3,3-tetraphenylbutane
10496-82-9

2,2,3,3-tetraphenylbutane

Conditions
ConditionsYield
With titanium(III) citrate; Tris buffer; tetra(n-butyl)ammonium hydroxide; vitamin B-12 In ethanol pH=8;A 5%
B 90%
With hydrogen In acetone at -78℃; under 2 Torr; for 0.5h;
benzophenone
119-61-9

benzophenone

methyllithium
917-54-4

methyllithium

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With <<(n-PrO)3WCl2>2> In tetrahydrofuran -78 deg C -> RT, 1 h, then reflux, 3 h;A 90%
B 90%
bromobenzene
108-86-1

bromobenzene

1-phenyl-2-bromoethane
103-63-9

1-phenyl-2-bromoethane

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With nickel(II) bromide dimethoxyethane; [Ir(dF(CF3)ppy)2(phen)]PF6; Bathocuproine; diisopropylamine; magnesium bromide In N,N-dimethyl-formamide at 20℃; for 24h; Inert atmosphere; Glovebox; Sealed tube; Irradiation; regioselective reaction;90%
With nickel(II) iodide; Bathocuproine; tetrabutylammomium bromide; zinc at 20℃; regioselective reaction;85%
1,1-diphenylethyl formate

1,1-diphenylethyl formate

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With triethylsilane; C19H3BF14 In dichloromethane at 20℃; Inert atmosphere; Schlenk technique;89%
1,1-diphenylethanol
599-67-7

1,1-diphenylethanol

A

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

B

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

C

1-chloro-1,1-diphenyl-ethane
947-40-0

1-chloro-1,1-diphenyl-ethane

Conditions
ConditionsYield
With acetyl chloride In dichloromethane 1.) 0 deg C, 2.) room temperature, 1 h; Yield given;A 88%
B 43%
C n/a
p,p'-DDT
50-29-3

p,p'-DDT

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

Conditions
ConditionsYield
With Pd(0)/HAP; hydrogen; caesium carbonate In isopropyl alcohol at 60℃; under 7600.51 Torr; for 28h;87%
Multi-step reaction with 2 steps
1: 12 percent / H2; Et3N / Pd/C / methanol / 0.5 h / 20 °C
2: 27 percent / H2; Et3N / Pd/C / methanol / 24 h / 20 °C
View Scheme
Multi-step reaction with 2 steps
1: 34 percent / H2; Et3N / Pd/C / methanol / 0.17 h / 20 °C
2: 27 percent / H2; Et3N / Pd/C / methanol / 24 h / 20 °C
View Scheme
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

1-methyl-1,3,3-triphenylindane
19303-32-3

1-methyl-1,3,3-triphenylindane

Conditions
ConditionsYield
With bromobenzene-d5; (di-p-tolylmethyl)triethylsilane; C24H20B(1-)*C20H29NSi*H(1+) at 100℃; under 3040.2 Torr; for 24h; Schlenk technique; Inert atmosphere;A 14%
B 86%
With diethyl ether; tris(pentafluorophenyl)borate; hydrogen In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 48h; Catalytic behavior; Concentration; Pressure; Reagent/catalyst; Solvent; Temperature; Time; Glovebox;
piperidine
110-89-4

piperidine

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

carbon monoxide
201230-82-2

carbon monoxide

A

N-Formylpiperidine
2591-86-8

N-Formylpiperidine

B

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

C

fenpiprane
3540-95-2

fenpiprane

Conditions
ConditionsYield
With [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; 1,1'-Binaphthalin-2,2'-diylbis(methylen)bis(diphenylphosphan); hydrogen In toluene at 125℃; for 60h; Reagent/catalyst; Autoclave;A 5.6%Chromat.
B 13.8%Chromat.
C 85%
With [(bicyclo[2.2.1]hepta-2,5-diene)(1,4-bis(diphenylphosphino)butane)rhodium(I)] tetrafluoroborate; 1,1'-Binaphthalin-2,2'-diylbis(methylen)bis(diphenylphosphan); hydrogen In methanol at 125℃; for 60h; Reagent/catalyst; Autoclave;A 22.1%Chromat.
B 40%Chromat.
C 48%
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

Diphenylphosphine oxide
4559-70-0

Diphenylphosphine oxide

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

(2,2-Diphenylethyl)diphenylphosphine oxide
13685-66-0

(2,2-Diphenylethyl)diphenylphosphine oxide

C

1,1-diphenyl-2-diphenylphosphinylethene oxide
78375-70-9

1,1-diphenyl-2-diphenylphosphinylethene oxide

Conditions
ConditionsYield
With pyridine; (difluoroboryl)dimethylglyoximatocobalt(II) bis(acetonitrile) In dichloromethane at 20℃; for 16h; Catalytic behavior; Reagent/catalyst; Solvent; Inert atmosphere; Irradiation;A n/a
B 9%
C 85%
1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

carbon monoxide
201230-82-2

carbon monoxide

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

3,3-diphenylpropanal
4279-81-6

3,3-diphenylpropanal

C

3,3-diphenylpropan-1-ol
20017-67-8

3,3-diphenylpropan-1-ol

Conditions
ConditionsYield
With hydrogen; di(rhodium)tetracarbonyl dichloride In toluene at 150℃; under 103430 Torr; for 2h; Product distribution; Mechanism; other catalysts, times, temp., solvents;A 11.3%
B 84.7%
C 3.9%
piperidine
110-89-4

piperidine

1,1-Diphenylethylene
530-48-3

1,1-Diphenylethylene

carbon monoxide
201230-82-2

carbon monoxide

A

1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

B

3,3-diphenylpropanal
4279-81-6

3,3-diphenylpropanal

C

fenpiprane
3540-95-2

fenpiprane

Conditions
ConditionsYield
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; 1,1'-Binaphthalin-2,2'-diylbis(methylen)bis(diphenylphosphan); hydrogen In toluene at 125℃; for 60h; Autoclave;A 11.7%Chromat.
B 6.7%Chromat.
C 81%
With bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate; hydrogen; 4,5-bis(diphenylphosphino)-9,9-dimethylxanthene In toluene at 125℃; for 60h; Autoclave;A 40.2%Chromat.
B 22.4%Chromat.
C 29%
1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

C14H10(2)H4

C14H10(2)H4

Conditions
ConditionsYield
With palladium on activated charcoal; water-d2 In methanol at 30℃; for 12h;99%
1,1'-ethylidenebis-benzene
612-00-0

1,1'-ethylidenebis-benzene

A

benzophenone
119-61-9

benzophenone

B

benzoic acid phenyl ester
93-99-2

benzoic acid phenyl ester

Conditions
ConditionsYield
With 2,2'-azobis(isobutyronitrile); oxygen; nickel dibromide In chloroform at 75℃; for 48h; Reagent/catalyst;A 88%
B 10%
With 2,2'-azobis(isobutyronitrile); oxygen In acetonitrile at 75℃; for 72h; Solvent; Reagent/catalyst;A 20%
B 44%
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