perfluoropropylene
perfluoropropanoyl fluoride
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With iron(III) trifluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave; | 98.2% |
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 95℃; under 1875.19 Torr; | |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
In diethylene glycol at 60℃; for 2h; Temperature; Reagent/catalyst; Autoclave; | 97.8% |
With triethylamine In acetonitrile at 30℃; for 0.166667h; Temperature; Reagent/catalyst; Solvent; Time; | 97.1% |
With sodium fluoride In 1,2-dimethoxyethane at 20℃; for 9h; | 94% |
polytetrafluoroethylene
perfluoroisobutyryl fluoride
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With iron(III) trifluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave; | 96.8% |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
trans-2,3-epoxyperfluoro-4-methylpentane
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In 1,2-dimethoxyethane at 50℃; for 9h; | 92% |
2,3-bi(fluorosulfato)perfluoro-4-methylpentane
A
pentafluoropropionic acid
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In N,N-dimethyl-formamide at 20℃; for 4h; | A 76% B 16% |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoro(2-propoxypropionyl) fluoride
B
perfluoro-2-methyl-2-pentene
C
perfluoro-2-methylpentan-3-one
D
perfluoro-4-methylpent-1-ene
Conditions | Yield |
---|---|
With potassium fluoride In diethylene glycol dimethyl ether | A 9.7% B n/a C 63.5% D 18% |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 93 percent / sodium hypochlorite / H2O; acetonitrile 2: 94 percent / NaF / 1,2-dimethoxy-ethane / 9 h / 20 °C View Scheme | |
Multi-step reaction with 2 steps 1: sodium hypochlorite; urea / acetonitrile; water / 3 h / 20 °C 2: potassium fluoride; 18-crown-6 ether / diethylene glycol dimethyl ether / 3 h / 30 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 70 percent / sodium hypochlorite / H2O; acetonitrile 2: antimony pentafluoride / 2.5 h / 250 °C View Scheme | |
Multi-step reaction with 2 steps 1: 70 percent / sodium hypochlorite / H2O; acetonitrile 2: 92 percent / CsF / 1,2-dimethoxy-ethane / 9 h / 50 °C View Scheme |
Hexafluoropropene oxide
perfluoropropylene
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
Stage #1: Hexafluoropropene oxide With potassium fluoride In diethylene glycol dimethyl ether for 2h; Heating; Stage #2: perfluoropropylene In diethylene glycol dimethyl ether; acetonitrile at 65 - 80℃; under 5250.53 Torr; for 2h; | |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoropropanoyl fluoride
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 130℃; Reagent/catalyst; Temperature; |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoro(2-propoxypropionyl) fluoride
B
perfluoropropanoyl fluoride
C
perfluoro-2-methylpentan-3-one
D
perfluoro-4-methylpent-1-ene
Conditions | Yield |
---|---|
With activated carbon BAU In neat (no solvent) at 130℃; Reagent/catalyst; Temperature; |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sulfolane; cesium fluoride / diethylene glycol dimethyl ether / 0.5 h / 70 °C 2: sodium hypochlorite; urea / acetonitrile; water / 3 h / 20 °C 3: potassium fluoride; 18-crown-6 ether / diethylene glycol dimethyl ether / 3 h / 30 °C View Scheme | |
Multi-step reaction with 3 steps 1: benzyltriethylammonium bromide; potassium fluoride / acetonitrile / 4 h 2: sodium hypochlorite / diethylene glycol dimethyl ether / 4 h 3: Aliquat 336 / diethylene glycol dimethyl ether / 10 h View Scheme |
perfluoro-2-methylpentan-3-one
A
perfluoropropylene
B
perfluoropropanoyl fluoride
Conditions | Yield |
---|---|
With cesium fluoride at 250℃; for 2h; Product distribution; | A 68% B n/a |
perfluoro-2-methylpentan-3-one
3-hydroperfluoro-2-methyl-3-pentanol
Conditions | Yield |
---|---|
Stage #1: perfluoro-2-methylpentan-3-one With polyethylsiloxane; tetrabutoxytitanium at 100℃; Stage #2: With sodium hydroxide In tetrahydrofuran Heating; | 42% |
With sodium tetrahydroborate In 1,4-dioxane for 1h; |
Vinylidene fluoride
perfluoro-2-methylpentan-3-one
1-<2-Trifluormethyl-perfluorpentyl-(3)-oxy>-1,1-difluor-2-brom-aethan
Conditions | Yield |
---|---|
(i) CsF, MeCN, (ii) /BRN= 1733321/, Br2; Multistep reaction; |
perfluoro-2-methylpentan-3-one
A
1,1,1,2,3,3,3-Heptafluoropropane
B
pentafluoropropionic acid
Conditions | Yield |
---|---|
With sodium hydroxide In water Product distribution; | A 92 % Chromat. B 85 % Chromat. |
perfluoro-2-methylpentan-3-one
dimethyl sulfate
1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane
Conditions | Yield |
---|---|
With potassium fluoride In diethylene glycol dimethyl ether at 45℃; |
pyrrolidine
perfluoro-2-methylpentan-3-one
A
N-tetramethyleneperfluoropropanamide
B
1,1,1,2,3,3,3-Heptafluoropropane
C
N-butyl pentafluoropropionamide
Conditions | Yield |
---|---|
With freon 11 |
perfluoropropylene
perfluoropropanoyl fluoride
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With iron(III) trifluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave; | 98.2% |
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 95℃; under 1875.19 Torr; | |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
In diethylene glycol at 60℃; for 2h; Temperature; Reagent/catalyst; Autoclave; | 97.8% |
With triethylamine In acetonitrile at 30℃; for 0.166667h; Temperature; Reagent/catalyst; Solvent; Time; | 97.1% |
With sodium fluoride In 1,2-dimethoxyethane at 20℃; for 9h; | 94% |
polytetrafluoroethylene
perfluoroisobutyryl fluoride
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With iron(III) trifluoride; 18-crown-6 ether In acetonitrile at 90℃; for 10h; Autoclave; | 96.8% |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
trans-2,3-epoxyperfluoro-4-methylpentane
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In 1,2-dimethoxyethane at 50℃; for 9h; | 92% |
2,3-bi(fluorosulfato)perfluoro-4-methylpentane
A
pentafluoropropionic acid
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In N,N-dimethyl-formamide at 20℃; for 4h; | A 76% B 16% |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoro(2-propoxypropionyl) fluoride
B
perfluoro-2-methyl-2-pentene
C
perfluoro-2-methylpentan-3-one
D
perfluoro-4-methylpent-1-ene
Conditions | Yield |
---|---|
With potassium fluoride In diethylene glycol dimethyl ether | A 9.7% B n/a C 63.5% D 18% |
1,1,1,4,5,5,5-heptafluoro-3-(pentafluoroethyl)-2,4-bis(trifluoromethyl)pent-2-ene
A
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With bis(fluorosulfuryl) peroxide at 80℃; for 192h; | A 61% B 49% |
With bis(fluorosulfuryl) peroxide at 70 - 80℃; |
1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane
A
perfluoro-2-methylpentan-3-one
B
2-chloroundecafluoro-2-methyl-3-pentanone
Conditions | Yield |
---|---|
With sodium chloride In diethylene glycol dimethyl ether for 20h; Heating; | A 35% B 55.8% |
2-chloroundecafluoro-2-methyl-3-pentanone
A
perfluoropropylene
B
perfluoropropanoyl fluoride
C
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In diethylene glycol dimethyl ether for 1h; Product distribution; Heating; | A n/a B n/a C 38% |
1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane
urea
A
perfluoro-2-methylpentan-3-one
B
1-(2,2,3,3,3-pentafluoropropionyl)-3-(2,2,2-trifluoro-1-trifluoromethylethyl)urea
Conditions | Yield |
---|---|
In acetonitrile for 17h; Heating; Sealed tube; | A n/a B 25% |
Conditions | Yield |
---|---|
With cesium fluoride In diethylene glycol dimethyl ether |
perfluoro(4-methyl-2-pentene) oxide
A
perfluoro(2,4-dimethyloxolane)
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With antimony pentafluoride at 200℃; for 10h; Yield given. Yields of byproduct given; |
2,3-bis(fluorosulfato)perfluoro-(2-methylpentane)
A
hexafluoroacetone hydrate
B
pentafluoropropionic acid
C
perfluoro-2-methylpentan-3-one
D
1,1,1,3,4,4,5,5,5-nonafluoro-2-trifluoromethyl-2,3-epoxypentane
Conditions | Yield |
---|---|
With cesium fluoride In N,N-dimethyl-formamide at 10℃; for 1h; Yield given; | A n/a B n/a C 1.5 g D 0.3 g |
With cesium fluoride In N,N-dimethyl-formamide at 10℃; for 1h; | A n/a B n/a C 1.5 g D 0.3 g |
trans-2,3-epoxyperfluoro-4-methylpentane
A
perfluoro(4-methyl-2-pentanone)
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With antimony pentafluoride at 250℃; for 2.5h; Yield given. Yields of byproduct given; |
2,3-epoxyperfluoro-3-isopropyl-4-methylpentane
A
perfluoropropylene
B
perfluoro-2-methylpent-2-ene
C
1,1,1,2,3,5,5,6,6,7,7,7-dodecafluoro-2,4-bis(trifluoromethyl)hept-3-ene
D
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With cesium fluoride In diethylene glycol dimethyl ether for 2h; Heating; Yield given. Further byproducts given. Yields of byproduct given. Title compound not separated from byproducts; | A 0.8 g B n/a C n/a D n/a |
With cesium fluoride In diethylene glycol dimethyl ether for 2h; Heating; Yield given. Further byproducts given. Title compound not separated from byproducts; | A 0.8 g B n/a C n/a D n/a |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 93 percent / sodium hypochlorite / H2O; acetonitrile 2: 94 percent / NaF / 1,2-dimethoxy-ethane / 9 h / 20 °C View Scheme | |
Multi-step reaction with 2 steps 1: sodium hypochlorite; urea / acetonitrile; water / 3 h / 20 °C 2: potassium fluoride; 18-crown-6 ether / diethylene glycol dimethyl ether / 3 h / 30 °C View Scheme |
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 70 percent / sodium hypochlorite / H2O; acetonitrile 2: antimony pentafluoride / 2.5 h / 250 °C View Scheme | |
Multi-step reaction with 2 steps 1: 70 percent / sodium hypochlorite / H2O; acetonitrile 2: 92 percent / CsF / 1,2-dimethoxy-ethane / 9 h / 50 °C View Scheme |
Hexafluoropropene oxide
perfluoropropylene
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
Stage #1: Hexafluoropropene oxide With potassium fluoride In diethylene glycol dimethyl ether for 2h; Heating; Stage #2: perfluoropropylene In diethylene glycol dimethyl ether; acetonitrile at 65 - 80℃; under 5250.53 Torr; for 2h; | |
at 160℃; under 750.075 Torr; for 10h; Gas phase; |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoropropanoyl fluoride
B
perfluoro-2-methylpentan-3-one
Conditions | Yield |
---|---|
With activated carbon BAU-A-2 supported 20 wtpercent CsF In neat (no solvent) at 130℃; Reagent/catalyst; Temperature; |
Hexafluoropropene oxide
perfluoropropylene
A
perfluoro(2-propoxypropionyl) fluoride
B
perfluoropropanoyl fluoride
C
perfluoro-2-methylpentan-3-one
D
perfluoro-4-methylpent-1-ene
Conditions | Yield |
---|---|
With activated carbon BAU In neat (no solvent) at 130℃; Reagent/catalyst; Temperature; |
Conditions | Yield |
---|---|
Multi-step reaction with 3 steps 1: sulfolane; cesium fluoride / diethylene glycol dimethyl ether / 0.5 h / 70 °C 2: sodium hypochlorite; urea / acetonitrile; water / 3 h / 20 °C 3: potassium fluoride; 18-crown-6 ether / diethylene glycol dimethyl ether / 3 h / 30 °C View Scheme | |
Multi-step reaction with 3 steps 1: benzyltriethylammonium bromide; potassium fluoride / acetonitrile / 4 h 2: sodium hypochlorite / diethylene glycol dimethyl ether / 4 h 3: Aliquat 336 / diethylene glycol dimethyl ether / 10 h View Scheme |
perfluoro-2-methylpentan-3-one
A
perfluoropropylene
B
perfluoropropanoyl fluoride
Conditions | Yield |
---|---|
With cesium fluoride at 250℃; for 2h; Product distribution; | A 68% B n/a |
perfluoro-2-methylpentan-3-one
1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)pentanol
Conditions | Yield |
---|---|
Stage #1: perfluoro-2-methylpentan-3-one With polyethylsiloxane; tetrabutoxytitanium at 100℃; Stage #2: With sodium hydroxide In tetrahydrofuran Heating; | 42% |
With sodium tetrahydroborate In 1,4-dioxane for 1h; | |
With sodium tetrahydroborate at 0℃; for 1.5h; |
Vinylidene fluoride
perfluoro-2-methylpentan-3-one
1-<2-Trifluormethyl-perfluorpentyl-(3)-oxy>-1,1-difluor-2-brom-aethan
Conditions | Yield |
---|---|
(i) CsF, MeCN, (ii) /BRN= 1733321/, Br2; Multistep reaction; |
perfluoro-2-methylpentan-3-one
A
1,1,1,2,3,3,3-Heptafluoropropane
B
pentafluoropropionic acid
Conditions | Yield |
---|---|
With sodium hydroxide In water Product distribution; | A 92 % Chromat. B 85 % Chromat. |
perfluoro-2-methylpentan-3-one
dimethyl sulfate
1,1,1,2,2,3,4,5,5,5-decafluoro-3-methoxy-4-(trifluoromethyl)-pentane
Conditions | Yield |
---|---|
With potassium fluoride In diethylene glycol dimethyl ether at 45℃; |
pyrrolidine
perfluoro-2-methylpentan-3-one
A
N-tetramethyleneperfluoropropanamide
B
1,1,1,2,3,3,3-Heptafluoropropane
C
N-butyl pentafluoropropionamide
Conditions | Yield |
---|---|
With freon 11 |
perfluoro-2-methylpentan-3-one
diethylamine
A
C9H12F5NO
B
1,1,1,2,3,3,3-Heptafluoropropane
C
N-Diethyl-pentafluor-propionsaeureamid
Conditions | Yield |
---|---|
With freon 11 |
perfluoro-2-methylpentan-3-one
N-butylamine
A
1,1,1,2,3,3,3-Heptafluoropropane
B
(butylidene)butylamine
C
N-butyl pentafluoropropionamide
Conditions | Yield |
---|---|
With freon 11 |
Conditions | Yield |
---|---|
With water pH=8 - 14; |
The cas register number of Perfluoro(2-methyl-3-pentanone) is 756-13-8. It also can be called as 1,1,1,2,2,4,5,5,5-Nonafluoro-4-(trifluoromethyl)pentan-3-one and the Systematic name about this chemical is 3-Pentanone, 1,1,1,2,2,4,5,5,5-nonafluoro-4-(trifluoromethyl)-.
Physical properties about Perfluoro(2-methyl-3-pentanone) are: (1)ACD/LogP: 8.24; (2)# of Rule of 5 Violations: 1; (3)ACD/LogD (pH 5.5): 8.24; (4)ACD/LogD (pH 7.4): 8.24; (5)ACD/BCF (pH 5.5): 1000000; (6)ACD/BCF (pH 7.4): 1000000; (7)ACD/KOC (pH 5.5): 721085; (8)ACD/KOC (pH 7.4): 721085; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 2; (12)Polar Surface Area: 17.07Å2; (13)Index of Refraction: 1.264; (14)Molar Refractivity: 31.66 cm3; (15)Molar Volume: 190.3 cm3; (16)Surface Tension: 13.6 dyne/cm; (17)Density: 1.66 g/cm3; (18)Flash Point: 9.1 °C; (19)Enthalpy of Vaporization: 30.25 kJ/mol; (20)Boiling Point: 60 °C at 760 mmHg; (21)Vapour Pressure: 196 mmHg at 25°C.
People can use the following data to convert to the molecule structure.
1.SMILES: FC(F)(F)C(F)(C(=O)C(F)(F)C(F)(F)F)C(F)(F)F
2.InChI: InChI=1/C6F12O/c7-2(4(10,11)12,5(13,14)15)1(19)3(8,9)6(16,17)18
3.InChIKey: RMLFHPWPTXWZNJ-UHFFFAOYAW
4.Std. InChI: InChI=1S/C6F12O/c7-2(4(10,11)12,5(13,14)15)1(19)3(8,9)6(16,17)18
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