PROPAZINE supplier | CasNO.139-40-2

Name
2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine
EINECS 205-359-9
CAS No. 139-40-2
Article Data16
CAS DataBase
Density 1.162
Solubility 8.6mg/L(22 oC)
Melting Point 212-214 ºC
Formula C9H16 Cl N5
Boiling Point 373.1 °C at 760 mmHg
Molecular Weight 229.713
Flash Point 179.4 °C
Transport Information UN 3077
Appearance Colorless powder.
Safety 36/37-60-61-45-24-16-7
Risk Codes R40;R50/53
Molecular Structure
Hazard Symbols
Synonyms 1,3,5-Triazine-2,4-diamine,6-chloro-N,N'-bis(1-methylethyl)- (9CI); s-Triazine, 2-chloro-4,6-bis(isopropylamino)-(6CI,8CI); 2,4-Bis(isopropylamino)-6-chloro-s-triazine;2,4-Bis[(1-methylethyl)amino]-6-chloro-s-triazine;2-Chloro-4,6-bis(isopropylamino)-1,3,5-triazine;2-Chloro-4,6-bis(isopropylamino)-s-triazine;2-Chloro-4-isopropylamino-6-isopropylamino-s-triazine; Atradex; G 30028; Geigy30,028; Gesamil; Milogard; NSC 26002; Plantulin; Primatol P; Propasin;Propazin; Propazine; Propazine (herbicide); Prozinex;s-Bis(isopropylamino)chlorotriazine
PSA 62.73000
LogP 2.31160

Synthetic route

: 108-77-0
1,3,5-trichloro-2,4,6-triazine

: 75-31-0
isopropylamine

: 139-40-2
propazine

Conditions

Conditions	Yield
With sodium hydroxide In water; toluene at 5 - 50℃;	98.8%
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 72h;	22.2 g

: 3703-10-4
2,4-dichloro-6-isopropylamino-1,3,5-triazine

: 75-31-0
isopropylamine

: 139-40-2
propazine

Conditions

Conditions	Yield
With sodium hydroxide

: 124-40-3
dimethyl amine

: 139-40-2
propazine

: 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin

Conditions

Conditions	Yield
With water; sodium carbonate for 1.5h; Heating;	100%

: 616-38-6
carbonic acid dimethyl ester

: 139-40-2
propazine

: 7287-19-6
2-methylthio-4,6-bis(isopropylamino)-s-triazine

Conditions

Conditions	Yield
With potassium tert-butylate; palladium diacetate; triphenylphosphine; potassium thioacetate In dimethyl sulfoxide at 120℃; Inert atmosphere;	91%
With potassium tert-butylate; palladium diacetate; triphenylphosphine; potassium thioacetate In dimethyl sulfoxide at 120℃; Schlenk technique; Inert atmosphere;	91%

: 1001-53-2
monoacetylaminoethylamine

: 139-40-2
propazine

: N-(2-((4,6-bis(isopropylamino)-1,3,5-triazine-2-yl)amino)ethyl)acetamide

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran for 24h; Reflux;	85%

: 371-40-4
4-fluoroaniline

: 139-40-2
propazine

: 92887-87-1
4,6-Di(isopropylamino)-6-(4-fluoranilino)-1,3,5-triazin

Conditions

Conditions	Yield
In N,N-dimethyl-formamide for 72h; Ambient temperature;	78%

: 141-43-5
ethanolamine

: 139-40-2
propazine

: 125101-22-6
2-(4,6-Bis-isopropylamino-[1,3,5]triazin-2-ylamino)-ethanol

Conditions

Conditions	Yield
With sodium methylate	76%

: 62-53-3
aniline

: 139-40-2
propazine

: 92887-84-8
2-Anilino-4,6-di(isopropylamino)-1,3,5-triazin

Conditions

Conditions	Yield
In acetone at 45℃; for 48h;	66%

: 68-12-2, 33513-42-7
N,N-dimethyl-formamide

: 139-40-2
propazine

A: 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin

B: 53736-41-7
2-cyanamino-4,6-bisisopropylamino-sym-triazine

Conditions

Conditions	Yield
With disodium cyanamide In water at 135℃; for 0.5h;	A 65% B 11%

...Expand

: 20611-81-8
disodium cyanamide

: 139-40-2
propazine

A: 74150-98-4
2,4-Bisisopropylamino-6-dimethylamino-1,3,5-triazin

B: 53736-41-7
2-cyanamino-4,6-bisisopropylamino-sym-triazine

Conditions

Conditions	Yield
In water; N,N-dimethyl-formamide at 135℃; for 0.5h;	A 65% B 11%

...Expand

: 20611-81-8
disodium cyanamide

: 139-40-2
propazine

: 53736-41-7
2-cyanamino-4,6-bisisopropylamino-sym-triazine

Conditions

Conditions	Yield
In water; dimethyl sulfoxide at 140℃; for 0.5h;	64%

: 372-19-0
meta-fluoroaniline

: 139-40-2
propazine

: 92887-86-0
4,6-Di(isopropylamino)-6-(3-fluoranilino)-1,3,5-triazin

Conditions

Conditions	Yield
In tetrahydrofuran for 48h; Heating;	63%

: 348-54-9
2-Fluoroaniline

: 139-40-2
propazine

: 92887-85-9
4,6-Di(isopropylamino)-6-(2-fluoranilino)-1,3,5-triazin

Conditions

Conditions	Yield
With copper at 150 - 200℃;	58%

: 33178-96-0
(R)-thiolactic acid

: 139-40-2
propazine

: C12H21N5O2S

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 3h; Alkaline conditions;	51%

: 139-40-2
propazine

: 107-96-0
3-mercaptopropionic acid

: C12H21N5O2S

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 3h; Alkaline conditions;	8.8%

: 139-40-2
propazine

: 2711-02-6
6-fluoro-N,N'-diisopropyl-[1,3,5]triazine-2,4-diamine

Conditions

Conditions	Yield
With potassium fluoride; perhydrodibenzo-18-crown-6 at 140℃; for 4h;

: 139-40-2
propazine

: 7287-19-6
2-methylthio-4,6-bis(isopropylamino)-s-triazine

: 139-40-2
propazine

: 504-08-5
2,4-diamino-1,3,5-triazine

Conditions

Conditions	Yield
With iron In phosphate buffer at 22℃; pH=6.6; Kinetics; Dehalogenation; dealkylation;

: 67-56-1
methanol

: 139-40-2
propazine

: 1610-18-0
prometon

Conditions

Conditions	Yield
With polymer (2-sulfoethyl methacrylate - methacrylic acid, In chloroform at 25℃; for 24h;

: 7144-05-0
4-Aminomethylpiperidine

: 139-40-2
propazine

: 6-(4-(aminomethyl)piperidin-1-yl)-N2,N4-diisopropyl-1,3,5-triazine-2,4-diamine

Conditions

Conditions	Yield
With N-ethyl-N,N-diisopropylamine In tetrahydrofuran at 20℃; for 24h;	27 g

: 52-90-4
L-Cysteine

: 139-40-2
propazine

: C12H22N6O2S

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 3h; Alkaline conditions;

: 6027-13-0
L-homocysteine

: 139-40-2
propazine

: C13H24N6O2S

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 3h; Alkaline conditions;

: 107-15-3
ethylenediamine

: 139-40-2
propazine

: N2-(2-aminoethyl)-N4,N6-diisopropyl-1,3,5-triazine-2,4,6-triamine

Conditions

Conditions	Yield
at 120℃; for 24h;

: 139-40-2
propazine

: N2,N4-diisopropyl-N6-(2-((pyridin-2-ylmethyl)amino)ethyl)-1,3,5-triazine-2,4,6-triamine

Conditions

Conditions	Yield
Multi-step reaction with 3 steps 1: 24 h / 120 °C 2: methanol / 6 h / 20 °C 3: sodium tetrahydroborate / methanol / 36.5 h / 20 - 75 °C View Scheme

: 139-40-2
propazine

: C24H33N9O

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 24 h / 120 °C 2: 24 h / 20 °C View Scheme

: 139-40-2
propazine

: N2,N4-diisopropyl-6-(2-( pyridin-2-yl)-3-(pyridin-2-ylmethyl)imidazolidin-1-yl)-1,3,5-triazine-2,4-diamine

Conditions

Conditions	Yield
Multi-step reaction with 4 steps 1: 24 h / 120 °C 2: methanol / 6 h / 20 °C 3: sodium tetrahydroborate / methanol / 36.5 h / 20 - 75 °C 4: sodium tetrahydroborate / methanol / 15 h / 20 - 75 °C View Scheme

: 94-74-6
MCPA

: 139-40-2
propazine

: 2-methyl,4-chlorophenoxyacetic acid propazine

Conditions

Conditions	Yield
In n-heptane at 50℃;

PROPAZINE Chemical Properties

MF: C₉H₁₆ClN₅
MW: 229.71
Density: 1.162
EINECS: 205-359-9
Melting Point: 212-214°C
Flash Point: 179.4 °C
Storage temp: APPROX 4°C
Index of Refraction: 1.59
Appearance: Colorless powder.
Solubility in water: 5 mg/L
Enthalpy of Vaporization: 62.03 kJ/mol
Boiling Point: 373.1 °C at 760 mmHg
Vapour Pressure: 9.19E-06 mmHg at 25°C
IUPAC Name: 6-chloro-2-N,4-N-di(propan-2-yl)-1,3,5-triazine-2,4-
diamine
Synonyms: G-30028 ; Gesamil(R) ; Chembrdg-BB 5348952 ; 6-Chloro-N,N'-bis(1-methylethyl)-1,3,5-triazine-2,4-diamine ; 2-Chloro-4，6-bis(isopropylamino)-1，3，5-triazine ; 2-Chloro-4,6-bis(Iisopropylamino)-S-triazine ; 2-Chloro-4,6-bis(ispropylamino)-S-triazine ; 2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine
Following is the molecular structure of Propazine (139-40-2):

PROPAZINE Uses

Propazine (139-40-2)is used as Herbicide.

PROPAZINE Toxicity Data With Reference

1.	eye-rbt 400 mg open	CIGET* Ciba-Geigy Toxicology Data/Indexes, 1977 .(Ciba-Geigy Corp.,Ardsley, NY.: )1977.
2.	orl-gpg LD50:1200 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,35.
3.	orl-mus LD50:3180 mg/kg	85GMAT Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure Izmerov, N.F., et al.,Moscow, USSR.: Centre of International Projects, GKNT,1982,35.

PROPAZINE Safety Profile

Moderately toxic by ingestion. Moderate eye irritation. Questionable carcinogen with experimental tumorigenic data. When heated to decomposition it emits toxic fumes of NO_x and Cl⁻.
Safety Information of Propazine (139-40-2):
Hazard Codes: Xn;N,N,Xn,T,F
Xn: Harmful N: Dangerous for the environment
T: Toxic F: Highly Flammable
Risk Statements: 40-50/53-39/23/24/25-23/24/25-11
40: Limited evidence of a carcinogenic effect
50/53: Very Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
39/23/24/25: Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed
23/24/25: Toxic by inhalation, in contact with skin and if swallowed
11: Highly Flammable
Safety Statements: 36/37-60-61-45-24-16-7
36/37: Wear suitable protective clothing and gloves
60: This material and/or its container must be disposed of as hazardous waste
61: Avoid release to the environment. Refer to special instructions safety data sheet
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
24: Avoid contact with skin
16: Keep away from sources of ignition - No smoking
7: Keep container tightly closed
RIDADR: UN 3077
RTECS: XY5300000

Product Name

2,4-Bis(isopropylamino)-6-chloro-1,3,5-triazine

Synthetic route

PROPAZINE Chemical Properties

PROPAZINE Uses

PROPAZINE Toxicity Data With Reference

PROPAZINE Safety Profile

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