Conditions | Yield |
---|---|
at 50℃; for 0.0833333h; | 99% |
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;; | |
In acetic acid crystn. on evapn. of the soln.;; | |
In acetic acid react. of freshly prepared Ag2O (by electrolysis) with stoichiometric amounts of concd. acid, evapn. until begin of crystn., removal of remaining H2O under diminished pressure; apparatus described;; |
Conditions | Yield |
---|---|
With acetic acid In water at 23℃; | 91% |
With acetic acid In water addn. of satd. aq. soln. of sodium acetate to satd. aq. soln. of AgNO3 contg. few drops of acetic acid in the dark; filtration, washing the residue with water, methanol, hexane, drying in vac.; | 90% |
In water soln. of AgNO3 in water was added to soln. of NaCH3CO2 in water; filtered in air, washed with water, EtOH, Et2O, dried in vacuo; elem. anal.; | 64% |
Pd[(μ-O2CMe)2Ag(HO2CMe)2]2
1,10-phenanthroline hydrate
(1,10-phenanthroline)-palladium(II) acetate
B
silver(I) acetate
Conditions | Yield |
---|---|
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (1:1 molar ratio), mixt. stirred at room temp. for 30 min; ppt. filtered off, concd., pptd. (heptane), dried, elem. anal.; | A 75% B n/a |
Conditions | Yield |
---|---|
In benzene benzene soln. of ligand added with stirring to benzene soln. of Pd compd. (3:1 molar ratio), mixt. stirred at room temp. for 1.5 h; ppt. filtered off, concd., crystd., dried, elem. anal.; | A 70% B n/a |
2,4,6-trimethyl-[1,3,5]dioxathiane
A
silver(I) acetate
Conditions | Yield |
---|---|
bei der Oxydation; |
Conditions | Yield |
---|---|
at 100℃; |
Conditions | Yield |
---|---|
In acetic anhydride boiling, pptn.;; recrystn. from glacial acetic acid;; |
silver(I) acetate
Conditions | Yield |
---|---|
With aldehyde In water | |
With aldehyde In water |
Conditions | Yield |
---|---|
In water in the air; | |
In water in the air; |
silver(I) acetate
Conditions | Yield |
---|---|
With trimethylamine acetate triacetatesolvate In not given addition of AgClO4 to a solution of the triacetatesolvate of trimethylamine acetate;; |
Conditions | Yield |
---|---|
In acetic acid in the light within several days;; |
Conditions | Yield |
---|---|
slow react.; |
Conditions | Yield |
---|---|
In water aq. soln. of Ag complex dried at 23°C for 24 h; detd. by X-ray diffraction; |
Conditions | Yield |
---|---|
In water at 20℃; | 3.1 g |
silver(I) acetate
2-<(N-cyclohexyl-N-methylamino)methyl>benzeneselenyl bromide
Conditions | Yield |
---|---|
In dichloromethane for 2h; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 100℃; for 3h; | 100% |
silver(I) acetate
4,6-bis(chloromethyl)-2,5-dimethoxytropone
4-acetoxymethyl-6-chloromethyl-2,5-dimethoxytropone
Conditions | Yield |
---|---|
In acetic acid at 80℃; for 2h; | 100% |
1-chloro-1,3-dihydro-3,3-dimethyl-1,2-benziodoxole
silver(I) acetate
3,3-dimethyl-1λ3-benzo[d][1,2]iodoxol-1(3H)-yl acetate
Conditions | Yield |
---|---|
In acetonitrile at 20℃; for 15h; | 100% |
In acetonitrile Darkness; | 98% |
97% |
silver(I) acetate
11-{[(1R,3aS,5aR,5bR,7aR,9S,11aR,11bR,13aR,13bS)-9-Acetoxy-1-(1-bromomethyl-vinyl)-5a,5b,8,8,11a-pentamethyl-icosahydro-cyclopenta[a]chrysene-3a-carbonyl]-amino}-undecanoic acid methyl ester
11-{[(1R,3aS,5aR,5bR,7aR,9S,11aR,11bR,13aR,13bS)-9-Acetoxy-1-(1-acetoxymethyl-vinyl)-5a,5b,8,8,11a-pentamethyl-icosahydro-cyclopenta[a]chrysene-3a-carbonyl]-amino}-undecanoic acid methyl ester
Conditions | Yield |
---|---|
With tetrabutylammomium bromide In toluene for 2h; Heating; | 100% |
silver(I) acetate
2-<(N-cyclohexyl-N-methylamino)methyl>benzeneselenyl bromide
Conditions | Yield |
---|---|
In dichloromethane | 100% |
silver(I) acetate
1-chloro-3,3-bis(trifluoromethyl)-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
Conditions | Yield |
---|---|
In acetonitrile Inert atmosphere; Darkness; | 100% |
In acetonitrile at 20℃; for 14.5h; | 98% |
In acetonitrile at 20℃; Darkness; | 92% |
In acetonitrile at 20℃; for 12h; Darkness; | 90% |
Conditions | Yield |
---|---|
In water at 40℃; for 24h; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In methanol; dichloromethane silver acetate added to soln. of Pd-compd. at room temp., stirred for 30 min.; filtered, evapd.; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In methanol Sonication; mixt. was ultrasonicated for 10 min at room temp.; soln. was filtered and aq. NH4PF6 was added, pptn. was filtered off, washed with water, dried over P2O5; elem. anal.; | 100% |
Conditions | Yield |
---|---|
In dichloromethane (N2); using of Schlenk techniques; combining of 1 equiv. of (((C6H4NC10H15)2C)PdCl2)2 with 4.1 equiv. of AgOAc in wet CH2Cl2; stirring under ambient conditions for 1.5 h; filtration, removal of volatiles in vac.; | 100% |
7,7-dichlorobicyclo<4.1.0>hept-3-ene
silver(I) acetate
Conditions | Yield |
---|---|
Stage #1: 7,7-dichlorobicyclo<4.1.0>hept-3-ene; silver(I) acetate With iodine; acetic acid Inert atmosphere; Stage #2: With water at 20℃; for 48h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
In diethyl ether (Ar), Ag acetate suspnd. in Et2O, reacted with 3 equiv. of (n-Bu)3P at 25°C for 1 h under stirring; evapd., elem. anal.; | 100% |
tributylphosphine
silver(I) acetate
tetra(tri-n-butyl phosphine)silver(I) acetate
Conditions | Yield |
---|---|
In diethyl ether (Ar), Ag acetate suspnd. in Et2O, reacted with 4 equiv. of (n-Bu)3P at 25°C for 1 h under stirring; evapd., elem. anal.; | 100% |
silver(I) acetate
Nevirapine
11-cyclopropyl-4-methyl-6-oxo-6,11-dihydro-5H-dipyrido[3,2-b:2',3'-e][1,4]diazepin-2-yl acetate
Conditions | Yield |
---|---|
With iodine In dichloromethane at 104℃; for 0.0833333h; | 100% |
1-(iodomethyl)-3-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H-benzo[e]indole-7-carbonitrile
silver(I) acetate
(7-cyano-3-(2,2,2-trifluoroacetyl)-2,3-dihydro-1H-benzo[e]indol-1-yl)methyl acetate
Conditions | Yield |
---|---|
In acetic acid for 48h; Reflux; | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In chloroform; acetonitrile | 100% |
silver(I) acetate
Conditions | Yield |
---|---|
In dichloromethane; acetonitrile at 20℃; for 1h; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 0.333333h; Inert atmosphere; Optical yield = 54.545 %de; | 100% |
trans-1,2-dimethylcyclopentane
silver(I) acetate
cobalt(II) acetate
Conditions | Yield |
---|---|
Stage #1: trans-1,2-dimethylcyclopentane; C40H76N2O2(2+)*2NO3(1-) In dichloromethane at 20℃; Stage #2: cobalt(II) acetate In dichloromethane at 20℃; for 12h; Stage #3: silver(I) acetate In dichloromethane for 12h; | 100% |
2,2-Dimethyl-1,3-diaminopropane
silver(I) acetate
cobalt(II) acetate
Conditions | Yield |
---|---|
Stage #1: 2,2-Dimethyl-1,3-diaminopropane; C40H76N2O2(2+)*2NO3(1-) In dichloromethane at 20℃; Stage #2: cobalt(II) acetate In dichloromethane at 20℃; for 12h; Stage #3: silver(I) acetate In dichloromethane for 12h; | 100% |
Conditions | Yield |
---|---|
In toluene at 25℃; for 2h; Glovebox; | 100% |
silver(I) acetate
cobalt(II) acetate
Conditions | Yield |
---|---|
Stage #1: trans-1,2-diaminocyclohexane monohydrochloride; {3-methyl-5-[{Bu3N+(CH2)3}2CMe]salicylaldehyde}(I-)2 With sodium t-butanolate In methanol for 4h; Inert atmosphere; Stage #2: silver nitrate In dichloromethane for 5h; Darkness; Stage #3: silver(I) acetate; cobalt(II) acetate Further stages; | 100% |
Conditions | Yield |
---|---|
In methanol for 0.333333h; | 100% |
Conditions | Yield |
---|---|
In methanol for 0.333333h; | 100% |
Conditions | Yield |
---|---|
In dichloromethane at 20℃; for 1h; Inert atmosphere; | 100% |
Conditions | Yield |
---|---|
Stage #1: C48H46N4; silver(I) acetate In methanol Stage #2: sodium hexaflorophosphate | 100% |
Conditions | Yield |
---|---|
With nickel(II) triflate In chlorobenzene at 140℃; for 24h; | 100% |
Reported in EPA TSCA Inventory.
ACGIH TLV: TWA 0.01 mg(Ag)/m3
The Silver(I) acetate, with the CAS registry number 563-63-3, is also known as Acetic acid, silver(1+) salt. It belongs to the product category of Organic-metal Salt. Its EINECS registry number is 209-254-9. This chemical's molecular formula is C2H3AgO2 and molecular weight is 166.91222. Its IUPAC name is called silver acetate.
Physical properties of Silver(I) acetate: (1)H-Bond Donor: 0; (2)H-Bond Acceptor: 2; (3)Rotatable Bond Count: 0; (4)Exact Mass: 165.918397; (5)MonoIsotopic Mass: 165.918397; (6)Topological Polar Surface Area: 40.1; (7)Heavy Atom Count: 5; (8)Formal Charge: 0; (9)Complexity: 25.5; (10)Covalently-Bonded Unit Count: 2.
Preparation: this chemical can be prepared by AgO and CH3COOH.
Uses of Silver(I) acetate: It can be used as a pesticide. It also produces a repulsive taste when combined with cigarette smoke, so it is used in chewing gum and lozenges to aid the cessation of smoking.
When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.
You can still convert the following datas into molecular structure:
(1)Canonical SMILES: CC(=O)[O-].[Ag+]
(2)InChI: InChI=1S/C2H4O2.Ag/c1-2(3)4;/h1H3,(H,3,4);/q;+1/p-1
(3)InChIKey: CQLFBEKRDQMJLZ-UHFFFAOYSA-M
The toxicity data is as follows:
Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
---|---|---|---|---|---|
mouse | LD50 | intraperitoneal | 34mg/kg (34mg/kg) | BEHAVIORAL: EXCITEMENT BEHAVIORAL: ATAXIA LUNGS, THORAX, OR RESPIRATION: DYSPNEA | Drug and Chemical Toxicology. Vol. 6, Pg. 267, 1983. |
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