Sodium acrylate supplier | CasNO.7446-81-3

Name
Sodium acrylate
EINECS 231-209-7
CAS No. 7446-81-3
Article Data43
CAS DataBase
Density 1.528[at 20℃]
Solubility 479g/L at 20℃
Melting Point >300 °C(lit.)
Formula C3H4 O2 . Na
Boiling Point 141oC at 760 mmHg
Molecular Weight 94.0454
Flash Point 61.6oC
Transport Information
Appearance solid
Safety S26;S36
Risk Codes R36/37/38
Molecular Structure
Hazard Symbols
Synonyms 2-Propenoicacid, sodium salt (9CI); Acrylic acid, sodium salt (6CI,7CI,8CI); Sodium2-propenoate; Sodium acrylate; Webac 240A1
PSA 40.13000
LogP -1.07770

Synthetic route

: 79-10-7
acrylic acid

: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
With sodium hydroxide In water; acetone	96.8%
With sodium hydroxide In water for 0.666667h;	95%
With sodium hydroxide In chlorobenzene

: 74-85-1
ethene

: (dtbpe)Ni(η2-sodium acrylate)complex

: 138419-50-8
[bis(di-tert-butylphosphino)ethane](ethylene)nickel

B: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
In tetrahydrofuran under 22502.3 Torr; for 18h; Inert atmosphere;	A 95% B n/a

...Expand

: 6487-38-3
3-hydroxypropanoic acid sodium salt

: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
With 1,3-dimethoxy-2-hydroxy-benzene; zirconium hydroxide at 200℃; for 1 - 4h; Product distribution / selectivity;	61.8%
1,3-dimethoxy-2-hydroxy-benzene; zirconium tetrahydroxide at 200℃; for 1 - 4h; Product distribution / selectivity;
1,3-dimethoxy-2-hydroxy-benzene for 2h; Product distribution / selectivity;
In water at 220℃; for 2h;	41.8 %Chromat.

: 12107-56-1
dichloro(1,5-cyclooctadiene)palladium(II)

: 74-85-1
ethene

: 124-38-9
carbon dioxide

: 367-05-5
Sodium 2-fluorophenoxide

: 23743-26-2
1,2-bis-(dicyclohexylphosphino)ethane

A: (dcpe)Pd(OPhFCO2)

B: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
Stage #1: dichloro(1,5-cyclooctadiene)palladium(II); ethene; Sodium 2-fluorophenoxide; 1,2-bis-(dicyclohexylphosphino)ethane With zinc In tetrahydrofuran under 7500.75 Torr; for 0.25h; Autoclave; Glovebox; Stage #2: carbon dioxide In tetrahydrofuran at 145℃; under 22502.3 Torr; for 20h; Autoclave;	A 1% B n/a

...Expand

: 219697-18-4
4-acrylamido-4-methyltetrahydrothiophene-1,1-dioxide-3-sulfonic acid

A: 7446-81-3
sodium 2-propenoate

B: 4-(3-amino-propionylamino)-4-methyl-1,1-dioxo-tetrahydro-1λ6-thiophene-3-sulfonic acid

C: sodium; 4-amino-4-methyl-1,1-dioxo-tetrahydro-1λ6-thiophene-3-sulfonate

Conditions

Conditions	Yield
With sodium hydroxide In water at 30℃; for 1h; Product distribution; other temperature, reaction time; effect of substrate concentration;

...Expand

: 116709-95-6
3-cyclohexanesulfonyl-propionic acid

aqueous NaOH-solution: aqueous NaOH-solution

A: 7446-81-3
sodium 2-propenoate

B: 74829-95-1
sodium cyclohexane sulfinate

...Expand

: Cu(2+)*2CH2CH(CO2)CH2CH(CO2)(2-)=Cu(CH2CH(CO2)CH2CH(CO2))2(2-)

A: Cu(2+)*CH2CH(CO2)CH2CH(CO2)(2-)=Cu(CH2CH(CO2)CH2CH(CO2))

B: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
In water Kinetics; 25°C, pH 7.0;

: 6487-38-3
3-hydroxypropanoic acid sodium salt

A poly(3-hydroxypropionic acid sodium salt): poly(3-hydroxypropionic acid sodium salt)

B: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
With 1,3-dimethoxy-2-hydroxy-benzene; zirconium tetrahydroxide at 200℃; for 1 - 4h; Product distribution / selectivity;
With 1,3-dimethoxy-2-hydroxy-benzene; ECS-3 at 200℃; for 2h; Product distribution / selectivity;

: 920-38-7
sodium propargylate

: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
With quinoline; hydrogen; hydroquinone In methanol at 20℃; under 760.051 Torr; for 5h; Inert atmosphere;
With quinoline; hydrogen In methanol at 20℃; for 5h; Concentration; Reagent/catalyst; Solvent; Time; Inert atmosphere;

: (dtbpe)Ni(η2-acrylic acid) complex

: 865-48-5
sodium t-butanolate

: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
In chlorobenzene under 15001.5 Torr; for 1h; Inert atmosphere; Autoclave;	2.55 mmol

: (1,1′-bis(diphenylphosphino)ferrocene)Ni(lactone)

A: 94202-32-1
(1,1′-bis(diphenylphosphino)ferrocene)2Ni

B: 7446-81-3
sodium 2-propenoate

C: 7440-02-0
nickel

Conditions

Conditions	Yield
With sodium t-butanolate In dimethyl sulfoxide

...Expand

: 74-85-1
ethene

: 124-38-9
carbon dioxide

: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
Stage #1: ethene With bis(1,5-cyclooctadiene)nickel (0); 1,2-bis(di-tert-butyl)phosphinoethane In chlorobenzene at 45℃; under 15001.5 Torr; for 0.5h; Autoclave; Stage #2: carbon dioxide In chlorobenzene at 20 - 60℃; under 7500.75 - 37503.8 Torr; Stage #3: With sodium t-butanolate In chlorobenzene for 1h;	2.55 mmol
With sodium t-butanolate In chlorobenzene at 45 - 60℃; under 7500.75 - 37503.8 Torr; for 4.5h;
With (R,R)-(-)-2,3-bis(tert-butylmethylphosphino)benzene; bis(1,5-cyclooctadiene)nickel (0); Sodium 2-fluorophenoxide; zinc In tetrahydrofuran at 25 - 100℃; under 15001.5 Torr; for 20h; Reagent/catalyst; Temperature; Autoclave; Glovebox; Inert atmosphere;

: 79-10-7
acrylic acid

A: sodium nitrite decahydrate

B: 7446-81-3
sodium 2-propenoate

Conditions

Conditions	Yield
Stage #1: acrylic acid With Dipentaerythritol; sulfuric acid; hydroquinone In toluene at 100℃; under 397.54 Torr; for 10h; Stage #2: With sodium hydroxide In water; toluene Reagent/catalyst; Temperature; Pressure;	A 179.6 g B 32.8 %Chromat.

inulin multi-methacrylate: inulin multi-methacrylate

: α-(2-methoxy-5-isothiocyanatophenyl)-1,4,7,10-tetraazacyclodecane-1,4,7,10-tetraacetic acid

: 1173-43-9
fluoresceinyl 5-isothiocyanate

: 7446-81-3
sodium 2-propenoate

: N-(3-aminopropyl)methacrylamide hydrochloride

FITC-labeled Gd-DOTA-containing articles: FITC-labeled Gd-DOTA-containing articles

Conditions

Conditions	Yield
Stage #1: inulin multi-methacrylate; α-(2-methoxy-5-isothiocyanatophenyl)-1,4,7,10-tetraazacyclodecane-1,4,7,10-tetraacetic acid; fluoresceinyl 5-isothiocyanate; sodium 2-propenoate; N-(3-aminopropyl)methacrylamide hydrochloride In water for 1.5h; pH=9.4; Alkaline aqueous solution; Stage #2: With gadolinium(III) chloride In water at 50℃; for 4h;	100%

...Expand

: 7446-81-3
sodium 2-propenoate

: 5188-07-8
sodium thiomethoxide

: 646-01-5
3-(methylsulfanyl)propionic acid

Conditions

Conditions	Yield
Stage #1: sodium 2-propenoate; sodium thiomethoxide at 30 - 45℃; for 3h; Stage #2: With hydrogenchloride In chloroform; water at 20℃; for 0.5h; pH=2-3; Temperature; Reagent/catalyst;	95.3%

: chromium dichloride

: 7446-81-3
sodium 2-propenoate

: chromium acrylate

Conditions

Conditions	Yield
In water byproducts: NaCl; room temp.; filtn., washing, drying (vac.); elem. anal.;	95%

: tetraazacalix[1]arene[3]pyridine

: 7446-81-3
sodium 2-propenoate

: 1169706-69-7
C28H27N7O2

Conditions

Conditions	Yield
Stage #1: tetraazacalix[1]arene[3]pyridine With air; copper(II) perchlorate monohydrate In methanol; chloroform at 20℃; for 1h; Stage #2: sodium 2-propenoate In acetonitrile at 20℃; for 0.0166667h;	95%

: 696-62-8
para-iodoanisole

: 7446-81-3
sodium 2-propenoate

: 943-89-5
(E)-3-(4-methoxyphenyl)acrylic acid

Conditions

Conditions	Yield
With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium carbonate In water; toluene at 150℃; for 0.5h; Catalytic behavior; Heck Reaction; Autoclave;	94%

: 591-50-4
iodobenzene

: 7446-81-3
sodium 2-propenoate

: 140-10-3
(E)-3-phenylacrylic acid

Conditions

Conditions	Yield
With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium carbonate In water; toluene at 150℃; for 0.5h; Catalytic behavior; Reagent/catalyst; Heck Reaction; Autoclave;	93%

: 7446-81-3
sodium 2-propenoate

: Acryloyloxyketone

Conditions

Conditions	Yield
	89%

: 390765-95-4
Co2(N(CH3)(CH2)2N(CH3)CH2(CCHC(C(CH3)3)CHCC(S))CH2N(CH3)(CH2)2)2Cl(1+)*ClO4(1-)=Co2(C38H64ClN6S2)ClO4

: 7446-81-3
sodium 2-propenoate

: 573959-59-8
Co2(N(CH3)(CH2)2N(CH3)CH2(CCHC(C(CH3)3)CHCC(S))CH2N(CH3)(CH2)2)2OC(O)CHCH2(1+)*ClO4(1-)=Co2(C41H67N6O2S2)ClO4

Conditions

Conditions	Yield
In methanol	88%

: 107-59-5
tert-Butyl chloroacetate

: 7446-81-3
sodium 2-propenoate

: tert-butyl acryloxyacetate

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; 4-methoxy-phenol In tetrahydrofuran for 10h; Reflux;	88%

: 75-77-4
chloro-trimethyl-silane

: 7446-81-3
sodium 2-propenoate

: 79-10-7
acrylic acid

: 13688-55-6
trimethylsilyl acrylate

Conditions

Conditions	Yield
Stage #1: chloro-trimethyl-silane; acrylic acid With 4-methoxy-phenol at 70℃; for 4h; Inert atmosphere; Stage #2: sodium 2-propenoate at 20℃; for 0.5h; Inert atmosphere;	87.9%

...Expand

: 702-26-1
tetrahydrofurfuryl chloroacetate

: 7446-81-3
sodium 2-propenoate

: C10H14O5

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; 4-methoxy-phenol In tetrahydrofuran for 10h; Reflux;	86%

: 7446-81-3
sodium 2-propenoate

: 107-96-0
3-mercaptopropionic acid

Conditions

Conditions	Yield
Stage #1: sodium 2-propenoate With sodium hydrogen sulfide at 50℃; under 1125.11 Torr; for 1h; Stage #2: With sodium sulfide at 110℃; under 1125.11 Torr; for 1h; Stage #3: With sulfuric acid at 60℃; for 1h; Reagent/catalyst; Temperature; Pressure;	85.4%
Stage #1: sodium 2-propenoate With sodium hydroxide; sodium hydrogensulfide In water at 80 - 100℃; for 6.5h; Stage #2: With sulfuric acid In water at 5℃; for 1h; Stage #3: With zinc In water at 40℃; Product distribution / selectivity;	70%

: 140-18-1
Benzyl chloroacetate

: 7446-81-3
sodium 2-propenoate

: acryloxy benzyl acetate

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; 4-methoxy-phenol In tetrahydrofuran for 10h; Reflux;	85.1%

: 995-25-5
chlorotripropylsilane

: 7446-81-3
sodium 2-propenoate

: tripropylsilyl acrylate

Conditions

Conditions	Yield
With tetrabutylammomium bromide; 4-methoxy-phenol In 1,2-dichloro-ethane at 55 - 60℃; for 7h; Inert atmosphere;	83%

: C26H27O4PSi2

: 7446-81-3
sodium 2-propenoate

: methyl(diphenyl)silyl acrylic acid ester

Conditions

Conditions	Yield
With tetrabutylammomium bromide; 4-methoxy-phenol at 100℃; for 48h;	82.1%

: 95-46-5
2-methylphenyl bromide

: 7446-81-3
sodium 2-propenoate

: 939-57-1, 2373-76-4, 41397-71-1
(E)-3-(2-methylphenyl)acrylic acid

Conditions

Conditions	Yield
With sodium carbonate; tris(4,6-dimethyl-3-sulfonatophenyl)phosphine trisodium salt hydrate; palladium diacetate In water; acetonitrile at 80℃; Heck coupling;	82%
With 4-(di-tert-butylphosphino)ethyltrimethylammonium chloride; diisopropylamine; palladium diacetate In water; acetonitrile at 80℃; for 5h; Heck reaction;	55%

: 106-38-7
para-bromotoluene

: 7446-81-3
sodium 2-propenoate

: 1866-39-3
trans-p-methylcinnamic acid

Conditions

Conditions	Yield
With sodium carbonate; tris(4,6-dimethyl-3-sulfonatophenyl)phosphine trisodium salt hydrate; palladium diacetate In water; acetonitrile at 80℃; Heck coupling;	81%
With 4-(di-tert-butylphosphino)ethyltrimethylammonium chloride; diisopropylamine; palladium diacetate In water; acetonitrile at 80℃; for 5h; Heck reaction;	78%
With trans-di(μ-acetato)bis[o-(di-o-tolylphosphino)benzyl]dipalladium(II); sodium carbonate In water; toluene at 150℃; for 0.5h; Catalytic behavior; Heck Reaction; Autoclave;	1%

: 2-chloropropionate tetrahydrofurfuryl alcohol

: 7446-81-3
sodium 2-propenoate

: C11H16O5

Conditions

Conditions	Yield
With N-benzyl-N,N,N-triethylammonium chloride; 4-methoxy-phenol In acetonitrile for 24h; Reflux;	80.9%

: C32H12IN8O9S3(5-)*Ga(3+)*HO(1-)*3Na(1+)

: 7446-81-3
sodium 2-propenoate

: C35H14N8O11S3(6-)*Ga(3+)*HO(1-)*4Na(1+)

Conditions

Conditions	Yield
With sodium carbonate; tris(4,6-dimethyl-3-sulfonatophenyl)phosphine trisodium salt hydrate; palladium diacetate In water; acetonitrile for 3h; Heck reaction;	80%

: 104-92-7
1-bromo-4-methoxy-benzene

: 7446-81-3
sodium 2-propenoate

: 943-89-5
(E)-3-(4-methoxyphenyl)acrylic acid

Conditions

Conditions	Yield
With sodium carbonate; tris(4,6-dimethyl-3-sulfonatophenyl)phosphine trisodium salt hydrate; palladium diacetate In water; acetonitrile at 80℃; Heck coupling;	79%
With 4-(di-tert-butylphosphino)ethyltrimethylammonium chloride; diisopropylamine; palladium diacetate In water; acetonitrile at 80℃; for 5h; Heck reaction;	75%

: 617-88-9
2-Chloromethylfuran

: 7446-81-3
sodium 2-propenoate

: 10525-17-4
furfuryl acrylate

Conditions

Conditions	Yield
N-benzyl-N,N,N-triethylammonium chloride In diethyl ether at 25 - 30℃; for 10h;	70%

: (nBu4N)2[Mo6Cl8(trifluoroacetate)6]

: 7446-81-3
sodium 2-propenoate

(Bu4N)2[(Mo6Cl8)(CF3COO)(6-x)(acrylate)(x)]: (Bu4N)2[(Mo6Cl8)(CF3COO)(6-x)(acrylate)(x)]

Conditions

Conditions	Yield
In dichloromethane under Ar atm.; to soln. of (Bu4N)2MoCl8(CF3COO)6 in CH2Cl2 added twofoldexcess of sodium acrylate; stirred for 48-60 hs; suspn. filtered; filtrate boiled down to 2-3 ml; Et2O added; crystals grown by the layering method;	70%

: 7446-81-3
sodium 2-propenoate

: 114044-23-4
1-chloromethylbenzindol-2(1H)-one (CMBI)

: 114044-45-0
BIM acrylate

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 0.166667h;	68%

: 7446-81-3
sodium 2-propenoate

: [7-Chloro-3,4-dihydro-2H-isoquinolin-(1Z)-ylidene]-acetic acid ethyl ester

: 10-Chloro-4-oxo-3,4,6,7-tetrahydro-2H-pyrido[2,1-a]isoquinoline-1-carboxylic acid ethyl ester

Conditions

Conditions	Yield
With chloroformic acid ethyl ester In tetrahydrofuran Ambient temperature;	68%

: 247939-31-7
[fac-Mn(CO)3(1,2-bis(diphenylphosphino)ethane)(OH2)]BF4

: 7446-81-3
sodium 2-propenoate

: 885008-48-0
[CH2-CH-[C(O)O(manganese(I))(carbonyl)3(bis(diphenylphosphino)ethan))]]n

Conditions

Conditions	Yield
In methanol; water (Ar); methanolic soln. of (CO)3(dppe)Mn(OH2)BF4 placed in a round bottomflask; aq. soln. of sodium polyacrylate added dropwise; resulting solut ion stirred for 2 h then overnight; evaporated to dryness with a rotary evaporator; washed with CHCl3 and CH3OH; dried in vacuum; elem. anal.;	67%

Sodium acrylate Chemical Properties

Molecular Structure:

Molecular Formula: C₃H₃NaO₂
Molecular Weight: 94.0445
IUPAC Name: Sodium prop-2-enoate
Synonyms of Sodium acrylate (CAS NO.7446-81-3): Acrylic acid, sodium salt ; EINECS 231-209-7 ; HSDB 6087 ; 2-Propenoic acid, sodium salt ; 2-Propenoic acid, sodium salt (1:1)
CAS NO: 7446-81-3
Melting point: >300 °C
Flash Point: 61.6 °C
Enthalpy of Vaporization: 41.72 kJ/mol
Boiling Point: 141 °C at 760 mmHg
Vapour Pressure of Sodium acrylate (CAS NO.7446-81-3): 3.42 mmHg at 25°C

Sodium acrylate Safety Profile

Hazard Codes of Sodium acrylate (CAS NO.7446-81-3): Irritant Xi
Risk Statements: 36/37/38
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36: Wear suitable protective clothing.
WGK Germany: 3
TSCA: Yes

Product Name

Sodium acrylate

Synthetic route

Sodium acrylate Chemical Properties

Sodium acrylate Safety Profile

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