PHENYLMAGNESIUM BROMIDE Basic information Product Name: PHENYLMAGNESIUM BROMIDE Synonyms: PHENYLMAGNESIUM BROMIDE;Phenyl magnesium bromide(in ethyl ether);bromophenyl-magnesiu;phenylmagnesiumbromidesolution;bromophenylmagnesium;PHENYLMAGNESIUM B
Cas:100-58-3
Min.Order:1 Liter
Negotiable
Type:Lab/Research institutions
inquiryDayangChem exported this product to many countries and regions at best price. If you are looking for the material's manufacturer or supplier in China, DayangChem is your best choice. Pls contact with us freely for getting detailed product spe
Cas:100-58-3
Min.Order:1 Kilogram
FOB Price: $3.0
Type:Lab/Research institutions
inquiryThe above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providi
Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block
Cas:100-58-3
Min.Order:5 Kiloliter
FOB Price: $1.2 / 5.0
Type:Manufacturers
inquiryHebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of chemicals. After many years of efforts, we have established stable
Cas:100-58-3
Min.Order:1 Metric Ton
FOB Price: $1.0 / 2.0
Type:Trading Company
inquiryPHENYLMAGNESIUM BROMIDE Basic information Product Name: PHENYLMAGNESIUM BROMIDE Synonyms: PHENYLMAGNESIUM BROMIDE;Phenyl magnesium bromide(in ethyl ether);bromophenyl-magnesiu;phenylmagn
Cas:100-58-3
Min.Order:1 Kilogram
Negotiable
Type:Lab/Research institutions
inquiryJ&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia
Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi
Cas:100-58-3
Min.Order:10 Gram
FOB Price: $100.0
Type:Lab/Research institutions
inquiryWe are leading fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...)
Cas:100-58-3
Min.Order:1 Kilogram
FOB Price: $5.0
Type:Lab/Research institutions
inquiryHangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical,
Cas:100-58-3
Min.Order:1 Metric Ton
Negotiable
Type:Lab/Research institutions
inquiryhigh purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:drum and bag Application:for pharma use Transportation:by sea or air Port:Beijing or Guangzhou
high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea
Cas:100-58-3
Min.Order:0
Negotiable
Type:Manufacturers
inquiryOur clients, like BASF,CHEMO,Brenntag,ASR,Evonik,Merck and etc.Appearance:COA Storage:in stock Application:MSDS/TDS
Product Description Description & Specification Category Pharmaceutical Raw Materials, Fine Chemicals, Bulk drug Standard Medical standard
Cas:100-58-3
Min.Order:1 Kilogram
FOB Price: $112.0
Type:Trading Company
inquiryAnsciep Chemical is a professional enterprise manufacturing and distributing fine chemicals and speciality chemicals. We have been dedicated to heterocycle compounds and phenyl rings for tens of years. This is our mature product for export. Our quali
in stock Application:100-58-3
Cas:100-58-3
Min.Order:0
Negotiable
Type:Trading Company
inquiry1.Professional synthesis laboratory and production base. 2.Strong synthesis team and service team. 3.Professional data management system. 4.We provide the professional test date and product information ,ex. HNMR ,CNMR,FNMR, HPLC/G
Cas:100-58-3
Min.Order:10 Milligram
Negotiable
Type:Lab/Research institutions
inquiryHenan Sunlake Enterprise Corporation Our Advantages 1, Any inquiry about ch
Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer and can provide high quality products with factory pric
Cas:100-58-3
Min.Order:0
Negotiable
Type:Lab/Research institutions
inquiryBetterbiochem is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in
Cas:100-58-3
Min.Order:1 Gram
Negotiable
Type:Lab/Research institutions
inquiryHebei ruishun trade co.,ltd, registered capital one million,have a production of pharmaceutical raw materials, pharmaceutical raw materials factory reagent r&d center,seek development by credit reputation.our products have a large price advanta
Cas:100-58-3
Min.Order:10 Gram
FOB Price: $0.9 / 1.2
Type:Trading Company
inquiryBaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art
HuBei ipure is a diversified product production and operation enterprise, with API, pharma intermediates, and other fine chemicals as well as R&D and pigments development and sales as one of the large enterprises, with more than 130 acres of pl
Cas:100-58-3
Min.Order:1 Gram
FOB Price: $1.0
Type:Trading Company
inquiryAt Share Chemical Company, we scrupulously abide by our policy of “Excellent Quality at a Reasonable Price”. We strive to satisfy all of our customers by providing the finest quality products supported by the finest in customer servi
Aopharm is specialized in APIs, pharmaceutical intermediates & fine chemicals. 1. The best quality, competitive price. 2. The best service before or after shipment. 3. Rich experience in export operation. 4. Rich experience in modes of
United Scientific Company Located in Shanghai of China , is a competitive player in the global specialty and fine chemical market. Fenghua has both the expertise and flexibility to produce a wide range of chemicals. Focusing on developing the innovat
please contact us to confirm the required quantity and quote, we will provide you with COA,NMR,HPLC and other relevant informationAppearance:Brown liquid Storage:Store in a cool place. Keep container tightly closed in a dry and well-ventilated place
Conditions | Yield |
---|---|
With magnesium In tetrahydrofuran at 40℃; for 0.25h; Inert atmosphere; Flow reactor; | 100% |
With magnesium In tetrahydrofuran | |
With magnesium In diethyl ether at 19.9℃; Rate constant; various concentrations of aryl halide; |
2-amino-5-chlorobenzonitrile
A
(2-amino-5-chlorophenyl)-phenyl-methane-imine
B
phenylmagnesium bromide
Conditions | Yield |
---|---|
A 92% B n/a |
Conditions | Yield |
---|---|
With magnesium In tetrahydrofuran | A 24% B n/a |
Conditions | Yield |
---|---|
In tetrahydrofuran; toluene |
Conditions | Yield |
---|---|
With hydrogenchloride In diethyl ether |
Conditions | Yield |
---|---|
In tetrahydrofuran |
Conditions | Yield |
---|---|
With ammonium chloride |
Conditions | Yield |
---|---|
With biphenyl; ethylmagnesium bromide; phenylmagnesium bromide In o-xylene |
Conditions | Yield |
---|---|
With hydrogenchloride; iodine In magnesium |
Conditions | Yield |
---|---|
With magnesium |
bromobenzene
1-methyl-3-fluoro-5,7-dichloro-2,3-dihydro-1H-1,4-benzodiazepin-2-one
B
phenylmagnesium bromide
Conditions | Yield |
---|---|
With HF In tetrahydrofuran |
Conditions | Yield |
---|---|
With magnesium In diethyl ether | A 17 g (34%) B n/a |
Conditions | Yield |
---|---|
In tetrahydrofuran | |
In tetrahydrofuran for 1.5h; Inert atmosphere; Reflux; | |
With iodine In tetrahydrofuran for 2h; Inert atmosphere; Reflux; | |
With iodine In tetrahydrofuran for 1h; Grignard Reaction; Heating / reflux; |
Conditions | Yield |
---|---|
With diethyl ether |
Conditions | Yield |
---|---|
With diethyl ether untersucht wurde die Geschwindigkeit; |
Conditions | Yield |
---|---|
With 3,5,3',5'-tetra-tert-butyl-4,4'-diphenoquinone at -20℃; Product distribution / selectivity; | 100% |
With iron(III) chloride; 1,2-dichloro-ethane In tetrahydrofuran at 0℃; for 0.0833333h; Ionic liquid; Inert atmosphere; | 100% |
With 1,2-bisperfluorotolyl-3,3,4,4,5,5-hexafluorocyclopentene In tetrahydrofuran at 25℃; for 1h; Reagent/catalyst; Inert atmosphere; | 99% |
Conditions | Yield |
---|---|
nickel(II) In tetrahydrofuran for 18h; Product distribution; other catalyst, other solvents; other Grignard compounds and alkyl or vinyl halides; | 100% |
With CpNi[1-(ethoxycarbonyl)methyl-3-(3,5-dimethylbenzyl)benzimidazolin-2-ylidene]Br In tetrahydrofuran at 25℃; for 3h; Kumada Cross-Coupling; Inert atmosphere; Schlenk technique; | 97% |
With Pd/Al(OH)3 In toluene at 140℃; for 36h; Kumada Cross-Coupling; Inert atmosphere; | 94% |
phenylmagnesium bromide
Conditions | Yield |
---|---|
In diethyl ether for 4h; Ambient temperature; | 100% |
phenylmagnesium bromide
Conditions | Yield |
---|---|
In diethyl ether for 4h; Ambient temperature; | 100% |
Conditions | Yield |
---|---|
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran at 0℃; | 100% |
Stage #1: benzoyl chloride With 1-methyl-pyrrolidin-2-one In toluene at 0℃; for 0.5h; Stage #2: phenylmagnesium bromide In tetrahydrofuran; toluene at -10 - 0℃; for 4.25h; chemoselective reaction; | 89% |
In 2-methyltetrahydrofuran at 25℃; for 1h; Solvent; Concentration; Flow reactor; Green chemistry; | 85% |
3-phenylbutanoyl chloride
phenylmagnesium bromide
1,3-diphenylbutane-1-one
Conditions | Yield |
---|---|
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride In tetrahydrofuran at 0℃; | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran | 100% |
methyl 3,3-dimethylglutarate
phenylmagnesium bromide
3,3-dimethy-5,5-diphenyl-5-hydroxypentanoic acid lactone
Conditions | Yield |
---|---|
In tetrahydrofuran 2 h; reflux, 2,5 h; | 100% |
phenylmagnesium bromide
methyl (S)-N-(tert-butoxycarbonyl)indoline-2-carboxylate
(S)-tert-butyl 2-(hydroxydiphenylmethyl)indoline-1-carboxylate
Conditions | Yield |
---|---|
In diethyl ether at 0℃; Inert atmosphere; Reflux; | 100% |
In tetrahydrofuran; diethyl ether at 0 - 20℃; for 7h; | 25% |
In diethyl ether at 0℃; |
phenylmagnesium bromide
(4-Methoxy-phenyl)-(4-phenyl-phthalazin-1-yl)-methanone
(4-Methoxy-phenyl)-phenyl-(4-phenyl-phthalazin-1-yl)-methanol
Conditions | Yield |
---|---|
In tetrahydrofuran for 1h; Ambient temperature; | 100% |
phenylmagnesium bromide
(2R,9S)-2,9-diphenyl-1-aza-4-oxabicyclo[4.3.0]nonane
(2S,6R,1'R)-N-2'-hydroxy-1'-phenylethyl-2,6-diphenylpiperidine
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 72h; | 100% |
Conditions | Yield |
---|---|
With [1,3-bis(2,6-diisopropylphenyl)-imidazolium][Ni(PPh3)Cl3] In tetrahydrofuran at 30℃; for 1h; Kumada Cross-Coupling; Schlenk technique; Inert atmosphere; | 100% |
With C70H40Cl2F68N2O6Pd2 In tetrahydrofuran at 100℃; for 0.0166667h; Kumada coupling reaction; Microwave irradiation; | 96% |
With C17H36ClN6NiP2(1+)*Cl(1-) In tetrahydrofuran for 6h; Reagent/catalyst; Kumada Cross-Coupling; Inert atmosphere; | 96% |
3-(3-bromophenyl)-N-methoxy-N-methylpropanamide
phenylmagnesium bromide
3-(3-bromophenyl)-1-phenyl-propan-1-one
Conditions | Yield |
---|---|
In tetrahydrofuran at -78 - 0℃; for 2h; | 100% |
(R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate
phenylmagnesium bromide
(R)-tert-butyl 3-benzoylpiperidine-1-carboxylate
Conditions | Yield |
---|---|
Stage #1: (R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate; phenylmagnesium bromide In tetrahydrofuran at -10 - 20℃; for 1.25h; Stage #2: With hydrogenchloride In tetrahydrofuran; water for 0.333333h; Stage #3: With ammonium chloride In tetrahydrofuran; hexane; water | 100% |
Stage #1: (R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate; phenylmagnesium bromide In tetrahydrofuran at -10 - 20℃; for 1.25h; Stage #2: With hydrogenchloride; water In tetrahydrofuran for 0.333333h; | 100% |
Stage #1: (R)-tert-butyl 3-(methoxy(methyl)carbamoyl)piperidine-1-carboxylate; phenylmagnesium bromide In tetrahydrofuran at -10 - 20℃; Inert atmosphere; Stage #2: With hydrogenchloride In tetrahydrofuran; water |
Conditions | Yield |
---|---|
Stage #1: 3-cyanobromobenzene; phenylmagnesium bromide In tetrahydrofuran at 20 - 60℃; for 4h; Stage #2: With methanol In tetrahydrofuran at 0℃; | 100% |
Stage #1: 3-cyanobromobenzene; phenylmagnesium bromide In tetrahydrofuran at 20 - 60℃; for 4h; Stage #2: With methanol In tetrahydrofuran at 0℃; |
Conditions | Yield |
---|---|
With hydrogenchloride; ammonium chloride In tetrahydrofuran | 100% |
Stage #1: 4-butanolide; phenylmagnesium bromide In tetrahydrofuran; diethyl ether at -78 - 20℃; Inert atmosphere; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether at 10℃; Cooling with ice; | |
In tetrahydrofuran Grignard reaction; Reflux; |
3-Ethoxycyclohex-2-en-1-one
phenylmagnesium bromide
3-phenylcyclohex-2-enone
Conditions | Yield |
---|---|
Stage #1: 3-Ethoxycyclohex-2-en-1-one; phenylmagnesium bromide In tetrahydrofuran at 0 - 20℃; for 1h; Stage #2: With hydrogenchloride; water In tetrahydrofuran | 100% |
Stage #1: 3-Ethoxycyclohex-2-en-1-one; phenylmagnesium bromide In tetrahydrofuran at 0 - 20℃; for 1h; Stage #2: With hydrogenchloride; water In tetrahydrofuran | 100% |
Stage #1: 3-Ethoxycyclohex-2-en-1-one; phenylmagnesium bromide In tetrahydrofuran at 0 - 20℃; for 1h; Stage #2: With hydrogenchloride In tetrahydrofuran; water at 20℃; | 100% |
Conditions | Yield |
---|---|
Stage #1: 2-fluoropyridine; phenylmagnesium bromide; bis(acetylacetonate)nickel(II); ((2-hydroxymethyl)phenyl)diphenylphosphine In diethyl ether for 0.5h; Stage #2: With methanol In diethyl ether Product distribution / selectivity; | 100% |
Stage #1: 2-fluoropyridine; phenylmagnesium bromide; 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) In diethyl ether for 2h; Stage #2: With methanol In diethyl ether Product distribution / selectivity; | 96% |
2-bromo-3,5-bis(methoxymethoxy)-6-phenylbenzaldehyde
phenylmagnesium bromide
1-[2-bromo-3,5-bis(methoxymethoxy)-6-phenylphenyl]-1-phenylmethanol
Conditions | Yield |
---|---|
In tetrahydrofuran; diethyl ether at 0℃; for 2h; | 100% |
N-(2-Diethylaminoethyl)-4'-(1-oxo-2-phenylbutyl)methanesulfonanilide
phenylmagnesium bromide
N-(2-Diethylaminoethyl)-4'-(1-hydroxy-1,2-diphenylbutyl)methanesulfonanilide
Conditions | Yield |
---|---|
With hydrogenchloride; ammonium chloride In diethyl ether; water | 100% |
Conditions | Yield |
---|---|
In tetrahydrofuran at 20℃; for 5h; | 100% |
Conditions | Yield |
---|---|
In diethyl ether; toluene Ar-atmosphere; stirring (1 h); filtering, evapn. (vac.), extg. (CH2Cl2), filtering, evapn., washing (pentane); | 100% |
In tetrahydrofuran |
phenylmagnesium bromide
(Z)-3-Trimethylstannanyl-hept-2-enal
1-phenyl-3-trimethylstannyl-hept-2-ene-1-al
Conditions | Yield |
---|---|
In diethyl ether Ar-atmosphere; slight excess PhMgBr, refluxing for 12 h; addn. of satd. aq. NH4Cl, extn. of aq. layer (Et2O), drying (MgSO4), solvent removal; isomer mixt. not sepd., detd. by (119)Sn-NMR spectroscopy; | 100% |
1-(4-fluorophenyl)-1H-indazole-5-carbaldehyde
phenylmagnesium bromide
(1-(4-fluorophenyl)-1H-indazol-5-yl)(phenyl)methanol
Conditions | Yield |
---|---|
Stage #1: 1-(4-fluorophenyl)-1H-indazol-5-carboxaldehyde; phenylmagnesium bromide In tetrahydrofuran at 0℃; for 1h; Stage #2: With water; ammonium chloride In tetrahydrofuran | 100% |
Stage #1: 1-(4-fluorophenyl)-1H-indazol-5-carboxaldehyde; phenylmagnesium bromide In tetrahydrofuran at 0℃; for 1h; Stage #2: With water; ammonium chloride In tetrahydrofuran | 100% |
5-formyl-N,N-dimethyl-1H-indole-1-carboxamide
phenylmagnesium bromide
5-(hydroxy(phenyl)methyl)-N,N-dimethyl-1H-indole-1-carboxamide
Conditions | Yield |
---|---|
Stage #1: 5-formyl-N,N-dimethyl-1H-indole-1-carboxamide; phenylmagnesium bromide In tetrahydrofuran; diethyl ether at -78 - 20℃; for 2h; Stage #2: With water; ammonium chloride In tetrahydrofuran; diethyl ether | 100% |
In tetrahydrofuran | 100% |
trifluoromethanesulfonic acid 1-bromonaphthalen-2-yl ester
phenylmagnesium bromide
1-bromo-2-phenylnaphthalene
Conditions | Yield |
---|---|
Stage #1: trifluoromethanesulfonic acid 1-bromonaphthalen-2-yl ester With 1,3-bis-(diphenylphosphino)propane; lithium bromide; tris-(dibenzylideneacetone)dipalladium(0) In diethyl ether at 20℃; for 0.0833333h; Stage #2: phenylmagnesium bromide In diethyl ether at 0 - 20℃; for 7h; | 100% |
With dichloro [1,1'-bis(diphenylphosphino)propane]palladium(II); lithium bromide In diethyl ether at 0℃; for 18h; Inert atmosphere; | |
With bis(diphenylphosphino)propanepalladium(II) dichloride; lithium bromide In diethyl ether for 1h; Inert atmosphere; Cooling with ice; | 17 g |
(3E,4aR,10aR)-3-benzylidene-4a-ethyl-7-hydroxy-3,4,4a,9,10,10a-hexahydro-1H-phenanthren-2-one
phenylmagnesium bromide
(2S,3E,4aR,10aR)-3-benzylidene-4a-ethyl-2-phenyl-1,2,3,4,4a,9,10,10a-octahydrophenanthrene-2,7-diol
Conditions | Yield |
---|---|
Stage #1: phenylmagnesium bromide With cerium(III) chloride In tetrahydrofuran at -78℃; for 1.5h; Stage #2: (3E,4aR,10aR)-3-benzylidene-4a-ethyl-7-hydroxy-3,4,4a,9,10,10a-hexahydro-1H-phenanthren-2-one In tetrahydrofuran at -40℃; for 2h; Stage #3: With water; acetic acid In tetrahydrofuran | 100% |
Stage #1: phenylmagnesium bromide With cerium(III) chloride In tetrahydrofuran at -78℃; for 1.5h; Inert atmosphere; Stage #2: (3E,4aR,10aR)-3-benzylidene-4a-ethyl-7-hydroxy-3,4,4a,9,10,10a-hexahydro-1H-phenanthren-2-one In tetrahydrofuran at -70 - -40℃; for 2.5h; Inert atmosphere; | 96% |
phenylmagnesium bromide
(2R,3R,4R)-3,4-bis(benzyloxy)-2-((benzyloxy)methyl)-3,4-dihydro-2H-pyrrole 1-oxide
(2R,3R,4R,5R)-3,4-bis(benzyloxy)-2-(benzyloxymethyl)-1-hydroxy-5-phenylpyrrolidine
Conditions | Yield |
---|---|
In tetrahydrofuran at 0℃; for 3h; | 100% |
3,6-di(piperidin-1-yl)-9H-xanthen-9-one
phenylmagnesium bromide
C29H31N2O(1+)*Cl(1-)
Conditions | Yield |
---|---|
In tetrahydrofuran at 0 - 20℃; | 100% |
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View