Sodium perchlorate monohydrate supplier

Name
SODIUM PERCHLORATE MONOHYDRATE
EINECS 231-511-9
CAS No. 7791-07-3
Article Data8
CAS DataBase
Density 2,02 g/cm3
Solubility Soluble in water.
Melting Point 130 °C
Formula NaClO₄^.H₂O
Boiling Point
Molecular Weight 140.456
Flash Point
Transport Information UN 1502
Appearance white adhering crystals
Safety 17-26-27-36/37/39-22-13
Risk Codes 9-22-36/37/38-8
Molecular Structure
Hazard Symbols O,Xi,Xn
Synonyms Sodiumperchlorate (NaClO4) monohydrate;Sodium perchlorate monohydrate;
PSA 83.50000
LogP 0.15000

Synthetic route

: 7601-90-3
perchloric acid

: 7732-18-5
water

: 144-55-8
sodium hydrogencarbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In perchloric acid by a react. of HClO4 with NaHCO3; evapn. to incipient crystn.;

...Expand

: sodium perchlorate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In water crystn. below 52.75°C;
In water crystn. below 52.75°C;

: 7601-90-3
perchloric acid

: 497-19-8
sodium carbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice;
In perchloric acid dissoln. of carbonate in HClO4 (72 %), repeated recrystn. (H2O);
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.;
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice;
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.;

: 497-19-8
sodium carbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
With aq. HClO4 dry box.;

: 7791-07-3
sodium perchlorate monohydrate

: 88035-85-2
{(NH3)5IrOCHN(CH3)2}(3+)*3ClO4(1-)={(NH3)5IrOCHN(CH3)2}(ClO4)3

: 15646-83-0
{(NH3)5IrOOCH}(2+)*2ClO4(1-)={(NH3)5IrOOCH}(ClO4)2

Conditions

Conditions	Yield
With sodium hydroxide In water Kinetics; stirred for 10 min at ambient temp., NaClO4*H2O was added in H2O; cooled, filtered, elem. anal.;	100%

: 7791-07-3
sodium perchlorate monohydrate

: [PdCl(η(3)-CH2C(Me)C(Me)2)]2

2-(propane-2-sulfanylmethyl)-pyridine: 2-(propane-2-sulfanylmethyl)-pyridine

: 460720-55-2
[Pd(η3-1,1,2-Me3C3H2)(2-isopropylthiomethylpyridine)](ClO4)

Conditions

Conditions	Yield
In methanol; dichloromethane stirred at room temp. under N2 for 1 h; evapd. in vacuo, residue dissolved in CH2Cl2, treated with activated charcoal, filtered through celite, filtrate was concd., treated with Et2O, ppt. was collected; elem. anal.;	99%

...Expand

: 553-26-4
4,4'-bipyridine

: 7791-07-3
sodium perchlorate monohydrate

: 563-63-3
silver(I) acetate

: Ag(4,4'-bipyridine)(perchlorate)

Conditions

Conditions	Yield
In water at 20℃; for 2h; Sealed tube;	99%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: cis-{Pt(P(CH3)3)2(μ-OH)}2(NO3)2

: di(cis-[bis(trimethylphosphane)(μ-hydroxo)platinum(II)]) nitrate

Conditions

Conditions	Yield
In not given to Pt-salt NaClO4*H2O added; filtered, washed (H2O), dried in vac., elem. anal.;	98%

: 7791-07-3
sodium perchlorate monohydrate

: tetrakis(acetonitrile)palladium(II) tetrafluoroborate

: C4H3SC4H2SCHNCH2CH((OC2H4OC2H4)2O)CH2

: 75-05-8
acetonitrile

: Pd(2+)*2CH3CN*2BF4(1-)*Na(1+)*ClO4(1-)*C4H3SC4H2SCHNCH2CH((OC2H4OC2H4)2O)CH2=Pd(CH3CN)2(C20H27NO5S2)(BF4)2NaClO4

Conditions

Conditions	Yield
In acetonitrile equimol., a soln. of salt added to a soln. of S compd., stirred overnight at room temp.; solvent evapd., residue washed (cold diethyl ether), dried (vac.); elem.anal.;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: C21H24N3Pd(1+)*ClO4(1-)

: 603-35-0
triphenylphosphine

: C39H39N3PPd(1+)*ClO4(1-)

Conditions

Conditions	Yield
Stage #1: C21H24N3Pd(1+)*ClO4(1-); triphenylphosphine In dichloromethane for 0.166667h; Inert atmosphere; Schlenk technique; Stage #2: sodium perchlorate monohydrate In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: C12H15ClN2Pd

: 603-35-0
triphenylphosphine

: C30H30N2PPd(1+)*ClO4(1-)

Conditions

Conditions	Yield
In methanol; dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 76358-92-4
2-<(phenylseleno)methyl>pyridine

: Pd(II)(η3-C3H5)(C5H4NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	97.6%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 12288-41-4
bis(μ-chloro)bis{(1,2,3-η)-3-methyl-2-butenyl}palladium

: 2-(phenyl-thiomethyl)-6-methyl-pyridine

: 404361-92-8
Pd(II)(η1,1-dimethyl-C3H3)(C5H3CH3NCH2SC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	97.3%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 81033-01-4
[Au(C6H4N2C6H5)Cl2]

: [Au(C6H4N2C6H5)(C5H5N)2](2+)*2ClO4(1-)=[Au(C6H4N2C6H5)(C5H5N)2](ClO4)2

Conditions

Conditions	Yield
With pyridine In acetone byproducts: NaCl; stirring (1 h, room temp.); evapn., extn. (CH2Cl2), filtration, concn., pptn. on Et2O addn., recrystn. (CH2Cl2/Et2O); elem. anal.;	97%

: 7791-07-3
sodium perchlorate monohydrate

: (η3-allyl)(N,N'-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)chloropalladium(II)

: 603-35-0
triphenylphosphine

: [Pd(1,3-dimesityl-2,3-dihydroimidazol-2-ylidene)(allyl)(triphenylphosphine)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of P compd. in CH2Cl2 to soln. of Pd complex in CH2Cl2, addn. of soln. of Na compd. in MeOH; filtration, stirring (30 min), evapn., dissolving in CH2Cl2, treatment with activated charcoal, filtration (Celite), concn. under reduced pressure, addn. of Et2O, filtration, washing with Et2O and n-pentane, drying under vacuum, elem. anal.;	97%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 119072-54-7, 2769-71-3
2,6-dimethylphenyl isonitrile

: 603-35-0
triphenylphosphine

: 1269182-47-9
[Pd(2,6-dimethylphenylisocyanide)(triphenylphosphine)(allyl)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of N compd. in CH2Cl2 to soln. of Pd complex in CH2Cl2, addn. of soln. of PPh3 in CH2Cl2, addn. of Na compd. in MeOH; filtration, stirring (30 min), evapn. under reduced pressure, dissolvingin CH2Cl2, treatment with charcoal, filtration (Celite), concn. under r educed pressure, addn. of Et2O, filtration, washing (Et2O, pentane), drying under vacuum, elem. anal.;	97%

Yield

In methanol; dichloromethane byproducts: NaCl; addn. of soln. of N compd. in CH2Cl2 to soln. of Pd complex in CH2Cl2, addn. of soln. of PPh3 in CH2Cl2, addn. of Na compd. in MeOH; filtration, stirring (30 min), evapn. under reduced pressure, dissolvingin CH2Cl2, treatment with charcoal, filtration (Celite), concn. under r educed pressure, addn. of Et2O, filtration, washing (Et2O, pentane), drying under vacuum, elem. anal.;

97%

...Expand

: 301668-92-8
N,N-bis(-pyridin-2ylmethyl)benzenamine

: 21264-30-2, 90243-59-7, 14592-56-4
dichloro bis(acetonitrile) palladium(II)

: 7791-07-3
sodium perchlorate monohydrate

: 1616255-21-0
N,N-di(2-picolyl)aniline(chloro)PdII perchlorate

Conditions

Conditions	Yield
In ethanol at 20℃; for 12h;	96.8%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: PdCl2(P(C6H5)3)(C4H4N2)

: PdCl(P(C6H5)3)2(C4H4N2)(1+)*ClO4(1-)=(PdCl(P(C6H5)3)2(C4H4N2))(ClO4)

Conditions

Conditions	Yield
With P(C6H5)3 In methanol; dichloromethane Pd complex treated with PPh3; NaClO4*H2O added to the soln.; stirring for 10 min; evapn.; extn. with CH2Cl2 and charcoal; filtration; concn.; addn. of Et2O; elem. anal.;	96.3%

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 404361-88-2
2-(phenyl-selenomethyl)-6-methyl-pyridine

Pd(II)(η3-C3H5)(C5H3CH3NCH2SeC6H5) perchlorate: Pd(II)(η3-C3H5)(C5H3CH3NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	96.2%

...Expand

: 7601-90-3
perchloric acid

: 7732-18-5
water

: 144-55-8
sodium hydrogencarbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In perchloric acid by a react. of HClO4 with NaHCO3; evapn. to incipient crystn.;

...Expand

: sodium perchlorate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In water crystn. below 52.75°C;
In water crystn. below 52.75°C;

: 7601-90-3
perchloric acid

: 497-19-8
sodium carbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice;
In perchloric acid dissoln. of carbonate in HClO4 (72 %), repeated recrystn. (H2O);
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.;
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice;
In not given neutralization, concg. to satn. concn., hot filtration, cooling the filtrate at stirring; recrystn. from water twice, washing by dry ether, drying in vac. for 10 h at ambient temp.;

: 497-19-8
sodium carbonate

: 7791-07-3
sodium perchlorate monohydrate

Conditions

Conditions	Yield
With aq. HClO4 dry box.;

: 7791-07-3
sodium perchlorate monohydrate

: 88035-85-2
{(NH3)5IrOCHN(CH3)2}(3+)*3ClO4(1-)={(NH3)5IrOCHN(CH3)2}(ClO4)3

: 15646-83-0
{(NH3)5IrOOCH}(2+)*2ClO4(1-)={(NH3)5IrOOCH}(ClO4)2

Conditions

Conditions	Yield
With sodium hydroxide In water Kinetics; stirred for 10 min at ambient temp., NaClO4*H2O was added in H2O; cooled, filtered, elem. anal.;	100%

: 7791-07-3
sodium perchlorate monohydrate

: [PdCl(η(3)-CH2C(Me)C(Me)2)]2

: 2-(propane-2-sulfanylmethyl)-pyridine

: 460720-55-2
[Pd(η3-1,1,2-Me3C3H2)(2-isopropylthiomethylpyridine)](ClO4)

Conditions

Conditions	Yield
In methanol; dichloromethane stirred at room temp. under N2 for 1 h; evapd. in vacuo, residue dissolved in CH2Cl2, treated with activated charcoal, filtered through celite, filtrate was concd., treated with Et2O, ppt. was collected; elem. anal.;	99%

...Expand

: 553-26-4
4,4'-bipyridine

: 7791-07-3
sodium perchlorate monohydrate

: 563-63-3
silver(I) acetate

: Ag(4,4'-bipyridine)(perchlorate)

Conditions

Conditions	Yield
In water at 20℃; for 2h; Sealed tube;	99%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: cis-{Pt(P(CH3)3)2(μ-OH)}2(NO3)2

: di(cis-[bis(trimethylphosphane)(μ-hydroxo)platinum(II)]) nitrate

Conditions

Conditions	Yield
In not given to Pt-salt NaClO4*H2O added; filtered, washed (H2O), dried in vac., elem. anal.;	98%

: 7791-07-3
sodium perchlorate monohydrate

: tetrakis(acetonitrile)palladium(II) tetrafluoroborate

: C4H3SC4H2SCHNCH2CH((OC2H4OC2H4)2O)CH2

: 75-05-8
acetonitrile

: Pd(2+)*2CH3CN*2BF4(1-)*Na(1+)*ClO4(1-)*C4H3SC4H2SCHNCH2CH((OC2H4OC2H4)2O)CH2=Pd(CH3CN)2(C20H27NO5S2)(BF4)2NaClO4

Conditions

Conditions	Yield
In acetonitrile equimol., a soln. of salt added to a soln. of S compd., stirred overnight at room temp.; solvent evapd., residue washed (cold diethyl ether), dried (vac.); elem.anal.;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: C21H24N3Pd(1+)*ClO4(1-)

: 603-35-0
triphenylphosphine

: C39H39N3PPd(1+)*ClO4(1-)

Conditions

Conditions	Yield
Stage #1: C21H24N3Pd(1+)*ClO4(1-); triphenylphosphine In dichloromethane for 0.166667h; Inert atmosphere; Schlenk technique; Stage #2: sodium perchlorate monohydrate In dichloromethane at 20℃; for 1h; Inert atmosphere; Schlenk technique;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: C12H15ClN2Pd

: 603-35-0
triphenylphosphine

: C30H30N2PPd(1+)*ClO4(1-)

Conditions

Conditions	Yield
In methanol; dichloromethane at 20℃; for 0.5h; Inert atmosphere; Schlenk technique;	98%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 76358-92-4
2-<(phenylseleno)methyl>pyridine

: Pd(II)(η3-C3H5)(C5H4NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	97.6%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 12288-41-4
bis(μ-chloro)bis{(1,2,3-η)-3-methyl-2-butenyl}palladium

: 2-(phenyl-thiomethyl)-6-methyl-pyridine

: 404361-92-8
Pd(II)(η1,1-dimethyl-C3H3)(C5H3CH3NCH2SC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	97.3%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 81033-01-4
[Au(C6H4N2C6H5)Cl2]

: [Au(C6H4N2C6H5)(C5H5N)2](2+)*2ClO4(1-)=[Au(C6H4N2C6H5)(C5H5N)2](ClO4)2

Conditions

Conditions	Yield
With pyridine In acetone byproducts: NaCl; stirring (1 h, room temp.); evapn., extn. (CH2Cl2), filtration, concn., pptn. on Et2O addn., recrystn. (CH2Cl2/Et2O); elem. anal.;	97%

: 7791-07-3
sodium perchlorate monohydrate

: (η3-allyl)(N,N'-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene)chloropalladium(II)

: 603-35-0
triphenylphosphine

: [Pd(1,3-dimesityl-2,3-dihydroimidazol-2-ylidene)(allyl)(triphenylphosphine)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of P compd. in CH2Cl2 to soln. of Pd complex in CH2Cl2, addn. of soln. of Na compd. in MeOH; filtration, stirring (30 min), evapn., dissolving in CH2Cl2, treatment with activated charcoal, filtration (Celite), concn. under reduced pressure, addn. of Et2O, filtration, washing with Et2O and n-pentane, drying under vacuum, elem. anal.;	97%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 119072-54-7, 2769-71-3
2,6-dimethylphenyl isonitrile

: 603-35-0
triphenylphosphine

: 1269182-47-9
[Pd(2,6-dimethylphenylisocyanide)(triphenylphosphine)(allyl)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of N compd. in CH2Cl2 to soln. of Pd complex in CH2Cl2, addn. of soln. of PPh3 in CH2Cl2, addn. of Na compd. in MeOH; filtration, stirring (30 min), evapn. under reduced pressure, dissolvingin CH2Cl2, treatment with charcoal, filtration (Celite), concn. under r educed pressure, addn. of Et2O, filtration, washing (Et2O, pentane), drying under vacuum, elem. anal.;	97%

Yield

97%

...Expand

: 301668-92-8
N,N-bis(-pyridin-2ylmethyl)benzenamine

: 21264-30-2, 90243-59-7, 14592-56-4
dichloro bis(acetonitrile) palladium(II)

: 7791-07-3
sodium perchlorate monohydrate

: 1616255-21-0
N,N-di(2-picolyl)aniline(chloro)PdII perchlorate

Conditions

Conditions	Yield
In ethanol at 20℃; for 12h;	96.8%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: PdCl2(P(C6H5)3)(C4H4N2)

: PdCl(P(C6H5)3)2(C4H4N2)(1+)*ClO4(1-)=(PdCl(P(C6H5)3)2(C4H4N2))(ClO4)

Conditions

Conditions	Yield
With P(C6H5)3 In methanol; dichloromethane Pd complex treated with PPh3; NaClO4*H2O added to the soln.; stirring for 10 min; evapn.; extn. with CH2Cl2 and charcoal; filtration; concn.; addn. of Et2O; elem. anal.;	96.3%

: 7791-07-3
sodium perchlorate monohydrate

: bis(η3-allyl-μ-chloropalladium(II))

: 404361-88-2
2-(phenyl-selenomethyl)-6-methyl-pyridine

: Pd(II)(η3-C3H5)(C5H3CH3NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	96.2%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

: 404361-88-2
2-(phenyl-selenomethyl)-6-methyl-pyridine

: Pd(II)(η3-1-phenyl-C3H4)(C5H3CH3NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	96%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 4097-89-6
2,2',2''-triaminotriethylamine

: 25224-72-0
1,4-dimethoxybenzene-2,6-dicarboxaldehyde

: silver nitrate

: Ag2(C42H54N8O6)(2+)*2ClO4(1-)*4H2O = [Ag2(C42H54N8O6)](ClO4)2*4H2O

Conditions

Conditions	Yield
In ethanol addn. of the amine in EtOH to the dialdehyde and AgNO3 in EtOH, stirring, filtration, addn. of excess NaClO4*H2O in EtOH; elem. anal.;	96%

...Expand

: 110-86-1
pyridine

: 7791-07-3
sodium perchlorate monohydrate

: [Pt(phpytabn)Cl]

: C25H20N5Pt(1+)*ClO4(1-)

Conditions

Conditions	Yield
Stage #1: pyridine; [Pt(phpytabn)Cl] In methanol; acetonitrile at 60℃; for 0.75h; Stage #2: sodium perchlorate monohydrate at 20℃; for 0.5h;	96%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: PdCl2(P(C6H5)3)(C4H4N2)

: PdCl(P(C6H5)3)2(C4H4N2)(1+)*ClO4(1-)=(PdCl(P(C6H5)3)2(C4H4N2))(ClO4)

Conditions

Conditions	Yield
With P(C6H5)3 In methanol; dichloromethane Pd complex treated with PPh3; NaClO4*H2O added to the soln.; stirring for 10 min; evapn.; extn. with CH2Cl2 and charcoal; filtration; concn.; addn. of Et2O; elem. anal.;	95.7%

: 7791-07-3
sodium perchlorate monohydrate

: 71897-63-7
2-[(phenylsulfanyl)methyl]pyridine

: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

: 404361-94-0
Pd(II)(η3-1-phenyl-C3H4)(C5H3CH3NCH2SC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	95.3%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: (ClPd(P(C6H5)3)2C5H3ClN)

: 77-78-1
dimethyl sulfate

: 92391-83-8
PdCl(P(C6H5)3)2C5H3NCH3Cl(1+)*ClO4(1-)=(PdCl(P(C6H5)3)2C5H3NCH3Cl)ClO4

Conditions

Conditions	Yield
In dichloromethane reflux for 4 h, standing overnight at room temp., concn., pptn. with Et2O, dissoln. in CH2Cl2, addn. of NaClO4*H2O in MeOH; stirring for 10 min;; evapn., extn. with CH2Cl2 and charcoal, filtn., concn. and pptn. with Et2O, elem. anal.;;	95%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 97465-54-8
bis(1,4,7-trithiacyclononane)cobalt(II) bisperchlorate

: 102573-49-9
[Co(1,4,7-trithiacyclononane)2](ClO4)3

Conditions

Conditions	Yield
With Na2S2O8 In water a soln. of Na2S2O8 added to a soln. of Co-complex; NaClO4*H2O added; pptd.; filtered; washed with ethanol and water; air-dried; elem. anal.;	95%

: 7791-07-3
sodium perchlorate monohydrate

: Pd2(C6H4)(O2CCH3)((CH3C5H3N)2)2(1+)*CH3CO2(1-)*3H2O={Pd2(C6H4)(O2CCH3)((CH3C5H3N)2)2}CH3COO*3H2O

: Pd2(C6H4)(O2CCH3)((CH3C5H3N)2)2(1+)*ClO4(1-)={Pd2(C6H4)(O2CCH3)((CH3C5H3N)2)2}ClO4

Conditions

Conditions	Yield
In methanol addn. of methanolic soln. of NaClO4 to methanolic soln. of Pd compd., stirred for 12 h at ambient temp.; evapn., extn. (CH2Cl2), concn., diln. (hexane); elem. anal.;	95%

: 7791-07-3
sodium perchlorate monohydrate

: bis[chloro(1,2,3-trihapto-allylbenzene)palladium(II)]

: 2-(phenyl-thiomethyl)-6-methyl-pyridine

: 404361-90-6
Pd(II)(η1-phenyl-C3H4)(C5H4NCH2SC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	95%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: [Pd(1,3-dimesityl-2,3-dihydroimidazol-2-ylidene)(1,1-dimethylallyl)(chloride)]

: 119072-54-7, 2769-71-3
2,6-dimethylphenyl isonitrile

: [Pd(1,3-dimesityl-2,3-dihydroimidazol-2-ylidene)(1,1-dimethylallyl)(2,6-dimethylisocyanide)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of CNC6H3Me2 in CH2Cl2 to Pd complex in CH2Cl2, addn. of soln. of Na compd. in MeOH; filtration, stirring for 30 min, evapn. under reduced pressure, dissolving in CH2Cl2, treatment with activated charcoal, filtration (Celite), concn., pptn. by addn. of Et2O, filtration, washing (Et2O, pentane), drying under vacuum, elem. anal.;	95%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: [Pd(1,3-dimesitylimidazolidin-2-ylidene)(1,1-dimethylallyl)(chloride)]

: 119072-54-7, 2769-71-3
2,6-dimethylphenyl isonitrile

: [Pd(1,3-dimesitylimidazolidin-2-ylidene)(1,1-dimethylallyl)(2,6-dimethylphenylisocyanide)]ClO4

Conditions

Conditions	Yield
In methanol; dichloromethane byproducts: NaCl; addn. of soln. of CNC6H3Me2 in CH2Cl2 to Pd complex in CH2Cl2, addn. of soln. of Na compd. in MeOH; filtration, stirring for 30 min, evapn. under reduced pressure, dissolving in CH2Cl2, treatment with activated charcoal, filtration (Celite), concn., pptn. by addn. of Et2O, filtration, washing (Et2O, pentane), drying under vacuum, elem. anal.;	95%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: (2-methylallyl)palladium-chloride dimer

: ([1-(phenylthio)methylene-3-mesityl]imidazolyl-2-ene)silverbromide

: C23H27N2PdS(1+)*ClO4(1-)

Conditions

Conditions	Yield
Stage #1: (2-methylallyl)palladium-chloride dimer; ([1-(phenylthio)methylene-3-mesityl]imidazolyl-2-ene)silverbromide In dichloromethane at 20℃; Inert atmosphere; Stage #2: sodium perchlorate monohydrate In methanol; dichloromethane Inert atmosphere;	95%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: 12288-41-4
bis(μ-chloro)bis{(1,2,3-η)-3-methyl-2-butenyl}palladium

: 76358-92-4
2-<(phenylseleno)methyl>pyridine

: Pd(II)(η3-C3H3(CH3)2)(C5H4NCH2SeC6H5) perchlorate

Conditions

Conditions	Yield
In dichloromethane mixed, stirred for 30 min; concd.(vac.), treated with activated charcoal in CH2Cl2, filtered, conctd., pptd.(diethyl ether), elem. anal., IR, NMR;	94.7%

...Expand

: 7791-07-3
sodium perchlorate monohydrate

: PdCl(1,2-bis(diphenylphosphino)ethane)(C5H4N-C(2))

: 78-95-5
chloroacetone

: 141239-38-5
cis-{PdCl((1-CH2COMe)C5H4N-C2)(dppe)}ClO4

Conditions

Conditions	Yield
In acetone Kinetics; reaction with excess chloride; stirred for 24 h at ambient temp.; addn. of perchlorate;; evapn.; extn. (CH2Cl2, charcoal); filtration; concn.; pptn. by addn. of Et2O; repptn. from CH2Cl2/Et2O; elem. anal.;	94.4%

...Expand

: 21264-30-2, 90243-59-7, 14592-56-4
dichloro bis(acetonitrile) palladium(II)

: 7791-07-3
sodium perchlorate monohydrate

: 26082-96-2
N,N-di(2-picolyl)benzylamine

: 1616255-18-5
N,N-di(2-picolyl)benzylamine(chloro)PdII perchlorate

Conditions

Conditions	Yield
In ethanol at 20℃; for 12h;	94.2%

...Expand

Sodium perchlorate monohydrate Standards and Recommendations

DOT Classification: 5.1; Label: Oxidizer

Sodium perchlorate monohydrate Specification

The Sodium perchlorate monohydrate, also known as CCRIS 8893, is an inorganic substance with the formula NaClO₄•H₂O. It belongs to the product categories of Oxidation; Perchlorates Metal and Ceramic Science; Salts; Sodium Salts; Synthetic Reagents; ACS Grade Synthetic Reagents; Essential Chemicals; Perchlorates; Routine Reagents; HPLC; HPLC Buffer; HPLC Buffer - SolidChromatography/CE Reagents; HPLC Buffers; Solid. Its EINECS registry number is 231-511-9. With the CAS registry number 7791-07-3, its IUPAC name is sodium perchlorate hydrate. Sodium perchlorate monohydrate is used for the manufacture of perchlorate and other perchlorate, and also for the gunpowder industry.

Physical properties of Sodium perchlorate monohydrate: (1)H-Bond Donor: 1; (2)H-Bond Acceptor: 5; (3)Rotatable Bond Count: 0; (4)Exact Mass: 139.948846; (5)MonoIsotopic Mass: 139.948846; (6)Topological Polar Surface Area: 75.3; (7)Heavy Atom Count: 7; (8)Formal Charge: 0; (9)Complexity: 118; (10)Isotope Atom Count: 0; (11)Defined Atom StereoCenter Count: 0; (12)Undefined Atom StereoCenter Count: 0; (13)Defined Bond StereoCenter Count: 0; (14)Undefined Bond StereoCenter Count: 0; (15)Covalently-Bonded Unit Count: 3.

Preparation of Sodium perchlorate monohydrate: this chemical can be prepared by Na₂CO₃ and HClO₄. Then the anhydrous sodium perchlorate was crystallized out. It can gradually absorb moisture in the air. At last, you will get Sodium perchlorate monohydrate.

When you are using this chemical, please be cautious about it as the following:
This chemical may cause inflammation to the skin or other mucous membranes. It is irritating to eyes, respiratory system and skin. In case of contact with eyes, you should rinse immediately with plenty of water and seek medical advice. Whenever you will contact it, please wear suitable protective clothing, gloves and eye/face protection.

You can still convert the following datas into molecular structure:
(1)Canonical SMILES: O.[O-]Cl(=O)(=O)=O.[Na+]
(2)InChI: InChI=1S/ClHO4.Na.H2O/c2-1(3,4)5;;/h(H,2,3,4,5);;1H2/q;+1;/p-1
(3)InChIKey: IXGNPUSUVRTQGW-UHFFFAOYSA-M

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
mouse	LD50	intraperitoneal	1150mg/kg (1150mg/kg)		Journal of Agricultural and Food Chemistry. Vol. 14, Pg. 512, 1966.

Product Name

SODIUM PERCHLORATE MONOHYDRATE

Synthetic route

Sodium perchlorate monohydrate Standards and Recommendations

Sodium perchlorate monohydrate Specification

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