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Dayang Chem (Hangzhou) Co.,Ltd.

As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

4'-Chloro-2-phenylacetophenone Manufacturer/High quality/Best price/In stock

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $3.0

Type:Lab/Research institutions

inquiry

Chemwill Asia Co., Ltd.

Our main production base is located in Xuzhou industry park. We are certified both to the ISO 9001 and ISO 14001 Standards, have a safety management system in place.Our R&D team masters core technology for process-design of target building block

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:5 Kiloliter

FOB Price: $1.2 / 5.0

Type:Manufacturers

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Zhuozhou Wenxi import and Export Co., Ltd

WITH US,YOUR MONEY IN SAFE,YOUR BUSINESS IN SAFE 1)Quick Response Within 12 hours; 2)Quality Guarantee: All products are strictly tested by our QC, confirmed by QA and approved by third party lab in China, USA, Canada, Germany, UK, Italy, France et

Manufacturer supply CAS 1889-71-0 with best quality

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $139.0 / 210.0

Type:Trading Company

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Shanghai Minstar Chemical Co., Ltd

Product Name: 4'-Chloro-2-phenylacetophenone Synonyms: -Chloro-2-phenylacetophenone;JR-8345, 4'-Chloro-2-phenylacetophenone, 97%;BENZYL 4-CHLOROPHENYL KETONE;DEOXY-4-CHLOROBENZOIN;CHLORODEOXYBENZOIN;4-CHLORODEOXYBENZOIN;4'-CHLORO-2-

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

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Shanghai Upbio Tech Co.,Ltd

1.In No Less 10 years exporting experience. you can 100% received goods 2.Lower Price with higher quality 3,Free sample 4,We are sincerely responsible for the "product quality" and "After Service" Upbio is Specializ

Ethanone,1-(4-chlorophenyl)-2-phenyl-

Cas:1889-71-0

Min.Order:1 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Hebei Nengqian Chemical Import and Export Co., LTD

Our Advantage Rich Experience Our products are sold all over Europe,North&South America, Sino-East, Asia and pacific area as well as Africa,we establish long term. Quality service Company cooperates with research institutes. We strictly con

4'-Chloro-2-phenylacetophenone CAS:1889-71-0

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $1.0 / 10.0

Type:Trading Company

inquiry

Henan Wentao Chemical Product Co., Ltd.

Henan Wentao Chemical Product Co.,Ltd is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds, which are widely used in the fields of prod

Ethanone,1-(4-chlorophenyl)-2-phenyl-

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

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Hebei Quanhe Biotechnology Co. LTD

1. Timely and efficient service to ensure communication with customers 2. Produce products of different specifications and sizes according to your requirements. 3. Quality procedures and standards recognized by SGS. Advanced plant equipment ensures

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $6.0 / 10.0

Type:Lab/Research institutions

inquiry

Hangzhou J&H Chemical Co., Ltd.

J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

4-Chlorodeoxybenzoin~4-Chloro-alpha-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Zibo Hangyu Biotechnology Development Co., Ltd

Zibo Hangyu Biotechnology Development Co., Ltd is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemi

Ethanone,1-(4-chlorophenyl)-2-phenyl-

Cas:1889-71-0

Min.Order:10 Gram

Negotiable

Type:Lab/Research institutions

inquiry

Ality Chemical Corporation

The above product is Ality Chemical's strong item with best price, good quality and fast supply. Ality Chemical has been focusing on the research and production of this field for over 14 years. At the same time, we are always committed to providing h

Factory Supply benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Tianfu Chemical Co., Ltd.

Our company was built in 2009 with an ISO certificate.In the past 6 years, we have grown up as a famous fine chemicals supplier in China and we had established stable business relationships with Samsung,LG,Merck,Thermo Fisher Scientific and so on.O

1889-71-0 4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $1000.0

Type:Lab/Research institutions

inquiry

TAIZHOU ZHENYU BIOTECHNOLOGY CO., LTD

Zhenyu biotech exported this product to many countries and regions at best price. if you are looking for the material's manufacturer or supplier in china, zhenyu biotech is your best choice. pls contact with us freely for getting detailed

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $2.0

Type:Lab/Research institutions

inquiry

Hunan chemfish Pharmaceutical co.,Ltd

Appearance:95%+ Package:R&D,Pilot run Transportation:per client require Port:Express ,Air, Sea

Benzyl4-chlorophenylketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Suzhou Health Chemicals Co., Ltd.

High quality,stable supply chain.Appearance:white/off-white or light yellow Storage:Store in cool and dry place, keep away from strong light and heat. Package:aluminum bottle,glass bottle,PTFE bottle,cardboard drum Application:This product can be use

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou Dingyan Chem Co., Ltd

R & D enterprises have their own stock in stockAppearance:To be subject to the object Package:Customized Application:pharmaceutical intermediates Transportation:Air Port:Shanghai;Guangzhou

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

GIHI CHEMICALS CO.,LIMITED

high purity,in stock Package:25kg/drum,or as per customers'demand Application:API,or Intermediates,fine chemicals Transportation:air,sea,courier

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Allgreen Chemical Co.,Ltd

high quality Storage:Sealed, dry, microtherm , avoid light and smell. Package:According to the demand of customer Application:Organic synthesis Transportation:by air or by sea

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Xi`an Eastling Biotech Co., Ltd.

high purity lowest priceAppearance:solid or liquid Storage:in sealed air resistant place Package:Foil bag; Drum; Plastic bottle Application:Pharma;Industry;Agricultural Transportation:by sea or air Port:Beijing or Guangzhou

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Xian Changyue Biological Technology Co., Ltd.

best seller Application:API

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Manufacturers

inquiry

Chemsigma International Co.,Ltd.

bulk productiongoods in stockswe have the best competitive price in the marketmeantime,we are committed to service to our every customer Chemsigma International Co.,Ltd. is a chemical manufacturer, specialize in custom synthesis and organic chemical

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Henan Sinotech Import&Export Corporation

Boiling point 393.8 °C at 760 mmHg Melting point 67 °C Density 1.094 g/cm3 Storage

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:1 Kilogram

FOB Price: $1.0

Type:Other

inquiry

Antimex Chemical Limied

factory?direct?sale Application:healing drugs

Ethanone,1-(4-chlorophenyl)-2-phenyl-

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Guangdong Juda Chemical Industrial Co.,Limited

Factory supply high purity low priceAppearance:solid or liquid Storage:sealed in cool and dry place Package:As customer's requested Application:Pharma Intermediate Transportation:by courier/air/sea Port:Any port in China

1-(4-chlorophenyl)-2-phenylethanone CAS No.1889-71-0

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

DB BIOTECH CO., LTD

best seller Application:API

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

BOC Sciences

We are committed to providing our customers with the best products and services at the most competitive prices.Appearance:crystalline powder Storage:Room temperature with sealed well Package:according to the clients requirement Application:Use as pri

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Trading Company

inquiry

Hangzhou Fandachem Co.,Ltd

4'-Chloro-2-phenylacetophenone cas 1889-71-0Appearance:white crystalline powder Storage:Store in dry, dark and ventilated place Package:25KG drum Application:intermediate Transportation:by air, by sea, by express

4'-Chloro-2-phenylacetophenone cas 1889-71-0

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Other

inquiry

Henan Kanbei Chemical Co.,LTD

factory?direct?saleAppearance:White powder Storage:Sealed and preserved Package:200/Kilograms Application:healing drugs Transportation:By sea Port:Shanghai/tianjin

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Hangzhou ZeErRui Chemical Co., Ltd.

Hangzhou ZeErRui Chemical Co., Ltd. is focused on customization, research and development and production of APIs and advanced intermediates, which can effectively compensate for the deficiencies of traditional CRO and CMO. Priority of high-tech barri

4'-Chloro-2-phenylacetophenone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

SAGECHEM LIMITED

1889-71-0 Application:intermediate

Benzyl 4-chlorophenyl ketone

Cas:1889-71-0

Min.Order:0

Negotiable

Type:Lab/Research institutions

inquiry

Synthetic route

α-benzyl-4,4'-dichlorobenzoin

α-benzyl-4,4'-dichlorobenzoin

A

4,4'-dichlorobenzoin
4254-20-0

4,4'-dichlorobenzoin

B

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With tetra-n-butylammonium cyanide In tetrahydrofuran for 1.5h; Ambient temperature;A 12%
B 100%
N-[1-(4-Chloro-phenyl)-1-cyano-2-phenyl-ethyl]-N-phenyl-benzamide
72867-63-1

N-[1-(4-Chloro-phenyl)-1-cyano-2-phenyl-ethyl]-N-phenyl-benzamide

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With potassium hydroxide In ethanol; water Heating;99%
S-phenyl 4-chlorobenzothioate
28122-82-9

S-phenyl 4-chlorobenzothioate

benzyl(bromo)zinc
62673-31-8

benzyl(bromo)zinc

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With (phenyl)(bis-triphenylphosphine)palladium(II) chloride In tetrahydrofuran; toluene at 20℃; for 1h; Fukuyama Coupling; Inert atmosphere;98%
4-chlorobenzenesulfinic acid
100-03-8

4-chlorobenzenesulfinic acid

phenylacetonitrile
140-29-4

phenylacetonitrile

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With [2,2]bipyridinyl; sulfuric acid; water; palladium diacetate In 2-methyl-propan-1-ol at 100℃; for 6h; Inert atmosphere;95%
2-(4-chlorophenyl)-2-oxo-1-phenylethyl benzoate
114679-00-4

2-(4-chlorophenyl)-2-oxo-1-phenylethyl benzoate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; hydrogen; [(4S)-4-[5-bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphanyl-1,3-benzodioxol-4-yl]-4,5,6,7-tetrahydro-1,3-benzodioxol-5-yl]-bis(3,5-di-tert-butyl-4-methoxyphenyl)phosphane In acetone at 60℃; under 45004.5 Torr; for 24h; Glovebox; Autoclave; chemoselective reaction;94%
2-(4-chlorophenyl)-2-oxo-1-phenylethyl acetate
119267-71-9

2-(4-chlorophenyl)-2-oxo-1-phenylethyl acetate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With tris(bipyridine)ruthenium(II) dichloride hexahydrate; diethyl 2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate; triethylamine In acetonitrile at 20℃; for 1h; Inert atmosphere; UV-irradiation;92%
benzyl bromide
100-39-0

benzyl bromide

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; zinc In 1,2-dimethoxyethane for 0.333333h; Ambient temperature;90%
With bis-triphenylphosphine-palladium(II) chloride; zinc In 1,2-dimethoxyethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;
C7H7ClZn*Cl3LiMg

C7H7ClZn*Cl3LiMg

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With iron(II) chloride In tetrahydrofuran at 25℃; for 0.5h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;90%
3-(4-chlorophenyl)-3-oxo-2-phenylpropanal

3-(4-chlorophenyl)-3-oxo-2-phenylpropanal

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With ethylenediamine In tetrahydrofuran for 4h; Heating;88%
chlorobenzene
108-90-7

chlorobenzene

phenylacetyl chloride
103-80-0

phenylacetyl chloride

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With zinc(II) oxide at 20℃; for 0.0833333h; Friedel-Crafts acylation;85%
With aluminum (III) chloride In dichloromethane at 0 - 20℃;79%
With aluminium trichloride at 20℃;74%
4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

benzyltetrabutyl stiborane
131973-46-1

benzyltetrabutyl stiborane

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
In tetrahydrofuran for 1h; Ambient temperature;85%
phenyl 1H-imidazole-1-sulfonate
1198183-95-7

phenyl 1H-imidazole-1-sulfonate

para-chloroacetophenone
99-91-2

para-chloroacetophenone

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With palladium diacetate; caesium carbonate; 4,5-bis(diphenylphos4,5-bis(diphenylphosphino)-9,9-dimethylxanthenephino)-9,9-dimethylxanthene In 1,4-dioxane at 110℃; for 24h; Inert atmosphere; chemoselective reaction;84%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

phenylhydrazine
100-63-0

phenylhydrazine

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane; 3,7-bis(dimethylamine)phenothiazonium In acetonitrile at 25℃; Irradiation; Green chemistry;83%
2-(4-Chloro-phenyl)-1,3-diphenyl-propan-2-ol

2-(4-Chloro-phenyl)-1,3-diphenyl-propan-2-ol

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With ammonium cerium(IV) nitrate In water; acetonitrile at 50 - 55℃; for 0.166667h;81%
4-Chlorophenylboronic acid
1679-18-1

4-Chlorophenylboronic acid

phenylacetonitrile
140-29-4

phenylacetonitrile

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With [2,2]bipyridinyl; potassium fluoride; acetic acid; palladium diacetate In tetrahydrofuran at 80℃; for 48h;80%
phenylacetic acid
103-82-2

phenylacetic acid

Methyl 4-chlorobenzoate
1126-46-1

Methyl 4-chlorobenzoate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With lithium hexamethyldisilazane In tetrahydrofuran; N,N-dimethyl-formamide at -4℃; Claisen Condensation; Inert atmosphere;80%
With sodium hexamethyldisilazane In N,N-dimethyl-formamide at -10℃; for 3.5h;
1-chloro-4-(2-phenylethynyl)benzene
5172-02-1

1-chloro-4-(2-phenylethynyl)benzene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With methanol In water at -5℃; for 0.5h; Irradiation; Green chemistry;77%
1-(2-(4-chlorophenyl)-2-oxoethyl)tetrahydro-1H-thiophen-1-ium tetraphenylborate
1619239-35-8

1-(2-(4-chlorophenyl)-2-oxoethyl)tetrahydro-1H-thiophen-1-ium tetraphenylborate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
In toluene at 120℃; Inert atmosphere;76%
1-(4-chloro-benzoyl)-1H-imidazole
10364-95-1

1-(4-chloro-benzoyl)-1H-imidazole

diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate
1539-57-7

diethyl 2,6-dimethyl-4-benzyl-1,4-dihydropyridine-3,5-dicarboxylate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With [4,4’-bis(1,1-dimethylethyl)-2,2’-bipyridine-N1,N1‘]bis [3,5-difluoro-2-[5-(trifluoromethyl)-2-pyridinyl-N]phenyl-C]iridium(III) hexafluorophosphate; caesium carbonate; 1,4-dimethyl-1,2,4-triazolium iodide In acetonitrile at 20℃; Inert atmosphere; Irradiation; Sealed tube;76%
benzyl chloride
100-44-7

benzyl chloride

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With nickel In 1,2-dimethoxyethane at 85℃; for 0.25h;72%
tris(4-chlorophenyl)bismuthane
5575-51-9

tris(4-chlorophenyl)bismuthane

phenylacetyl chloride
103-80-0

phenylacetyl chloride

A

4,4'-dichlorobiphenyl
2050-68-2

4,4'-dichlorobiphenyl

B

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With bis-triphenylphosphine-palladium(II) chloride; triethylamine In tetrahydrofuran at 80℃; for 3h; Schlenk tube; Inert atmosphere;A n/a
B 71%
4-vinylbenzyl chloride
1073-67-2

4-vinylbenzyl chloride

benzenediazonium tetrafluoroborate
369-57-3

benzenediazonium tetrafluoroborate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With ascorbic acid In N,N-dimethyl-formamide at 20℃; for 20h; Cooling with ice;71%
N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide
80351-84-4

N-Benzyl-N-(benzylsulfanyl-phenyl-methyl)-4-chloro-benzamide

A

N-benzylidene benzylamine
780-25-6

N-benzylidene benzylamine

B

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C

S

S

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran for 4h; Ambient temperature; addition, -70 deg C;A n/a
B 70%
C n/a
1-(4-Chloro-phenyl)-2-phenyl-1-quinazolin-4-yl-ethanol
187336-13-6

1-(4-Chloro-phenyl)-2-phenyl-1-quinazolin-4-yl-ethanol

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With potassium cyanide In N,N-dimethyl-formamide at 80℃; for 1h;68%
1-(4-Chloro-phenyl)-2-phenyl-1-quinazolin-4-yl-ethanol
187336-13-6

1-(4-Chloro-phenyl)-2-phenyl-1-quinazolin-4-yl-ethanol

A

quinazoline-4-carbonitrile
36082-71-0

quinazoline-4-carbonitrile

B

quinazoline-4-carbonamide
16499-37-9

quinazoline-4-carbonamide

C

4-benzyl-quinazoline
92437-11-1

4-benzyl-quinazoline

D

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With potassium cyanide In N,N-dimethyl-formamide at 80℃; for 1h;A 9%
B 10%
C 9%
D 68%
sodium p-chlorobenzenesulphinate
14752-66-0

sodium p-chlorobenzenesulphinate

phenylacetonitrile
140-29-4

phenylacetonitrile

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With palladium(II) trifluoroacetate; trifluoroacetic acid; 6-methyl-2,2'-bipyridine In tetrahydrofuran; water at 100℃; for 1h; Microwave irradiation;66%
benzylic zinc mesylate

benzylic zinc mesylate

4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With copper(l) cyanide; lithium chloride In tetrahydrofuran at 0℃; for 2h; Inert atmosphere;60%
4-chloro-benzoyl chloride
122-01-0

4-chloro-benzoyl chloride

toluene
108-88-3

toluene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With dipotassium hydrogenphosphate; nickel(II) chloride hexahydrate; 4-acetoxybenzophenone; 4,4'-di-tert-butyl-2,2'-bipyridine at 35℃; for 48h; Inert atmosphere; Sealed tube; Irradiation; Schlenk technique;60%
1-(4-chlorophenyl)-3-phenyl-2,3-ditosyloxypropanone

1-(4-chlorophenyl)-3-phenyl-2,3-ditosyloxypropanone

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With potassium hydroxide In ethanol Heating;58%
benzyl (N-benzyl-p-chlorobenzamido)methylsulfide
77863-85-5

benzyl (N-benzyl-p-chlorobenzamido)methylsulfide

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

Conditions
ConditionsYield
With sodium hydride In tetrahydrofuran for 13h; Heating;55%
With sodium hydride In tetrahydrofuran for 13h; Heating;55%
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-bromo-1-(4-chlorophenyl)-2-phenylethanone
1889-78-7

2-bromo-1-(4-chlorophenyl)-2-phenylethanone

Conditions
ConditionsYield
With bromine In diethyl ether for 0.5h;100%
With copper(II) nitrate trihydrate; hydrogen bromide; oxygen In acetic acid at 60℃; for 4.5h; Green chemistry;91%
With bromine In chloroform; acetic acid at 20℃; for 24h;86%
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

4-chlorobenzil
22711-23-5

4-chlorobenzil

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In N,N-dimethyl-formamide at 90℃; for 24h;100%
With potassium hydrogencarbonate; dimethyl sulfoxide at 80℃;91%
With oxygen; copper(II) acetate monohydrate; potassium carbonate In N,N-dimethyl-formamide at 50℃; under 760.051 Torr; for 0.5h;87%
N,N-dimethyl-formamide dimethyl acetal
4637-24-5

N,N-dimethyl-formamide dimethyl acetal

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C17H16ClNO
611217-74-4

C17H16ClNO

Conditions
ConditionsYield
In toluene at 20 - 50℃; for 156h;100%
3-Iodotoluene
625-95-6

3-Iodotoluene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1-(4-chlorophenyl)-2-phenyl-2-m-tolylethanone
1443223-40-2

1-(4-chlorophenyl)-2-phenyl-2-m-tolylethanone

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 1,4-dioxane at 110℃; for 24h; Inert atmosphere;99%
3,5-dimethylphenyl iodide
22445-41-6

3,5-dimethylphenyl iodide

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1-(4-chlorophenyl)-2-(3,5-dimethylphenyl)-2-phenylethanone
1443223-42-4

1-(4-chlorophenyl)-2-(3,5-dimethylphenyl)-2-phenylethanone

Conditions
ConditionsYield
With copper(l) iodide; 1,10-Phenanthroline; caesium carbonate In 1,4-dioxane at 110℃; for 24h; Inert atmosphere;99%
With copper(l) iodide; caesium carbonate; 1,7-phenanthroline In 1,4-dioxane at 110℃; for 24h; Inert atmosphere;95%
4-fluoro-1-iodobenzene
352-34-1

4-fluoro-1-iodobenzene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-(4-fluorophenyl)-2-(4-chlorophenyl)-1-phenylethanone
1443223-60-6

2-(4-fluorophenyl)-2-(4-chlorophenyl)-1-phenylethanone

Conditions
ConditionsYield
With copper(l) iodide; 2-acetylcyclohexanone; caesium carbonate In tert-butyl alcohol at 70℃; for 24h; Inert atmosphere;99%
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

(1S)-(-)-1-(4'-chlorophenyl)-2-phenylethanol
650601-10-8

(1S)-(-)-1-(4'-chlorophenyl)-2-phenylethanol

Conditions
ConditionsYield
With (S)-methyl oxazaboralidine; borane In tetrahydrofuran at 30℃; for 1h;98%
With D-glucose In ethanol; hexane; water; allyl alcohol at 50℃; for 168h; optical yield given as %ee; enantioselective reaction;
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

(R)-1-(4'-chlorophenyl)-2-phenylethanol
811830-11-2

(R)-1-(4'-chlorophenyl)-2-phenylethanol

Conditions
ConditionsYield
With borane-THF In tetrahydrofuran at 30℃; for 16h; Inert atmosphere; optical yield given as %ee; enantioselective reaction;98%
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol; dichloromethane / 24 h / 20 °C
2: Pseudomonas cepacia lipase / tert-butyl methyl ether / 168 h / 20 °C / Resolution of racemate
View Scheme
Multi-step reaction with 2 steps
1: sodium tetrahydroborate / methanol; dichloromethane / 24 h / 20 °C
2: Porcine pancreas lipase type II / tert-butyl methyl ether / 264 h / 40 °C / Resolution of racemate
View Scheme
5,5-dimethyl-2-(2-methylallyl)-1,3,2-dioxaborinane
1398647-62-5

5,5-dimethyl-2-(2-methylallyl)-1,3,2-dioxaborinane

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

(R)-2-(4-chlorophenyl)-4-methyl-1-phenylpent-4-en-2-ol
1428476-55-4

(R)-2-(4-chlorophenyl)-4-methyl-1-phenylpent-4-en-2-ol

Conditions
ConditionsYield
With (S)-3,3'-difluoro-1,1'-binaphthyl-2,2'-diol In tert-Amyl alcohol at 40℃; for 2h; Inert atmosphere; enantioselective reaction;97%
benzylacrylate
2495-35-4

benzylacrylate

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

benzyl 5-(4-chlorophenyl)-5-oxo-4-phenylpentanoate

benzyl 5-(4-chlorophenyl)-5-oxo-4-phenylpentanoate

Conditions
ConditionsYield
With tetrabutylammonium tricarbonylnitrosylferrate In acetonitrile at 100℃; for 30h; Michael Addition; Inert atmosphere; Schlenk technique;97%
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1-(4-chlorophenyl)-2-phenylethanol
31233-66-6

1-(4-chlorophenyl)-2-phenylethanol

Conditions
ConditionsYield
With sodium tetrahydroborate In ethanol96%
With sodium tetrahydroborate In methanol; dichloromethane at 20℃; for 24h;94%
With C19H29N4Ru(1+)*C24H20B(1-); potassium hydroxide In isopropyl alcohol at 80℃; for 2h; Inert atmosphere; Schlenk technique;92%
1,2-diamino-benzene
95-54-5

1,2-diamino-benzene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-(4-chlorophenyl)-3-phenylquinoxaline
193145-75-4

2-(4-chlorophenyl)-3-phenylquinoxaline

Conditions
ConditionsYield
With 1,4-diaza-bicyclo[2.2.2]octane In N,N-dimethyl-formamide at 90℃; for 3h;96%
With [Cu(II)[5,11,17,23-tetrakis(trimethylammonium)-25,26,27,28-tetrahydroxycalix[4]arene](H2O)]I2; oxygen; potassium carbonate In water for 15h; Reflux; Green chemistry;88%
2-azido-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium hexafluorophosphate (V)
1266134-54-6

2-azido-1,3-dimethyl-4,5-dihydro-1H-imidazol-3-ium hexafluorophosphate (V)

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C19H20ClN3O
1309977-03-4

C19H20ClN3O

Conditions
ConditionsYield
With triethylamine In tetrahydrofuran; acetonitrile at 0℃; for 0.5h;96%
methanol
67-56-1

methanol

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1-(4-chlorophenyl)-2-phenyl-1-propanone
126866-24-8

1-(4-chlorophenyl)-2-phenyl-1-propanone

Conditions
ConditionsYield
With C34H27IrN2P(1+)*C32H12BF24(1-); caesium carbonate at 65℃; for 24h; Inert atmosphere;96%
With sodium hydroxide at 100℃; for 15h; Sealed tube; Autoclave; Inert atmosphere;85%
bromoacetic acid methyl ester
96-32-2

bromoacetic acid methyl ester

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

β-p-Chlorbenzoyl-β-phenyl-propionsaeure-methylester
101441-22-9

β-p-Chlorbenzoyl-β-phenyl-propionsaeure-methylester

Conditions
ConditionsYield
With sodium hydride In dimethyl sulfoxide at 20℃; for 1h;95%
benzaldehyde
100-52-7

benzaldehyde

toluene-4-sulfonamide
70-55-3

toluene-4-sulfonamide

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

(2S,3S)-1-(4-chlorophenyl)-2,3-diphenyl-3-(tosylamino)propan-1-one
1421353-67-4

(2S,3S)-1-(4-chlorophenyl)-2,3-diphenyl-3-(tosylamino)propan-1-one

Conditions
ConditionsYield
With C35H32F6N4OS In toluene at 0℃; for 35h; Mannich Aminomethylation; Molecular sieve; enantioselective reaction;95%
β-azidostyrene
16722-99-9

β-azidostyrene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C22H16ClN3

C22H16ClN3

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dimethyl sulfoxide at 25℃; for 0.82h; regioselective reaction;95%
2-Amino-5-chlorobenzophenone
719-59-5

2-Amino-5-chlorobenzophenone

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-(4-chlorophenyl)-3,4-diphenyl-6-chloroquinoline
144757-84-6

2-(4-chlorophenyl)-3,4-diphenyl-6-chloroquinoline

Conditions
ConditionsYield
With 2,4,6-tripropyl-1,3,5,2,4,6-trioxatriphosphinane-2,4,6-trioxide In ethyl acetate at 60℃; Friedlaender synthesis;94%
ethylene glycol
107-21-1

ethylene glycol

phenethylamine
64-04-0

phenethylamine

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C24H20ClN

C24H20ClN

Conditions
ConditionsYield
With C34H27MnNO3P2(1+)*Br(1-); potassium tert-butylate In tert-Amyl alcohol at 135℃; for 24h;94%
4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1,4-bis(4-chlorophenyl)-2,3-diphenylbutane-1,4-dione
36122-13-1

1,4-bis(4-chlorophenyl)-2,3-diphenylbutane-1,4-dione

Conditions
ConditionsYield
With silver fluoride In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 4.5h;93%
With copper(II) acetate monohydrate In 5,5-dimethyl-1,3-cyclohexadiene at 140℃; for 2h;81%
In benzene Irradiation;
1-azidostyrene
16717-64-9

1-azidostyrene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

C22H16ClN3

C22H16ClN3

Conditions
ConditionsYield
With 1,8-diazabicyclo[5.4.0]undec-7-ene In dimethyl sulfoxide at 25℃; for 0.5h; regioselective reaction;93%
2-aminopyridine
504-29-0

2-aminopyridine

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-(4-chlorophenyl)-3-phenylimidazo[1,2-a]pyridine
342783-28-2

2-(4-chlorophenyl)-3-phenylimidazo[1,2-a]pyridine

Conditions
ConditionsYield
With potassium hydrogencarbonate In acetonitrile at 80℃; for 4h;91%
thiourea
17356-08-0

thiourea

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

2-amino-4-(p-chlorophenyl)-5-phenylthiazole

2-amino-4-(p-chlorophenyl)-5-phenylthiazole

Conditions
ConditionsYield
With cesium bicarbonate; Bromotrichloromethane In acetonitrile at 80℃; for 2h;91%
1-azido-4-bromobenzene
2101-88-4

1-azido-4-bromobenzene

4'-chloro-2-phenylacetophenone
1889-71-0

4'-chloro-2-phenylacetophenone

1-(4-bromophenyl)-5-(4-chlorophenyl)-4-phenyl-1H-1,2,3-triazole

1-(4-bromophenyl)-5-(4-chlorophenyl)-4-phenyl-1H-1,2,3-triazole

Conditions
ConditionsYield
With tetra(n-butyl)ammonium hydrogensulfate; potassium hydroxide In water at 100℃; for 24h; Inert atmosphere; regioselective reaction;91%

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