Silver benzoate supplier | CasNO.532-31-0

Name
Silver benzoate
EINECS 208-533-2
CAS No. 532-31-0
Article Data12
CAS DataBase
Density 1.103g/mLat 25°C(lit.)
Solubility Insoluble in water.
Melting Point 7-8°C(lit.)
Formula C₇H₆AgO₂
Boiling Point 249.3 °C at 760 mmHg
Molecular Weight 228.984
Flash Point 111.4 °C
Transport Information
Appearance Off-White Crystalline Powder
Safety 24/25
Risk Codes
Molecular Structure
Hazard Symbols
Synonyms Silver-benzoic acid (1:1);
PSA 26.30000
LogP 1.30770

Synthetic route

: silver nitrate

: 65-85-0
benzoic acid

: 532-31-0
silver benzoate

Conditions

Conditions	Yield
With NaOH In water; acetonitrile to aq. soln. of acid aq. soln. of NaOH added with stirring, then soln. of AgNO3 in CH3CN added under stirring; soln. slowly evapd. in air for 48 h, ppt. filtered, washed (H2O), dried (avc.); elem. anal.;	95%
With NaOH; acetic acid In water dissolving NaOH in water, addn. of acetic acid (several drops) and benzoic acid, addn. of resulting soln. to a satd. aq. soln. of AgNO3 in the dark; filtration, washing the residue, drying in vac.;	80%
With acetic acid; sodium hydroxide In water	59%

: 1863-63-4
ammonium benzoate

: silver nitrate

: 532-31-0
silver benzoate

Conditions

Conditions	Yield
In water dropwise addn. of a satd. aq. soln. of AgNO3 to an aq. soln. of ammonium benzoate; pptn., cooling in ice, filtration, washing (cold water, cold ethanol, ether), drying by suction;	90%

: 65-85-0
benzoic acid

: 20667-12-3
silver(l) oxide

: 532-31-0
silver benzoate

Conditions

Conditions	Yield
In acetonitrile at 20℃; for 24h; Darkness;	79%

: O-benzoyl-N-(2-benzyl-3-phenyl-propionyl)-hydroxylamine; silver salt

A: 253177-44-5
1-benzyl-2-phenyl-ethyl isocyanate

B: 532-31-0
silver benzoate

Conditions

Conditions	Yield
at 143℃;

: 532-32-1
sodium benzoate

: silver nitrate

: 532-31-0
silver benzoate

Conditions

Conditions	Yield
In water pH 6-7;

: 65-85-0
benzoic acid

: 532-31-0
silver benzoate

Conditions

Conditions	Yield
With silver nitrate; sodium hydroxide In water

: 675201-60-2
PdITol(2,2'-bipyridine)

: 532-31-0
silver benzoate

: 675201-55-5
Pd(O2CPh)Tol(2,2'-bipyridine)

Conditions

Conditions	Yield
In dichloromethane silver aroate was added to suspn. PdITol(bpy) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo;	100%

: [(η(5)-C5H4SiMe3)2Ti(C.tplbond.CSiMe3)2*CuBr]

: 532-31-0
silver benzoate

: [(η(5)-C5H4SiMe3)2Ti(C.tplbond.CSiMe3)2]CuOC(O)C6H5

Conditions

Conditions	Yield
In dichloromethane byproducts: silver bromide; under N2; react. of Ti-Cu complex with equimolar amt. of silver carboxylate in CH2Cl2 at 25°C;	99%

: methyl-iod-(N,N,N',N'-tetramethylethanediamine)palladium(II)

: 532-31-0
silver benzoate

: 675201-49-7
Pd(O2CPh)Me(N,N,N',N'-tetramethylethylenediamine)

Conditions

Conditions	Yield
In dichloromethane silver aroate was added to suspn. PdIMe(tmeda) in CH2Cl2 and stirred for15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo;	99%

: {PdI(p-tolyl)(N,N,N',N''-tetramethylethane-1,2-diamine)}

: 532-31-0
silver benzoate

: 675201-57-7
Pd(O2CPh)Tol(N,N,N',N'-tetramethylethylenediamine)

Conditions

Conditions	Yield
In dichloromethane silver aroate was added to suspn. PdITol(tmeda) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo;	99%

: 1192747-85-5, 1192748-05-2
[Au2Cl2(μ-2-C6F4PPh2)2]

: 532-31-0
silver benzoate

: 1192747-96-8, 1192748-33-6
[Au2(benzoato)2(μ-2-C6F4PPh2)2]

Conditions

Conditions	Yield
In dichloromethane a soln. of Au complex treated with Ag salt, stirred for 3 h at room temp. and shielded from light; filtered, concd. (vac.), pptd. (hexane), filtered, washed (hexane), dried;	99%

: 82112-98-9
chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

: 532-31-0
silver benzoate

: 797057-61-5
benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Conditions

Conditions	Yield
In acetone under Ar; soln. of Pd complex in acetone added to Ag salt (molar ratio 1:1.1); stirred for 1 h in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;	98%

: 532-31-0
silver benzoate

: 76186-82-8
3,4-dihydro-dibenzacridine

: 76186-84-0, 93715-98-1
trans-1,2-bis(benzoyloxy)-1,2,3,4-tetrahydrodibenzacridine

Conditions

Conditions	Yield
In benzene for 0.333333h; Heating;	97%

: {palladium(I)(methyl)(2,2'-bipyridine)

: 532-31-0
silver benzoate

: 388634-04-6
Pd(O2CPh)Me(2,2'-bipyridine)

Conditions

Conditions	Yield
In dichloromethane silver aroate was added to suspn. PdIMe(bpy) in CH2Cl2 and stirred for 15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo; elem. anal.;	97%

: 591252-79-8
1,2-bis[tris(trimethylsilyl)methyl]-1,2-diiododigallane

: 532-31-0
silver benzoate

: 736155-16-1
bis(tris(trimethylsilyl)methyl)bis(μ-benzoate-O,O')digallium(II) diiodide

Conditions

Conditions	Yield
In toluene byproducts: AgI; Ar, a soln. of Ga compd. added to a soln. of Ag compd. at -90°C, stirred, slowly warmed to -65°C; ppt. filtered (-70°C), solvent removed (vac., room temp.), recrystd. (cyclopentane) (from 20 to -15°C);	97%

: C54H74Cl2I2MnN2O4

: 532-31-0
silver benzoate

: C68H84I2MnN2O8

Conditions

Conditions	Yield
In dichloromethane at -40.16℃; for 3h;	97%

: 14267-08-4
N,N,N',N'-tetramethylethylenediamine palladium(II) chloride

: 532-31-0
silver benzoate

: 388634-05-7
Pd(O2CPh)2(N,N,N',N'-tetramethylethylenediamine)

Conditions

Conditions	Yield
In dichloromethane silver aroate was added to suspn. PdCl2(tmeda) in CH2Cl2 and stirred for15 min in the absence of light; soln. was filtered, filtrate was evapd. to dryness in vacuo, residue wasrinsed with n-pentane and dried in vacuo; elem. anal.;	96%

: 128247-54-1
bis(η5-trimethylsilylcyclopentadienyl)bis(trimethylsilylethynyl)-titanium

: 532-31-0
silver benzoate

: (η(5)-C5H4SiMe3)2Ti(C*CSiMe3)2AgOC(O)Ph

Conditions

Conditions	Yield
In tetrahydrofuran N2-atmosphere; stirring soln. of equimolar amts. of Ti-complex with Ag-compound at 25°C for 3 h; filtration (Celite), evapn., washing (pentane), crystn. (THF, -30°C); elem. anal.;	95%

: 663164-11-2
chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

: 532-31-0
silver benzoate

: 797057-62-6
benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)platinum(II)

Conditions

Conditions	Yield
In acetone under Ar; soln. of Pt complex in acetone added to Ag salt (molar ratio 1:1); stirred overnight in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;	95%

: 532-31-0
silver benzoate

: 737805-71-9
Acetic acid (2S,3S,4S)-4-iodo-2-(4-methoxy-benzyl)-1-(9-phenyl-9H-fluoren-9-yl)-pyrrolidin-3-yl ester

: (2S,3S,4S)-3-acetoxy-4-benzoyloxy-2-(p-methoxybenzyl)-N-(9-phenylfluoren-9-yl)pyrrolidine

Conditions

Conditions	Yield
In toluene for 5h; Prevost reaction; Heating;	94%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 532-31-0
silver benzoate

: 1663-45-2
1,2-bis-(diphenylphosphino)ethane

: 105471-29-2
{Pt(OCOC6H5)2(P(C6H5)2CH2CH2P(C6H5)2)}

Conditions

Conditions	Yield
In dichloromethane addn. of dppe to a soln. of (PtCl2(cod)) in CH2Cl2, stirring (0.5 h), addn. of AgOCOPh, stirring in the absence of light (72 h); filtration, concg. the pale yellow soln., addn. of hexane, pptn., washing (hexane), drying by suction; elem. anal.;	94%

...Expand

: 1094771-92-2
1,4-bis(pyridazin-4-yl)benzene

: 7732-18-5
water

: 532-31-0
silver benzoate

: [Ag2(1,4-bis(pyridazin-4-yl)benzene)(benzoate)2]*2H2O

Conditions

Conditions	Yield
In water High Pressure; under hydrothermal conditions; Ag(C6H5CO2), ligand and H2O sealed in Pyrex glass tube; heated at 180°C (glycerine bath) for 8 h; cooled to room temp. over 40 h; crystals sepd.; elem. anal.;	94%

...Expand

: 67865-68-3
benzyl (S)-(4-diazo-3-oxobutan-2-yl)carbamate

: 532-31-0
silver benzoate

: 83509-88-0
(S)-3-benzyloxycarbonylaminobutyric acid

Conditions

Conditions	Yield
In 1,4-dioxane; water for 6h; Reflux;	93%

: 15878-00-9
4-chloro-1H-pyrazole

: 532-31-0
silver benzoate

: C3H2ClN2(1-)*Ag(1+)

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 12h;	93%
In tetrahydrofuran at 20℃; for 12h;	93%

: 2075-46-9
4-nitro-1H-pyrazole

: 532-31-0
silver benzoate

: Ag(4-nitropyrazolate)

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 12h;	93%

: 853092-42-9
(2R,3R,4R)-N-(9-phenylfluoren-9-yl)-3-acetoxy-4-iodo-2-(p-methoxybenzyl)pyrrolidine

: 532-31-0
silver benzoate

: 853092-44-1
(2R,3R,4R)-N-(9-phenylfluoren-9-yl)-4-O-benzoylanisomycin

Conditions

Conditions	Yield
In toluene for 12h; Heating;	92%

: 15196-02-8
(S)-3-[(benzyloxycarbonyl)amino]-1-diazo-4-phenyl-2-butanone

: 532-31-0
silver benzoate

: 26250-86-2
(S)-3-benzyloxycarbonylamino-4-phenylbutyric acid

Conditions

Conditions	Yield
In 1,4-dioxane; water for 6h; Reflux;	92%

: 532-31-0
silver benzoate

: benzyl (S)-(1-(4-(benzyloxy)phenyl)-4-diazo-3-oxobutan-2-yl)carbamate

: 1616868-37-1
(S)-3-(benzyloxycarbonylamino)-4-[4-(benzyloxy)phenyl]butanoic acid

Conditions

Conditions	Yield
In 1,4-dioxane; water for 6h; Reflux;	92%

: 948311-76-0
[2,6-(iPr2PO)2C6H3]NiCl

: 532-31-0
silver benzoate

: C25H36NiO4P2

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 6h; Inert atmosphere; Schlenk technique; Darkness;	92%

: C39H46AgBrN2

: 532-31-0
silver benzoate

: C46H51AgN2O2

Conditions

Conditions	Yield
In tetrahydrofuran at 20℃; for 18h;	92%

: (η5-pentamethylcyclopentadienyl)Cl2(Me2SO)iridium

: 532-31-0
silver benzoate

: (C5(CH3)5)Ir(OOCC6H4)((CH3)2SO)

Conditions

Conditions	Yield
In dichloromethane byproducts: AgCl, C6H5COOH; silver benzoate was added to a soln. of (C5Me5)IrCl2(Me2SO) in CH2Cl2 and stirred for 2 h at 20°C; the pptd. AgCl was filtered off, filtrate washed with sodium bicarbonatesoln. (to remove benzoic acid) and dried over sodium sulphate, solvent removed, crystd. from CH2Cl2; elem. anal.;	91%
In not given	60%

: (chloro)[hydrotris(3-phenylpyrazol-1-yl)borato]cobalt(II)

: 532-31-0
silver benzoate

: (benzoato)[hydrotris(3-phenylpyrazol-1-yl)borato]cobalt(II)

Conditions

Conditions	Yield
In tetrahydrofuran byproducts: AgCl; N2-atmosphere; equimolar amts., stirring in dark overnight; filtration (Celite), solvent removal (reduced pressure), dissoln. in CH2Cl2, filtration, crystn.; elem. anal.;	91%

: cis-[PtCl(κ2-C6H3-5-Me-2-PPh2)(PPh2-4-tol)]*0.5toluene

: 532-31-0
silver benzoate

: 1173144-48-3
cis-[Pt(OCOPh)(κ2-C6H3-5-Me-2-PPh2)(PPh2-4-tol)]

B: silver(I) chloride

Conditions

Conditions	Yield
In chloroform silver benzoate was added to soln. Pt complex in CHCl3 and stirred in the dark for 15 min; ppt. was removed by centrifugation, supernatant was concd. in vacuo, n-pentane was added, ppt. was redissolved in CH2Cl2 and repptd. with n-pentane, washed with n-pentane and dried in vacuo;	A 91% B n/a

...Expand

: 532-31-0
silver benzoate

: 8,9-dihydroacenaphtho[1,2-b]benzo[d]thiophene

: trans-10,11-dibenzoyloxy-8,9,10,11-tetrahydroacenaphtho[1,2-b]benzo[d]thiophene

Conditions

Conditions	Yield
With iodine In benzene for 18h; Prevost reaction; Heating;	90.5%

: 62618-11-5
N'--N-2,4-dinitrophenyl-N-methylhydrazine

: 532-31-0
silver benzoate

: 62618-12-6
O-benzoyl-NN-dimethyl-N'-(N-methyl-2,4-dinitroanilino)isourea

Conditions

Conditions	Yield
In chloroform for 0.2h; Heating;	90%

Silver benzoate Specification

The Silver benzoate, with the CAS registry number 532-31-0, is also known as Silver-benzoic acid (1:1). This chemical's molecular formula is C₇H₆AgO₂and molecular weight is 229.9895. What's more, its IUPAC name is called Benzoic acid; silver.

Physical properties about Silver benzoate are: (1)ACD/LogP: 1.90; (2)#of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 0.58; (4)ACD/LogD (pH 7.4): -0.98; (5)ACD/BCF (pH 5.5): 1; (6)ACD/BCF (pH 7.4): 1; (7)ACD/KOC (pH 5.5): 12.43; (8)ACD/KOC (pH 7.4): 1; (9)#H bond acceptors: 2; (10)#H bond donors: 1; (11)#Freely Rotating Bonds: 1; (12)Polar Surface Area: 26.3Å²; (13)Flash Point: 111.4 °C; (14)Enthalpy of Vaporization: 51.4 kJ/mol; (15)Boiling Point: 249.3 °C at 760 mmHg; (16)Vapour Pressure: 0.0122 mmHg at 25 °C.

You can still convert the following datas into molecular structure:
(1) SMILES: [Ag].O=C(O)c1ccccc1
(2) InChI: InChI=1/C7H6O2.Ag/c8-7(9)6-4-2-1-3-5-6;/h1-5H,(H,8,9);
(3) InChIKey: GQCYXEOBZQXHPO-UHFFFAOYAJ

Product Name

Silver benzoate

Synthetic route

Silver benzoate Specification

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