Product Name

  • Name

    Potassium sodium tartrate

  • EINECS 206-156-8
  • CAS No. 304-59-6
  • Density 1.24
  • Solubility soluble
  • Melting Point 70-80 °C
  • Formula C4H4KNaO6
  • Boiling Point 399.3 °C at 760 mmHg
  • Molecular Weight 210.16
  • Flash Point 209.4 °C
  • Transport Information UN 1824 8/PG 2
  • Appearance often supplied as a colourless aqueous solution
  • Safety 45-37/39-26-36/37/39
  • Risk Codes 35
  • Molecular Structure Molecular Structure of 304-59-6 (Potassium sodium tartrate)
  • Hazard Symbols CorrosiveC
  • Synonyms Butanedioic acid, 2,3-dihydroxy- (2R,3R)-, monopotassium monosodiumsalt;Rochelle salt;Sodium potassium (dl)-tartrate;Sodium potassium L-tartrate;Monopotassium monosodium tartrate;Tartaric acid, monopotassium monosodium salt;Potassium sodium L(+)-tartrate;Potassium sodium tartrate anhydrous;Butanedioic acid, 2,3-dihydroxy- (theta-(theta,theta))-, monopotassium monosodium salt;Butanedioic acid, 2,3-dihydroxy- (R-(R*,R*))-, monopotassium monosodium salt;Butanedioic acid, 2,3-dihydroxy-, monopotassium monosodium salt;Monopotassium monosodium 2,3-dihydroxybutanedioate, (R-(R*,R*))-;potassium sodium (2R,3R)-2,3-dihydroxybutanedioate;Seignette salt;2,3-Dihydroxybutanedioic acid, monopotassium monosodium salt;Butanedioic acid,2,3-dihydroxy- (2R,3R)-,compounds,monopotassium monosodium salt;
  • PSA 120.72000
  • LogP -4.79200

Synthetic route

(+)-(2R,3R)-{3-Ethyl-3-[2-methoxy-6-(trimethylsilanyl)pyridin-4-yl]-oxiranyl}-methanol

(+)-(2R,3R)-{3-Ethyl-3-[2-methoxy-6-(trimethylsilanyl)pyridin-4-yl]-oxiranyl}-methanol

Rochelle's salt
304-59-6

Rochelle's salt

(Z)-3-[2-methoxy-3-methoxymethoxymethyl-6-(trimethylsilanyl)pyridin-4-yl]pent-2-en-1-ol
412046-42-5

(Z)-3-[2-methoxy-3-methoxymethoxymethyl-6-(trimethylsilanyl)pyridin-4-yl]pent-2-en-1-ol

Conditions
ConditionsYield
With lithium aluminium tetrahydride In diethyl ether99%
diethyl ether
60-29-7

diethyl ether

Rochelle's salt
304-59-6

Rochelle's salt

3-butyl-2-hepten-1-ol
163267-92-3

3-butyl-2-hepten-1-ol

Conditions
ConditionsYield
In toluene99%
diethyl ether
60-29-7

diethyl ether

diisobutylaluminium hydride
1191-15-7

diisobutylaluminium hydride

Rochelle's salt
304-59-6

Rochelle's salt

3-butyl-2-hepten-1-ol
163267-92-3

3-butyl-2-hepten-1-ol

Conditions
ConditionsYield
In toluene99%
Rochelle's salt
304-59-6

Rochelle's salt

p-(trans-5-butyl-1,3-dioxan-2-yl)benzonitrile
74240-65-6

p-(trans-5-butyl-1,3-dioxan-2-yl)benzonitrile

p-(trans-5-butyl-1,3-dioxan-2-yl)benzaldehyde

p-(trans-5-butyl-1,3-dioxan-2-yl)benzaldehyde

Conditions
ConditionsYield
With diisobutylaluminium hydride In toluene98.3%
water
7732-18-5

water

Rochelle's salt
304-59-6

Rochelle's salt

methyl-2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)acetate
213250-62-5

methyl-2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)acetate

2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)ethanol
213250-63-6

2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)ethanol

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride In dichloromethane; toluene97%
With hydrogenchloride; diisobutylaluminium hydride In dichloromethane; toluene97%
Rochelle's salt
304-59-6

Rochelle's salt

methyl-2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)acetate
213250-62-5

methyl-2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)acetate

2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)ethanol
213250-63-6

2-((3R,5R)-3,5-bis(tertbutyldimethylsilyloxy)-4-methylenecyclohexylidene)ethanol

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride In dichloromethane; water; toluene97%
With hydrogenchloride; diisobutylaluminium hydride In dichloromethane; water; toluene97%
[1-(Methoxy-methyl-carbamoyl)-2-(1-trityl-1H-imidazol-4-yl)-ethyl]-carbamic acid tert-butyl ester

[1-(Methoxy-methyl-carbamoyl)-2-(1-trityl-1H-imidazol-4-yl)-ethyl]-carbamic acid tert-butyl ester

Rochelle's salt
304-59-6

Rochelle's salt

[1-Formyl-2-(1-trityl-1H-imidazol-4-yl)-ethyl]-carbamic acid tert-butyl ester

[1-Formyl-2-(1-trityl-1H-imidazol-4-yl)-ethyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
In tetrahydrofuran; diethyl ether; water84%
[1R-[1β(1R*,2E,4S*),[4S*],3aα,7aβ]]-Octahydro-7a -methyl-1-[1,4-dimethyl-4-[(2,24-trimethyl-1,3-dioxolan-4-yl)-2-butenyl]-4H-inden-4 -one

[1R-[1β(1R*,2E,4S*),[4S*],3aα,7aβ]]-Octahydro-7a -methyl-1-[1,4-dimethyl-4-[(2,24-trimethyl-1,3-dioxolan-4-yl)-2-butenyl]-4H-inden-4 -one

[3S-(3α,5β,Z)]-2-[2-methylene-3,5 bis-[(1,1-dimethylethyl)dimethylsilyloxy] cyclohexylidene]ethyldiphenylphosphine oxide

[3S-(3α,5β,Z)]-2-[2-methylene-3,5 bis-[(1,1-dimethylethyl)dimethylsilyloxy] cyclohexylidene]ethyldiphenylphosphine oxide

1α,25(S),26-trihydroxycholecalciferol

1α,25(S),26-trihydroxycholecalciferol

potassium carbonate
584-08-7

potassium carbonate

Rochelle's salt
304-59-6

Rochelle's salt

1α,25S,26-trihydroxyergocalciferol

1α,25S,26-trihydroxyergocalciferol

Conditions
ConditionsYield
With n-butyllithium; potassium hydrogencarbonate In tetrahydrofuran; methanol; ethanol; hexane; dichloromethane; ethyl acetate83%
diisobutylaluminum hydride (Dibal-H)

diisobutylaluminum hydride (Dibal-H)

(S)-γ-pivaloyloxymethyl-γ-butyrolactone

(S)-γ-pivaloyloxymethyl-γ-butyrolactone

dichloromethane
75-09-2

dichloromethane

Rochelle's salt
304-59-6

Rochelle's salt

2-(R,S)-Hydroxy-5-(S)-(pivaloyloxymethyl)tetrahydrofuran
145164-89-2

2-(R,S)-Hydroxy-5-(S)-(pivaloyloxymethyl)tetrahydrofuran

Conditions
ConditionsYield
In tetrahydrofuran; methanol82%
3,3-diphenyl-2-propenal
1210-39-5

3,3-diphenyl-2-propenal

Rochelle's salt
304-59-6

Rochelle's salt

3,3-diphenylprop-2-en-1-ol
4801-14-3

3,3-diphenylprop-2-en-1-ol

Conditions
ConditionsYield
With diisobutylaluminium hydride In methanol; toluene80%
With diisobutylaluminium hydride In methanol; toluene80%
ethyl 5-iodo-4-(methylsulfonamido)-2-(methylthio)benzoate
1456693-17-6

ethyl 5-iodo-4-(methylsulfonamido)-2-(methylthio)benzoate

Rochelle's salt
304-59-6

Rochelle's salt

N-(4-(hydroxymethyl)-2-iodo-5-(methylthio)phenyl)methanesulfonamide
1456693-19-8

N-(4-(hydroxymethyl)-2-iodo-5-(methylthio)phenyl)methanesulfonamide

Conditions
ConditionsYield
With diisobutylaluminium hydride In toluene80%
With diisobutylaluminium hydride In toluene80%
With diisobutylaluminium hydride In toluene80%
With diisobutylaluminium hydride In toluene80%
ethyl 2-[2-(1-ethoxyethoxy)ethyl]-2H-thieno[3,2-e]-1,2-thiazine-3-carboxylate 1,1-dioxide
198774-56-0

ethyl 2-[2-(1-ethoxyethoxy)ethyl]-2H-thieno[3,2-e]-1,2-thiazine-3-carboxylate 1,1-dioxide

Rochelle's salt
304-59-6

Rochelle's salt

2-(2-Hydroxyethyl)-3-hydroxymethyl-2H-thieno[3,2-e]-1,2-thiazine 1,1-dioxide
198774-57-1

2-(2-Hydroxyethyl)-3-hydroxymethyl-2H-thieno[3,2-e]-1,2-thiazine 1,1-dioxide

Conditions
ConditionsYield
With hydrogenchloride; diisobutylaluminium hydride In water; acetone79%
cis-3-tert-butoxycarbonylamino-4-(tert-butyl-dimethyl-silanyloxy)-but-2-enoic acid ethyl ester

cis-3-tert-butoxycarbonylamino-4-(tert-butyl-dimethyl-silanyloxy)-but-2-enoic acid ethyl ester

Rochelle's salt
304-59-6

Rochelle's salt

trans-[2-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-but-2-enyl]-carbamic acid tert-butyl ester
558443-43-9

trans-[2-(tert-butyl-dimethyl-silanyloxymethyl)-4-hydroxy-but-2-enyl]-carbamic acid tert-butyl ester

Conditions
ConditionsYield
With diisobutylaluminium hydride In dichloromethane77%
3-(3-benzyloxy-phenyl)-benzonitrile
893736-89-5

3-(3-benzyloxy-phenyl)-benzonitrile

Rochelle's salt
304-59-6

Rochelle's salt

3-(3-benzyloxy-phenyl)-benzaldehyde
893736-16-8

3-(3-benzyloxy-phenyl)-benzaldehyde

Conditions
ConditionsYield
With diisobutylaluminium hydride In tetrahydrofuran; hexane; water75%
S(+)-phenylglycine

S(+)-phenylglycine

Rochelle's salt
304-59-6

Rochelle's salt

benzoyl chloride
98-88-4

benzoyl chloride

N-(2-hydroxy-1-phenylethyl)benzamide
96392-53-9

N-(2-hydroxy-1-phenylethyl)benzamide

Conditions
ConditionsYield
With hydrogenchloride; sodium hydroxide; sodium chloride In tetrahydrofuran; methanol; dichloromethane; water62%
carbon dioxide
124-38-9

carbon dioxide

ethyl(diethylphosphono)(fluoro)acetate
2356-16-3

ethyl(diethylphosphono)(fluoro)acetate

(R)-2,2-difluoro-3-(2-fluorophenyl)-3-(R)-2-methylpropane-2-sulfinylaminobutyric acid ethyl ester
1393802-40-8

(R)-2,2-difluoro-3-(2-fluorophenyl)-3-(R)-2-methylpropane-2-sulfinylaminobutyric acid ethyl ester

ammonium chloride

ammonium chloride

Rochelle's salt
304-59-6

Rochelle's salt

(R)-ethyl 5-((R)-1,1-dimethylethylsulfinamido)-2,4,4-trifluoro-5-(2-fluorophenyl)-hex-2-enoate

(R)-ethyl 5-((R)-1,1-dimethylethylsulfinamido)-2,4,4-trifluoro-5-(2-fluorophenyl)-hex-2-enoate

Conditions
ConditionsYield
With N-ethyl-N,N-diisopropylamine; SiO2 In water; ethyl acetate; toluene; acetonitrile60%
4-benzylthio-2,3,5,6-tetrahydro-4-nitromethyl-4H-pyran
133762-55-7

4-benzylthio-2,3,5,6-tetrahydro-4-nitromethyl-4H-pyran

Rochelle's salt
304-59-6

Rochelle's salt

4-aminomethyl-4-benzylthio-2,3,5,6-tetrahydro-4H-pyran
133762-56-8

4-aminomethyl-4-benzylthio-2,3,5,6-tetrahydro-4H-pyran

Conditions
ConditionsYield
In water; isopropyl alcohol59%
(1R,3R,5R) Methyl [3,5-Bis(tert.-butyldimethylsilyloxy)-1-hydroxycyclohexane carboxylate

(1R,3R,5R) Methyl [3,5-Bis(tert.-butyldimethylsilyloxy)-1-hydroxycyclohexane carboxylate

Rochelle's salt
304-59-6

Rochelle's salt

1-hydroxy-1-hydroxymethylcyclohexane

1-hydroxy-1-hydroxymethylcyclohexane

Conditions
ConditionsYield
With diisobutylaluminium hydride In ethyl acetate; toluene59%
(2R,4R)-1-[2-(hydroxymethyl)-1,3-dioxolan-4-yl]-5-E-(2-carbomethoxy-vinyl)uracil

(2R,4R)-1-[2-(hydroxymethyl)-1,3-dioxolan-4-yl]-5-E-(2-carbomethoxy-vinyl)uracil

Rochelle's salt
304-59-6

Rochelle's salt

(2S,4S)-5-(3-hydroxypropenyl)-1-[2-(hydroxymethyl)-1,3-dioxolan-4-yl]uracil

(2S,4S)-5-(3-hydroxypropenyl)-1-[2-(hydroxymethyl)-1,3-dioxolan-4-yl]uracil

Conditions
ConditionsYield
With diisobutylaluminium hydride In methanol; hexane; toluene56%
Rochelle's salt
304-59-6

Rochelle's salt

methyl benzo-2,1,3-thiadiazole-5-carboxylate

methyl benzo-2,1,3-thiadiazole-5-carboxylate

2,1,3-benzothiadiazol-5-ylmethanol
89795-51-7

2,1,3-benzothiadiazol-5-ylmethanol

Conditions
ConditionsYield
In diethyl ether; ethyl acetate; Petroleum ether47%
benzyl(2-methyl-1-nitropropan-2-yl)sulfane
105780-12-9

benzyl(2-methyl-1-nitropropan-2-yl)sulfane

Rochelle's salt
304-59-6

Rochelle's salt

2-benzylthio 2-methyl propylamine
59681-09-3

2-benzylthio 2-methyl propylamine

Conditions
ConditionsYield
In water; isopropyl alcohol46%

Potassium sodium tartrate Specification

The Sodium potassium tartrate, with the CAS registry number 304-59-6 and EINECS registry number 206-156-8, has the systematic name of potassium sodium 2,3-dihydroxybutanedioate. It is often supplied as a colourless aqueous solution. And the molecular formula of this chemical is C4H4KNaO6.The Sodium potassium tartrate and monopotassium phosphate were the first materials discovered to exhibit piezoelectricity, and this property led to its extensive use in "crystal" gramophone (phono) pick-ups, microphones and earpieces during the post-War consumer electronics boom of the mid-20th Century. It is slightly soluble in alcohol but more completely soluble in water.

The physical properties of Potassium sodium tartrate are as followings:
(1)ACD/LogP: -1.43; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): -6; (4)ACD/LogD (pH 7.4): -6; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 1; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 6; (10)#H bond donors: 4; (11)#Freely Rotating Bonds: 5; (12)Polar Surface Area: 93.06 Å2; (13)Flash Point: 209.4 °C; (14)Enthalpy of Vaporization: 75.13 kJ/mol; (15)Boiling Point: 399.3 °C at 760 mmHg; (16)Vapour Pressure: 4.93E-08 mmHg at 25°C.

Preparation of Potassium sodium tartrate:
It can be prepared by adding 0.5 mol sodium carbonate to heated solution containing 1 mol potassium bitartrate. The solution is filtered while hot. Then dried the solution to precipitate solid potassium sodium tartrate, as small crystallites.

Uses of Potassium sodium tartrate:
 It is used medicinally as a laxative. And it is also used in the process of silvering mirrors. What's more, it is an ingredient of Fehling's solution, and formerly used in the determination of reducing sugars in solutions.

Uses of Potassium sodium tartrate:
You should be cautious while dealing with this chemical. It may causes severe burns. Therefore, you had better take the following instructions: Wear suitable protective clothing, gloves and eye/face protection, and in case of contacting with eyes, rinse immediately with plenty of water and seek medical advice. And in case of accident or if you feel unwell, seek medical advice immediately (show label where possible).

You can still convert the following datas into molecular structure:
(1)SMILES: [K+].[Na+].O=C([O-])C(O)C(O)C([O-])=O
(2)InChI: InChI=1/C4H6O6.K.Na/c5-1(3(7)8)2(6)4(9)10;;/h1-2,5-6H,(H,7,8)(H,9,10);;/q;2*+1/p-2
(3)InChIKey: LJCNRYVRMXRIQR-NUQVWONBAG

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